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Phase II

Environmental Site Assessment


Central Services Facility
202 South Thornton Avenue
Madison, Wisconsin
DFD Project No. 09H2L

Prepared for:
Wisconsin Department of Administration
Division of Facilities Development
PO Box 7866
Madison, WI 53707
September 2013

Phase II Environmental Site Assessment


Central Services Facility
202 South Thornton Avenue
Madison, Wisconsin

This report prepared by:

________________________________
Mitchell C. Banach
Environmental Scientist

________________________________
Neil E. Carney, PE
Project Engineer

This report reviewed by:

________________________________
Dennis L. Johnson, PE
Supervisor Environmental Services

5201 E. Terrace Drive, Suite 200


Madison, WI 53718
608.443.1200 Fax: 608.443.1250
www.AyresAssociates.com
Ayres Associates Project No. 19-0291.10
File: v:\env\final\19029110\09h2l - thornton ave phase ii esa.docx

Contents
Page No.
Executive Summary ................................................................................................................... iii
Phase II ESA Scope ..............................................................................................................iv
Findings ................................................................................................................................. v
General Findings ............................................................................................................... v
Introduction ................................................................................................................................ 1
Site Location and Project Numbers ........................................................................................ 2
Project Contacts .................................................................................................................... 3
Drilling and Laboratory Contractors........................................................................................ 3
Site Background ......................................................................................................................... 4
Phase II ESA Scope ................................................................................................................... 5
Fieldwork .................................................................................................................................... 6
Findings ..................................................................................................................................... 8
Soil Texture ........................................................................................................................... 8
Soil Quality .......................................................................................................................... 10
Headspace Screening ..................................................................................................... 10
VOCs .............................................................................................................................. 10
PAHs............................................................................................................................... 10
Metals ............................................................................................................................. 10
PCBs............................................................................................................................... 11
Groundwater Quality ............................................................................................................ 11
PAHs............................................................................................................................... 11
Metals ............................................................................................................................. 11
PCBs............................................................................................................................... 12
Conclusions .............................................................................................................................. 13
Recommendations ................................................................................................................... 14
Standard of Care ................................................................................................................. 14

List of Appendices
Appendix A 2013 Phase I ESA Sanborn Maps
Appendix B Field Procedures
Appendix C Soil Probe Logs and Abandonment Forms
Appendix D Laboratory Analytical Results

List of Figures
Figure 1 Regional Location Map
Figure 2 Sample Location Map
Figure 3 Regulatory Exceedance Map

List of Tables
Table 1A Volatile Organic Compounds (VOCs) in Soil
Table 1B Polycyclic Aromatic Hydrocarbons (PAHs) in Soil
Table 1C Metals in Soil
Table 1D Polychlorinated Biphenyls (PCBs) in Soil
Table 2 Summary of Groundwater Analytical Results

ii

Executive Summary
The State of Wisconsin Department of Administration (DOA), Division of Facilities
Development (DFD) intends to construct the new State Archive Preservation Facility (SAPF)
(DFD Project No. 09H2L) proposed to be located at 202 S. Thornton Avenue in Madison,
Wisconsin. This 5.10 acre property is the current site of the DOA Central Services Facility.
Prior to construction of the new facility, existing site improvements including buildings and
pavements will be removed, and buried utilities will be abandoned. In order to conduct
environmental due diligence efforts in advance of proposed demolition and construction
activities, the DFD retained Ayres Associates to conduct a Phase I and Phase II
Environmental Site Assessment (ESA) of the facility. The Phase I ESA of the property was
completed in June 2013. This report presents the findings of the Phase II ESA.
Review of historical Sanborn fire insurance maps compiled during the Phase I ESA identified
recognized environmental conditions (RECs) primarily related to the historical operation of
electric motor and machine manufacturing companies, including a machine shop, paint shop,
brass foundry, and loading/unloading activities from adjacent railroad spurs. Additional
information sources also indicated the former presence of polychlorinated biphenyls (PCB)
containing transformers, storage tanks, and historical releases. The Phase I ESA identified
several RECs on the property. Descriptions of RECs as stated in the Phase I ESA are
detailed below:

The current presence of a 10,000-gallon underground storage tank (UST) system,


operational since 1988. Although the UST system has been subject to annual
inspection and is compliant with applicable regulations, regular operation of the
system over time is likely to result in releases from spills, overfills and leaks below
detection thresholds (See Figure 2 Area 4).

Foundry slag observed at the ground surface in the west wing of the courtyard, and
its use as fill material to a depth of 2 feet as indicated by soil probe boring logs from
2007. The slag is believed to have originated from a former brass foundry as
identified by historical fire insurance maps, and may contain heavy metals such as
lead (See Figure 2 Area 2).

The former presence of PCB-containing material in the courtyard cistern that was not
investigated for horizontal or vertical extent. Although PCBs were found to be present
in cistern contents, and impacts in the vicinity were investigated in 2007, the
investigation did not include the analysis of PCBs in soil and groundwater
surrounding the cistern. PCBs in cistern contents were present at concentrations that
exceed Residual Contaminant Levels (RCLs) for the protection of groundwater (See
Table 1D, Figure 2 Area 1).

The former presence of oil dipping rooms, as identified on historical fire insurance
maps. The quantity of oil used is presumed to be significant due to the size of the
rooms depicted, and releases may have occurred from the regular operation of these
tanks or leakage over time (See Figure 2 Area 3).

The former presence of scrap sheds along rail lines adjacent to the north and south
property boundaries as identified by historical fire insurance maps. The regular
loading and unloading of the bins may have resulted in contamination from metal
scrap or dust and residual oils from machining (See Figure 2 Areas 5 and 8).

iii

The former presence of three coal bins located throughout the site, as identified by
historical fire insurance maps. Soil impacts from metals such as arsenic may exist
due to the accumulation of coal dust in these areas (See Figure 2 Areas 1, 6, and
7).

The former presence of a paint shop, as identified on historical fire insurance maps.
There is a reasonable likelihood of subsurface impacts from the operational cleaning
of painting equipment using solvents on the site. Although previous investigations
have discovered low concentrations of chlorinated solvents in the groundwater, no
previous investigations have included soil sampling in this area (See Figure 2 Area
9).

The former presence of an oil house, as identified on historical fire insurance maps
(See Figure 2 Area 10).

The former presence of a gasoline house, as identified on historical fire insurance


maps (See Figure 2 Area 11).

The former presence of PCB transformers on the site as revealed by the EDR Radius
Map Report; former transformer locations were also revealed by a 1956 building
survey drawing by Gisholt Machine Company. Releases may have occurred due to
the deterioration of transformers that were on site, estimated to be from 1956 to 2007,
and PCBs were previously detected on the site during a 2007 investigation of the
courtyard, a known transformer location (See Figure 2 Areas 1 and 12).

The former operation of a machine shop on the site from 1895 to 1970, which is
associated with the regular use of various oils and solvents. Although one of the two
former machine shop areas was previously investigated for potential subsurface
impacts, the report contains no data regarding polycyclic aromatic hydrocarbons
(PAHs), which are commonly present in machine oils and lubricants (See Figure 2
Areas 4 and 13).

The former operation of a railway power house, as identified on historical fire


insurance maps. The power house is likely to have utilized significant quantities of
coal or oil, and although one soil sample was indicated to be previously collected in
this area, there is no information in the report describing the sampling rationale,
procedure or laboratory analysis (See Figure 2 Area 14).

Because of these findings, a Phase II ESA was completed to evaluate soil and groundwater
quality on the subject property.

Phase II ESA Scope


To investigate the areas identified in the Phase I ESA, the following scope of services was
conducted:

Retained a drilling contractor and installed 26 soil probes to a maximum depth of 12


feet (ft) below ground surface (bgs). Selected boreholes were converted to temporary
wells for the purpose of collecting groundwater samples.

Collected soil samples at approximately 2-2.5-foot intervals and screened samples for
the presence of organic compounds using a photoionization detector (PID).

iv

Submitted soil and groundwater samples to a Wisconsin certified laboratory for


analysis for select volatile organic compounds (VOCs), PAHs, Resource
Conservation & Recovery Act (RCRA) metals (arsenic, barium, cadmium, chromium,
mercury, silver and selenium) and PCBs.

Analyzed soils with potentially hazardous concentrations of lead by toxicity


characteristic leaching procedure (TCLP) to address potential disposal
considerations.

Prepared soil probe logs and abandonment forms, tables summarizing laboratory
results, and a site map showing probe locations.

Prepared this Phase II ESA report to document field procedures and findings of the
assessment and to present conclusions and recommendations for the site.

Phase II ESA fieldwork was completed on June 13 and 14, 2013. Field procedures, soil
probe logs, analytical results, and findings relative to the soil quality are described in the
main body of this report.

Findings
This Phase II ESA investigated the potential for soil and groundwater contamination
associated with the RECs identified in the June 2013 Phase I ESA. The following paragraphs
provide a general summary of conclusions derived from field observations and laboratory
analytical results for soil and groundwater samples obtained from the site. The discussion is
broken down into the areas identified as RECs during the Phase I ESA, and also includes
locations where geotechnical borings were previously advanced by Badger State Drilling in
April 2013 and Soil Essentials in May 2013 during site design activities.
General Findings
The majority of the site contains a layer of fill material from 0-3 feet below ground surface
(bgs) which demonstrates dark discoloration and contains detectable levels of PAHs and
metals (arsenic, cadmium, and lead) in exceedance of RCLs listed in the United States
Environmental Protection Agency (USEPA) Regional Screening Level Web-Calculator.
Arsenic concentrations were compared to background threshold value (BTV) of 8 parts per
million, which is endorsed by the Wisconsin Department of Natural Resources (WDNR),
based on data provided in a study published by the United States Geological Survey (USGS)
titled Distribution and Variation of Arsenic in Wisconsin Soils, With Data on Other Trace
Elements (February 2013). Groundwater data indicated Wisconsin Administrative Code NR
140 Enforcement Standard (ES) exceedances for metals across the site.

Area 1, Courtyard (Former Cistern, Central Coal Bin; GP-1 through GP-3)
Probes were advanced to 12 feet bgs. Detectable levels of PCBs (below RCLs) were
detected in soils from 5-7 feet bgs. No PCBs were detected in groundwater. Soil data
indicates RCL exceedances from 0-2 feet for various metals. Groundwater data
indicates levels of arsenic, chromium, and lead above Chapter NR 140, Wis. Admin.
Code ESs. Impacted soils are anticipated from 0-3 feet bgs.

Area 2, Former Brass Foundry (West Wing of Courtyard; GP-4 and GP-5)
Probes were advanced to 12 feet bgs. Soil data indicates RCL exceedances from 0-2

feet for various PAHs and metals. Groundwater data indicates levels of arsenic and
lead above ESs. Impacted soils are anticipated from 0-3 feet bgs.

Area 3, Former Oil Dipping Rooms (GP-6) Probe was advanced to 12 feet bgs.
No VOCs were detected in shallow or deep soils. RCL exceedances were detected
from 1-3 feet for PAHs. No RCL exceedances were detected in soils from 5-7 feet
bgs. Impacted soils are anticipated from 0-3 feet bgs.

Area 4, Current Fuel Tank Systems (GP-7 through GP-9) Probes were advanced
to 12 feet bgs. No VOCs were detected and PAHs concentrations are below RCLs. A
release from the current above ground storage tank (AST) or UST is not indicated
based upon available data.

Area 5, Former North Scrap Shed (GP-10) Probe was advanced to 4 feet bgs.
Soil data indicates RCL exceedances from 1-3 feet bgs for PAHs. No metals
concentrations were indicated to exceed RCLs. Impacted soils are anticipated from 03 feet bgs.

Area 6 Former West Coal Bin (GP-11) Probe was advanced to 4 feet bgs. Soil
data indicates RCL exceedances from 1-3 feet bgs for PAHs. Metals concentrations
in soil were found to exceed RCLs for protection of groundwater. Impacted soils are
anticipated from 0-4 feet bgs.

Area 7 Former East Coal Bin (GP-12) Probe was advanced to 4 feet bgs. Soil
data indicates RCL exceedances from 2-3 feet bgs for PAHs. Metals concentrations
in soil were found to exceed RCLs for protection of groundwater. Impacted soils are
anticipated from 0-4 feet bgs.

Area 8, South Scrap Shed (GP-13 and GP-14) Probes were advanced to 4 feet
bgs. Soil data indicates RCL exceedances from 1-2 feet bgs for PAHs and metals.
Relatively high levels of lead and cadmium in soils are indicated at this location. Due
to high levels of lead observed at this location, a TCLP analysis was conducted by
the laboratory; results indicated that the soil at this location is not characteristically
hazardous. Impacted soils are anticipated from 0-4 feet bgs.

Area 9, Former Paint Shop (GP-15 and GP-16) Probes were advanced to 12 feet
bgs. No VOCs were detected in soil or groundwater. Soil data indicates BTV
exceedances from 2-4 feet bgs for arsenic. Lead concentrations in soil were found to
exceed RCLs for protection of groundwater from 2-4 feet bgs. Groundwater data
indicates levels of lead above ESs. Impacted soils are anticipated from 0-5 feet bgs.

Area 10, Former Oil House (GP-17) Probe was advanced to 12 feet bgs. No VOCs
detected in shallow or deeper soils. Soil data indicates an RCL exceedance from 2-4
feet bgs for one PAH compound. No compounds were present at detectable
concentrations from 5-7 feet bgs. Impacted soils are anticipated from 0-4 feet bgs.

Area 11, Former Gasoline House (GP-18) Probe was advanced to 12 feet bgs. No
VOCs were detected in shallow (2-4 feet bgs) or deeper (5-7 feet bgs) soils. Soil data
indicates RCL exceedances at both 2-4 feet and 5-7 feet bgs for PAHs and lead.
Groundwater data indicates levels of lead and PAHs above ESs. Impacted soils are
anticipated from 0-8 feet bgs.

vi

Area 12, Former PCB Transformer Area (GP-19) Probe was advanced to 12 feet
bgs. No detectable PCB concentrations were identified at this area. One VOC
compound (naphthalene) was detected below RCLs. Soil data indicates RCL
exceedances from 2-4 feet for PAHs. Impacted soils are anticipated from 0-6 feet
bgs. Impacts to groundwater have not been determined for this area.

Area 13, Former Machine Shop (GP-20 and GP-21) Probes were advanced to 12
feet bgs. No detectable PAH concentrations were identified at this area from 5-7 feet
bgs. Groundwater data indicates levels above Chapter NR 140, Wis. Admin. Code
Preventative Action Limits (PALs) for PAHs.

Area 14, Former Rail Powerhouse (GP-22) Probe was advanced to 12 feet bgs.
Soil data indicates RCL exceedances from 1-3 feet bgs for PAHs. Lead
concentrations in soil were found to exceed RCLs for protection of groundwater.
Impacted soils are anticipated from 0-4 feet bgs.

Former Geotech Boring #11 (GP-23) Probe was advanced to 12 feet bgs. No
suspected contamination based on soil observation. Fill under the existing concrete
slab appeared clean with no traces of coal or slag. Soil from this location was not
analyzed based on indicators for non-impacted media.

Former Geotech Boring #12 (GP-24) Probe was advanced to 12 feet bgs.
Geoprobe refusal at approximately two feet below grade due to unknown obstruction.
Based on observations of Area 9 to the north, this area is assumed to have impacted
soils from 0-3 feet bgs.

Former Geotech Boring #15 (GP-25) Probe was advanced to 12 feet bgs. Suspect
fill material encountered from approximately 0-2 feet bgs. Soil from this location was
not analyzed based on similar appearance to material from nearby Area 7, for which
soil data indicates RCL exceedances from 2-3 feet bgs for PAHs and metals
concentrations in soil which exceed RCLs for protection of groundwater. Impacted
soils are anticipated from 0-3 feet bgs.

Former Geotech Boring #7 (GP-26) Probe was advanced to 12 feet bgs. Suspect
black fill material was encountered from 1-2 feet bgs in this location. No VOCs or
PAHs were detected in soil from 5-7 feet bgs. Lead concentrations in soil were found
to exceed RCLs for protection of groundwater from 1-2 feet bgs. Groundwater data
indicates levels of lead above ESs. Impacted soils are anticipated from 0-3 feet bgs.

Recommendations
Because several metals and PAH compounds above regulatory standards were indicated at
the site and have not been documented to have been previously investigated, we
recommend that the site owner submit this report to the WDNR for review prior to beginning
construction at the property.
Development plans for the new SAPF are currently being prepared. DFD has indicated that
impacted soils will remain on site, during and following construction, and will be managed
long-term through construction of an engineered cap. A cap maintenance plan will be

vii

developed and implemented at the site. Details of the cap maintenance plan should be
submitted to the WDNR for review and approval prior to construction of the new facility.
DFD will conduct building demolition and utility removal activities in the fall/winter of 2013 to
prepare the site for new construction. Because these activities will likely expose areas of
impacted soils, we recommend that DFD develop separate Soils Management Plans for the
demolition phase and construction phase of the project to appropriately manage impacted
soils identified in the Phase II ESA.

viii

Introduction
The State of Wisconsin Department of Administration (DOA), Division of Facilities
Development (DFD) intends to construct the new State Archive Preservation Facility (SAPF)
(DFD Project No. 09H2L) proposed to be located at 202 S. Thornton Avenue in Madison,
Wisconsin. This 5.10-acre property is the current site of the DOA Central Services Facility.
Prior to construction of the new facility, existing site improvements including buildings and
pavements will be removed, and buried utilities will be abandoned. In order to conduct
environmental due diligence efforts in advance of proposed demolition and construction
activities, the DFD retained Ayres Associates to conduct a Phase I and Phase II
Environmental Site Assessment (ESA) of the facility. The Phase I ESA of the property was
completed in June 2013. This report presents the findings of the Phase II ESA.
Review of historical Sanborn fire insurance maps compiled during the Phase I ESA identified
recognized environmental conditions (RECs) primarily related to the historical operation of
electric motor and machine manufacturing companies, including a machine shop, paint shop,
brass foundry, and loading/unloading activities from adjacent railroad spurs. Additional
information sources also indicated the former presence of polychlorinated biphenyl (PCB)
containing transformers, storage tanks and historical releases. Descriptions of RECs as
stated in the Phase I ESA are detailed below:

The current presence of a 10,000-gallon underground storage tank (UST) system in


use since 1988. Although the UST system has been subject to annual inspection and
is compliant with applicable regulations, regular operation of the system over time is
likely to result in releases from spills, overfills and leaks below detection thresholds
(See Figure 2 Area 4).

The current presence of foundry slag observed at the ground surface in the west wing
of the courtyard and use as fill material to a depth of 2 feet as indicated by soil probe
boring logs from 2007. The slag believed to have originated from a former brass
foundry as identified by historical fire insurance maps, and is likely to contain heavy
metals such as lead (Pb) (See Figure 2 Area 2).

The former presence of PCB-containing material in the courtyard cistern that was not
thoroughly investigated. Although PCBs were found to be present in cistern contents,
and impacts in the vicinity were investigated in 2007, the investigation did not include
the analysis of PCBs in soil and groundwater surrounding the cistern. PCBs in cistern
contents were present at concentrations that exceed Residual Contaminant Levels for
the protection of groundwater (See Figure 2 Area 1).

The former presence of oil dipping rooms, as identified on historical fire insurance
maps. The quantity of oil used is presumed to be significant due to the size of the
rooms depicted, and releases likely result from the regular operation of these tanks or
leakage over time (See Figure 2 Area 3).

The former presence of scrap sheds along rail lines adjacent to the north and south
property boundaries as identified by historical fire insurance maps. The regular
loading and unloading of the bins is likely to result in contamination from metal scrap
or dust and residual oils from machining (See Figure 2 Areas 5 and 8).

The former presence of three coal bins located throughout the site, as identified by
historical fire insurance maps. Soil impacts from metals such as arsenic are likely to
exist due to the accumulation of coal dust in these areas (See Figure 2 Areas 1, 6,
and 7).

The former presence of a paint shop, as identified on historical fire insurance maps.
There is a reasonable likelihood of subsurface impacts from the operational cleaning
of painting equipment using solvents on the site. Although previous investigations
have discovered low concentrations of chlorinated solvents in the groundwater, no
previous investigations have included soil sampling in this area (See Figure 2 Area
9).

The former presence of an oil house, as identified on historical fire insurance maps
(See Figure 2 Area 10).

The former presence of a gasoline house, as identified on historical fire insurance


maps (See Figure 2 Area 11).

The former presence of PCB transformers on the site as revealed by the EDR Radius
Map Report; former transformer locations were also revealed by a 1956 building
survey drawing by Gisholt Machine Company. Releases may have occurred due to
the deterioration of transformers that were on site from at least 1956 to 2007, and
PCBs were previously detected on the site during a 2007 investigation of the
courtyard, a known transformer location (See Figure 2 Areas 1 and 12).

The former operation of a machine shop on the site from 1895 to 1970, which is
associated with the regular use of various oils and solvents. Although one of the two
former machine shop areas was previously investigated for potential subsurface
impacts, the report contains no data regarding polycyclic aromatic hydrocarbons
(PAHs), which are commonly present in machine oils and lubricants (See Figure 2
Areas 4 and 13).

The former operation of a railway power house, as identified on historical fire


insurance maps. The power house is likely to have utilized significant quantities of
coal or oil, and although one soil sample was indicated to be previously collected in
this area, there is no information in the report describing the sampling rationale,
procedure or laboratory analysis (See Figure 2 Area 14).

Because of these findings, a Phase II ESA was completed to evaluate soil and groundwater
quality on the subject property.
This report presents the results of the Phase II ESA. The report includes a discussion of site
background, field procedures, findings, and recommendations as well as site drawings, soil
probe logs and abandonment forms, laboratory reports and tables that summarize analytical
results.

Site Location and Project Numbers


The subject property is located in the Northwest 1/4 of the Northwest 1/4 of Section 7,
Township 7 North, Range 10 East, in the City of Madison, Dane County, Wisconsin, and
measures approximately 5.10 acres. Figure 1 shows the regional location of the property and
Figure 2 is an aerial photograph that shows the current layout of subject property.
2

Project Contacts
The project contacts for this site are as follows:
Client/Property Owner:

Wisconsin Department of Administration


Division of Facilities Development
PO Box 7866
Madison, Wisconsin 53707
Bill Napier, PE
bill.napier@wisconsin.gov

Consultant:

Ayres Associates
5201 E. Terrace Drive, Suite 200
Madison, Wisconsin 53718
Neil E. Carney, PE
carneyn@ayresassociates.com
608.443.1298

Drilling and Laboratory Contractors


Pace Analytical, Green Bay, Wisconsin, provided analytical services. This laboratory is
certified by the Wisconsin Department of Natural Resources (Certification No. 405132750).
Horizon Construction and Exploration, of Grafton, Wisconsin, provided drilling services.

