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Paper 1

Time Allotted: 3 Hours

FIITJEE Students From All Programs have bagged 34 in Top 100, 66 in Top 200 and 174 in Top 500 All India Ranks. FIITJEE Performance in JEE (Advanced), 2014:

2521 FIITJEE Students from Classroom / Integrated School Programs & 3579 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2014.

FIITJEE

Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es

s p ec i f i c a ll y f o r t h i s p u r p o s e.

Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f

t h e t es t .

INSTRUCTIONS

A. General Instructions

1.

2.

3.

4.

5.

Attempt ALL the questions. Answers have to be marked on the OMR sheets.

This question paper contains Three Parts.

Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

Each part is further divided into two sections: Section-A & Section-C

Rough spaces are provided for rough work inside the question paper. No additional sheets will be

provided for rough work.

6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic

devices, in any form, are not allowed.

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers

on OMR sheet.

2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your

Enrolment No. and write your Name, Test Centre and other details at the designated places.

3. OMR sheet contains alphabets, numerals & special characters for marking answers.

(i)

Section-A (01 10) contains 10 multiple choice questions which have one or more than one

correct answer. Each question carries +3 marks for correct answer. There is no negative

marking.

(ii) Section-C (01 10) contains 10 Numerical based questions with answers as numerical value

from 0 to 9 and each question carries +3 marks for correct answer. There is no negative

marking.

Enrolment No.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

2

AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

Useful Data

PHYSICS

Acceleration due to gravity

g = 10 m/s2

Planck constant

Charge of electron

e = 1.6 1019 C

Mass of electron

me = 9.1 1031 kg

Density of water

Atmospheric pressure

Pa = 105 N/m2

Gas constant

R = 8.314 J K1 mol1

CHEMISTRY

Gas Constant

Avogadro's Number Na

Plancks constant h

1 Faraday

1 calorie

1 amu

1 eV

=

=

=

=

=

=

=

=

=

=

8.314 J K1 mol1

0.0821 Lit atm K1 mol1

1.987 2 Cal K1 mol1

6.023 1023

6.625 1034 Js

6.625 1027 ergs

96500 coulomb

4.2 joule

1.66 1027 kg

1.6 1019 J

Atomic No:

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,

Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,

Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,

Br=35,

Ag=47, Sn=50, I=53, Xe=54, Ba=56,

Pb=82, U=92.

Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,

F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,

Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,

Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,

Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

3

AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

Physics

PART I

SECTION A

(One or More than One Options Correct Type)

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C)

and (D) out of which ONE or MORE THAN ONE are correct.

1.

Initially two particles A and B are present at (0, 0) and (d, 0) respectively. They start

moving with speed v A vi vj and v B vj . If R is magnitude of relative separation

between them and T0 be the time when separation between them is minimum, then

(A) T0

d

5v

(B) R min

2d

5

2.

(A) all of them are in the same plane

(B) they are opposite to each other in pair

(C) the sum of x, y and z components of force is zero separately

(D) they form a closed figure of 4 sides

3.

(A) impulse on the man by ground will be 539 N-s

(B) average force on man if he land with stiffed leg and body moves by 1.0 cm during

5

impact is 2.1 10 N

(C) average force on man feet by ground if he land with bent legs and body moves by

50 cm is 4.2 103 N

(D) average force on man feet by ground if he land with bent legs and body moves by

3

50 cm is (4.9 10 N)

4.

A mass m of radius r is rolling horizontally without any slip with a linear speed v. It then

rolls up to a height given by

3 v2

4 g

(B) the body is a solid sphere

(C) MOI of the body about instantaneous axis of rotation is

3

mr 2

2

2 2

mr

5

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942

website: www.fiitjee.com

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AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

5.

gravitational field. In the process following physical quantities associated with the particle

are measured

U change in gravitational potential energy

K change in kinetic energy

W1 work done by the force F

(A) W2 U

(C) K U W1 W2

(B) K W1 W2

(D) W1 W2

6.

