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RDPUCPA District level Preparatory


Examination, January 2015

tr

il P.U.C.

CHEMISTRY

Max. Marks :70

Time : 3% Hours

Mention the unit for rate of reaction.


State Hardy-Schulze rule.
Write the composition of copper matte?
How Xe Pt Fuis prepared?
What are
Complete the following

freons?

reaction.

CH,

CH,OH Conc' HrSOo,

'

acid?

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10. Give an example for acidic amino

PART-B
Answer any five of the following questions. Each question carries
two marks

.p
ed

II'

ib

4:
5.
6.
7.
8.
9.

11. Acon

c,o,iffi

L0x1:10

lo

g.

PART.A
Answer all the following questions. Each question carries one mark each.
1. Give an example for solid-solid solution
2. What is the effect of increase in temperature on the solubility of gas in liquid?

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I.

Use 1og tables and simple calculator it necessary.

3)

co

General Instructions :
1) The question paper has four parts A, B, c and D. All questions are compulsory.
2) Write balanced chemical equations and labeled diagrams where required.

each. 5 x 2: l0

Htlf;,:mr'jl"Ti:iff ;H::'"?,rl::11ffi ;,iJt?r#ffixi,?1il_$$l*

swart's reaction with example. 16. How carboxylic acids


are prepared from nitriles?
18. What areianalgesics. Give an example ?
PART-C
Answer any five of the following questions. Each question
carries three marks.
5x3:15
19' With reference to the extraction of aluminium Uy uatt-Heroult
process.
i) Draw labelled diagram. b) Write the reaction taking place
at cathode andAnode.
20. Explain how nitric acid is manufactured by ostrvalds process?
21. Complete the following reactions.

,:t-,
3113* saponification with
l7' Explain
example.

-_)

L2. Write the reactions which takes plpce at cathode and anode in a dry cell?
13. Define second order reaction. Give an example
14. Give rea$on.
i) Cerium exhibits +4 oxidation state ii)Actinoid contaction is more
then lanthanoid contraction

rrr'

1l

2Kclo,

22. Write

Mno,,

ii) H,S + cl,-+

iii) 30,

electric discharge

the equation for


i) the action of chlorine with excess ammonia.
ii) oxidation of ferrous sulphate to ferric sulphate by acidified
chlorine.
iii) Laboratory preparation of hydrogen chloride.

23. Explain how potassium dichromate is manufactured from


chromite ore.
24. With reference to first row transition series.

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P.T.O.

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,,7 ..

Mn,* is pink give reason.

25' Using vBT account for Geometry


26. i) Write cis and hans isomers of
ii) Give

and magnetic property

co

Se3. is colourless and

of [co (NHr)u],*

[Coclr(en)J.

an example for didentate ligand.

g.

iii)

i) Write general electronic configuration.


ii) Formation of coloured ions.

PARGD

IV Answer any three of the following questions. Each question


carries live marks.

29.

of the solute.
b) What are azeotropes. Give an example.
a) calculate the equilibrium constant of the
reaction

ia

of a first order reaction is 30min. calculate the


time required to complet

B0o/o

a) Give any three differences between physisorption


and chemisorption.

i) Tyndatl effect ii) Dialysis.

.p
ed

is

3+2

Answer any four of the following questior:}X'ruestion


corries live marks
32. a) Explain i) wurtz - fitting reaction ii) state

3.H;[l];rt"fations

each. 4 x 5:20

zaitsev rure.

forthe steps in S*2 mechanism of conversion


of methyt chloride into

a) Explain rcimer-Tiemann reactionwith


example.
b) what is w,liamsons ether synthesis
writ" its gerrerar equation.
tvrite equation for i) The reaction between
carboxyric acid and pcr,
L)
ii) The formation of oxime by aldehydes and
hydroxyl amine. iii) clemenson reduction.

33.

3+2

electrode and give its standard

a) Derive an integrated rate equation for


the velocity constant for a first order reaction.

b) What

3+2

at 29gK
Mg (s) + 2Ag.(aq)
i+ Mg.'(aq) + 2 Ag(s). E.."r: + 3.16V.
b) write the symbolic representation of standard
hydrogen

:Iil3lJf,,lf"o
31.

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?lTht boiling point of water becomes 100.52'c when l.5g of a non volatile solute dissolved in
100g of it. Calculate the motar mass

electrode potential.

30'

5x3=15
3+2

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28'

a) calculate the packing efficiency in ccp rauice.b)


Name any two crystal system.

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27

34.

35.

b) Explain aldol condensation with example.


a) Complete the following reaction

i) R-co-NH, + 4 [H]
NH.

LiA1H4>

ii)

3+2

c6HsNH2 + HNo2 +

iii)O+3Brz Br,/HzO, i

H"t o'r,

b) Methyt amine is skonger base than


Ammonia. ci[rgalson.
36. a) i) what is denaturation of protein
ii) Give an example for water soluble vitamin.
iii) How do you confirm glucose cpntain five _OH
group.
I
b) Write the haworth,s structure of cr _ D (+)
glucose.
37. a) Mention the monomers and partial
structure of terylene
b) what is wlcanrisation of rubber. c)
Give an example for biodegradable polymer.
*****x****{<**

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3+2

2+2+1

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