Site Background
The subject property is an approximately 5.10-acre lot located at 202 South Thornton
Avenue, Madison, Wisconsin, that includes an approximately 147,700-square-foot building
complex constructed between 1895 and 1942.
The earliest known developed use of the property was as Northern Electrical Manufacturing
Company, established in 1895. The company specialized in the design and manufacturing of
electrical motors, and had its own brass foundry. Site features also included a machine shop,
punch press room, dipping rooms, winding department, tool room, paint shop, oil house, and
gasoline house. Two scrap houses were also located along the railroads to the north and the
south. Three rail spurs entered the property on the north and south sides to provide transport
of supplies and finished goods. By 1942, the property had become Gisholt Machine
Company, after the founder of Northern Electrical Manufacturing Company, Conrad
Conradson, had passed away in 1940. Conradson was the former Vice President of Gisholt
prior to founding Northern Electrical and continued to patent machine tool designs while
running Northern Electrical.
Gisholt Machine Company used the site for the manufacturing of machine tools, such as
lathes and balancing machines, and employed approximately 1,200 people. Gisholt
expanded the facilities with new construction on the eastern half of the property. A building
survey map produced in 1954 also indicates that the east half of the Gisholt complex was
occupied by Smith White Truck Sales and Nagle Hart Company, and used the building for
tractor repair and storage. Gisholt was later purchased by Giddings & Lewis Machine Tool in
1966, and was shut down in 1970 due to economic downturn. The property is presumed to
have been vacant for approximately two years before being sold to the State of Wisconsin in
1972 for its current use.
The property is currently known as the Central Services Building, operated by the State of
Wisconsin Department of Administration. Several entities occupy the property including
Information Technology Services, State Agency Services, Transportation Services and
University of Wisconsin Tandem Press, and primary operations consist of vehicle fleet
maintenance, printing and mailing services, art studios and administrative offices.
Demolition of the existing buildings are scheduled to occur during 2014, with construction of
a new, State-owned, archival storage facility on the subject property from 2014-2016.

Phase II ESA Scope


To investigate the areas with RECs identified in the previous environmental studies, Ayres
Associates conducted the following scope of services:

Retained a drilling contractor and installed 26 soil probes to a maximum depth of 12


feet (ft) below ground surface (bgs). Selected boreholes were converted to temporary
wells for the purpose of collecting groundwater samples.

Collected soil samples at approximately 2-2.5-foot intervals and screened samples for
the presence of organic compounds using a photoionization detector (PID).

Submitted soil and groundwater samples to a Wisconsin certified laboratory for


analysis for select volatile organic compounds (VOCs), PAHs, Resource
Conservation & Recovery Act (RCRA) metals (arsenic, barium, cadmium, chromium,
mercury, silver and selenium) and PCBs.

Analyzed soils with potentially hazardous concentrations of lead by toxicity


characteristic leaching procedure (TCLP) to address potential disposal
considerations.

Prepared soil probe logs and abandonment forms, tables summarizing laboratory
results, and a site map showing probe locations.

Prepared this Phase II ESA report to document field procedures and findings of the
assessment and to present conclusions and recommendations for the site.

Fieldwork
Ayres Associates observed the installation of 26 soil probes (GP-1 through GP-26) on
June 13 and 14, 2013. Horizon Construction and Exploration of Grafton, Wisconsin,
performed the soil probing using a direct push Geoprobe machine. Weather conditions were
dry and sunny with temperatures up to 89 degrees Fahrenheit. Field procedures used to
obtain soil and groundwater samples are summarized in Appendix B.
The 26 soil probes were installed to a depth of 4 to 12 feet below ground surface (bgs). Soil
samples were collected at continuous intervals in each probe starting at the surface to the
terminus. Soils were classified, field screened, and collected for laboratory analysis. Soil
samples were screened in the field for the presence of organic vapors using a calibrated PID.
Soil probe logs with soil classification and PID readings and abandonment forms are in
Appendix C.
The soil probes and temporary monitoring wells were installed at selected locations to
address RECs identified in the Phase 1 ESA. The locations, sampling rationale, and
quantities are summarized in the following table:

Location

Area 1

Area 2

Area 3

Area 4

Area 5

Area 6

Description

Former Cistern

Former Brass Foundry

Sampling Rationale

PCBs, Pb, and Cr in former cistern during


previous investigations were greater than
Residual Contaminant Levels (RCLs) for
direct contact and protection of
groundwater. No samples were previously
collected outside of cistern to determine
potential horizontal or vertical extent.
Analysis included: PCBs, PAHs, RCRA
metals.
Brass foundry slag not previously
investigated. Analysis included: PCBs,
PAHs, RCRA metals.

Former Oil Dipping


Rooms

Not previously investigated. Analysis


included: VOCs and PAHs. Temporary
MW was installed due to visual indicators
for impacted soil.

Existing 10,000-gal
Gasoline UST, Former
Machine Shop

Not previously investigated. Analysis


included: VOCs and PAHs.

Former North Scrap


Shed

Not previously investigated. Analysis


included: PAHs and RCRA metals.

Former West Coal Bin

Not previously investigated. Analysis


included: PAHs and RCRA metals.

No. of
Bores

Sample
Quantities

(Depth)

Soil

GW

(12 feet)

2
(12 feet)
1
(12 feet)

3
(12 feet)
1
(4 feet)
1
(4 feet)

Location

Description

Sampling Rationale

No. of
Bores
(Depth)

Area 7

Area 8

Area 9

Area 10

Area 11

Area 12

Area 13

Area 14

Former East Coal Bin


(now in warehouse)

Not previously investigated. Analysis


included: PAHs and RCRA metals.

Former South Scrap


Shed

Not previously investigated. Analysis


included: PAHs and RCRA metals.

Former Paint Shop

Not previously investigated. Analysis


included: VOCs and RCRA metals.

Former Oil House

Former Gasoline House

Not previously investigated. Analysis


included: VOCs and PAHs.
Not previously investigated. Analysis
included: Pb, VOCs and PAHs. Temporary
MW was installed due to visual indicators
for impacted soil.

Former PCB
Transformer Area

Not previously investigated. Analysis


included: VOCs, PAHs, and PCBs.
Temporary MW was installed due to visual
indicators for impacted soil.

Former Machine Shop

Previously investigated by Ivertech in


2006, but no data was collected for PAHs
from hydraulic and lubricating oil. Analysis
included: PAHs.

Former Railway Power


House

No information available regarding


historical sampling events for impacts from
coal and oil. Historical activity at the site
included the use of coal and oil. Analysis
included: PAHs and RCRA metals.

Former Geotechnical
Borings

No environmental screening data collected


during 2013 geotechnical investigation for
mechanical system construction. Three
additional borings were conducted to
supplement data from Areas 1 to 14 to
match previous geotechnical investigation.
Analysis included: VOCs, PAHs, and
RCRA metals.

Sample
Quantities
1

(4 feet)
2
(4 feet)
2
(12 feet)
1
(12 feet)
1
(12 feet)

1
(12 feet)

2
(12 feet)

1
(12 feet)

3
(12 feet)

Soil probe locations are shown on Figures 2 and 3.


Soil samples were collected for laboratory analysis from every probe, with the exception of
GP-24 which experienced refusal at 0.5 ft bgs due to a subsurface obstruction. Sample depth
was determined by observation of likely contaminated soil (staining, odor, slag, etc.) and
depth to groundwater (approximately 6 to 7 feet bgs). Laboratory reports and the chain-ofcustody forms are in Appendix D. Laboratory results for the soil samples are summarized in
Table 1.

Findings
Soil Texture
Soils were classified using the United Soil Classification System (USCS) and classifications
are listed on the boring logs in Appendix C. A description of soil textures by area is provided
in the following table:
Area
1

Description
Former Cistern

Probe #
GP-1 through
GP-3

General Soil Description


Black sandy fill with coal and slag from 0-2
ft bgs. Medium brown silty clay or sandy
clay from 2-6 ft bgs, and clayey sand and
gravel from 6-12 ft bgs. Groundwater
encountered at approximately 6 ft bgs.

Former Brass
Foundry

GP-4 and GP-5

Sand and slag fill from 0-2 ft bgs. Medium


brown clayey sand from 2-4 ft bgs, and
clayey sand and gravel from 4 to 12 ft bgs.
Groundwater encountered at approximately
6 ft bgs.

Former Oil
Dipping Rooms

GP-6

Asphalt and gravel fill from 0-1.5 ft bgs,


black fill from 1.5-2 ft bgs, medium brown
silty clay from 2-8 ft bgs, and sand and
gravel from 8-12 ft bgs. Groundwater
encountered at approximately 7 ft bgs.

Existing
10,000-gal
Gasoline UST,
Former
Machine Shop

GP-7 through
GP-9

Asphalt and gravel fill from 0-2 ft bgs, pea


gravel from 2-11 ft bgs and medium brown
sand or clayey sand and gravel from 11-12
ft bgs around UST. Medium brown silty clay
from 3.5-4.5 ft bgs, and dark brown silty
clay from 4.5-5 ft bgs near pump island.
Groundwater encountered at approximately
7.5 ft bgs.

Former North
Scrap Shed

GP-10

Medium brown silty clay from 0-1.5 ft bgs,


dark brown sandy fill from 1.5-2.5 ft bgs
and medium brown sand and gravel from
2.5-4 ft bgs.

Former West
Coal Bin

GP-11

Asphalt and gravel fill from 0-1 ft bgs, silty


clay with coal from 1-1.5 ft, gravel fill from
1.5-3.5 ft, and sand and gravel from 3.5-4 ft
bgs.

Former East
Coal Bin (now
in warehouse)

GP-12

Concrete and clayey sand or gravel fill from


0-2 ft bgs, black fill with coal from 2-3 ft,
medium brown clayey silt from 3-3.5 ft and
medium brown sand from 3.-5-4 ft bgs.

Former South
Scrap Shed

GP-13 and GP14

Dark brown fill and slag from 0-2 ft bgs with


medium brown sand and gravel from 2-4 ft
bgs.

Former Paint
Shop

GP-15 and GP16

Concrete and sand fill from 0-2 ft bgs, black


fill and coal from 2-3 ft, medium brown

Area

Description

Probe #

General Soil Description


sandy clay from 3-6 ft, and sand and gravel
from 6-12 ft bgs. Groundwater encountered
at approximately 7 ft bgs.

10

Former Oil
House

GP-17

Asphalt and gravel fill from 0-2 ft bgs,


medium brown clayey sand with trace coal
from 2-6 ft, and medium brown sand from
6-12 ft bgs. Groundwater encountered at
approximately 7 ft bgs.

11

Former
Gasoline
House

GP-18

Asphalt and gravel fill from 0-2 ft bgs, black


sandy fill with coal from 2-6 ft bgs, and
medium brown clayey sand and gravel
from 6-9 ft bgs. Groundwater encountered
at approximately 6 ft bgs.

12

Former PCB
Transformer
Area

GP-19

Gravel fill from 0-1 ft bgs, black gravel fill


from 1-3 ft, medium brown clayey silt from
3-4.5 ft, sand and gravel from 4.5-6.5 ft,
sandy clay from 6.5-9 ft, peat from 9-10 ft,
medium brown sand from 10-11.5 ft and
peat from 11.5-12 ft bgs. Groundwater
encountered at approximately 6 ft bgs.

13

Former
Machine Shop

GP-20 and GP21

GP-20: Concrete and medium brown silty


sand from 0-2.5 ft bgs, silty clay from 2.5-6
ft, and silty sand and gravel from 6-12 ft
bgs. Groundwater encountered at
approximately 6 ft bgs.
GP-21: Concrete and medium brown sand
and gravel from 0-6 ft bgs. Silty sand and
gravel from 6-12 ft bgs.

14

Former
Railway Power
House

GP-22

Asphalt and black fill from 0-2.5 ft bgs,


medium brown silty clay from 2.5-4 ft,
reddish-brown sand from 4-5.5 ft, and
medium brown sand from 5.5-12 ft bgs.
Groundwater encountered at approximately
6.5 ft bgs.

Former Geotech
Boring #11

Former
Geotechnical
Borings

GP-23

Concrete and sand fill from 0-2.5 ft bgs,


medium brown silty clay from 2.5-7 ft bgs,
and silty sand and gravel from 7-12 ft bgs.
Groundwater was encountered at
approximately 7.5 ft bgs.

Former Geotech
Boring #12

Former
Geotechnical
Borings

GP-24

No soil was sampled. The boring could not


be completed due to an obstruction in the
borehole.

Former Geotech
Boring #15

Former
Geotechnical
Borings

GP-25

Concrete and sand and gravel fill from 0-2


ft bgs, black fill from 2-3 ft, medium brown
sand from 3-6 ft and silty sand and gravel
from 6-12 ft bgs. Groundwater was
encountered at approximately 6 ft bgs.

Area
Former Geotech
Boring #7

Description
Former
Geotechnical
Borings

Probe #
GP-26

General Soil Description


Asphalt and gravel fill from 0-1.5 ft bgs,
black fill from 1.5-2 ft, medium brown silty
clay from 2-3 ft, reddish-brown sand from
3-7 ft and medium brown sand from 7-12 ft
bgs. Groundwater was encountered at
approximately 7 ft bgs.

Soil Quality
Headspace Screening
PID readings were generally low (<10 instrument units (i.u.s.)) in soil probes, with the
exception of three probes. Elevated PID readings were recorded in GP-2 (60 i.u.s.) at 10-12
feet bgs in a layer of stained soil, GP-5 (62 i.u.s.) at 2-4 feet bgs, and GP-26 (38 i.u.s.) at
7.5-10 feet bgs. GP-2 was the only boring with observable soil staining and/or odor.
VOCs
With the exception of naphthalene in shallow soil (2-4 feet bgs) at GP-19, no VOCs were
detected in soil on the site. The naphthalene concentration was below the compound RCL. .
Table 1A provides a summary of VOCs analyzed in soil.
PAHs
Elevated concentrations of PAHs over residual contaminant levels (RCLs) from the USEPA
Regional Screening Level Calculator proposed for Chapter NR 720, Wisconsin
Administrative Code, were observed in 12 of 21 probe locations (GP-4, GP-5, GP-6, GP-10,
GP-11, GP-12, GP-13, GP-14, GP-17, GP-18, GP-19, and GP-22). PAHs were primarily
detected in shallow fill material on the site, from 0-4 feet bgs. Elevated levels of PAHs in
deeper soils (typically 5-7 feet bgs) were detected at GP-18. All locations with RCL
exceedances included exceedances for direct contact in a non-industrial setting, and 10 of
the locations exceeded RCLs for protection of groundwater (GP-5, GP-6, GP-10, GP-12, GP13, GP-14, GP-18, GP-19, and GP-22). PAH compounds in exceedance of direct contact
RCLs include benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene,
benzo(k)fluoranthene, dibenz(a,h)anthracene and indeno(1,2,3-cd)pyrene. PAH compounds
in exceedance of protection of groundwater RCLs include benzo(a)pyrene,
benzo(b)fluoranthene, chrysene and naphthalene. Table 1B provides a summary of PAHs
analyzed in soil.
Metals
Several metals, including arsenic, cadmium, lead, mercury, selenium and silver were
detected in soil at levels exceeding RCLs. Elevated levels of metals were detected in 13 of
15 boring locations in shallow fill material from 0-4 feet bgs, with the exception of GP-18,
where lead in soil from 5-7 feet was found to exceed the RCL for protection of groundwater.
Elevated arsenic levels exceeding the Wisconsin background threshold value (BTV) were
observed at 6 of 15 boring locations (GP-1, GP-3, GP-5, GP-13, GP-14 and GP-16). A recent
study by the United States Geological Survey (USGS), Scientific Investigations Report
2011-5202 (pubs.usgs.gov/sir/2011/5202) researched naturally occurring arsenic
10

concentrations in surface soils in Wisconsin. Based on the findings of this study, the WDNR
Remediation and Redevelopment Program concluded that the data set in this report is of
sufficient scope and quality to establish a statewide soil arsenic BTV of 8 mg/kg.
Cadmium was found to exceed RCLs for protection of groundwater at GP-1, GP-11, GP-13,
and GP-14.
Lead was found to exceed RCLs for protection of groundwater at GP-1, GP-11, GP-12, GP13, GP-14, GP-15, GP-16, GP-18, GP-22, and GP-26, with exceedances for direct contact at
GP-13 and GP-14. Due to significantly higher concentrations of lead at GP-13 and GP-14
(404 mg/kg and 1190 mg/kg, respectively), soil samples from 1-2 feet bgs were analyzed
using the toxicity characteristic leaching procedure (TCLP) to determine if the soil may be
classified as characteristically hazardous. Neither sample indicated concentrations meeting
the TCLP lead threshold to be classified as characteristically hazardous. Slightly deeper soil
at these locations (2-4 feet bgs) was not found to contain metal concentrations over RCLs.
Selenium and mercury levels were found to exceed RCLs for protection of groundwater in
shallow soil at GP-5, and silver was found to exceed the RCL for the protection of
groundwater in shallow soil at GP-16.
Table 1C includes a summary of metals and TCLP analysis results in soil.
PCBs
No PCBs were detected in soil on the site, with the exception of GP-2 from 5-7 feet bgs.
Total PCBs were found to exceed the RCL for protection of groundwater. Table 1B includes
a summary of PCBs analyzed in soil.
A map depicting areas of regulatory exceedances in soil and groundwater is provided as
Figure 3.

Groundwater Quality
PAHs
PAHs were detected at levels of regulatory significance [above a Preventative Action Limit
(PAL) or Enforcement Standard (ES) in Ch. NR 140] in 6 of 10 temporary wells. The only
location which exceeded an NR 140 ES was GP-18, with ES exceedances for
benzo(a)pyrene, benzo(b)fluoranthene and chrysene. NR 140 PAL exceedances on the site
included benzo(a)pyrene, benzo(b)fluoranthene and chrysene in GP-1, GP-3, GP-20 and
GP-25. Benzo(b)fluoranthene and chrysene were above the PAL in GP-21. Table 2 includes
a summary of groundwater analytical results.
Metals
Arsenic, barium, cadmium, chromium, lead and mercury were detected at levels of regulatory
significance in 6 of 7 temporary wells sampled for lead or RCRA metals. Arsenic was above
the PAL in GP-2 and above the ES in GP-3 and GP-4. Barium was above the PAL in GP-3.

11

Cadmium was above the PAL in GP-3 and GP-4. Chromium was above the ES in GP-3 and
the PAL in GP-4. Lead was above the ES in GP-3, GP-4, GP-16, GP-18 and GP-26. Mercury
was above the PAL in GP-3, but was not detected in other temporary wells.
PCBs
No PCBs were detected in groundwater from any of the four temporary wells analyzed.

12

Conclusions
This Phase II ESA investigated the potential for soil contamination associated with RECs
primarily related to the historical operation of electric motor and machine manufacturing
companies, including a machine shop, paint shop, brass foundry, and loading/unloading
activities from adjacent railroad spurs. We conclude the following:

The majority of the site contains a layer of fill material on average from 0-3 feet bgs
which demonstrates dark discoloration and contains detectable levels of PAHs and
metals (arsenic, cadmium, and lead) in exceedance of RCLs listed in the USEPA
Regional Screening Level Web-Calculator. Arsenic concentrations were compared to
a BTV of 8 parts per million, which is endorsed by the WDNR based on data provided
in a study published by the USGS titled Distribution and Variation of Arsenic in
Wisconsin Soils, With Data on Other Trace Elements (February 2013).

An undefined area of groundwater across the site appears to be impacted by lead.


Other metals compounds were detected at levels exceeding the NR 140 ES in the
courtyard area.

The highest detected levels of lead were identified in Area 8, Former South Scrap
Shed. Based on TCLP testing, the soil has been determined to be non-hazardous.

Elevated levels of PAHs are present in Area 12 Former PCB Transformer. Shallow
soils (2-4 feet bgs) at this location display higher PAH concentrations than other
areas of fill around the site, and several PAH compounds exceed RCLs for protection
of groundwater.

Although PCBs were detected in one soil boring in the courtyard, there no
groundwater impacts from PCBs were detected in the area.

13

Recommendations
Because several metals and PAH compounds above regulatory standards were indicated at
the site and have not been documented to have been previously investigated, we
recommend that the site owner submit this report to the WDNR for review prior to beginning
construction at the property.
Development plans for the new SAPF are currently being prepared. DFD has indicated that
impacted soils will remain on site, during and following construction, and will be managed
long-term through construction of an engineered cap. A cap maintenance plan will be
developed and implemented at the site. Details of the cap maintenance plan should be
submitted to the WDNR for review and approval prior to construction of the new facility.
DFD will conduct building demolition and utility removal activities in the fall/winter of 2013 to
prepare the site for new construction. Because these activities will likely expose areas of
impacted soils, we recommend that DFD develop separate Soils Management Plans for the
demolition phase and construction phase of the project to appropriately manage impacted
soils identified in the Phase II ESA.

Standard of Care
This Phase II ESA investigation report is based on data obtained by Ayres Associates and
other contractors associated with the property through placement of soil probes, temporary
wells and collection and analysis of soil and groundwater samples. Soil qualities reported
apply only to the specific locations and times at which the work was performed.
Conclusions and recommendations made represents our professional engineering judgment
in interpreting these data, as well as data obtained from reports prepared by others relative
to soil conditions in the study area. Data, computations, and correspondence supporting the
information presented in this report are kept on file by Ayres Associates.

14

Figures

Approximate Site Location

Source: USGS Quadrangle 7.5


Minute Series, Madison East, 1983
1 = 2000

Figure 1 Site Location Map


202 S. Thornton Ave.
Madison, Wisconsin

19-0291.20

RAILROAD

5
GP-7
GP-8
12

S.DI
CKI
NSON ST.

GP-9
4

GP-19
GP-15

11

GP-16
GP-17

9
GP-11

GP-18

10

GP-6

GP-1

GP-23

GP-26
GP-12

1
GP-2

GP-3

TH
KE PA
I
VER B
I
R
E
R
YAHA

GP-10

GP-4
GP-5

GP-25
2

GP-20

13

GP-21
GP-22
GP-13

GP-14
14

LEGEND
V:
\ENV\CAD\W isconsin DOA\SITE SLM .
dgn

W:
\Bentley_V8i\W orkSpace\Projects\Engineering_Services\pltcfg\ES_text_sub.
tbl

W:
\Bentley_V8i\W orkSpace\Standards\pltcfg\Ayres_pdf.
pltcfg

7/19/2013

CAPITAL CITY TRAIL

N
O

GP-11
GEOPROBE LOCATION (JUNE 13-14, 2013)
GP-2
GEOPROBE/ TEMP WELL LOCATION (JUNE 13-14, 2013)

BOOK NO.

DR.BY

JOB NO.

SCALE
JULY 2013

202 S. THORNTON AVENUE

19-0291.20

M. BANACH
DATE

AS SHOWN

NO.

DATE

REVISION

MADISON, WISCONSIN

60

RECOGNIZED ENVIRONMENTAL
CONDITION LOCATION
DRAWING NO.

PHASE II ENVIRONMENTAL SITE ASSESSMENT

T. SHUPERT
CHK.BY

R
T
H

SAMPLE LOCATION MAP


ASSOCIATES
Eau Claire, Wisconsin

RAILROAD

GP-8
GP-7

S.DI
CKI
NSON ST.

4
GP-19

GP-9
GP-16

11

GP-17

GP-15

GP-11

GP-18

10

GP-6

GP-1

GP-23

GP-26
GP-12

3
GP-24

1
GP-2

GP-3

TH
KE PA
I
VER B
I
R
E
R
YAHA

GP-10

GP-4
GP-5

GP-25
2

GP-20

13

GP-21
GP-22
GP-13

14

GP-14

N
O

LEGEND

R
T
H

GP-11
GEOPROBE LOCATION (JUNE 13-14, 2013)

60

GP-2
V:
\ENV\CAD\W isconsin DOA\Regulatory Exceedance.
dgn

W:
\Bentley_V8i\W orkSpace\Projects\Engineering_Services\pltcfg\ES_text_sub.
tbl

W:
\Bentley_V8i\W orkSpace\Standards\pltcfg\Ayres_pdf.
pltcfg

7/19/2013

CAPITAL CITY TRAIL

GEOPROBE/ TEMP WELL LOCATION (JUNE 13-14, 2013)


NO RESIDUAL CONTAMINANT LEVEL EXCEEDANCE IN SOIL
NO ENFORCEMENT STANDARD EXCEEDANCE IN GROUNDWATER
PROTECTION OF GROUNDWATER RESIDUAL CONTAMINANT LEVEL EXCEEDANCE
DIRECT CONTACT RESIDUAL CONTAMINANT LEVEL EXCEEDANCE
ENFORCEMENT STANDARD EXCEEDANCE IN GROUNDWATER

BOOK NO.