Choose the correct option(s)

(A) Buoyant force increases as lift accelerates up

(B) Buoyant force decreases as lift accelerates up

(C) Buoyant force remains constant as lift accelerates

(D) The fraction of solid submerged into liquid does not change

7.

constant angular velocity 40 rad/s. Frequency of the source is

300 Hz. A detector is kept at some distance from the circle in the

same plane of the circle (as shown in figure). Which of the

following is not the possible value of frequency registered by the

detector? (Speed of sound = 320 m/s)

(A) 250 Hz

(B) 360 Hz

(C) 410 Hz

(D) 220 Hz

8.

S

D

Two gases have same initial pressure, volume and temperature. They expand to same

final volume, one adiabatically and the other isothermally.

(A) the final temperature is greater for isothermal process

(B) the final temperature is lesser for isothermal process

(C) the work done by the gas is greater for isothermal process

(D) the work done by the gas is greater for adiabatic process

Space for Rough work

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5

AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

9.

radius R(<d), then in static condition at the centre of sphere

kq

d2

kq

(B) magnitude of electric field due to induced charge is 2

R

(A) magnitude of electric field due to induced charge is

(D) magnitude of electric field due to charge q is

10.

kq

d2

mass 1 kg are placed on a horizontal

smooth table. The velocity give to

middle ball parallel to the surface is 9

m/s. Then:

(where k = 1/40)

9m / s

1m

1m

(B) the speed of any of the balls when they collide is 9 m/s

(C) the tension in the string connected between balls just before the two balls collide is 5

newton

(D) the tension in the string connected between balls just before the two balls collide is 9

newton

Space for Rough work

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6

AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

SECTION C

(One Integer Value Correct Type)

This section contains 10 questions. Each question, when worked out will result in one integer

from 0 to 9 (both inclusive).

1.

When the ball reaches the diametrically opposite point. The position

of point A in shown by point 1, 2, 3 and 4. Find the correct position

of point A:

3

4

1

A

2.

subtends an angle of 15 at a point P which is also the

centre of curvature of a circular arc having same linear

charge density as shown in figure. If the net electric field

bK

at the origin is

. Find the value of b:

R

3.

P

R

I0

v0

is initially

current carrying wire as shown in figure. The maximum

distance from the wire the charge will go, if it is given

X0

b v0

velocity v0 perpendicular to the wire is X 0e

. Find

0 I 0

the value of b:

4.

points with wires. The resistance of each side and the

connecting wires is R. An ideal battery of emf E is joined as

shown in figure. Find the current passing through the battery.

Consider the wire connected with the cell is ideal. [take

E 11 Volt ; R 6 ohm ]

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AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

5.

boundary width of 30 cm and other medium having

refractive index 2 is having boundary width 20 cm as

shown in figure. The position of image of object O as

seen from air through the curved part is 10k. Find the

value of k.

6.

If the change in heat content of the gas in this process

is

Air

K

PV

0 0 . Then find the value of K:

2

4/3

15cm

20cm

P

2P0

18cm

1

2

P0

V0

7.

Air

2V0

A source of sound of frequency 1000 Hz is moving towards a stationary wall with velocity

30 m/s and observer is also moving behind the source with the same velocity. If the

2

frequency band width detected by the observer is K 10 . There find the value of

8.

k:

is accelerated

10 m / s in a gravity free

space. A small sphere of density 2 is released from rest

horizontally with acceleration

sphere with respect to the vessel:

9.

X L 50 2ohm

X C 50 2ohm

voltage is 100 volts. Then find the current passing through the

source.

100volts

10.

Out of the three conducting identical plates, middle flat is given charge

3 C and other two plates are not having any charge. If switch S is

closed. Find the charge passing through switch S. (in

3 C

C ):

d

S

2d

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AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

Chemistry

PART II

SECTION A

(One or More than One Options Correct Type)

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C)

and (D) out of which ONE or MORE THAN ONE are correct.

1.

2.

(A) Phthalic acid

(C) Benzoic acid

(D) Terephthalic acid

A

B

(C) A and B are isodiaphers

(D) A and C are isotones

3.

(A) Kinetic energy of gas molecules remain same

(B) Kinetic energy of gaseous molecule decreases

(C) Pressure of gas decrease

(D) Kinetic energy of gaseous molecule increases

4.

5.3% (w/v) Na2CO3 solution and 6.3%(w/v) H2C2O4.2H2O solution have same:

(A) Molality

(B) Molarity

(C) Normality

(D) Mole fraction

5.

Given that

o

o

ENi

0.25V, ECu

0.34V

2

2

/Ni

/Cu

EoAg / Ag 0.80V, EoZn2 / Zn 0.76 V

Which of the following redox process will not take place in specified direction?

(A) Ni2 aq Cu s Ni s Cu2 aq

(B) Cu s 2Ag aq Cu2 aq 2Ag s

(C) Cu s 2H aq Cu2 aq H2 g

(D) Zn s 2H aq Zn2 aq H2 g

Space for Rough work

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9

AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

6.

H /

OH OH

The product A is

(A)

(B)

O

O

(C)

(D)

O

i CH MgBr

H SO /

HBO

3

2

4

CH3 CHO

A

B

C

ii H O

7.

(A) Identical

(C) Functional isomer

(D) Optical isomers

8.

(A) C6H6

(B) O C C C O

(C) CH2 C CH2

(D) CH2 CH CH CH2

9.

(A) Bond length of NO NO

(B) Bond order of NO NO

(C) Bond energy of NO NO

(D) NO is paramagnetic but NO is diamagnetic

10.

CrCl6 3

(A) Magnetic moment

(B) EAN of central metal

(C) Magnitude of splitting energy

(D) Colour

(I)

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SECTION C

Integer Answer Type

This section contains 10 questions. Each question, when worked out will result in one integer

from 0 to 9 (both inclusive).

1.

For the complex compound Pt NH3 NO2 Py ONO , total number of geometrical

isomers will be:

2.

Find the total number of acidic radicals which produce volatile product with dilute HCl:

SO24 ,I ,NO2 ,NO3 ,SO32 ,HCO3

3.

4.

i HNO conc.

X,

ii Cl /FeCl

2

5.

N

H

, N

, graphite, diamond.

N

6.

7.

Total number of electron in phosphorus which have zero value of at least one quantum

number.

8.

The pressure necessary to obtain 50% dissociation of PCl 5 at 400 K is numerically equal

to .times of Kp.

9.

10.

Space for Rough work

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AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

Mathematics

PART III

SECTION A

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C)

and (D) out of which ONE or MORE THAN ONE are correct.

1.

If x1, x2, x3, x4 are four positive real numbers such that

1

1

1

1

x1

4, x 2

1, x 3

4 and x 4

1 , then

x2

x3

x4

x1

(A) x1 = x3

(B) x2 = x4

(C) x1x2 = 1

(D) x3x4 = 1

2.

If the normals at (xi, yi) i = 1, 2, 3, 4 to the rectangular hyperbola xy = 2 meet at the point

(3, 4), then

(A) x1 + x2 + x3 + x4 = 3

(B) y1 + y2 + y3 + y4 = 4

(C) x1x2x3x4 = 4

(D) y1y2y3y4 = 4

3.

In a triangle ABC with sides a, b and c, a semicircle touching the sides AC and CB is

inscribed whose diameter lies on AB, then the radius of the semicircle is

a

2abc

A

B

C

(A)

(B)

sin sin sin

s a b

2

2

2

2

(C)

4.