DR.BY

JOB NO.

SCALE
JULY 2013

202 S. THORNTON AVENUE

19-0291.20

M. BANACH
DATE

DRAWING NO.

PHASE II ENVIRONMENTAL SITE ASSESSMENT

T. SHUPERT
CHK.BY

AS SHOWN

NO.

DATE

REVISION

MADISON, WISCONSIN

REGULATORY EXCEEDANCE MAP


ASSOCIATES
Eau Claire, Wisconsin

Tables

Table 1A
VOLATILE ORGANIC COMPUNDS (VOCs) IN SOIL
PHASE II ENVIRONMENTAL SITE ASSESSMENT
202 SOUTH THORNTON AVENUE, MADISON, WI
Parameter

Units

DC

GW

GP-6(D) GP-6(S)

Sample Date 6/14/13


Sample Depth

5-7

GP-7

GP-8

GP-9

GP-15

GP-16

GP-19

GP-26

6/14/13

6/14/13

6/14/13

6/14/13

6/13/13

6/13/13

GP-17(D) GP-17(S)
6/13/13

6/13/13

GP-18(D) GP-18(S)
6/13/13

6/13/13

6/13/13

6/14/13

1-3

10-12

6-8

4-5

2-4

2-4

5-7

2-4

5-7

2-4

2-4

5-7

Method EPA 8260


1,1,1,2-Tetrachloroethane

mg/kg

2.59

0.0533

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,1,1-Trichloroethane

mg/kg

640

0.1402

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,1,2,2-Tetrachloroethane

mg/kg

0.753

0.0002

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,1,2-Trichloroethane

mg/kg

1.42

0.0032

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250
<0.0250

1,1-Dichloroethane

mg/kg

4.72

0.4836

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,1-Dichloroethene

mg/kg

342

0.005

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,1-Dichloropropene

mg/kg

NA

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,2,3-Trichlorobenzene

mg/kg

243

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,2,3-Trichloropropane

mg/kg

0.005

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,2,4-Trichlorobenzene

mg/kg

22.1

0.408

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,2,4-Trimethylbenzene

mg/kg

89.8

1.3793

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,2-Dibromo-3-chloropropane

mg/kg

0.008

0.0002

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

<0.0498

1,2-Dibromoethane (EDB)

mg/kg

0.047

0.0000282

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,2-Dichlorobenzene

mg/kg

193

1.168

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,2-Dichloroethane

mg/kg

0.608

0.0028

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,2-Dichloropropane

mg/kg

1.33

0.0033

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,3,5-Trimethylbenzene

mg/kg

182

1.3793

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,3-Dichlorobenzene

mg/kg

297

1.1522

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,3-Dichloropropane

mg/kg

1490

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

1,4-Dichlorobenzene

mg/kg

3.48

0.144

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

2,2-Dichloropropane

mg/kg

527

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

2-Chlorotoluene

mg/kg

907

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

4-Chlorotoluene

mg/kg

253

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Benzene

mg/kg

1.49

0.0051

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Bromobenzene

mg/kg

354

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Bromochloromethane

mg/kg

232

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Bromodichloromethane

mg/kg

0.39

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Bromoform

mg/kg

61.6

0.0023

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Bromomethane

mg/kg

10.3

0.0051

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Carbon tetrachloride

mg/kg

0.854

0.0039

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Chlorobenzene

mg/kg

392

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Chloroethane

mg/kg

NA

0.2266

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Chloroform

mg/kg

0.423

0.0033

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Chloromethane

mg/kg

171

0.0155

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Dibromochloromethane

mg/kg

0.933

0.032

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Dibromomethane

mg/kg

35

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Dichlorodifluoromethane

mg/kg

135

3.0825

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Diisopropyl ether

mg/kg

2260

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Ethylbenzene

mg/kg

7.47

1.57

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Hexachloro-1,3-butadiene

mg/kg

6.23

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Isopropylbenzene (Cumene)

mg/kg

268

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Methyl-tert-butyl ether

mg/kg

59.4

0.027

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Methylene Chloride

mg/kg

60.7

0.0026

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Naphthalene

mg/kg

5.15

0.6587

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

0.0649 J

<0.0250

Styrene

mg/kg

867

0.22

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Tetrachloroethene

mg/kg

30.7

0.0045

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Toluene

mg/kg

818

1.1072

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Trichloroethene

mg/kg

0.644

0.0036

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Trichlorofluoromethane

mg/kg

1120

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

Vinyl chloride

mg/kg

0.067

0.0001

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

cis-1,2-Dichloroethene

mg/kg

156

0.0412

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

cis-1,3-Dichloropropene

mg/kg

1220

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

m&p-Xylene

mg/kg

388/390

3.94

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

<0.0500

n-Butylbenzene

mg/kg

108

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

n-Propylbenzene

mg/kg

NA

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

o-Xylene

mg/kg

434

3.94

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

p-Isopropyltoluene

mg/kg

162

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

sec-Butylbenzene

mg/kg

145

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

tert-Butylbenzene

mg/kg

183

NA

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

trans-1,2-Dichloroethene

mg/kg

211

0.0588

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

trans-1,3-Dichloropropene

mg/kg

1570

0.0003

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

<0.0250

NA = Not Applicable
Bold exceeds WDNR RR Spreadsheet values for Direct Contact (non-industrial) (DC), adopted from USEPA Regional Screening Level Calculator proposed for WI NR 720
Italic exceeds WDNR RR Spreadsheet values for Protection of Groundwater (GW), adopted from USEPA Regional Screening Level Calculator proposed for WI NR 720

Table 1B
POLYCLYCLIC AROMATIC HYDROCARBONS (PAHs) IN SOIL
PHASE II ENVIRONMENTAL SITE ASSESSMENT
202 SOUTH THORNTON AVENUE, MADISON, WI
Parameter

Units

DC

GW

GP-1

GP-2(D)

GP-2

GP-3

GP-4

GP-5

GP-6(D)

GP-6(S)

GP-7

GP-8

GP-9

GP-10

GP-11

GP-12

GP-13

GP-14

GP-17(D)

GP-17(S)

GP-18(D)

GP-18(S)

GP-19

GP-20

GP-21

GP-22

GP-26

Sample Date

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/13/13

6/13/13

6/13/13

6/13/13

6/13/13

6/13/13

6/13/13

6/14/13

6/14/13

Sample Depth

0-2

10-12

0-2

5-7

0-2

1-2

5-7

1-3

10-12

6-8

4-5

1-3

1-2

2-3

1-2

1-2

5-7

2-4

5-7

2-4

2-4

5-6

5-6

1-3

5-7

<0.0033

Method EPA 8270 by SIM


1-Methylnaphthalene

mg/kg

15.6

NA

<0.0035

<0.0033

<0.0034

<0.0034

0.0365

0.120

<0.0036

0.0093 J

<0.0034

<0.0036

<0.0035

0.0110 J

0.0092 J

0.144

0.414 J

0.169 J

<0.0034

<0.0034

0.0486

0.0747

0.882 J

<0.0034

<0.0032

0.0895

2-Methylnaphthalene

mg/kg

229

NA

<0.0098

<0.0093

<0.0097

<0.0097

0.0389

0.131

<0.0102

<0.0200

<0.0096

<0.0102

<0.0100

<0.0099

<0.0111

0.183

<0.393

<0.382

<0.0095

<0.0097

0.0560

0.0795

0.502 J

<0.0096

<0.0091

0.137

<0.0093

Acenaphthene

mg/kg

3440

NA

<0.0098

<0.0093

<0.0097

<0.0097

<0.0102

0.232

<0.0102

<0.0200

<0.0096

<0.0102

<0.0100

0.0206

<0.0111

<0.0095

0.393 J

0.798

<0.0095

<0.0097

0.0250

0.0173 J

1.02

<0.0096

<0.0091

<0.0091

<0.0093

Acenaphthylene

mg/kg

NA

NA

<0.0098

<0.0093

<0.0097

<0.0097

<0.0102

<0.0593

<0.0102

0.141

<0.0096

<0.0102

<0.0100

0.0162 J

<0.0111

0.0180 J

0.588 J

<0.382

<0.0095

<0.0097

<0.0107

0.0237

<0.481

<0.0096

<0.0091

0.0292

<0.0093

Anthracene

mg/kg

17,200

196.7442

<0.0098

<0.0093

<0.0097

<0.0097

0.0173 J

0.693

<0.0102

0.0806

<0.0096

<0.0102

<0.0100

0.102

0.0185 J

0.0401

1.71

2.34

<0.0095

0.0110 J

0.0844

0.0691

3.49

<0.0096

<0.0091

0.0248

<0.0093

Benzo(a)anthracene

mg/kg

0.148

NA

<0.0098

<0.0093

<0.0097

<0.0097

0.0339

0.915

<0.0102

0.237

<0.0096

<0.0102

<0.0100

0.285

0.0893

0.0962

3.61

3.16

<0.0095

0.0250

0.136

0.176

6.24

<0.0096

<0.0091

0.125

<0.0093

Benzo(a)pyrene

mg/kg

0.015

0.47

<0.0035

<0.0033

<0.0035

<0.0034

0.0366

0.858

0.0100 J

0.252

<0.0034

<0.0036

<0.0036

0.384

0.132

0.0624

3.58

3.29

<0.0034

0.0251

0.133

0.188

6.06

<0.0034

<0.0032

0.184

<0.0033

Benzo(b)fluoranthene

mg/kg

0.148

0.48

<0.0098

<0.0093

<0.0097

<0.0097

0.0491

1.12

0.0116 J

0.285

<0.0096

<0.0102

<0.0100

0.470

0.133

0.0914

4.71

4.29

<0.0095

0.0363

0.149

0.153

7.46

<0.0096

<0.0091

0.257

<0.0093

Benzo(g,h,i)perylene

mg/kg

NA

NA

<0.0098

<0.0093

<0.0097

<0.0097

0.0313

0.560

<0.0102

0.247

<0.0096

<0.0102

<0.0100

0.283

0.102

0.0524

2.29

2.18

<0.0095

0.0153 J

0.0751

0.118

3.75

<0.0096

<0.0091

0.134

<0.0093

Benzo(k)fluoranthene

mg/kg

1.48

NA

<0.0035

<0.0033

<0.0034

<0.0034

0.0271

0.585

0.0092 J

0.153

<0.0034

0.0044 J

<0.0035

0.328

0.0895

0.0690

2.12

2.34

<0.0034

0.0149 J

0.109

0.176

3.88

<0.0034

<0.0032

0.186

<0.0033

Chrysene

mg/kg

14.8

0.1451

<0.0098

<0.0093

<0.0097

<0.0097

0.0657

1.18

0.0128 J

0.314

<0.0096

<0.0102

<0.0100

0.392

0.132

0.239

4.93

4.73

<0.0095

0.0364

0.181

0.237

8.09

<0.0096

<0.0091

0.228

<0.0093

Dibenz(a,h)anthracene

mg/kg

0.015

NA

<0.0098

<0.0093

<0.0097

<0.0097

0.0123 J

0.165

<0.0102

0.0741

<0.0096

<0.0102

<0.0100

0.103

0.0241

0.0289

0.827

0.565 J

<0.0095

<0.0097

0.0296

0.0449

1.37

<0.0096

<0.0091

0.0525

<0.0093

Fluoranthene

mg/kg

2290

88.8179

<0.0098

<0.0093

<0.0097

<0.0097

0.0490

2.52

0.0136 J

0.383

<0.0096

<0.0102

<0.0100

0.510

0.194

0.0997

9.87

10.6

<0.0095

0.0609

0.316

0.369

16.7

<0.0096

<0.0091

0.171

<0.0093

Fluorene

mg/kg

2290

14.8148

<0.0098

<0.0093

<0.0097

<0.0097

<0.0102

0.268

<0.0102

<0.0200

<0.0096

<0.0102

<0.0100

0.0208

<0.0111

<0.0095

1.02

0.860

<0.0095

<0.0097

0.0250

0.0149 J

1.25

<0.0096

<0.0091

<0.0091

<0.0093

Indeno(1,2,3-cd)pyrene

mg/kg

0.148

NA

<0.0098

<0.0093

<0.0097

<0.0097

0.0230

0.487

<0.0102

0.174

<0.0096

<0.0102

<0.0100

0.252

0.0819

0.0304

2.01

1.92

<0.0095

0.0141 J

0.0676

0.101

3.46

<0.0096

<0.0091

0.112

<0.0093

Naphthalene

mg/kg

5.15

0.6587

<0.0098

<0.0093

<0.0097

<0.0097

0.0197 J

0.593

<0.0102

<0.0200

<0.0096

<0.0102

<0.0100

0.0114 J

0.0214 J

0.0932

<0.393

1.01

<0.0095

<0.0097

0.0438

0.0448

1.62

<0.0096

<0.0091

0.248

<0.0093

Phenanthrene

mg/kg

NA

NA

<0.0098

<0.0093

<0.0097

<0.0097

0.0780

2.38

<0.0102

0.212

<0.0096

<0.0102

<0.0100

0.313

0.140

0.280

9.47

9.56

<0.0095

0.0381

0.367

0.335

18.1

<0.0096

<0.0091

0.136

<0.0093

Pyrene

mg/kg

1720

54.4725

<0.0098

<0.0093

<0.0097

<0.0097

0.0531

1.99

0.0136 J

0.596

<0.0096

<0.0102

<0.0100

0.449

0.200

0.112

7.70

7.80

<0.0095

0.0482

0.271

0.391

14.2

<0.0096

<0.0091

0.179

<0.0093

NA = Not Applicable
mg/L & mg/kg = PPM
Bold exceeds WDNR RR Spreadsheet values for Direct Contact (non-industrial) (DC), adopted from USEPA Regional Screening Level Calculator proposed for WI NR 720
Italic exceeds WDNR RR Spreadsheet values for Protection of Groundwater (GW), adopted from USEPA Regional Screening Level Calculator proposed for WI NR 720

Table 1C
METALS IN SOIL
PHASE II ENVIRONMENTAL SITE ASSESSMENT
202 SOUTH THORNTON AVENUE, MADISON, WI
Parameter

Units

DC

GW

TCLP

GP-1

GP-2

GP-3

GP-4

GP-5

GP-10

GP-11

GP-12

GP-13

GP-14

GP-15

GP-16

GP-18(D) GP-18(S)

Sample Date 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/13/13 6/13/13 6/13/13
Sample Depth

0-2

0-2

1-2

0-2

1-2

2-4

1-3

1-2

2-3

1-2

2-4

1-2

2-4

2-4

2-4

4-6

6/13/13

6/13/13

5-7

2-4

GP-22

GP-26

6/14/13 6/14/13
1-3

1-2

Method EPA 6010


Arsenic

mg/kg

0.39 (8*)

0.584 (8*)

NA

50.6

6.4

8.6

5.6

24.5

5.00

2.6

4.9

4.7

19.0

2.1

15.4

2.0 J

7.3

14.2

3.2

5.8

7.1

Barium

mg/kg

15,300

164.8

NA

96.6

72.1

68.7

54.7

24.3

14.6

101

124

85.8

134

72.4

65.3

45.4

60.8

Cadmium

mg/kg

70.2

0.752

NA

1.8

0.19 J

0.41 J

0.39 J

0.68

0.23 J

0.78

0.32 J

3.1

2.1

0.72

2.9

0.61

0.37 J

Chromium

mg/kg

100,000

360,000

NA

23.4

17.9

13.5

13.6

15.4

5.8

14.3

12.1

30.9

13.8

19.8

9.6

14.7

13.4

Lead

mg/kg

400

27

NA

310

8.9

25.6

11.7

21.2

6.9

69.9

200

404

2.5

1190

3.6

66.4

99.9

99.8

152

82.7

186

Selenium

mg/kg

391

0.52

NA

<0.68

<0.58

<0.61

<0.67

1.8 J

<0.64

<0.68

<0.67

<0.66

<0.61

<0.67

<0.66

<0.55

<0.62

Silver

mg/kg

391

0.8497

NA

0.30 J

<0.21

<0.22

<0.24

0.32 J

<0.23

<0.25

<0.24

0.47 J

0.43 J

<0.24

1.2

<0.20

<0.22

3.13

0.208

NA

0.11

0.039

0.012

0.023

0.45

0.024

0.10

0.021

0.10

0.068

0.033

0.10

0.070

0.036

0.088

0.34

Method EPA 7471


Mercury

mg/kg

Method EPA 1311 - Toxicity Characteristic Leaching Procedure


Lead

mg/L

NA

NA

* WDNR utilizes Background Threshold Value of 8ppm based on 2012 USGS Report.
Bold exceeds WDNR RR Spreadsheet values for Direct Contact (non-industrial) (DC), adopted from USEPA Regional Screening Level Calculator proposed for WI NR 720
Italic exceeds WDNR RR Spreadsheet values for Protection of Groundwater (GW), adopted from USEPA Regional Screening Level Calculator proposed for WI NR 720
- not analyzed
NA - not applicable
TCLP - toxicity characteristic leaching procedure; regulatory standards from WI NR 661, Table 2

Table 1D
POLYCHLORINATED BIPHENYLS (PCBs) IN SOIL
PHASE II ENVIRONMENTAL SITE ASSESSMENT
202 SOUTH THORNTON AVENUE, MADISON, WI
Parameter

Units

DC

GW

GP-1

Sample Date 6/14/13


Sample Depth

5-7

GP-2

GP-3

GP-4

GP-5

GP-19

6/14/13

6/14/13

6/14/13

6/14/13

6/14/13

6/13/13

0-2

5-7

5-7

5-7

1-2

1-3

Method EPA 8082


PCB, Total

mg/kg

0.222

0.0094

<0.0294 <0.0343

0.125

<0.0290 <0.0305 <0.0356 <0.0289

PCB-1016 (Aroclor 1016)

mg/kg

3.93

NA

<0.0294 <0.0343

<0.0291

<0.0290 <0.0305 <0.0356 <0.0289

PCB-1221 (Aroclor 1221)

mg/kg

0.159

NA

<0.0294 <0.0343

<0.0291

<0.0290 <0.0305 <0.0356 <0.0289

PCB-1232 (Aroclor 1232)

mg/kg

0.159

NA

<0.0294 <0.0343

<0.0291

<0.0290 <0.0305 <0.0356 <0.0289

PCB-1242 (Aroclor 1242)

mg/kg

0.222

NA

<0.0294 <0.0343

<0.0291

<0.0290 <0.0305 <0.0356 <0.0289

PCB-1248 (Aroclor 1248)

mg/kg

0.222

NA

<0.0294 <0.0343

<0.0291

<0.0290 <0.0305 <0.0356 <0.0289

PCB-1254 (Aroclor 1254)

mg/kg

0.222

NA

<0.0294 <0.0343

0.0834

<0.0290 <0.0305 <0.0356 <0.0289

PCB-1260 (Aroclor 1260)

mg/kg

0.222

NA

<0.0294 <0.0343

0.0417 J <0.0290 <0.0305 <0.0356 <0.0289

Bold exceeds WDNR RR Spreadsheet values for Direct Contact (non-industrial) (DC), adopted from USEPA Regional Screening
Level Calculator proposed for WI NR 720
Italic exceeds WDNR RR Spreadsheet values for Protection of Groundwater (GW), adopted from USEPA Regional Screening Level
Calculator proposed for WI NR 720
NA - not applicable

Table 2
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
PHASE II ENVIRONMETNAL SITE ASSESSMENT
202 SOUTH THORNTON AVENUE, MADISON, WISCONSIN

Parameter

Units

WI NR 140 GW Quality
Preventive Action Limits

WI NR 140 GW Quality
Enforcement Standards

Sample Date

GP-1
6/14/13

GP-20

GP-21

GP-23

GP-25

GP-26

6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13 6/14/13

GP-2

GP-3

GP-4

GP-6

GP-16

GP-18

6/14/13

6/14/13

6/14/13

6/14/13

Method EPA 6010


Arsenic, Dissolved

ug/L

10

Barium, Dissolved

ug/L

400

2000

<4.2
62.5

5.0
61.8

Cadmium, Dissolved

ug/L

.5

Chromium, Dissolved

ug/L

10

Lead, Dissolved

ug/L

Selenium, Dissolved
Silver, Dissolved

69.7

11.2
160

<0.48
2.9 J

<0.48

100

<1.4

4.6

1.2

184

36.5

1.5

15

<2.7

<2.7

81.0

35.5

45.4

38.4

<5.2

15.1
6.7 J

ug/L

10

50

<5.2

<5.2

ug/L

10

50

<1.7

<1.7

<1.7

3.0 J

ug/L

.2

<0.10

<0.10

0.34

<0.10

PCB, Total

ug/L

.003

.03

PCB-1016 (Aroclor 1016)

ug/L

N/A

N/A

<0.29

<0.28

<0.27

<0.31

<0.29

<0.28

<0.27

<0.31

PCB-1221 (Aroclor 1221)

ug/L

N/A

N/A

<0.29

<0.28

<0.27

<0.31

PCB-1232 (Aroclor 1232)

ug/L

PCB-1242 (Aroclor 1242)

ug/L

N/A

N/A

<0.29

<0.28

<0.27

<0.31

N/A

N/A

<0.29

<0.28

<0.27

<0.31

PCB-1248 (Aroclor 1248)

ug/L

N/A

N/A

<0.29

<0.28

<0.27

<0.31

PCB-1254 (Aroclor 1254)

ug/L

N/A

N/A

<0.29

<0.28

<0.27

<0.31

PCB-1260 (Aroclor 1260)

ug/L

N/A

N/A

<0.29

<0.28

<0.27

<0.31

596

Method EPA 7470


Mercury, Dissolved

Method EPA 8082

Method EPA 8270 by HVI


1-Methylnaphthalene

ug/L

N/A

N/A

0.011 J

0.015 J

0.0093 J

0.015 J

0.050

0.061 J

0.012 J

0.021 J

0.015 J

0.036 J

2-Methylnaphthalene

ug/L

N/A

N/A

0.015 J

0.021 J

0.014 J

0.029 J

0.025 J

0.068 J

0.020 J

0.036 J

0.032 J

0.051

Acenaphthene

ug/L

N/A

N/A

0.0095 J

0.0060 J

0.10 J

N/A

N/A

<0.0035

0.25 J

Anthracene

ug/L

600

3000

<0.0038
0.016 J

0.0049 J 0.0041 J <0.0039 0.027 J


<0.0035 0.0042 J <0.0035 0.0082 J

ug/L

<0.0042
0.0051 J

<0.0038

Acenaphthylene

<0.0039
0.0037 J

<0.0052

<0.0048

1.0

0.012 J

0.022 J

0.0051 J

0.032 J

0.025 J

0.032 J

0.0082 J

0.044 J

<0.0049

<0.0038
0.011 J

Benzo(a)anthracene

ug/L

N/A

N/A

0.029 J

<0.0048

0.034 J

<0.0051

<0.0047

1.6

Benzo(a)pyrene

ug/L

.02

.2

0.027

<0.0050

0.031

<0.0053

<0.0049

1.3

0.022

0.010 J

0.0057 J

0.040

Benzo(b)fluoranthene

ug/L

.02

.2

<0.0068

<0.0067

N/A

N/A

<0.0081

<0.0087

<0.0080

0.98
0.71

0.038
0.020 J

0.048
0.026 J

<0.0068

ug/L

0.032
0.023 J

<0.0073

Benzo(g,h,i)perylene

0.026
0.020 J

0.043
0.027 J

Benzo(k)fluoranthene

ug/L

N/A

N/A

0.022 J

<0.010

0.031 J

<0.011

<0.010

1.1

0.034 J

ug/L

.02

.2

<0.0062

0.041

<0.0067

<0.0062

ug/L

N/A

N/A

<0.0055

ug/L

80

400

0.077

3.0

0.13

Fluorene

ug/L

80

400

<0.0052
0.0096 J 0.0056 J

<0.0059 <0.0054
0.0065 J 0.0082 J

0.054
0.012 J

Fluoranthene

<0.0059
0.079

1.5
0.23 J

Dibenz(a,h)anthracene

0.035
0.0078 J

0.037 J
<0.010
0.013 J
0.048
0.066
0.0083 J 0.0093 J <0.0055
0.065
0.19
0.017 J

0.040 J

Chrysene

0.0054 J

<0.0042

0.0047 J

0.37 J

0.0071 J

0.013 J

0.0043 J

0.027 J

Indeno(1,2,3-cd)pyrene

ug/L

N/A

N/A

0.016 J

0.018 J

0.018 J

0.021 J

100

0.049 J

0.049

0.095 J

0.041 J

0.038 J

<0.0059
0.050

0.023 J

10

<0.0058
0.024 J

0.64

ug/L

<0.0063
0.095

Naphthalene

<0.0059
0.072

0.16

0.013 J

0.062

0.0095 J

0.018 J

2.9

0.073

0.15

0.024 J

0.18

<0.0053

0.081

0.0081 J 0.0094 J

2.8

0.062

0.18

0.019 J

0.13

Phenanthrene

ug/L

N/A

N/A

0.069

Pyrene

ug/L

50

250

0.074

N/A = Not Applicable


ug/L & ug/kg = PPB
- not analyzed
Bold values exceed NR 140 ES
Italic values exceed NR 140 PAL

<0.0081

Appendix A
Phase I ESA Sanborn Maps

State Preservation Storage Facility


202 S Thornton
Madison, WI 53703
Inquiry Number: 3613445.3
May 22, 2013

Certified Sanborn Map Report

Certified Sanborn Map Report


Site Name:
State Preservation Storage
202 S Thornton
Madison, WI 53703

Client Name:
Ayres Associates
1802 Pankratz Street
Madison, WI 53704

EDR Inquiry # 3613445.3

Contact: Tom Gaieck

5/22/13

The complete Sanborn Library collection has been searched by EDR, and fire insurance maps covering the target
property location provided by Ayres Associates were identified for the years listed below. The certified Sanborn Library
search results in this report can be authenticated by visiting www.edrnet.com/sanborn and entering the certification
number. Only Environmental Data Resources Inc. (EDR) is authorized to grant rights for commercial reproduction of
maps by Sanborn Library LLC, the copyright holder for the collection.

Certified Sanborn Results:


Site Name:
Address:
City, State, Zip:
Cross Street:
P.O. #
Project:
Certification #

State Preservation Storage Facility


202 S Thornton
Madison, WI 53703
NA
8.19
018D-4119-911F

Maps Provided:

Sanborn Library search results


Certification # 018D-4119-911F

The Sanborn Library includes more than 1.2 million


Sanborn fire insurance maps, which track historical
property usage in approximately 12,000 American
cities and towns. Collections searched:

1986
1950
1942
1908

Library of Congress

1902

University Publications of America

1898

EDR Private Collection


The Sanborn Library LLC Since 1866

Limited Permission To Make Copies


Ayres Associates (the client) is permitted to make up to THREE photocopies of this Sanborn Map transmittal and each fire insurance map
accompanying this report solely for the limited use of its customer. No one other than the client is authorized to make copies. Upon request made
directly to an EDR Account Executive, the client may be permitted to make a limited number of additional photocopies. This permission is
conditioned upon compliance by the client, its customer and their agents with EDR's copyright policy; a copy of which is available upon request.

Disclaimer - Copyright and Trademark notice


This Report contains certain information obtained from a variety of public and other sources reasonably available to Environmental Data Resources, Inc. It cannot be
concluded from this Report that coverage information for the target and surrounding properties does not exist from other sources. NO WARRANTY EXPRESSED OR
IMPLIED, IS MADE WHATSOEVER IN CONNECTION WITH THIS REPORT. ENVIRONMENTAL DATA RESOURCES, INC. SPECIFICALLY DISCLAIMS THE
MAKING OF ANY SUCH WARRANTIES, INCLUDING WITHOUT LIMITATION, MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR PURPOSE. ALL
RISK IS ASSUMED BY THE USER. IN NO EVENT SHALL ENVIRONMENTAL DATA RESOURCES, INC. BE LIABLE TO ANYONE, WHETHER ARISING OUT OF
ERRORS OR OMISSIONS, NEGLIGENCE, ACCIDENT OR ANY OTHER CAUSE, FOR ANY LOSS OF DAMAGE, INCLUDING, WITHOUT LIMITATION, SPECIAL,
INCIDENTAL CONSEQUENTIAL, OR EXEMPLARY DAMAGES. ANY LIABILITY ON THE PART OF ENVIRONMENTAL DATA RESOURCES, INC. IS STRICTLY
LIMITED TO A REFUND OF THE AMOUNT PAID FOR THIS REPORT. Purchaser accepts this Report "AS IS". Any analyses, estimates, ratings, environmental risk
levels or risk codes provided in this Report are provided for illustrative purposes only, and are not intended to provide, nor should they be interpreted as providing
any facts regarding, or prediction or forecast of, any environmental risk for any property. Only a Phase I Environmental Site Assessment performed by an
environmental professional can provide information regarding the environmental risk for any property. Additionally, the information provided in this Report is not to be
construed as legal advice.
Copyright 2013 by Environmental Data Resources, Inc. All rights reserved. Reproduction in any media or format, in whole or in part, of any report or map of
Environmental Data Resources, Inc., or its affiliates, is prohibited without prior written permission.
EDR and its logos (including Sanborn and Sanborn Map) are trademarks of Environmental Data Resources, Inc. or its affiliates. All other trademarks used herein are
the property of their respective owners.

3613445 - 3

page 2

Sanborn Sheet Thumbnails


This Certified Sanborn Map Report is based upon the following Sanborn
Fire Insurance map sheets.

1986 Source Sheets

Volume 1, Sheet 79

Volume 1, Sheet 81

1950 Source Sheets

Volume 1, Sheet 79

Volume 1, Sheet 81

1942 Source Sheets

Volume 1, Sheet 79

Volume 1, Sheet 81

1908 Source Sheets

Volume 1, Sheet 3

Volume 1, Sheet 4

3613445 - 3

page 3

1902 Source Sheets

Volume 1, Sheet 17

Volume 1, Sheet 19

1898 Source Sheets

Volume 1, Sheet 27

3613445 - 3

page 4

018D-4119-911F

1986 Certified Sanborn Map

Site Name:
Address:

State Preservation Storage Facility


202 S Thornton

City, ST, ZIP:

Madison WI 53703

Client:

Ayres Associates

EDR Inquiry:
Order Date:
Certification #

3613445.3
5/22/2013 1:03:00 PM
018D-4119-911F

Copyright:

This Certified Sanborn Map combines the following sheets.


Outlined areas indicate map sheets within the collection.

0 Feet

150

1986

300

600

Volume 1, Sheet 79
Volume 1, Sheet 81

3613445 - 3

page 5

018D-4119-911F

1950 Certified Sanborn Map

Site Name:
Address:

State Preservation Storage Facility


202 S Thornton

City, ST, ZIP:

Madison WI 53703

Client:

Ayres Associates

EDR Inquiry:
Order Date:
Certification #

3613445.3
5/22/2013 1:03:00 PM
018D-4119-911F

Copyright:

This Certified Sanborn Map combines the following sheets.


Outlined areas indicate map sheets within the collection.

0 Feet

150

1950

300

600

Volume 1, Sheet 79
Volume 1, Sheet 81

3613445 - 3

page 6

018D-4119-911F

1942 Certified Sanborn Map

Site Name:
Address:

State Preservation Storage Facility


202 S Thornton

City, ST, ZIP:

Madison WI 53703

Client:

Ayres Associates

EDR Inquiry:
Order Date:
Certification #

3613445.3
5/22/2013 1:03:00 PM
018D-4119-911F

Copyright:

This Certified Sanborn Map combines the following sheets.


Outlined areas indicate map sheets within the collection.

0 Feet

150

1942

300

600

Volume 1, Sheet 79
Volume 1, Sheet 81

3613445 - 3

page 7

1908 Certified Sanborn Map


Site Name:
Address:

State Preservation Storage Facility


202 S Thornton

City, ST, ZIP:

Madison WI 53703

Client:

Ayres Associates

EDR Inquiry:
Order Date:
Certification #

3613445.3
5/22/2013 1:03:00 PM
018D-4119-911F

Copyright:

1908

018D-4119-911F

This Certified Sanborn Map combines the following sheets.


Outlined areas indicate map sheets within the collection.

0 Feet

150

300

600

Volume 1, Sheet 3
Volume 1, Sheet 4

3613445 - 3

page 8

1902 Certified Sanborn Map


Site Name:
Address:

State Preservation Storage Facility


202 S Thornton

City, ST, ZIP:

Madison WI 53703

Client:

Ayres Associates

EDR Inquiry:
Order Date:
Certification #

3613445.3
5/22/2013 1:03:00 PM
018D-4119-911F

Copyright:

1902

018D-4119-911F

This Certified Sanborn Map combines the following sheets.


Outlined areas indicate map sheets within the collection.

0 Feet

150

300

600

Volume 1, Sheet 17
Volume 1, Sheet 19

3613445 - 3

page 9

018D-4119-911F

1898 Certified Sanborn Map

Site Name:
Address:

State Preservation Storage Facility


202 S Thornton

City, ST, ZIP:

Madison WI 53703

Client:

Ayres Associates

EDR Inquiry:
Order Date:
Certification #

3613445.3
5/22/2013 1:03:00 PM
018D-4119-911F

Copyright:

This Certified Sanborn Map combines the following sheets.


Outlined areas indicate map sheets within the collection.

0 Feet

150

1898

300

600

Volume 1, Sheet 27

3613445 - 3

page 10

Appendix B
Field Procedures

Field Procedures
This appendix describes field work procedures for this project. Where applicable, these
procedures are performed in accordance with Wisconsin Department of Natural Resources
(WDNR), Wisconsin Administrative Code requirements, American Society for Testing and
Materials (ASTM) standards, or accepted engineering or geologic standards.

Soil Probe Installation


Soil probes are installed by the contractor, in accordance the procedures described in
Wisconsin Administrative Code, Chapter NR 141. Soil probe sampling consists of installing a
hydraulically-driven steel 2-inch-diameter rod. The steel sampling device at the end of the rods
is 5 feet long and is assembled with a disposable plastic liner for sample collection. Samples are
collected continuously using the following method:
When the rod is positioned at the top of the desired sampling interval, the piston stop pin
is removed, and the sampler is driven the desired sample interval to encase the soil
sample in the plastic liner. The rods are then retracted from the hole and brought to the
surface. The plastic liner is removed from the sample rod that contains the undisturbed
soil sample. The liner is split open with a clean utility knife and the soil is classified and
then transferred to laboratory and field screening containers as described in the soil
sample collection section in this appendix.
An Ayres Associates representative is present during the field work to establish soil probe
locations, determine soil sample intervals, classify soils using the Unified Soil Classification
System (USCS), log soil probes, and collect and screen soil samples. Soil classification
information is recorded on the soil boring logs (WDNR Form 4400-122), and copies are included
in the site investigation report.
Sampling equipment is decontaminated as described under decontamination in this appendix.
All probe equipment is steam cleaned before reuse. Plastic liners are disposable, and are not
reused.
When the sampling is completed, soil probe holes are filled with bentonite and the surface
material restored. Soil probe abandonment details are described on WDNR Form 3300-5W, and
copies are included in the site investigation report. Soil cuttings generated during drilling are
containerized in 5-gallon buckets on site and are labeled with the date and the soils origin.
Because of the small quantity, these cuttings are typically disposed of in a dumpster.

Soil Sample Collection


Ayres Associates personnel retrieve soil samples from the sampling equipment using a clean
wooden spatula or a clean 20- to 30-milliliter polyethylene syringe, and avoid collecting slough
materials.
At each sampling point, we will collect samples for potential laboratory analysis. Soil collection
methods used are in accordance with WDNR's Leaking Underground Storage Tank and
Petroleum Analytical and Quality Assurance Guidance, July 1993, PUBL SW-130 93.

During collection of laboratory grade samples, we place the required amount of soil in the
laboratory provided container. We then place the selected laboratory samples on ice in a cooler
immediately after collection, and keep samples cool until analysis by the laboratory.
The specific collection method, including the size and type of containers used, are dependent
on the type of analysis to be conducted:

Percent solids (moisture analysis) and RCRA metals - Fill a 125-milliliter plastic jar with
soil.

VOCs Place 10 cubic centimeters of soil in pre-weighed VOA vial with methanol
preservative.

PAHs and PCBs Fill 4-ounce amber jar.

Ayres Associates initiates a chain-of-custody log, WDNR Form 4400-151 or equivalent, when
the samples are collected. We record the project name and number, sampler's name(s), sample
location and depth, sample number, date and time of collection, type of sample, method of
sample collection, number of containers, type of preservation, type of chemical analyses to be
performed, field screening results (soils only), and additional remarks about the sample if
needed on the chain-of-custody log. The individual(s) handling the samples signs and dates the
log. Shipment arrangements are made so the samples arrive within the appropriate shipping
time allowed by WDNR guidance.

Soil Laboratory Analysis


Samples are analyzed by a laboratory certified by the WDNR. Analytical methods used are as
follows:
PARAMETER

METHOD

MDL

VOCs

EPA Method 8260

25 g/kg

PAHs

EPA Method 8270

0.15-1.2 mg/kg

RCRA Metals

EPA Method 6010/7410

0.1 mg/kg

PCBs

EPA Method 8082

34.3 mg/kg

Percent Moisture

ASTM-D2974-87

0.10 mg/kg

Headspace Screening (PID)


Headspace screening samples are qualitatively screened for organic vapors using a photo
ionization detector (PID) equipped with a 10.6 eV lamp. Before we use the PID, it is calibrated
using 100 ppm isobutylene gas.

After allowing the soil sample to equilibrate in accordance with WDNR guidance, we screen the
total organic vapors in the jar by piercing the lid and then immediately inserting the PID probe.
Meter responses are recorded as instrument units (i.u.s) isobutylene gas equivalents. The
highest meter response is recorded in the field notes and/or on the soil boring logs. The PID
responses are a relative indication of total ionizable volatile organic compounds present in the
atmosphere surrounding the sample and do not necessarily represent the concentration of any
specific compound.

Groundwater Sample Collection from Soil Probes


Ayres Associates personnel conduct ground water sampling in accordance with the procedures
described in the Groundwater Sampling Field Manual (PUBL-DG-038 96) and the Groundwater
Sampling Desk Reference (PUBL-DG-037 96).
Following soil probe installation, a screened 1 PVC well casing is driven to the water table. A
1/8-inch-diameter disposable high density polyethylene hose is inserted into the well and
connected to a peristaltic pump to collect water samples directly into containers. Alternatively, a
disposable plastic bailer may be used to collect water. We continue this process until enough
volume is retrieved to fill all sample containers.
Samples are collected for analysis of the following parameters:

RCRA MetalsCollect 250 milliliters in a disposable plastic container and store on ice.
Filter sample through a 0.45-micron disposable filter within 2 hours of collection. Pour
the filtrate into a polyethylene jar and preserve the sample with nitric acid. Store sample
in an ice slurry.

Polynuclear aromatic hydrocarbons (PAH) and PCBsFill a 1-liter amber jar that has a
cap (no septum). No preservative is added to this sample.

We place the samples on ice in a cooler; enclose a completed WDNR chain-of-custody record,
Form 4400-151 or equivalent; and ship the cooler to the laboratory so it arrives within the
shipping time allowed by WDNR.

Groundwater Laboratory Analysis


Samples are analyzed by a laboratory certified by the WDNR. Analytical methods used are as
follows:
PARAMETER

METHOD

LOD

LOQ

PAHs

EPA Method 8270

0.0039-0.010 g/L

0.045 g/L

RCRA Metals

EPA Method 6010/7410

0.1-5.2 g/L

0.2-20 g/L

PCBs

EPA Method 8082

0.29 g/L

0.58 g/L

Appendix C
Phase II ESA
Soil Probe Logs and Abandonment Forms

Appendix D
Laboratory Analytical Results Soil

#=CL#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

LIMS USE: FR - MITCHELL BANACH


LIMS OBJECT ID: 4079685

June 19, 2013

Mitchell Banach
Ayres & Associates, Inc.
3433 Oakwood Hills Parkway
Eau Claire, WI 547017698

RE: Project: 19-0291.20 DEPT OF ADMIN.


Pace Project No.: 4079685
Dear Mitchell Banach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 15, 2013. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,

Steven Mleczko
steve.mleczko@pacelabs.com
Project Manager

Enclosures

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 1 of 60

#=CP#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

CERTIFICATIONS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Green Bay Certification IDs


1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334

New York Certification #: 11888


North Dakota Certification #: R-150
South Carolina Certification #: 83006001
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 2 of 60

#=SS#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE SUMMARY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Lab ID

Sample ID

Matrix

Date Collected

Date Received

4079685001

GP-12

Solid

06/14/13 00:00

06/15/13 09:45

4079685002

GP-15

Solid

06/13/13 00:00

06/15/13 09:45

4079685003

GP-16

Solid

06/13/13 00:00

06/15/13 09:45

4079685004

GP-17(S)

Solid

06/13/13 00:00

06/15/13 09:45

4079685005

GP-17(D)

Solid

06/13/13 00:00

06/15/13 09:45

4079685006

GP-18(S)

Solid

06/13/13 00:00

06/15/13 09:45

4079685007

GP-18(D)

Solid

06/13/13 00:00

06/15/13 09:45

4079685008

GP-19

Solid

06/13/13 00:00

06/15/13 09:45

4079685009

GP-20

Solid

06/13/13 00:00

06/15/13 09:45

4079685010

GP-20

Water

06/13/13 00:00

06/15/13 09:45

4079685011

GP-21

Solid

06/13/13 00:00

06/15/13 09:45

4079685012

GP-21

Water

06/13/13 00:00

06/15/13 09:45

4079685013

GP-23

Solid

06/13/13 00:00

06/15/13 09:45

4079685014

GP-23

Water

06/13/13 00:00

06/15/13 09:45

4079685015

GP-25

Solid

06/14/13 00:00

06/15/13 09:45

4079685016

GP-25

Water

06/14/13 00:00

06/15/13 09:45

4079685017

TRIP BLANK

Water

06/13/13 00:00

06/15/13 09:45

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 3 of 60

#=SA#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE ANALYTE COUNT


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Lab ID

Sample ID

4079685001

GP-12

4079685002

4079685003

4079685004

4079685005

4079685006

4079685007

4079685008

GP-15

GP-16

GP-17(S)

GP-17(D)

GP-18(S)

GP-18(D)

GP-19

Method

Analysts

EPA 6010

DLB

Analytes
Reported

Laboratory

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8082

BLM

10

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

4079685009

GP-20

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

4079685010

GP-20

EPA 8270 by HVI

RJN

20

PASI-G

4079685011

GP-21

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

4079685012

GP-21

EPA 8270 by HVI

RJN

20

PASI-G

4079685013

GP-23

ASTM D2974-87

SKW

PASI-G

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 4 of 60

#=SA#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE ANALYTE COUNT


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Lab ID

Sample ID

4079685015

GP-25

4079685017

TRIP BLANK

Analytes
Reported

Method

Analysts

Laboratory

ASTM D2974-87

SKW

PASI-G

EPA 8260

HNW

64

PASI-G

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 5 of 60

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079685001

GP-12

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Percent Moisture

4079685002

GP-15

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Percent Moisture

4079685003

GP-16

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Silver
Mercury
Percent Moisture

4079685004

GP-17(S)

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM

Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene

Units

Report Limit

Analyzed

4.7
124
0.32J
12.1
200
0.021
<9.5
18.0J
40.1
96.2
62.4
91.4
52.4
69.0
239
28.9
99.7
30.4
144
183
93.2
280
112
12.1

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

2.3
0.57
0.57
0.57
1.1
0.0067
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
0.10

06/18/13 13:39
06/18/13 13:39
06/18/13 13:39
06/18/13 13:39
06/18/13 13:39
06/18/13 07:58
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/17/13 13:02

7.3
72.4
0.72
19.8
66.4
0.033
18.1

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%

2.3
0.56
0.56
0.56
1.1
0.0078
0.10

06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 08:00
06/17/13 16:52

14.2
65.3
2.9
9.6
99.9
1.2
0.10
12.0

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%

11.1
0.56
2.8
0.56
5.6
1.1
0.0074
0.10

06/19/13 09:15
06/18/13 13:51
06/19/13 09:15
06/18/13 13:51
06/19/13 09:15
06/18/13 13:51
06/18/13 08:02
06/17/13 16:52

11.0J
25.0
25.1
36.3

ug/kg
ug/kg
ug/kg
ug/kg

19.3
19.3
19.3
19.3

06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34

Qualifiers

M0

M0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 6 of 60

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079685004

GP-17(S)

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Fluoranthene
Indeno(1,2,3-cd)pyrene
Phenanthrene
Pyrene
Percent Moisture

4079685005

GP-17(D)

ASTM D2974-87

Percent Moisture

4079685006

GP-18(S)

EPA 6010
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Lead
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Percent Moisture

15.3J
14.9J
36.4
60.9
14.1J
38.1
48.2
13.7

Units

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

12.6 %

4079685007

GP-18(D)

EPA 6010
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM

Lead
Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene

Report Limit

Analyzed

19.3
19.3
19.3
19.3
19.3
19.3
19.3
0.10

06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/17/13 13:02

0.10

06/17/13 13:02

152
17.3J
23.7
69.1
176
188
153
118
176
237
44.9
369
14.9J
101
74.7
79.5
44.8
335
391
14.4

mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

1.1
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
0.10

06/18/13 13:54
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/17/13 13:03

99.8
25.0
84.4
136
133
149
75.1
109
181
29.6
316
25.0
67.6
48.6

mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

1.1
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5

06/18/13 13:56
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 7 of 60

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079685007

GP-18(D)

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Percent Moisture

4079685008

GP-19

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8260
ASTM D2974-87

Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Naphthalene
Percent Moisture

4079685009

GP-20

ASTM D2974-87

Percent Moisture

Units

GP-20

EPA 8270 by HVI


EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene

Analyzed

56.0
43.8
367
271
22.4

ug/kg
ug/kg
ug/kg
ug/kg
%

21.5
21.5
21.5
21.5
0.10

06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/17/13 13:03

1020
3490
6240
6060
7460
3750
3880
8090
1370
16700
1250
3460
882J
502J
1620
18100
14200
64.9J
13.4

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

962
962
962
962
962
962
962
962
962
962
962
962
962
962
962
962
962
69.3
0.10

06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/17/13 16:04
06/17/13 13:03