2

ab

(D)

2abc

A

B

C

cos cos cos

s a b

2

2

2

An urn contains fair tickets with numbers 112, 121, 211, 222 and one ticket is drawn. Let

Ai (i = 1, 2, 3) be the event that the ith digit of the number of ticket drawn is 1 then

1

(A) P(A1) = P(A2) = P(A3) =

(B) P(A1 A2) = P(A1) P(A2)

2

(C) A1, A 2, A3 are pair wise independent events (D) P(A1 A 2 A3) P(A1) p(A2) P(A3)

Space for rough work

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5.

z4

is purely

z 2i

imaginary. If the complex number z1 represents the mid-point of chord OA of this curve,

O being the origin, then z 1 necessarily satisfies

z 2

z1

(A) 1

ik , k R {0}

(B)

ik , k R {0}

z1 i

z1 2 i

Suppose that the complex number z lies on the curve such that

(C)

z1 2

k , k R {0}

2z1 i

6.

(D) z1

cos x ln x 1 x 2 dx

3

, then can be

2

(A) 1

(C) 3

7.

8.

(B) 2

(D) 4

max. f t ; 0 t x ; 0 x 1

3

2

Let f(x) = x x + x + 1 and g x

then

; 1 x 2

3 x

(A) g(x) is discontinuous at x = 1

(B) g(x) is continuous at x = 1

(C) g(x) is differentiable at x = 1

(D) g(x) is non-differentiable at x = 1

Which of the following set of values of x satisfies the equation

2

2 sin

22 2 sin

x 3 sin x 1

(A) x n

x 3 sin x

,nI

6

,nI

3

(D) x 2n , n I

2

(B) x n

(C) x = n, n I

9.

5

2

Consider all the strings of n-digits which can be formed using the numbers from the set

{0, 1, 2, 3} (may be starting with zero also). If En denotes the number of strings containing

even number of zeros and On denotes the strings containing odd number of zeros then

4n 2n

n

(A) En + On = 4

(B) En

2

n

n

4 2

(C) O n

(D) En = On

2

Space for rough work

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10.

dy

The solution of x 2 y 3 xy 1 is

dx

2

1

(A) 2 y 2 c e y /2

x

2

(C) 1 y 2 e y /2

x

2

1

2 y 2 c e y /2

x

2

1 2x

(D)

y 2 c e y /2

x

(B)

SECTION C

(One Integer Value Correct Type)

This section contains 10 questions. Each question, when worked out will result in one integer

from 0 to 9 (both inclusive)

1.

Three circles lie on a plane so that each of them externally touches the other two. Two of

them has radius 3, the third having radius unity. If A, B and C are the points of tangency

a b

of those circles and the area of the triangle ABC is

then value of c a b is, where

c

a, b and c are positive integers _____

2.

where a, b, c {1, 2, 3, .., 10} is 10k, then k is _____

3.

OABC is a tetrahedron in which O is the origin and position vector of points A, B, C are

i 2j 3k , 2i j k and i 3 j 2k respectively. An integral value of for which

4.

3

is _____

2

1 2 1 2x

If f x f

, where x is a real number x 0, x 1, then the value of f(2)

1 x x 1 x

must be _____

Space for rough work

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14

AITS-CRT-I(Paper-1)-PCM-JEE(Advanced)/15

5.

6.

ac

maximum value of 2 is _____

b

7.

If f(x) = (x 1)

100

(x 2)

2(99)

3(98)

(x 3)

.. (x n)

100

, let k

f ' 101

, then

97 is

f 101

50

_____

(a2 b2 c 2 )

8.

d2

of quadrilateral, is k then 6k is equal to _____

9.

The number of integral values of parameter , so that the point (, (1 + 2)1) does not lie

outside the triangle formed by the lines L1 : 15y = x + 1, L2 : 78y = 118 23x and

L3 : y + 2 = 0, is equal to _____

10.

1

sin 3x + 2ax, increases throughout the number line then

3

minimum prime value of a is equal to _____

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