0.10

06/17/13 13:03

0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045

06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21

13.1 %

4079685010

Report Limit

0.0049J
0.012J
0.025J
0.022J
0.038J
0.020J
0.034J
0.048
0.0083J
0.065
0.0071J
0.018J
0.012J
0.020J
0.041J
0.073
0.062

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 8 of 60

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079685011

GP-21

ASTM D2974-87

Percent Moisture

4079685012

GP-21

EPA 8270 by HVI


EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene

4079685013

GP-23

8.1 %

ASTM D2974-87

Percent Moisture

4079685014

GP-23

EPA 8270 by HVI


EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Chrysene
Fluoranthene
Fluorene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene

4079685015

GP-25

ASTM D2974-87

Percent Moisture

Units

0.0041J
0.0042J
0.022J
0.032J
0.010J
0.048
0.026J
0.037J
0.066
0.0093J
0.19
0.013J
0.021J
0.021J
0.036J
0.038J
0.15
0.18

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

14.3 %

0.0051J
0.0082J
0.0057J
0.013J
0.017J
0.0043J
0.015J
0.032J
0.050
0.024J
0.019J

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

13.4 %

4079685016

GP-25

EPA 8270 by HVI


EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene

0.027J
0.0082J
0.032J
0.044J
0.040J
0.043J
0.027J

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

Report Limit

Analyzed

0.10

06/17/13 13:03

0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045

06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39

0.10

06/17/13 13:03

0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045

06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57

0.10

06/17/13 13:03

0.049
0.049
0.049
0.049
0.049
0.049
0.049

06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 9 of 60

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079685016

GP-25

EPA 8270 by HVI


EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene

0.040J
0.054
0.012J
0.13
0.027J
0.023J
0.036J
0.051
0.16
0.18
0.13

Units

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

Report Limit

0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049

Analyzed

Qualifiers

06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 10 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-12

Lab ID: 4079685001

Collected: 06/14/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


4.7
124
0.32J
12.1
200
<0.67
<0.24

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.3
0.57
0.57
0.57
1.1
2.3
1.1

0.61
0.099
0.058
0.14
0.33
0.67
0.24

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 13:39
06/18/13 13:39
06/18/13 13:39
06/18/13 13:39
06/18/13 13:39
06/18/13 13:39
06/18/13 13:39

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

M0

M0

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.021 mg/kg

0.0067

0.0033

06/17/13 16:14 06/18/13 07:58 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.5
18.0J
40.1
96.2
62.4
91.4
52.4
69.0
239
28.9
99.7
<9.5
30.4
144
183
93.2
280
112

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

57 %
59 %

19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0
19.0

9.5
9.5
9.5
9.5
3.4
9.5
9.5
3.3
9.5
9.5
9.5
9.5
9.5
3.4
9.5
9.5
9.5
9.5

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42
06/18/13 17:42

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 17:42 321-60-8


06/18/13 06:50 06/18/13 17:42 1718-51-0

Analytical Method: ASTM D2974-87


12.1 %

0.10

0.10

06/17/13 13:02

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 11 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-15

Lab ID: 4079685002

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


7.3
72.4
0.72
19.8
66.4
<0.67
<0.24

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.3
0.56
0.56
0.56
1.1
2.3
1.1

0.61
0.098
0.057
0.14
0.33
0.67
0.24

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.033 mg/kg

0.0078

0.0039

06/17/13 16:14 06/18/13 08:00 7439-97-6

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 12 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-15

Lab ID: 4079685002

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47
06/17/13 13:47

10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

113 %
115 %
100 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

57-130
54-133
49-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

1
1
1

06/17/13 12:54 06/17/13 13:47 1868-53-7


06/17/13 12:54 06/17/13 13:47 2037-26-5
06/17/13 12:54 06/17/13 13:47 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

Analytical Method: ASTM D2974-87


18.1 %

0.10

0.10

06/17/13 16:52

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 13 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-16

Lab ID: 4079685003

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


14.2
65.3
2.9
9.6
99.9
<0.66
1.2

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

11.1
0.56
2.8
0.56
5.6
2.2
1.1

3.0
0.096
0.28
0.14
1.6
0.66
0.24

5
1
5
1
5
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/19/13 09:15
06/18/13 13:51
06/19/13 09:15
06/18/13 13:51
06/19/13 09:15
06/18/13 13:51
06/18/13 13:51

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.10 mg/kg

0.0074

0.0037

06/17/13 16:14 06/18/13 08:02 7439-97-6

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 14 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-16

Lab ID: 4079685003

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10
06/17/13 14:10

10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

119 %
118 %
103 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

57-130
54-133
49-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

1
1
1

06/17/13 12:54 06/17/13 14:10 1868-53-7


06/17/13 12:54 06/17/13 14:10 2037-26-5
06/17/13 12:54 06/17/13 14:10 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

Analytical Method: ASTM D2974-87


12.0 %

0.10

0.10

06/17/13 16:52

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 15 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-17(S)

Lab ID: 4079685004

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.7
<9.7
11.0J
25.0
25.1
36.3
15.3J
14.9J
36.4
<9.7
60.9
<9.7
14.1J
<3.4
<9.7
<9.7
38.1
48.2

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

67 %
77 %

19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3

9.7
9.7
9.7
9.7
3.4
9.7
9.7
3.4
9.7
9.7
9.7
9.7
9.7
3.4
9.7
9.7
9.7
9.7

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34
06/18/13 18:34

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 18:34 321-60-8


06/18/13 06:50 06/18/13 18:34 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 16 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-17(S)

Lab ID: 4079685004

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32
06/17/13 14:32

106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

116 %
119 %
100 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133
49-130

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

1
1
1

06/17/13 12:54 06/17/13 14:32 1868-53-7


06/17/13 12:54 06/17/13 14:32 2037-26-5
06/17/13 12:54 06/17/13 14:32 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 17 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-17(S)

Lab ID: 4079685004

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


13.7 %

0.10

0.10

06/17/13 13:02

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 18 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-17(D)

Lab ID: 4079685005

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.5
<9.5
<9.5
<9.5
<3.4
<9.5
<9.5
<3.4
<9.5
<9.5
<9.5
<9.5
<9.5
<3.4
<9.5
<9.5
<9.5
<9.5

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

61 %
69 %

19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1
19.1

9.5
9.5
9.5
9.5
3.4
9.5
9.5
3.4
9.5
9.5
9.5
9.5
9.5
3.4
9.5
9.5
9.5
9.5

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50
06/18/13 16:50

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 16:50 321-60-8


06/18/13 06:50 06/18/13 16:50 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 19 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-17(D)

Lab ID: 4079685005

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55
06/17/13 14:55

106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

113 %
112 %
98 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133
49-130

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

1
1
1

06/17/13 12:54 06/17/13 14:55 1868-53-7


06/17/13 12:54 06/17/13 14:55 2037-26-5
06/17/13 12:54 06/17/13 14:55 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 20 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-17(D)

Lab ID: 4079685005

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


12.6 %

0.10

0.10

06/17/13 13:02

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 21 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-18(S)

Lab ID: 4079685006

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Lead
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


152 mg/kg

1.1

0.31

06/17/13 10:05 06/18/13 13:54 7439-92-1

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


17.3J
23.7
69.1
176
188
153
118
176
237
44.9
369
14.9J
101
74.7
79.5
44.8
335
391

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

64 %
63 %

19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5
19.5

9.7
9.7
9.7
9.7
3.5
9.7
9.7
3.4
9.7
9.7
9.7
9.7
9.7
3.4
9.7
9.7
9.7
9.7

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07
06/18/13 17:07

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 17:07 321-60-8


06/18/13 06:50 06/18/13 17:07 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 22 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-18(S)

Lab ID: 4079685006

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18
06/17/13 15:18

74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

121 %
119 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

1
1

06/17/13 12:54 06/17/13 15:18 1868-53-7


06/17/13 12:54 06/17/13 15:18 2037-26-5

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 23 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-18(S)

Lab ID: 4079685006

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
Surrogates
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


106 %

49-130

06/17/13 12:54 06/17/13 15:18 460-00-4

Analytical Method: ASTM D2974-87


14.4 %

0.10

0.10

06/17/13 13:03

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 24 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-18(D)

Lab ID: 4079685007

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Lead
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


99.8 mg/kg

1.1

0.32

06/17/13 10:05 06/18/13 13:56 7439-92-1

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


25.0
<10.7
84.4
136
133
149
75.1
109
181
29.6
316
25.0
67.6
48.6
56.0
43.8
367
271

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

79 %
75 %

21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5
21.5

10.7
10.7
10.7
10.7
3.8
10.7
10.7
3.8
10.7
10.7
10.7
10.7
10.7
3.8
10.7
10.7
10.7
10.7

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59
06/18/13 17:59

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 17:59 321-60-8


06/18/13 06:50 06/18/13 17:59 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 25 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-18(D)

Lab ID: 4079685007

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41
06/17/13 15:41

74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

118 %
117 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

1
1

06/17/13 12:54 06/17/13 15:41 1868-53-7


06/17/13 12:54 06/17/13 15:41 2037-26-5

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 26 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-18(D)

Lab ID: 4079685007

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
Surrogates
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


102 %

49-130

06/17/13 12:54 06/17/13 15:41 460-00-4

Analytical Method: ASTM D2974-87


22.4 %

0.10

0.10

06/17/13 13:03

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 27 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-19

Lab ID: 4079685008

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3541


<28.9
<28.9
<28.9
<28.9
<28.9
<28.9
<28.9
<28.9

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

89 %
97 %

57.7
57.7
57.7
57.7
57.7
57.7
57.7
57.7

28.9
28.9
28.9
28.9
28.9
28.9
28.9
28.9

40-130
48-130

1
1
1
1
1
1
1
1

06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30

06/19/13 11:33
06/19/13 11:33
06/19/13 11:33
06/19/13 11:33
06/19/13 11:33
06/19/13 11:33
06/19/13 11:33
06/19/13 11:33

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/18/13 12:30 06/19/13 11:33 877-09-8


06/18/13 12:30 06/19/13 11:33 2051-24-3

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


1020
<481
3490
6240
6060
7460
3750
3880
8090
1370
16700
1250
3460
882J
502J
1620
18100
14200

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

64 %
65 %

962
962
962
962
962
962
962
962
962
962
962
962
962
962
962
962
962
962

481
481
481
481
171
481
481
170
481
481
481
481
481
170
481
481
481
481

40-130
40-130

50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00
06/19/13 09:00

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

50
50

06/18/13 06:50 06/19/13 09:00 321-60-8


06/18/13 06:50 06/19/13 09:00 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6

W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 28 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-19

Lab ID: 4079685008

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
64.9J
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
69.3
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
28.9
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04

56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 29 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-19

Lab ID: 4079685008

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04
06/17/13 16:04

75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

120 %
121 %
106 %

60.0
60.0
60.0
60.0
60.0
120
60.0

25.0
25.0
25.0
25.0
25.0
50.0
25.0

57-130
54-133
49-130

1
1
1
1
1
1
1

06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54
06/17/13 12:54

1
1
1

06/17/13 12:54 06/17/13 16:04 1868-53-7


06/17/13 12:54 06/17/13 16:04 2037-26-5
06/17/13 12:54 06/17/13 16:04 460-00-4

W
W
W
W
W
W
W

Analytical Method: ASTM D2974-87


13.4 %

0.10

0.10

06/17/13 13:03

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 30 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-20

Lab ID: 4079685009

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.6
<9.6
<9.6
<9.6
<3.4
<9.6
<9.6
<3.4
<9.6
<9.6
<9.6
<9.6
<9.6
<3.4
<9.6
<9.6
<9.6
<9.6

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

64 %
72 %

19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2

9.6
9.6
9.6
9.6
3.4
9.6
9.6
3.4
9.6
9.6
9.6
9.6
9.6
3.4
9.6
9.6
9.6
9.6

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12
06/18/13 14:12

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 14:12 321-60-8


06/18/13 06:50 06/18/13 14:12 1718-51-0

Analytical Method: ASTM D2974-87


13.1 %

0.10

0.10

06/17/13 13:03

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 31 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-20
Parameters

Lab ID: 4079685010


Results

Units

Collected: 06/13/13 00:00


LOQ

LOD

Received: 06/15/13 09:45

DF

Prepared

8270 MSSV PAH by HVI

Analytical Method: EPA 8270 by HVI Preparation Method: EPA 3510

Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

0.0049J
<0.0035
0.012J
0.025J
0.022J
0.038J
0.020J
0.034J
0.048
0.0083J
0.065
0.0071J
0.018J
0.012J
0.020J
0.041J
0.073
0.062

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

65 %
106 %

0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
39-130
73-155

0.0038
0.0035
0.0048
0.0047
0.0049
0.0067
0.0080
0.010
0.0062
0.0054
0.0052
0.0038
0.0058
0.0036
0.0061
0.0033
0.0038
0.0053

Matrix: Water

Analyzed

06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21
06/19/13 08:21

CAS No.

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44

1
1

06/18/13 07:44 06/19/13 08:21 321-60-8


06/18/13 07:44 06/19/13 08:21 1718-51-0

Qual

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 32 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-21

Lab ID: 4079685011

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.1
<9.1
<9.1
<9.1
<3.2
<9.1
<9.1
<3.2
<9.1
<9.1
<9.1
<9.1
<9.1
<3.2
<9.1
<9.1
<9.1
<9.1

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

59 %
62 %

18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1

9.1
9.1
9.1
9.1
3.2
9.1
9.1
3.2
9.1
9.1
9.1
9.1
9.1
3.2
9.1
9.1
9.1
9.1

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38
06/18/13 15:38

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 15:38 321-60-8


06/18/13 06:50 06/18/13 15:38 1718-51-0

Analytical Method: ASTM D2974-87


8.1 %

0.10

0.10

06/17/13 13:03

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 33 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-21
Parameters

Lab ID: 4079685012


Results

Units

Collected: 06/13/13 00:00


LOQ

LOD

Received: 06/15/13 09:45

DF

Prepared

8270 MSSV PAH by HVI

Analytical Method: EPA 8270 by HVI Preparation Method: EPA 3510

Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

0.0041J
0.0042J
0.022J
0.032J
0.010J
0.048
0.026J
0.037J
0.066
0.0093J
0.19
0.013J
0.021J
0.021J
0.036J
0.038J
0.15
0.18

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

66 %
108 %

0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
39-130
73-155

0.0039
0.0035
0.0049
0.0048
0.0050
0.0068
0.0081
0.010
0.0062
0.0055
0.0052
0.0039
0.0059
0.0036
0.0061
0.0033
0.0039
0.0053

Matrix: Water

Analyzed

06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39
06/19/13 08:39

CAS No.

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44

1
1

06/18/13 07:44 06/19/13 08:39 321-60-8


06/18/13 07:44 06/19/13 08:39 1718-51-0

Qual

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 34 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-23

Lab ID: 4079685013

Collected: 06/13/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


14.3 %

0.10

0.10

06/17/13 13:03

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 35 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-23
Parameters

Lab ID: 4079685014


Results

Units

Collected: 06/13/13 00:00


LOQ

LOD

Received: 06/15/13 09:45

DF

Prepared

Matrix: Water

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by HVI Preparation Method: EPA 3510


Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

<0.0039
<0.0035
0.0051J
0.0082J
0.0057J
<0.0068
<0.0081
<0.010
0.013J
<0.0055
0.017J
0.0043J
<0.0059
0.015J
0.032J
0.050
0.024J
0.019J

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

65 %
101 %

0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
39-130
73-155

0.0039
0.0035
0.0049
0.0048
0.0050
0.0068
0.0081
0.010
0.0062
0.0055
0.0052
0.0039
0.0059
0.0036
0.0061
0.0033
0.0039
0.0053

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44

06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57
06/19/13 08:57

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:44 06/19/13 08:57 321-60-8


06/18/13 07:44 06/19/13 08:57 1718-51-0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 36 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-25

Lab ID: 4079685015

Collected: 06/14/13 00:00

Received: 06/15/13 09:45

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


13.4 %

0.10

0.10

06/17/13 13:03

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 37 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: GP-25
Parameters

Lab ID: 4079685016


Results

Units

Collected: 06/14/13 00:00


LOQ

LOD

Received: 06/15/13 09:45

DF

Prepared

Matrix: Water

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by HVI Preparation Method: EPA 3510


Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

0.027J
0.0082J
0.032J
0.044J
0.040J
0.043J
0.027J
0.040J
0.054
0.012J
0.13
0.027J
0.023J
0.036J
0.051
0.16
0.18
0.13

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

71 %
101 %

0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
39-130
73-155

0.0042
0.0038
0.0052
0.0051
0.0053
0.0073
0.0087
0.011
0.0067
0.0059
0.0056
0.0042
0.0063
0.0039
0.0066
0.0036
0.0042
0.0057

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44

06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15
06/19/13 09:15

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:44 06/19/13 09:15 321-60-8


06/18/13 07:44 06/19/13 09:15 1718-51-0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 38 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: TRIP BLANK


Parameters
8260 MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane

Lab ID: 4079685017


Results

Units

Collected: 06/13/13 00:00


LOQ

LOD

Received: 06/15/13 09:45

DF

Prepared

Matrix: Water

Analyzed

CAS No.

Qual

Analytical Method: EPA 8260


<0.50
<0.48
<0.49
<0.45
<0.23
<0.43
<0.40
<0.60
<0.42
<0.37
<0.36
<0.44
<0.69
<0.39
<0.48
<0.48
<1.5
<1.9
<0.38
<0.48
<0.44
<0.45
<0.43
<0.40
<0.28
<0.48
<0.43
<0.42
<0.37
<0.50
<0.46
<0.37
<0.51
<0.29
<0.26
<0.50
<0.50
<1.3
<0.34
<0.40
<0.36
<0.49
<2.5
<0.50
<0.35
<0.45

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0

0.50
0.48
0.49
0.45
0.23
0.43
0.40
0.60
0.42
0.37
0.36
0.44
0.69
0.39
0.48
0.48
1.5
1.9
0.38
0.48
0.44
0.45
0.43
0.40
0.28
0.48
0.43
0.42
0.37
0.50
0.46
0.37
0.51
0.29
0.26
0.50
0.50
1.3
0.34
0.40
0.36
0.49
2.5
0.50
0.35
0.45

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 39 of 60

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Sample: TRIP BLANK


Parameters
8260 MSV
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)

Lab ID: 4079685017


Results

Units

Collected: 06/13/13 00:00


LOQ

LOD

Received: 06/15/13 09:45

DF

Prepared

Matrix: Water

Analyzed

CAS No.

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50
06/17/13 23:50

79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

1
1
1

06/17/13 23:50 460-00-4


06/17/13 23:50 1868-53-7
06/17/13 23:50 2037-26-5

Qual

Analytical Method: EPA 8260


<0.38
<0.47
<0.44
<0.77
<2.5
<0.44
<0.39
<0.43
<0.48
<0.47
<0.57
<2.5
<0.18
<0.82
<0.50

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

90 %
94 %
101 %

1.0
1.0
1.0
5.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
43-137
70-130
55-137

0.38
0.47
0.44
0.77
2.5
0.44
0.39
0.43
0.48
0.47
0.57
2.5
0.18
0.82
0.50

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 40 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

MERP/3700

Analysis Method:

EPA 7471

QC Batch Method:

EPA 7471

Analysis Description:

7471 Mercury

Associated Lab Samples:


METHOD BLANK:

4079685001, 4079685002, 4079685003

809241

Associated Lab Samples:


Parameter

Matrix: Solid
4079685001, 4079685002, 4079685003
Blank
Units
Result

Mercury

mg/kg

LABORATORY CONTROL SAMPLE:

809242

Parameter
Mercury

<0.0033

Spike
Conc.

Units
mg/kg

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
Mercury

0.0067

LCS
Result

.17

0.042

Analyzed

Qualifiers

06/18/13 07:48

LCS
% Rec
0.15

809243

10231800001
Units
Result
mg/kg

Reporting
Limit

% Rec
Limits
92

Qualifiers

85-115

809244
MS
Spike
Conc.

MSD
Spike
Conc.
.2

MS
Result
.2

0.22

MSD
Result

MS
% Rec

0.21

91

MSD
% Rec
84

% Rec
Limits
85-115

Max
RPD RPD
5

Qual

20 M0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 41 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

MPRP/8637

Analysis Method:

EPA 6010

QC Batch Method:

EPA 3050

Analysis Description:

6010 MET

Associated Lab Samples:


METHOD BLANK:

4079685001, 4079685002, 4079685003, 4079685006, 4079685007

809183

Associated Lab Samples:


Parameter

Matrix: Solid
4079685001, 4079685002, 4079685003, 4079685006, 4079685007
Blank
Reporting
Analyzed
Units
Result
Limit

Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

LABORATORY CONTROL SAMPLE:

809184

Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver

<0.54
<0.087
<0.051
<0.13
<0.29
<0.59
<0.21

Spike
Conc.

Units
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver

Units
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.0
0.50
0.50
0.50
1.0
2.0
1.0

LCS
Result

50
50
50
50
50
50
25

809185

4079685001
Result
4.7
124
0.32J
12.1
200
<0.67
<0.24

06/18/13 13:34
06/18/13 13:34
06/18/13 13:34
06/18/13 13:34
06/18/13 13:34
06/18/13 13:34
06/18/13 13:34

LCS
% Rec
48.4
50.4
48.2
49.5
49.0
47.3
23.7

Qualifiers

% Rec
Limits
97
101
96
99
98
95
95

Qualifiers

80-120
80-120
80-120
80-120
80-120
80-120
80-120

809186
MS
Spike
Conc.
56.4
56.4
56.4
56.4
56.4
56.4
28.2

MSD
Spike
Conc.
56.4
56.4
56.4
56.4
56.4
56.4
28.2

MS
Result
56.6
198
53.3
67.8
188
51.8
26.4

MSD
Result

MS
% Rec

57.7
210
53.5
68.0
215
52.0
26.8

92
131
94
99
-22
92
93

MSD
% Rec
94
153
94
99
26
92
95

% Rec
Limits
75-125
75-125
75-125
75-125
75-125
75-125
75-125

Max
RPD RPD
2
6
0
0
13
0
2

Qual

20
20 M0
20
20
20 M0
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 42 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

MSV/20114

Analysis Method:

EPA 8260

QC Batch Method:

EPA 5035/5030B

Analysis Description:

8260 MSV Med Level Normal List

Associated Lab Samples:


METHOD BLANK:

4079685002, 4079685003, 4079685004, 4079685005, 4079685006, 4079685007, 4079685008

809326

Associated Lab Samples:


Parameter

Matrix: Solid
4079685002, 4079685003, 4079685004, 4079685005, 4079685006, 4079685007, 4079685008
Blank
Reporting
Analyzed
Units
Result
Limit
Qualifiers

1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0

06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 43 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

METHOD BLANK:

809326

Associated Lab Samples:


Parameter

Matrix: Solid
4079685002, 4079685003, 4079685004, 4079685005, 4079685006, 4079685007, 4079685008
Blank
Reporting
Analyzed
Units
Result
Limit
Qualifiers

m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane

<50.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
90
100
100

809327
Units

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

120
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
49-130
57-130
54-133

06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52
06/17/13 11:52

809328
Spike
Conc.
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500

LCS
Result
2590
2770
2570
2390
2350
2440
2650
2580
2540
2670
2710
2550
2510
2560
2840
2820
2230
2600
2550
2100

LCSD
Result
2600
2770
2550
2460
2360
2570
2670
2540
2600
2640
2620
2580
2620
2620
2830
2840
2290
2630
2590
2340

LCS LCSD
% Rec % Rec
103
111
103
96
94
98
106
103
102
107
108
102
100
102
113
113
89
104
102
84

104
111
102
98
94
103
107
102
104
105
105
103
105
105
113
114
91
105
103
93

% Rec
Limits
70-130
70-130
70-130
70-130
64-130
68-130
50-150
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
63-130
41-142
70-130
70-130
57-130

Max
RPD

RPD
1
0
1
3
0
5
1
1
2
1
3
1
5
2
0
1
2
1
1
10

Qualifiers

20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 44 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)

809327
Units

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%

809328
Spike
Conc.
2500
2500
2500
2500
2500
2500
2500
2500
5000
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500

LCS
Result
2400
2520
2270
2680
2700
2250
2740
2680
5480
2260
2350
2780
2490
2350
2630
2310
2870
2620
2290
2690

LCSD
Result
2440
2540
2230
2650
2780
2170
2720
2710
5550
2290
2390
2740
2460
2430
2660
2350
2870
2650
2300
2660

LCS LCSD
% Rec % Rec
96
101
91
107
108
90
109
107
110
91
94
111
100
94
105
92
115
105
91
108
107
101
105

97
102
89
106
111
87
109
108
111
91
96
109
98
97
106
94
115
106
92
107
109
102
106

% Rec
Limits
70-130
57-130
70-130
70-130
70-130
31-150
65-137
70-130
64-139
69-130
70-130
63-135
69-130
70-130
70-130
70-130
70-130
70-130
50-150
57-130
49-130
57-130
54-133

Max
RPD

RPD
1
1
2
1
3
4
0
1
1
1
2
2
2
3
1
2
0
1
1
1

Qualifiers

20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 45 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

MSV/20103

Analysis Method:

EPA 8260

QC Batch Method:

EPA 8260

Analysis Description:

8260 MSV

Associated Lab Samples:


METHOD BLANK:

4079685017

809255

Associated Lab Samples:

Matrix: Water
4079685017

Parameter
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)

Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

Blank
Result
<0.45
<0.44
<0.38
<0.39
<0.28
<0.43
<0.51
<0.77
<0.47
<2.5
<0.57
<1.5
<0.38
<0.44
<0.48
<0.50
<2.5
<0.45
<0.46
<0.43
<0.37
<0.48
<0.48
<0.50
<0.48
<0.49
<0.45
<0.23
<0.43
<0.37
<0.36
<0.44
<0.69
<0.39
<0.42
<0.29
<1.9
<0.48
<0.40
<0.50
<0.50
<1.3
<0.34

Reporting
Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
5.0
5.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0

Analyzed

Qualifiers

06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 46 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

METHOD BLANK:

809255

Associated Lab Samples:

Matrix: Water
4079685017

Parameter
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane

Blank
Result

Units

<0.82
<0.49
<0.36
<0.40
<0.50
<2.5
<0.50
<0.40
<0.60
<0.35
<0.42
<0.47
<0.44
<0.37
<0.26
<0.43
<0.48
<0.18
89
94
102

2.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
43-137
70-130
55-137

809256
Units

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

Reporting
Limit

Analyzed

Qualifiers

06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08
06/17/13 18:08

809257
Spike
Conc.
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50

LCS
Result
46.2
49.1
52.2
50.9
53.4
46.4
39.7
49.9
51.4
48.7
50.2
49.1
50.9
50.6
48.2
42.6
30.5
46.7
53.0
52.2

LCSD
Result
46.9
50.4
51.8
51.6
53.3
47.8
38.3
50.9
52.0
47.9
52.7
50.3
51.8
50.4
48.7
44.2
35.2
48.8
54.1
53.6

LCS LCSD
% Rec % Rec
92
98
104
102
107
93
79
100
103
97
100
98
102
101
96
85
61
93
106
104

94
101
104
103
107
96
77
102
104
96
105
101
104
101
97
88
70
98
108
107

% Rec
Limits
70-136
70-130
70-130
70-146
70-130
70-130
46-150
70-130
70-130
70-144
70-136
70-130
70-130
70-137
70-133
59-130
41-148
70-154
70-130
70-139

Max
RPD

RPD
2
2
1
1
0
3
4
2
1
1
5
2
2
0
1
4
14
4
2
3

Qualifiers

20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 47 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

LABORATORY CONTROL SAMPLE & LCSD:


Parameter

809256
Units

Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene

Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

809257
Spike
Conc.
50
50
50
50
50
50
50
50
100
50
50
50
50
50
50
50
50
50
50
50

LCS
Result
50.5
47.0
50.2
42.0
46.1
57.2
52.1
51.6
107
42.4
52.1
53.1
52.3
51.6
53.2
50.0
44.3
53.5
63.0
53.6

809376

4079576008
Result
<0.44
<0.38
<0.39
<0.28
<0.43
<2.5
<1.5
<0.38
<0.44
<0.48
<0.50
<0.45
<0.43
<0.50
<0.45
<0.23
<0.43
<0.37
<0.36

LCSD
Result
50.9
48.9
49.9
42.7
46.5
57.6
53.0
52.5
108
41.8
52.0
54.3
52.9
52.4
53.6
50.1
44.2
54.3
62.8
54.2

LCS LCSD
% Rec % Rec
101
94
100
84
92
114
104
103
107
85
104
106
105
103
106
100
89
107
126
107
97
99
101

% Rec
Limits

102
98
100
85
93
115
106
105
108
84
104
109
106
105
107
100
88
109
126
108
96
98
102

Max
RPD

RPD

70-130
45-154
70-130
70-136
70-130
20-157
70-130
70-130
70-130
59-141
70-130
70-130
70-130
70-130
70-130
70-130
55-135
70-130
50-150
61-143
43-137
70-130
55-137

1
4
1
1
1
1
2
2
2
2
0
2
1
1
1
0
0
1
0
1

Qualifiers

20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20

809377
MS
Spike
Conc.
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50

MSD
Spike
Conc.
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50

MS
Result
46.5
48.2
50.9
50.5
52.5
46.9
37.8
50.0
51.4
47.1
51.3
49.1
51.1
50.3
47.8
43.4
35.0
47.8
52.7

MSD
Result

MS
% Rec

47.4
50.9
53.8
52.2
54.2
48.3
41.4
51.9
52.7
49.0
53.2
50.9
52.1
51.7
49.7
45.1
36.5
50.1
53.7

93
96
102
101
105
92
76
100
102
94
103
98
102
101
96
87
70
96
105

MSD
% Rec
95
102
108
104
108
95
83
104
105
98
106
101
104
103
99
90
73
100
107

% Rec
Limits
70-136
70-130
70-130
70-146
70-130
70-130
46-150
70-130
70-130
70-146
70-136
70-130
70-130
70-137
70-133
57-130
41-148
70-154
70-130

Max
RPD RPD
2
6
6
3
3
3
9
4
3
4
4
4
2
3
4
4
4
5
2

Qual

20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 48 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)

Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%

809376

4079576008
Result
<0.44
<0.69
<0.39
<0.42
<0.29
<1.9
<0.40
<0.50
<0.34
<0.49
<0.36
<0.35
<0.47
<0.44
<0.37
<0.26
<0.43
<0.48
<0.18

809377
MS
Spike
Conc.
50
50
50
50
50
50
50
50
50
100
50
50
50
50
50
50
50
50
50
50
50

MSD
Spike
Conc.
50
50
50
50
50
50
50
50
50
100
50
50
50
50
50
50
50
50
50
50
50

MS
Result
52.1
50.1
47.8
49.9
42.1
46.0
54.9
51.7
51.3
106
41.5
51.4
52.6
51.7
51.1
52.9
49.3
44.6
52.9
61.5
53.0

MSD
Result

MS
% Rec

53.7
52.0
50.3
51.7
44.0
47.7
56.7
52.6
52.2
109
44.1
52.7
53.9
52.8
52.8
53.8
51.8
46.0
54.0
62.8
54.7

104
100
96
100
84
92
110
103
102
106
83
103
105
103
102
105
99
89
106
123
106
96
99
102

MSD
% Rec
107
104
101
103
88
95
113
105
104
109
88
105
108
106
106
107
104
92
108
126
109
95
99
101

% Rec
Limits
70-140
70-130
45-154
70-130
70-136
70-130
10-157
70-130
70-130
70-130
59-141
70-130
70-130
35-164
70-130
70-130
70-130
55-137
70-130
50-150
59-144
43-137
70-130
55-137

Max
RPD RPD
3
4
5
4
4
4
3
2
2
3
6
3
3
2
3
2
5
3
2
2
3

Qual

20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 49 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

OEXT/18642

Analysis Method:

EPA 8082

QC Batch Method:

EPA 3541

Analysis Description:

8082 GCS PCB

Associated Lab Samples:


METHOD BLANK:

4079685008

809863

Associated Lab Samples:

Matrix: Solid
4079685008

Parameter
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

LABORATORY CONTROL SAMPLE:

809864

Parameter
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)

PCB-1016 (Aroclor 1016)


PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)

Spike
Conc.

Units
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

50.0
50.0
50.0
50.0
50.0
50.0
50.0
48-130
40-130

LCS
Result

809865

<29.4
<29.4
<29.4
<29.4
<29.4
<29.4
<29.4

Analyzed

Qualifiers

06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06

LCS
% Rec

<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
507

500

4079703001
Units
Result
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

Reporting
Limit

<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
97
79

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter

Blank
Result

Units

% Rec
Limits

101
102
84

Qualifiers

70-130
48-130
40-130

809866
MS
Spike
Conc.

588

MSD
Spike
Conc.

588

MS
Result
<29.4
<29.4
<29.4
<29.4
<29.4
<29.4
594

MSD
Result

MS
% Rec

<29.4
<29.4
<29.4
<29.4
<29.4
<29.4
602

101
98
83

MSD
% Rec

102
101
89

% Rec
Limits

40-149
48-130
40-130

Max
RPD RPD

Qual

31
31
31
31
31
31
31

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 50 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

OEXT/18628

Analysis Method:

EPA 8270 by SIM

QC Batch Method:

EPA 3546

Analysis Description:

8270/3546 MSSV PAH by SIM

Associated Lab Samples:


METHOD BLANK:

4079685001, 4079685004, 4079685005, 4079685006, 4079685007, 4079685008, 4079685009, 4079685011

809525

Associated Lab Samples:


Parameter

Matrix: Solid
4079685001, 4079685004, 4079685005, 4079685006, 4079685007, 4079685008, 4079685009, 4079685011
Blank
Reporting
Analyzed
Units
Result
Limit
Qualifiers

1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

LABORATORY CONTROL SAMPLE:

809526

Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene

<2.9
<8.3
<8.3
<8.3
<8.3
<8.3
<3.0
<8.3
<8.3
<2.9
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
61
70

Units
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

Spike
Conc.
333
333
333
333
333
333
333
333
333
333
333
333
333
333
333
333
333

16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
40-130
40-130

LCS
Result

06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41

% Rec
Limits

LCS
% Rec
223
205
253
248
265
200
228
223
234
230
262
243
218
248
236
194
213

67
61
76
74
80
60
68
67
70
69
78
73
65
74
71
58
64

Qualifiers

47-130
48-130
55-130
55-130
66-130
55-130
56-130
53-130
51-130
52-130
58-130
55-130
62-130
58-130
54-130
41-130
60-130

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 51 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

LABORATORY CONTROL SAMPLE:

809526

Parameter
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

ug/kg
%
%

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

Spike
Conc.

Units

Units
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

333

220

809527

4079703008
Result
<3.4
<9.6
<9.6
<9.6
<9.6
<9.6
<3.4
<9.6
<9.6
<3.4
<9.6
<9.6
<9.6
<9.6
<9.6
<9.6
<9.6
<9.6

LCS
% Rec

LCS
Result

% Rec
Limits
66
71
76

Qualifiers

51-130
40-130
40-130

809528
MS
Spike
Conc.
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384

MSD
Spike
Conc.
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384

MS
Result
228
217
261
260
271
186
236
187
225
259
270
235
219
249
231
216
222
214

MSD
Result

MS
% Rec

215
222
263
252
258
153
194
150
195
239
237
198
195
191
202
227
199
187

59
57
68
68
71
48
61
49
58
67
70
61
57
65
60
56
58
56
67
65

MSD
% Rec
56
58
68
66
67
40
50
39
51
62
62
52
51
50
53
59
52
49
62
54

% Rec
Limits
42-130
34-130
31-130
32-130
39-131
29-130
35-130
21-142
12-134
35-130
37-130
23-130
29-137
32-130
17-134
24-130
27-135
24-130
40-130
40-130

Max
RPD RPD
6
2
1
3
5
20
19
22
14
8
13
17
11
27
13
5
11
13

Qual

32
35
35
25
38
30
33
44
33
37
38
27
50
32
28
40
46
49

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 52 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

OEXT/18634

Analysis Method:

EPA 8270 by HVI

QC Batch Method:

EPA 3510

Analysis Description:

8270 Water PAH by HVI

Associated Lab Samples:


METHOD BLANK:

4079685010, 4079685012, 4079685014, 4079685016

809563

Associated Lab Samples:


Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

Matrix: Water
4079685010, 4079685012, 4079685014, 4079685016
Blank
Reporting
Units
Result
Limit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene

<0.0040
<0.0068
<0.0043
<0.0039
<0.0054
<0.0053
<0.0055
<0.0075
<0.0090
<0.012
<0.0069
<0.0061
<0.0058
<0.0043
<0.0065
<0.0037
<0.0043
<0.0059
69
116

809564
Units

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
39-130
73-155

Analyzed

Qualifiers

06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26
06/19/13 07:26

809565
LCS
Result

Spike
Conc.
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2

0.11
0.11
0.15
0.15
0.17
0.21
0.19
0.20
0.19
0.21
0.21
0.19
0.19
0.15
0.19
0.14
0.17

LCSD
Result
0.11
0.11
0.15
0.15
0.18
0.20
0.19
0.20
0.19
0.21
0.21
0.19
0.19
0.15
0.19
0.12
0.17

LCS LCSD
% Rec % Rec
54
54
75
75
87
103
93
99
94
107
104
93
95
76
93
69
87

54
53
74
73
89
101
95
100
94
106
106
93
93
77
93
61
86

% Rec
Limits
23-130
22-130
31-130
31-130
26-130
47-130
41-130
37-130
37-130
51-130
50-130
34-130
49-130
30-130
36-130
24-130
39-130

Max
RPD

RPD
1
1
1
2
2
2
3
2
0
1
2
0
2
1
1
11
0

Qualifiers

49
50
34
37
35
27
28
27
29
26
26
30
26
34
29
40
30

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 53 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

809564
Units

ug/L
%
%

809565
Spike
Conc.

LCS
Result
.2

0.22

LCSD
Result
0.21

LCS LCSD
% Rec % Rec
108
68
101

106
66
101

% Rec
Limits
47-130
39-130
73-155

Max
RPD

RPD
2

Qualifiers

25

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 54 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

PMST/8578

Analysis Method:

ASTM D2974-87

QC Batch Method:

ASTM D2974-87

Analysis Description:

Dry Weight/Percent Moisture

Associated Lab Samples:


SAMPLE DUPLICATE:

4079685001, 4079685004, 4079685005, 4079685006, 4079685007, 4079685008, 4079685009, 4079685011,


4079685013, 4079685015

809329

Parameter
Percent Moisture

Units
%

4079693002
Result
17.6

Dup
Result

Max
RPD

RPD
18.2

Qualifiers
10

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 55 of 60

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

QC Batch:

PMST/8583

Analysis Method:

ASTM D2974-87

QC Batch Method:

ASTM D2974-87

Analysis Description:

Dry Weight/Percent Moisture

Associated Lab Samples:


SAMPLE DUPLICATE:

4079685002, 4079685003

809467

Parameter
Percent Moisture

Units
%

4079685002
Result
18.1

Dup
Result

Max
RPD

RPD
18.0

Qualifiers
10

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 56 of 60

#=QL#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALIFIERS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-G

Pace Analytical Services - Green Bay

BATCH QUALIFIERS
Batch: MSV/20115
[M5]

A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.

Batch: MSSV/5759
Benzo(b)fluoranthene and benzo(k)fluoranthene were in the check standard but did not meet the resolution criteria in
[IP]
SW846 Method 8270C. Whereas sample results included are reported as individual isomers, the lab and the customer
must recognize them as an isomeric pair.
Batch: MSSV/5762
[M5]

A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.

ANALYTE QUALIFIERS
M0

Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

Non-detect results are reported on a wet weight basis.

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 57 of 60

#=CR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA CROSS REFERENCE TABLE


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079685

Analytical Method

Analytical
Batch

Lab ID

Sample ID

QC Batch Method

QC Batch

4079685008

GP-19

EPA 3541

OEXT/18642 EPA 8082

GCSV/9725

4079685001
4079685002
4079685003
4079685006
4079685007

GP-12
GP-15
GP-16
GP-18(S)
GP-18(D)

EPA 3050
EPA 3050
EPA 3050
EPA 3050
EPA 3050

MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010

ICP/7673
ICP/7673
ICP/7673
ICP/7673
ICP/7673

4079685001
4079685002
4079685003

GP-12
GP-15
GP-16

EPA 7471
EPA 7471
EPA 7471

MERP/3700
MERP/3700
MERP/3700

EPA 7471
EPA 7471
EPA 7471

MERC/4611
MERC/4611
MERC/4611

4079685001
4079685004
4079685005
4079685006
4079685007
4079685008
4079685009
4079685011

GP-12
GP-17(S)
GP-17(D)
GP-18(S)
GP-18(D)
GP-19
GP-20
GP-21

EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546

OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM

MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759

4079685010
4079685012

GP-20
GP-21

EPA 3510
EPA 3510

OEXT/18634 EPA 8270 by HVI


OEXT/18634 EPA 8270 by HVI

MSSV/5762
MSSV/5762

4079685002
4079685003
4079685004
4079685005
4079685006
4079685007
4079685008

GP-15
GP-16
GP-17(S)
GP-17(D)
GP-18(S)
GP-18(D)
GP-19

EPA 5035/5030B
EPA 5035/5030B
EPA 5035/5030B
EPA 5035/5030B
EPA 5035/5030B
EPA 5035/5030B
EPA 5035/5030B

MSV/20114
MSV/20114
MSV/20114
MSV/20114
MSV/20114
MSV/20114
MSV/20114

MSV/20115
MSV/20115
MSV/20115
MSV/20115
MSV/20115
MSV/20115
MSV/20115

4079685017

TRIP BLANK

EPA 8260

MSV/20103

4079685001

GP-12

ASTM D2974-87

PMST/8578

4079685002
4079685003

GP-15
GP-16

ASTM D2974-87
ASTM D2974-87

PMST/8583
PMST/8583

4079685004
4079685005
4079685006
4079685007
4079685008
4079685009
4079685011
4079685013
4079685015

GP-17(S)
GP-17(D)
GP-18(S)
GP-18(D)
GP-19
GP-20
GP-21
GP-23
GP-25

ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87

PMST/8578
PMST/8578
PMST/8578
PMST/8578
PMST/8578
PMST/8578
PMST/8578
PMST/8578
PMST/8578

EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260
EPA 8260

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:55 PM

without the written consent of Pace Analytical Services, Inc..

Page 58 of 60

Page 59 of 60

Page 60 of 60

#=CL#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

LIMS USE: FR - MITCHELL BANACH


LIMS OBJECT ID: 4079686

June 26, 2013

Mitchell Banach
Ayres & Associates, Inc.
3433 Oakwood Hills Parkway
Eau Claire, WI 547017698

RE: Project: 19-0291.20 DEPT OF ADMIN.


Pace Project No.: 4079686
Dear Mitchell Banach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 15, 2013. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,

Steven Mleczko
steve.mleczko@pacelabs.com
Project Manager

Enclosures

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 1 of 11

#=CP#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

CERTIFICATIONS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079686

Green Bay Certification IDs


1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334

New York Certification #: 11888


North Dakota Certification #: R-150
South Carolina Certification #: 83006001
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 2 of 11

#=SS#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE SUMMARY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079686

Lab ID

Sample ID

Matrix

Date Collected

Date Received

4079686001

GP-15

Water

06/14/13 00:00

06/15/13 09:45

4079686002

GP-16

Water

06/14/13 00:00

06/15/13 09:45

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 3 of 11

#=SA#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE ANALYTE COUNT


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079686

Lab ID

Sample ID

4079686002

GP-16

Method

Analysts

EPA 6010

DLB

Analytes
Reported
1

Laboratory
PASI-G

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 4 of 11

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079686

Lab Sample ID

Client Sample ID

Method

Parameters

4079686002

GP-16

EPA 6010

Lead, Dissolved

Result

Units

35.5 ug/L

Report Limit

7.5

Analyzed

Qualifiers

06/25/13 16:00

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 5 of 11

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079686

Sample: GP-16
Parameters
6010 MET ICP, Dissolved
Lead, Dissolved

Lab ID: 4079686002


Results

Units

Collected: 06/14/13 00:00


LOQ

LOD

Received: 06/15/13 09:45

DF

Prepared

Analyzed

Matrix: Water
CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3010


35.5 ug/L

7.5

2.7

06/24/13 15:50 06/25/13 16:00 7439-92-1

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/26/2013 01:09 PM

without the written consent of Pace Analytical Services, Inc..

Page 6 of 11

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079686

QC Batch:

MPRP/8681

Analysis Method:

EPA 6010

QC Batch Method:

EPA 3010

Analysis Description:

6010 MET Dissolved

Associated Lab Samples:


METHOD BLANK:

4079686002

813229

Associated Lab Samples:

Matrix: Water
4079686002

Parameter
Lead, Dissolved

ug/L

LABORATORY CONTROL SAMPLE:

813230

Parameter

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Lead, Dissolved

Spike
Conc.

ug/L

Units
ug/L

Reporting
Limit

<2.7

Units

Lead, Dissolved

Parameter

Blank
Result

Units

7.5

LCS
Result

500

4079686002
Result
35.5

Qualifiers

06/25/13 15:56

LCS
% Rec
477

813231

Analyzed

% Rec
Limits
95

Qualifiers

80-120

813232
MS
Spike
Conc.
500

MSD
Spike
Conc.
500

MS
Result
496

MSD
Result

MS
% Rec

505

92

MSD
% Rec
94

% Rec
Limits
75-125

Max
RPD RPD
2

Qual

20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/26/2013 01:09 PM

without the written consent of Pace Analytical Services, Inc..

Page 7 of 11

#=QL#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALIFIERS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079686

DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-G

Pace Analytical Services - Green Bay

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/26/2013 01:09 PM

without the written consent of Pace Analytical Services, Inc..

Page 8 of 11

#=CR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA CROSS REFERENCE TABLE


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079686

Lab ID

Sample ID

QC Batch Method

QC Batch

Analytical Method

Analytical
Batch

4079686002

GP-16

EPA 3010

MPRP/8681

EPA 6010

ICP/7703

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/26/2013 01:09 PM

without the written consent of Pace Analytical Services, Inc..

Page 9 of 11

Page 10 of 11

Page 11 of 11

#=CL#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

LIMS USE: FR - MITCHELL BANACH


LIMS OBJECT ID: 4079703

June 19, 2013

Mitchell Banach
Ayres & Associates, Inc.
3433 Oakwood Hills Parkway
Eau Claire, WI 547017698

RE: Project: 19-0291.20 DEPT OF ADMIN.


Pace Project No.: 4079703
Dear Mitchell Banach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 15, 2013. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,

Steven Mleczko
steve.mleczko@pacelabs.com
Project Manager

Enclosures

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 1 of 63

#=CP#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

CERTIFICATIONS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Green Bay Certification IDs


1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334

New York Certification #: 11888


North Dakota Certification #: R-150
South Carolina Certification #: 83006001
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 2 of 63

#=SS#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE SUMMARY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab ID

Sample ID

Matrix

Date Collected

Date Received

4079703001

GP-1

Solid

06/14/13 00:00

06/15/13 12:01

4079703002

GP-2

Solid

06/14/13 00:00

06/15/13 12:01

4079703003

GP-3

Solid

06/14/13 00:00

06/15/13 12:01

4079703004

GP-4

Solid

06/14/13 00:00

06/15/13 12:01

4079703005

GP-5

Solid

06/14/13 00:00

06/15/13 12:01

4079703006

GP-6(S)

Solid

06/14/13 00:00

06/15/13 12:01

4079703007

GP-6(D)

Solid

06/14/13 00:00

06/15/13 12:01

4079703008

GP-7

Solid

06/14/13 00:00

06/15/13 12:01

4079703009

GP-8

Solid

06/14/13 00:00

06/15/13 12:01

4079703010

GP-9

Solid

06/14/13 00:00

06/15/13 12:01

4079703011

GP-10

Solid

06/14/13 00:00

06/15/13 12:01

4079703012

GP-11

Solid

06/14/13 00:00

06/15/13 12:01

4079703013

GP-13

Solid

06/14/13 00:00

06/15/13 12:01

4079703014

GP-14

Solid

06/14/13 00:00

06/15/13 12:01

4079703015

GP-22

Solid

06/14/13 00:00

06/15/13 12:01

4079703016

GP-26

Solid

06/14/13 00:00

06/15/13 12:01

4079703017

GP-2(D)

Solid

06/14/13 00:00

06/15/13 12:01

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 3 of 63

#=SA#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE ANALYTE COUNT


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab ID

Sample ID

4079703001

GP-1

4079703002

4079703003

4079703004

4079703005

4079703006

4079703007

4079703008

4079703009

GP-2

GP-3

GP-4

GP-5

GP-6(S)

GP-6(D)

GP-7

GP-8

Analytes
Reported

Method

Analysts

Laboratory

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 4 of 63

#=SA#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE ANALYTE COUNT


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab ID

Sample ID

4079703010

GP-9

4079703011

4079703012

4079703013

4079703014

4079703015

4079703016

4079703017

GP-10

GP-11

GP-13

GP-14

GP-22

GP-26

GP-2(D)

Analytes
Reported

Method

Analysts

EPA 8270 by SIM

ARO

20

Laboratory
PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 6010

DLB

PASI-G

EPA 7471

CMS

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

EPA 8260

SMT

64

PASI-G

ASTM D2974-87

SKW

PASI-G

EPA 8270 by SIM

ARO

20

PASI-G

ASTM D2974-87

SKW

PASI-G

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 5 of 63

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab Sample ID

Client Sample ID

Method

Parameters

4079703001

GP-1

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Silver
Mercury
Percent Moisture

Result

4079703002

GP-2

EPA 8082
EPA 8082
EPA 8082
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
ASTM D2974-87

PCB-1254 (Aroclor 1254)


PCB-1260 (Aroclor 1260)
PCB, Total
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Percent Moisture

4079703003

GP-3

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Percent Moisture

4079703004

GP-4

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM

Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene

Units

Report Limit

Analyzed

50.6
96.6
1.8
23.4
310
0.30J
0.11
14.9

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%

2.3
0.57
0.57
0.57
1.1
1.1
0.0077
0.10

06/18/13 14:03
06/18/13 14:03
06/18/13 14:03
06/18/13 14:03
06/18/13 14:03
06/18/13 14:03
06/18/13 08:12
06/18/13 13:16

83.4
41.7J
125
6.4
72.1
0.19J
17.9
8.9
0.039
14.1

ug/kg
ug/kg
ug/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%

58.2
58.2
58.2
2.0
0.49
0.49
0.49
0.98
0.0061
0.10

06/19/13 11:16
06/19/13 11:16
06/19/13 11:16
06/18/13 14:05
06/18/13 14:05
06/18/13 14:05
06/18/13 14:05
06/18/13 14:05
06/18/13 08:14
06/18/13 13:16

8.6
68.7
0.41J
13.5
25.6
0.012
13.7

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%

2.1
0.51
0.51
0.51
1.0
0.0072
0.10

06/18/13 14:07
06/18/13 14:07
06/18/13 14:07
06/18/13 14:07
06/18/13 14:07
06/18/13 08:17
06/18/13 13:16

5.6
54.7
0.39J
13.6
11.7
0.023
17.3J
33.9
36.6
49.1
31.3
27.1
65.7
12.3J
49.0
23.0
36.5
38.9

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

2.3
0.57
0.57
0.57
1.1
0.0071
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3

06/18/13 14:14
06/18/13 14:14
06/18/13 14:14
06/18/13 14:14
06/18/13 14:14
06/18/13 08:19
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 6 of 63

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079703004

GP-4

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Naphthalene
Phenanthrene
Pyrene
Percent Moisture

4079703005

GP-5

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Mercury
Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Percent Moisture

4079703006

GP-6(S)

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM

Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
Phenanthrene
Pyrene

Units

Report Limit

Analyzed

19.7J
78.0
53.1
18.0

ug/kg
ug/kg
ug/kg
%

20.3
20.3
20.3
0.10

06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 13:16

24.5
24.3
0.68
15.4
21.2
1.8J
0.32J
0.45
232
693
915
858
1120
560
585
1180
165
2520
268
487
120
131
593
2380
1990
29.7

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

2.6
0.64
0.64
0.64
1.3
2.6
1.3
0.0092
119
119
119
119
119
119
119
119
119
119
119
119
119
119
119
119
119
0.10

06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 08:21
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/18/13 13:16

141
80.6
237
252
285
247
153
314
74.1
383
174
9.3J
212
596

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1

06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 7 of 63

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079703006

GP-6(S)

ASTM D2974-87

Percent Moisture

4079703007

GP-6(D)

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Chrysene
Fluoranthene
Pyrene
Percent Moisture

4079703008

GP-7

ASTM D2974-87

Percent Moisture

16.9 %

4079703009

GP-8

EPA 8270 by SIM


ASTM D2974-87

Benzo(k)fluoranthene
Percent Moisture

4079703010

GP-9

ASTM D2974-87

Percent Moisture

Units

4079703011

GP-10

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Percent Moisture

4079703012

GP-11

EPA 6010
EPA 6010

Arsenic
Barium

Report Limit

Analyzed

0.10

06/18/13 14:21

20.3
20.3
20.3
20.3
20.3
20.3
0.10

06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 14:22

13.3 %

0.10

06/18/13 14:22

4.4J ug/kg
18.6 %

20.5
0.10

06/18/13 17:25
06/18/13 14:22

16.6 %

0.10

06/18/13 14:22

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

2.1
0.54
0.54
0.54
1.1
0.0064
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
0.10

06/18/13 14:18
06/18/13 14:18
06/18/13 14:18
06/18/13 14:18
06/18/13 14:18
06/18/13 08:23
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 14:22

4.9 mg/kg
101 mg/kg

2.3
0.58

06/18/13 14:20
06/18/13 14:20

10.0J
11.6J
9.2J
12.8J
13.6J
13.6J
17.9

2.6
14.6
0.23J
5.8
6.9
0.024
20.6
16.2J
102
285
384
470
283
328
392
103
510
20.8
252
11.0J
11.4J
313
449
15.6

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 8 of 63

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079703012

GP-11

EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Cadmium
Chromium
Lead
Mercury
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Percent Moisture

4079703013

GP-13

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Silver
Mercury
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
Phenanthrene
Pyrene
Percent Moisture

4079703014

GP-14

EPA 6010

Arsenic

Units

Report Limit

Analyzed

0.78
14.3
69.9
0.10
18.5J
89.3
132
133
102
89.5
132
24.1
194
81.9
9.2J
21.4J
140
200
25.1

mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

0.58
0.58
1.2
0.0083
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
0.10

06/18/13 14:20
06/18/13 14:20
06/18/13 14:20
06/18/13 08:25
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/18/13 14:22

19.0
85.8
3.1
30.9
404
0.47J
0.10
393J
588J
1710
3610
3580
4710
2290
2120
4930
827
9870
1020
2010
414J
9470
7700
15.1

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

2.2
0.56
0.56
0.56
1.1
1.1
0.0073
785
785
785
785
785
785
785
785
785
785
785
785
785
785
785
785
0.10

06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 08:27
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/18/13 14:22

15.4 mg/kg

4.1

06/19/13 09:18

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 9 of 63

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079703014

GP-14

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Barium
Cadmium
Chromium
Lead
Silver
Mercury
Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Percent Moisture

4079703015

GP-22

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Percent Moisture

Units

Report Limit

Analyzed

134
2.1
13.8
1190
0.43J
0.068
798
2340
3160
3290
4290
2180
2340
4730
565J
10600
860
1920
169J
1010
9560
7800
12.8

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

0.52
1.0
0.52
2.1
1.0
0.0072
764
764
764
764
764
764
764
764
764
764
764
764
764
764
764
764
0.10

06/18/13 14:25
06/19/13 09:18
06/18/13 14:25
06/19/13 09:18
06/18/13 14:25
06/18/13 08:29
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/18/13 14:22

5.8
45.4
0.61
14.7
82.7
0.070
29.2
24.8
125
184
257
134
186
228
52.5
171
112
89.5
137
248
136
179
8.1

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%

1.9
0.46
0.46
0.46
0.93
0.0067
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
0.10

06/18/13 14:27
06/18/13 14:27
06/18/13 14:27
06/18/13 14:27
06/18/13 14:27
06/18/13 08:31
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/18/13 14:22

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 10 of 63

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab Sample ID

Client Sample ID

Method

Parameters

4079703016

GP-26

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7471
ASTM D2974-87

Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Percent Moisture

4079703017

GP-2(D)

ASTM D2974-87

Percent Moisture

Result

7.1
60.8
0.37J
13.4
186
0.036
10.3

Units

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%

10.3 %

Report Limit

Analyzed

2.1
0.53
0.53
0.53
1.1
0.0058
0.10

06/18/13 14:30
06/18/13 14:30
06/18/13 14:30
06/18/13 14:30
06/18/13 14:30
06/18/13 08:37
06/18/13 14:22

0.10

06/18/13 14:22

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 11 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-1

Lab ID: 4079703001

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3541


<29.4
<29.4
<29.4
<29.4
<29.4
<29.4
<29.4
<29.4

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

89 %
102 %

58.8
58.8
58.8
58.8
58.8
58.8
58.8
58.8

29.4
29.4
29.4
29.4
29.4
29.4
29.4
29.4

40-130
48-130

1
1
1
1
1
1
1
1

06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30

06/19/13 11:50
06/19/13 11:50
06/19/13 11:50
06/19/13 11:50
06/19/13 11:50
06/19/13 11:50
06/19/13 11:50
06/19/13 11:50

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/18/13 12:30 06/19/13 11:50 877-09-8


06/18/13 12:30 06/19/13 11:50 2051-24-3

Analytical Method: EPA 6010 Preparation Method: EPA 3050


50.6
96.6
1.8
23.4
310
<0.68
0.30J

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.3
0.57
0.57
0.57
1.1
2.3
1.1

0.62
0.099
0.058
0.14
0.33
0.68
0.24

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:03
06/18/13 14:03
06/18/13 14:03
06/18/13 14:03
06/18/13 14:03
06/18/13 14:03
06/18/13 14:03

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.11 mg/kg

0.0077

0.0038

06/17/13 16:14 06/18/13 08:12 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.8
<9.8
<9.8
<9.8
<3.5
<9.8
<9.8
<3.5
<9.8
<9.8
<9.8
<9.8
<9.8
<3.5
<9.8
<9.8
<9.8
<9.8

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60 %

19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
19.6
40-130

9.8
9.8
9.8
9.8
3.5
9.8
9.8
3.5
9.8
9.8
9.8
9.8
9.8
3.5
9.8
9.8
9.8
9.8

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29
06/18/13 14:29

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

06/18/13 06:50 06/18/13 14:29 321-60-8

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 12 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-1

Lab ID: 4079703001

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Surrogates
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


70 %

40-130

06/18/13 06:50 06/18/13 14:29 1718-51-0

Analytical Method: ASTM D2974-87


14.9 %

0.10

0.10

06/18/13 13:16

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 13 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-2

Lab ID: 4079703002

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3541


<29.1
<29.1
<29.1
<29.1
<29.1
83.4
41.7J
125

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

88 %
96 %

58.2
58.2
58.2
58.2
58.2
58.2
58.2
58.2

29.1
29.1
29.1
29.1
29.1
29.1
29.1
29.1

40-130
48-130

1
1
1
1
1
1
1
1

06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30

06/19/13 11:16
06/19/13 11:16
06/19/13 11:16
06/19/13 11:16
06/19/13 11:16
06/19/13 11:16
06/19/13 11:16
06/19/13 11:16

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/18/13 12:30 06/19/13 11:16 877-09-8


06/18/13 12:30 06/19/13 11:16 2051-24-3

Analytical Method: EPA 6010 Preparation Method: EPA 3050


6.4
72.1
0.19J
17.9
8.9
<0.58
<0.21

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.0
0.49
0.49
0.49
0.98
2.0
0.98

0.53
0.085
0.050
0.12
0.29
0.58
0.21

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:05
06/18/13 14:05
06/18/13 14:05
06/18/13 14:05
06/18/13 14:05
06/18/13 14:05
06/18/13 14:05

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.039 mg/kg

0.0061

0.0030

06/17/13 16:14 06/18/13 08:14 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.7
<9.7
<9.7
<9.7
<3.5
<9.7
<9.7
<3.4
<9.7
<9.7
<9.7
<9.7
<9.7
<3.4
<9.7
<9.7
<9.7
<9.7

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

59 %

19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
19.4
40-130

9.7
9.7
9.7
9.7
3.5
9.7
9.7
3.4
9.7
9.7
9.7
9.7
9.7
3.4
9.7
9.7
9.7
9.7

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46
06/18/13 14:46

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

06/18/13 06:50 06/18/13 14:46 321-60-8

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 14 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-2

Lab ID: 4079703002

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Surrogates
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


60 %

40-130

06/18/13 06:50 06/18/13 14:46 1718-51-0

Analytical Method: ASTM D2974-87


14.1 %

0.10

0.10

06/18/13 13:16

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 15 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-3

Lab ID: 4079703003

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3541


<29.0
<29.0
<29.0
<29.0
<29.0
<29.0
<29.0
<29.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

90 %
102 %

58.0
58.0
58.0
58.0
58.0
58.0
58.0
58.0

29.0
29.0
29.0
29.0
29.0
29.0
29.0
29.0

40-130
48-130

1
1
1
1
1
1
1
1

06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30

06/19/13 12:07
06/19/13 12:07
06/19/13 12:07
06/19/13 12:07
06/19/13 12:07
06/19/13 12:07
06/19/13 12:07
06/19/13 12:07

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/18/13 12:30 06/19/13 12:07 877-09-8


06/18/13 12:30 06/19/13 12:07 2051-24-3

Analytical Method: EPA 6010 Preparation Method: EPA 3050


8.6
68.7
0.41J
13.5
25.6
<0.61
<0.22

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.1
0.51
0.51
0.51
1.0
2.1
1.0

0.56
0.089
0.052
0.13
0.30
0.61
0.22

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:07
06/18/13 14:07
06/18/13 14:07
06/18/13 14:07
06/18/13 14:07
06/18/13 14:07
06/18/13 14:07

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.012 mg/kg

0.0072

0.0036

06/17/13 16:14 06/18/13 08:17 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.7
<9.7
<9.7
<9.7
<3.4
<9.7
<9.7
<3.4
<9.7
<9.7
<9.7
<9.7
<9.7
<3.4
<9.7
<9.7
<9.7
<9.7

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60 %

19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
19.3
40-130

9.7
9.7
9.7
9.7
3.4
9.7
9.7
3.4
9.7
9.7
9.7
9.7
9.7
3.4
9.7
9.7
9.7
9.7

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04
06/18/13 15:04

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

06/18/13 06:50 06/18/13 15:04 321-60-8

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 16 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-3

Lab ID: 4079703003

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Surrogates
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


64 %

40-130

06/18/13 06:50 06/18/13 15:04 1718-51-0

Analytical Method: ASTM D2974-87


13.7 %

0.10

0.10

06/18/13 13:16

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 17 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-4

Lab ID: 4079703004

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3541


<30.5
<30.5
<30.5
<30.5
<30.5
<30.5
<30.5
<30.5

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

83 %
100 %

60.9
60.9
60.9
60.9
60.9
60.9
60.9
60.9

30.5
30.5
30.5
30.5
30.5
30.5
30.5
30.5

40-130
48-130

1
1
1
1
1
1
1
1

06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30

06/19/13 12:25
06/19/13 12:25
06/19/13 12:25
06/19/13 12:25
06/19/13 12:25
06/19/13 12:25
06/19/13 12:25
06/19/13 12:25

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/18/13 12:30 06/19/13 12:25 877-09-8


06/18/13 12:30 06/19/13 12:25 2051-24-3

Analytical Method: EPA 6010 Preparation Method: EPA 3050


5.6
54.7
0.39J
13.6
11.7
<0.67
<0.24

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.3
0.57
0.57
0.57
1.1
2.3
1.1

0.61
0.099
0.058
0.14
0.33
0.67
0.24

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:14
06/18/13 14:14
06/18/13 14:14
06/18/13 14:14
06/18/13 14:14
06/18/13 14:14
06/18/13 14:14

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.023 mg/kg

0.0071

0.0036

06/17/13 16:14 06/18/13 08:19 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<10.2
<10.2
17.3J
33.9
36.6
49.1
31.3
27.1
65.7
12.3J
49.0
<10.2
23.0
36.5
38.9
19.7J
78.0
53.1

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

63 %

20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
40-130

10.2
10.2
10.2
10.2
3.6
10.2
10.2
3.6
10.2
10.2
10.2
10.2
10.2
3.6
10.2
10.2
10.2
10.2

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17
06/18/13 18:17

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

06/18/13 06:50 06/18/13 18:17 321-60-8

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 18 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-4

Lab ID: 4079703004

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Surrogates
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


64 %

40-130

06/18/13 06:50 06/18/13 18:17 1718-51-0

Analytical Method: ASTM D2974-87


18.0 %

0.10

0.10

06/18/13 13:16

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 19 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-5

Lab ID: 4079703005

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3541


<35.6
<35.6
<35.6
<35.6
<35.6
<35.6
<35.6
<35.6

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

89 %
96 %

71.2
71.2
71.2
71.2
71.2
71.2
71.2
71.2

35.6
35.6
35.6
35.6
35.6
35.6
35.6
35.6

40-130
48-130

1
1
1
1
1
1
1
1

06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30
06/18/13 12:30

06/19/13 12:42
06/19/13 12:42
06/19/13 12:42
06/19/13 12:42
06/19/13 12:42
06/19/13 12:42
06/19/13 12:42
06/19/13 12:42

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/18/13 12:30 06/19/13 12:42 877-09-8


06/18/13 12:30 06/19/13 12:42 2051-24-3

Analytical Method: EPA 6010 Preparation Method: EPA 3050


24.5
24.3
0.68
15.4
21.2
1.8J
0.32J

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.6
0.64
0.64
0.64
1.3
2.6
1.3

0.69
0.11
0.065
0.16
0.37
0.76
0.27

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 14:16
06/18/13 14:16

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.45 mg/kg

0.0092

0.0046

06/17/13 16:14 06/18/13 08:21 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


232
<59.3
693
915
858
1120
560
585
1180
165
2520
268
487
120
131
593
2380
1990

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

61 %

119
119
119
119
119
119
119
119
119
119
119
119
119
119
119
119
119
119
40-130

59.3
59.3
59.3
59.3
21.1
59.3
59.3
20.9
59.3
59.3
59.3
59.3
59.3
21.0
59.3
59.3
59.3
59.3

5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11
06/19/13 10:11

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

06/18/13 06:50 06/19/13 10:11 321-60-8

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 20 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-5

Lab ID: 4079703005

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Surrogates
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


62 %

40-130

06/18/13 06:50 06/19/13 10:11 1718-51-0

Analytical Method: ASTM D2974-87


29.7 %

0.10

0.10

06/18/13 13:16

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 21 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-6(S)

Lab ID: 4079703006

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<20.0
141
80.6
237
252
285
247
153
314
74.1
383
<20.0
174
9.3J
<20.0
<20.0
212
596

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

68 %
79 %

40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1

20.0
20.0
20.0
20.0
7.1
20.0
20.0
7.1
20.0
20.0
20.0
20.0
20.0
7.1
20.0
20.0
20.0
20.0

40-130
40-130

2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43
06/19/13 08:43

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

2
2

06/18/13 06:50 06/19/13 08:43 321-60-8


06/18/13 06:50 06/19/13 08:43 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 22 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-6(S)

Lab ID: 4079703006

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42
06/17/13 18:42

106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

101 %
110 %
99 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133
49-130

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

1
1
1

06/17/13 13:34 06/17/13 18:42 1868-53-7


06/17/13 13:34 06/17/13 18:42 2037-26-5
06/17/13 13:34 06/17/13 18:42 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 23 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-6(S)

Lab ID: 4079703006

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


16.9 %

0.10

0.10

06/18/13 14:21

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 24 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-6(D)

Lab ID: 4079703007

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<10.2
<10.2
<10.2
<10.2
10.0J
11.6J
<10.2
9.2J
12.8J
<10.2
13.6J
<10.2
<10.2
<3.6
<10.2
<10.2
<10.2
13.6J

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

64 %
64 %

20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3
20.3

10.2
10.2
10.2
10.2
3.6
10.2
10.2
3.6
10.2
10.2
10.2
10.2
10.2
3.6
10.2
10.2
10.2
10.2

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08
06/18/13 19:08

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 19:08 321-60-8


06/18/13 06:50 06/18/13 19:08 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 25 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-6(D)

Lab ID: 4079703007

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05
06/17/13 19:05

106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

90 %
98 %
88 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133
49-130

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

1
1
1

06/17/13 13:34 06/17/13 19:05 1868-53-7


06/17/13 13:34 06/17/13 19:05 2037-26-5
06/17/13 13:34 06/17/13 19:05 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 26 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-6(D)

Lab ID: 4079703007

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


17.9 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 27 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-7

Lab ID: 4079703008

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.6
<9.6
<9.6
<9.6
<3.4
<9.6
<9.6
<3.4
<9.6
<9.6
<9.6
<9.6
<9.6
<3.4
<9.6
<9.6
<9.6
<9.6

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

63 %
63 %

19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2
19.2

9.6
9.6
9.6
9.6
3.4
9.6
9.6
3.4
9.6
9.6
9.6
9.6
9.6
3.4
9.6
9.6
9.6
9.6

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19
06/18/13 13:19

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 13:19 321-60-8


06/18/13 06:50 06/18/13 13:19 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 28 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-7

Lab ID: 4079703008

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28
06/17/13 19:28

106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

95 %
104 %
93 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133
49-130

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

1
1
1

06/17/13 13:34 06/17/13 19:28 1868-53-7


06/17/13 13:34 06/17/13 19:28 2037-26-5
06/17/13 13:34 06/17/13 19:28 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 29 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-7

Lab ID: 4079703008

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


13.3 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 30 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-8

Lab ID: 4079703009

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<10.2
<10.2
<10.2
<10.2
<3.6
<10.2
<10.2
4.4J
<10.2
<10.2
<10.2
<10.2
<10.2
<3.6
<10.2
<10.2
<10.2
<10.2

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

63 %
62 %

20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5
20.5

10.2
10.2
10.2
10.2
3.6
10.2
10.2
3.6
10.2
10.2
10.2
10.2
10.2
3.6
10.2
10.2
10.2
10.2

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50
06/18/13 06:50

06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25
06/18/13 17:25

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 06:50 06/18/13 17:25 321-60-8


06/18/13 06:50 06/18/13 17:25 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 31 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-8

Lab ID: 4079703009

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51
06/17/13 19:51

106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

102 %
110 %
98 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133
49-130

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

1
1
1

06/17/13 13:34 06/17/13 19:51 1868-53-7


06/17/13 13:34 06/17/13 19:51 2037-26-5
06/17/13 13:34 06/17/13 19:51 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 32 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-8

Lab ID: 4079703009

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


18.6 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 33 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-9

Lab ID: 4079703010

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<10
<10
<10
<10
<3.6
<10
<10
<3.5
<10
<10
<10
<10
<10
<3.5
<10
<10
<10
<10

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

76 %
76 %

20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0

10
10
10
10
3.6
10
10
3.5
10
10
10
10
10
3.5
10
10
10
10

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00

06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15
06/18/13 16:15

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:00 06/18/13 16:15 321-60-8


06/18/13 07:00 06/18/13 16:15 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 34 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-9

Lab ID: 4079703010

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14
06/17/13 20:14

106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

108 %
114 %
101 %

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
60.0
57-130
54-133
49-130

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

1
1
1

06/17/13 13:34 06/17/13 20:14 1868-53-7


06/17/13 13:34 06/17/13 20:14 2037-26-5
06/17/13 13:34 06/17/13 20:14 460-00-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 35 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-9

Lab ID: 4079703010

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: ASTM D2974-87


16.6 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 36 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-10

Lab ID: 4079703011

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


2.6
14.6
0.23J
5.8
6.9
<0.64
<0.23

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.1
0.54
0.54
0.54
1.1
2.1
1.1

0.58
0.093
0.055
0.13
0.31
0.64
0.23

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:18
06/18/13 14:18
06/18/13 14:18
06/18/13 14:18
06/18/13 14:18
06/18/13 14:18
06/18/13 14:18

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.024 mg/kg

0.0064

0.0032

06/17/13 16:14 06/18/13 08:23 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


20.6
16.2J
102
285
384
470
283
328
392
103
510
20.8
252
11.0J
<9.9
11.4J
313
449

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

88 %
91 %

19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8
19.8

9.9
9.9
9.9
9.9
3.5
9.9
9.9
3.5
9.9
9.9
9.9
9.9
9.9
3.5
9.9
9.9
9.9
9.9

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00

06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25
06/18/13 19:25

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:00 06/18/13 19:25 321-60-8


06/18/13 07:00 06/18/13 19:25 1718-51-0

Analytical Method: ASTM D2974-87


15.6 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 37 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-11

Lab ID: 4079703012

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


4.9
101
0.78
14.3
69.9
<0.68
<0.25

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.3
0.58
0.58
0.58
1.2
2.3
1.2

0.63
0.10
0.059
0.14
0.34
0.68
0.25

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:20
06/18/13 14:20
06/18/13 14:20
06/18/13 14:20
06/18/13 14:20
06/18/13 14:20
06/18/13 14:20

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.10 mg/kg

0.0083

0.0041

06/17/13 16:14 06/18/13 08:25 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<11.1
<11.1
18.5J
89.3
132
133
102
89.5
132
24.1
194
<11.1
81.9
9.2J
<11.1
21.4J
140
200

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

83 %
98 %

22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3
22.3

11.1
11.1
11.1
11.1
4.0
11.1
11.1
3.9
11.1
11.1
11.1
11.1
11.1
3.9
11.1
11.1
11.1
11.1

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00

06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52
06/19/13 09:52

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:00 06/19/13 09:52 321-60-8


06/18/13 07:00 06/19/13 09:52 1718-51-0

Analytical Method: ASTM D2974-87


25.1 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 38 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-13

Lab ID: 4079703013

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


19.0
85.8
3.1
30.9
404
<0.66
0.47J

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.2
0.56
0.56
0.56
1.1
2.2
1.1

0.61
0.097
0.057
0.14
0.33
0.66
0.24

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.10 mg/kg

0.0073

0.0037

06/17/13 16:14 06/18/13 08:27 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


393J
588J
1710
3610
3580
4710
2290
2120
4930
827
9870
1020
2010
414J
<393
<393
9470
7700

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

67 %
70 %

785
785
785
785
785
785
785
785
785
785
785
785
785
785
785
785
785
785

393
393
393
393
140
393
393
138
393
393
393
393
393
139
393
393
393
393

40-130
40-130

40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40

06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00

06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17
06/19/13 09:17

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

40
40

06/18/13 07:00 06/19/13 09:17 321-60-8


06/18/13 07:00 06/19/13 09:17 1718-51-0

Analytical Method: ASTM D2974-87


15.1 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 39 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-14

Lab ID: 4079703014

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


15.4
134
2.1
13.8
1190
<0.61
0.43J

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

4.1
0.52
1.0
0.52
2.1
2.1
1.0

1.1
0.090
0.11
0.13
0.61
0.61
0.22

2
1
2
1
2
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/19/13 09:18
06/18/13 14:25
06/19/13 09:18
06/18/13 14:25
06/19/13 09:18
06/18/13 14:25
06/18/13 14:25

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.068 mg/kg

0.0072

0.0036

06/17/13 16:14 06/18/13 08:29 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


798
<382
2340
3160
3290
4290
2180
2340
4730
565J
10600
860
1920
169J
<382
1010
9560
7800

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

0 %
0 %

764
764
764
764
764
764
764
764
764
764
764
764
764
764
764
764
764
764

382
382
382
382
136
382
382
135
382
382
382
382
382
135
382
382
382
382

40-130
40-130

40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40

06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00

06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34
06/19/13 09:34

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

40
40

06/18/13 07:00 06/19/13 09:34 321-60-8


06/18/13 07:00 06/19/13 09:34 1718-51-0

S4
S4

Analytical Method: ASTM D2974-87


12.8 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 40 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-22

Lab ID: 4079703015

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


5.8
45.4
0.61
14.7
82.7
<0.55
<0.20

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

1.9
0.46
0.46
0.46
0.93
1.9
0.93

0.50
0.081
0.047
0.12
0.27
0.55
0.20

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:27
06/18/13 14:27
06/18/13 14:27
06/18/13 14:27
06/18/13 14:27
06/18/13 14:27
06/18/13 14:27

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.070 mg/kg

0.0067

0.0033

06/17/13 16:14 06/18/13 08:31 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.1
29.2
24.8
125
184
257
134
186
228
52.5
171
<9.1
112
89.5
137
248
136
179

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

47 %
56 %

18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1
18.1

9.1
9.1
9.1
9.1
3.2
9.1
9.1
3.2
9.1
9.1
9.1
9.1
9.1
3.2
9.1
9.1
9.1
9.1

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00

06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23
06/19/13 13:23

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:00 06/19/13 13:23 321-60-8


06/18/13 07:00 06/19/13 13:23 1718-51-0

Analytical Method: ASTM D2974-87


8.1 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 41 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-26

Lab ID: 4079703016

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7471 Mercury
Mercury
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
8260 MSV Med Level Normal List
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 6010 Preparation Method: EPA 3050


7.1
60.8
0.37J
13.4
186
<0.62
<0.22

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.1
0.53
0.53
0.53
1.1
2.1
1.1

0.57
0.091
0.053
0.13
0.31
0.62
0.22

1
1
1
1
1
1
1

06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05
06/17/13 10:05

06/18/13 14:30
06/18/13 14:30
06/18/13 14:30
06/18/13 14:30
06/18/13 14:30
06/18/13 14:30
06/18/13 14:30

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7471 Preparation Method: EPA 7471


0.036 mg/kg

0.0058

0.0029

06/17/13 16:14 06/18/13 08:37 7439-97-6

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.3
<9.3
<9.3
<9.3
<3.3
<9.3
<9.3
<3.3
<9.3
<9.3
<9.3
<9.3
<9.3
<3.3
<9.3
<9.3
<9.3
<9.3

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

73 %
84 %

18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6

9.3
9.3
9.3
9.3
3.3
9.3
9.3
3.3
9.3
9.3
9.3
9.3
9.3
3.3
9.3
9.3
9.3
9.3

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00

06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32
06/18/13 16:32

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:00 06/18/13 16:32 321-60-8


06/18/13 07:00 06/18/13 16:32 1718-51-0

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37

71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5

W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 42 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-26

Lab ID: 4079703016

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0

25.0
25.0
25.0
25.0
25.0
25.0
49.8
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37

108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
96-12-8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60-5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98-82-8
99-87-6
75-09-2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4

W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W
W

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 43 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-26

Lab ID: 4079703016

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8260 MSV Med Level Normal List
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37
06/17/13 20:37

96-18-4
95-63-6
108-67-8
75-01-4
179601-23-1
95-47-6

Qual

Analytical Method: EPA 8260 Preparation Method: EPA 5035/5030B


<25.0
<25.0
<25.0
<25.0
<50.0
<25.0

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

101 %
109 %
98 %

60.0
60.0
60.0
60.0
120
60.0

25.0
25.0
25.0
25.0
50.0
25.0

57-130
54-133
49-130

1
1
1
1
1
1

06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34
06/17/13 13:34

1
1
1

06/17/13 13:34 06/17/13 20:37 1868-53-7


06/17/13 13:34 06/17/13 20:37 2037-26-5
06/17/13 13:34 06/17/13 20:37 460-00-4

W
W
W
W
W
W

Analytical Method: ASTM D2974-87


10.3 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 44 of 63

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Sample: GP-2(D)

Lab ID: 4079703017

Collected: 06/14/13 00:00

Received: 06/15/13 12:01

Matrix: Solid

Results reported on a "dry-weight" basis


Parameters
8270 MSSV PAH by SIM
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Percent Moisture
Percent Moisture

Results

Units

LOQ

LOD

DF

Prepared

Analyzed

CAS No.

Qual

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3546


<9.3
<9.3
<9.3
<9.3
<3.3
<9.3
<9.3
<3.3
<9.3
<9.3
<9.3
<9.3
<9.3
<3.3
<9.3
<9.3
<9.3
<9.3

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

78 %
90 %

18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6
18.6

9.3
9.3
9.3
9.3
3.3
9.3
9.3
3.3
9.3
9.3
9.3
9.3
9.3
3.3
9.3
9.3
9.3
9.3

40-130
40-130

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00
06/18/13 07:00

06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58
06/18/13 15:58

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:00 06/18/13 15:58 321-60-8


06/18/13 07:00 06/18/13 15:58 1718-51-0

Analytical Method: ASTM D2974-87


10.3 %

0.10

0.10

06/18/13 14:22

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 45 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

QC Batch:

MERP/3700

Analysis Method:

EPA 7471

QC Batch Method:

EPA 7471

Analysis Description:

7471 Mercury

Associated Lab Samples:


METHOD BLANK:

4079703001, 4079703002, 4079703003, 4079703004, 4079703005, 4079703011, 4079703012, 4079703013,


4079703014, 4079703015, 4079703016

809241

Associated Lab Samples:

Parameter

Matrix: Solid
4079703001, 4079703002, 4079703003, 4079703004, 4079703005, 4079703011, 4079703012, 4079703013,
4079703014, 4079703015, 4079703016
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers

Mercury

mg/kg

LABORATORY CONTROL SAMPLE:

809242

Parameter
Mercury

<0.0033

Spike
Conc.

Units
mg/kg

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
Mercury

LCS
Result

.17

0.042

06/18/13 07:48

% Rec
Limits

LCS
% Rec
0.15

809243

10231800001
Units
Result
mg/kg

0.0067

92

Qualifiers

85-115

809244
MS
Spike
Conc.

MSD
Spike
Conc.
.2

MS
Result
.2

0.22

MSD
Result

MS
% Rec

0.21

91

MSD
% Rec
84

% Rec
Limits
85-115

Max
RPD RPD
5

Qual

20 M0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 46 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

QC Batch:

MPRP/8637

Analysis Method:

EPA 6010

QC Batch Method:

EPA 3050

Analysis Description:

6010 MET

Associated Lab Samples:


METHOD BLANK:

4079703001, 4079703002, 4079703003, 4079703004, 4079703005, 4079703011, 4079703012, 4079703013,


4079703014, 4079703015, 4079703016

809183

Associated Lab Samples:

Parameter

Matrix: Solid
4079703001, 4079703002, 4079703003, 4079703004, 4079703005, 4079703011, 4079703012, 4079703013,
4079703014, 4079703015, 4079703016
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers

Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

LABORATORY CONTROL SAMPLE:

809184

Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver

<0.54
<0.087
<0.051
<0.13
<0.29
<0.59
<0.21

Spike
Conc.

Units
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver

LCS
Result

50
50
50
50
50
50
25

4.7
124
0.32J
12.1
200
<0.67
<0.24

06/18/13 13:34
06/18/13 13:34
06/18/13 13:34
06/18/13 13:34
06/18/13 13:34
06/18/13 13:34
06/18/13 13:34

LCS
% Rec
48.4
50.4
48.2
49.5
49.0
47.3
23.7

809185

4079685001
Units
Result
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

2.0
0.50
0.50
0.50
1.0
2.0
1.0

% Rec
Limits
97
101
96
99
98
95
95

Qualifiers

80-120
80-120
80-120
80-120
80-120
80-120
80-120

809186
MS
Spike
Conc.
56.4
56.4
56.4
56.4
56.4
56.4
28.2

MSD
Spike
Conc.
56.4
56.4
56.4
56.4
56.4
56.4
28.2

MS
Result
56.6
198
53.3
67.8
188
51.8
26.4

MSD
Result

MS
% Rec

57.7
210
53.5
68.0
215
52.0
26.8

92
131
94
99
-22
92
93

MSD
% Rec
94
153
94
99
26
92
95

% Rec
Limits
75-125
75-125
75-125
75-125
75-125
75-125
75-125

Max
RPD RPD
2
6
0
0
13
0
2

Qual

20
20 M0
20
20
20 M0
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 47 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

QC Batch:

MSV/20116

Analysis Method:

EPA 8260

QC Batch Method:

EPA 5035/5030B

Analysis Description:

8260 MSV Med Level Normal List

Associated Lab Samples:


METHOD BLANK:

4079703006, 4079703007, 4079703008, 4079703009, 4079703010, 4079703016

809334

Associated Lab Samples:


Parameter

Matrix: Solid
4079703006, 4079703007, 4079703008, 4079703009, 4079703010, 4079703016
Blank
Reporting
Analyzed
Units
Result
Limit

1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<49.8
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0

60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
250
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0

Qualifiers

06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 48 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

METHOD BLANK:

809334

Associated Lab Samples:


Parameter

Matrix: Solid
4079703006, 4079703007, 4079703008, 4079703009, 4079703010, 4079703016
Blank
Reporting
Analyzed
Units
Result
Limit

m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
p-Isopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane

<50.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
85
89
92

809335
Units

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

120
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
49-130
57-130
54-133

Qualifiers

06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05
06/17/13 14:05

809336
Spike
Conc.
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500

LCS
Result
2770
2670
2720
2700
2750
2660
2130
2540
2640
2750
2790
2630
2620
2690
2420
2560
2770
2530
2620
2560

LCSD
Result
2700
2610
2670
2620
2700
2590
2070
2450
2570
2540
2680
2540
2520
2620
2370
2550
2530
2480
2550
2540

LCS LCSD
% Rec % Rec
111
107
109
108
110
106
85
102
105
110
112
105
105
108
97
102
111
101
105
102

108
104
107
105
108
104
83
98
103
102
107
102
101
105
95
102
101
99
102
101

% Rec
Limits
70-130
70-130
70-130
70-130
64-130
68-130
50-150
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
63-130
41-142
70-130
70-130
57-130

Max
RPD

RPD
2
2
2
3
2
2
3
4
3
8
4
3
4
3
2
0
9
2
3
1

Qualifiers

20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 49 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
o-Xylene
Styrene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)

809335
Units

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%

809336
Spike
Conc.
2500
2500
2500
2500
2500
2500
2500
2500
5000
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500
2500

LCS
Result
2600
2750
2620
2360
2400
2540
2740
2800
5580
2560
2760
2810
2640
2650
2690
2650
2490
2660
2690
2820

LCSD
Result
2540
2660
2550
2300
2330
2450
2660
2720
5480
2510
2640
2770
2550
2550
2630
2620
2450
2590
2660
2720

LCS LCSD
% Rec % Rec
104
110
105
94
96
101
110
112
112
102
110
113
106
106
107
106
100
106
108
113
104
103
101

102
107
102
92
93
98
106
109
110
100
106
111
102
102
105
105
98
104
106
109
102
98
102

% Rec
Limits
70-130
57-130
70-130
70-130
70-130
31-150
65-137
70-130
64-139
69-130
70-130
63-135
69-130
70-130
70-130
70-130
70-130
70-130
50-150
57-130
49-130
57-130
54-133

Max
RPD

RPD
2
3
3
2
3
4
3
3
2
2
4
2
3
4
2
1
2
3
1
4

Qualifiers

20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 50 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

QC Batch:

OEXT/18642

Analysis Method:

EPA 8082

QC Batch Method:

EPA 3541

Analysis Description:

8082 GCS PCB

Associated Lab Samples:


METHOD BLANK:

4079703001, 4079703002, 4079703003, 4079703004, 4079703005

809863

Associated Lab Samples:


Parameter

Matrix: Solid
4079703001, 4079703002, 4079703003, 4079703004, 4079703005
Blank
Reporting
Analyzed
Units
Result
Limit

PCB-1016 (Aroclor 1016)


PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

LABORATORY CONTROL SAMPLE:

809864

Parameter
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)

<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
97
79

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)

Spike
Conc.

Units

LCS
Result

809865

<29.4
<29.4
<29.4
<29.4
<29.4
<29.4
<29.4

06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06
06/19/13 10:06

LCS
% Rec

<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
507

500

4079703001
Units
Result
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

50.0
50.0
50.0
50.0
50.0
50.0
50.0
48-130
40-130

Qualifiers

% Rec
Limits

101
102
84

Qualifiers

70-130
48-130
40-130

809866
MS
Spike
Conc.

588

MSD
Spike
Conc.

588

MS
Result
<29.4
<29.4
<29.4
<29.4
<29.4
<29.4
594

MSD
Result

MS
% Rec

<29.4
<29.4
<29.4
<29.4
<29.4
<29.4
602

101
98
83

MSD
% Rec

102
101
89

% Rec
Limits

40-149
48-130
40-130

Max
RPD RPD

Qual

31
31
31
31
31
31
31

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 51 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

QC Batch:

OEXT/18628

Analysis Method:

EPA 8270 by SIM

QC Batch Method:

EPA 3546

Analysis Description:

8270/3546 MSSV PAH by SIM

Associated Lab Samples:


METHOD BLANK:

4079703001, 4079703002, 4079703003, 4079703004, 4079703005, 4079703006, 4079703007, 4079703008,


4079703009

809525

Associated Lab Samples:

Parameter

Matrix: Solid
4079703001, 4079703002, 4079703003, 4079703004, 4079703005, 4079703006, 4079703007, 4079703008,
4079703009
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers

1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

LABORATORY CONTROL SAMPLE:

809526

Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene

<2.9
<8.3
<8.3
<8.3
<8.3
<8.3
<3.0
<8.3
<8.3
<2.9
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
61
70

Units
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

Spike
Conc.
333
333
333
333
333
333
333
333
333
333
333
333
333
333
333
333

16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
40-130
40-130

LCS
Result

06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41
06/18/13 10:41

% Rec
Limits

LCS
% Rec
223
205
253
248
265
200
228
223
234
230
262
243
218
248
236
194

67
61
76
74
80
60
68
67
70
69
78
73
65
74
71
58

Qualifiers

47-130
48-130
55-130
55-130
66-130
55-130
56-130
53-130
51-130
52-130
58-130
55-130
62-130
58-130
54-130
41-130

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 52 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

LABORATORY CONTROL SAMPLE:

809526

Parameter
Phenanthrene
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

ug/kg
ug/kg
%
%

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

Spike
Conc.

Units

Units
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

333
333

213
220

809527

4079703008
Result
<3.4
<9.6
<9.6
<9.6
<9.6
<9.6
<3.4
<9.6
<9.6
<3.4
<9.6
<9.6
<9.6
<9.6
<9.6
<9.6
<9.6
<9.6

LCS
% Rec

LCS
Result

% Rec
Limits
64
66
71
76

Qualifiers

60-130
51-130
40-130
40-130

809528
MS
Spike
Conc.
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384

MSD
Spike
Conc.
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384
384

MS
Result
228
217
261
260
271
186
236
187
225
259
270
235
219
249
231
216
222
214

MSD
Result

MS
% Rec

215
222
263
252
258
153
194
150
195
239
237
198
195
191
202
227
199
187

59
57
68
68
71
48
61
49
58
67
70
61
57
65
60
56
58
56
67
65

MSD
% Rec
56
58
68
66
67
40
50
39
51
62
62
52
51
50
53
59
52
49
62
54

% Rec
Limits
42-130
34-130
31-130
32-130
39-131
29-130
35-130
21-142
12-134
35-130
37-130
23-130
29-137
32-130
17-134
24-130
27-135
24-130
40-130
40-130

Max
RPD RPD
6
2
1
3
5
20
19
22
14
8
13
17
11
27
13
5
11
13

Qual

32
35
35
25
38
30
33
44
33
37
38
27
50
32
28
40
46
49

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 53 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

QC Batch:

OEXT/18629

Analysis Method:

EPA 8270 by SIM

QC Batch Method:

EPA 3546

Analysis Description:

8270/3546 MSSV PAH by SIM

Associated Lab Samples:


METHOD BLANK:

4079703010, 4079703011, 4079703012, 4079703013, 4079703014, 4079703015, 4079703016, 4079703017

809529

Associated Lab Samples:


Parameter

Matrix: Solid
4079703010, 4079703011, 4079703012, 4079703013, 4079703014, 4079703015, 4079703016, 4079703017
Blank
Reporting
Analyzed
Units
Result
Limit
Qualifiers

1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%

LABORATORY CONTROL SAMPLE:

809530

Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene

<2.9
<8.3
<8.3
<8.3
<8.3
<8.3
<3.0
<8.3
<8.3
<2.9
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
<8.3
78
84

Units
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg

Spike
Conc.
333
333
333
333
333
333
333
333
333
333
333
333
333
333
333
333
333

16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
16.7
40-130
40-130

LCS
Result

06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16
06/18/13 11:16

% Rec
Limits

LCS
% Rec
295
272
336
331
356
245
311
268
304
316
363
312
286
322
305
274
280

88
82
101
99
107
73
93
80
91
95
109
94
86
97
91
82
84

Qualifiers

47-130
48-130
55-130
55-130
66-130
55-130
56-130
53-130
51-130
52-130
58-130
55-130
62-130
58-130
54-130
41-130
60-130

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 54 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

LABORATORY CONTROL SAMPLE:

809530

Parameter
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

Units
ug/kg
%
%

Spike
Conc.
333

LCS
% Rec

LCS
Result
311

% Rec
Limits
93
90
91

Qualifiers

51-130
40-130
40-130

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 55 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

QC Batch:

PMST/8584

Analysis Method:

ASTM D2974-87

QC Batch Method:

ASTM D2974-87

Analysis Description:

Dry Weight/Percent Moisture

Associated Lab Samples:


SAMPLE DUPLICATE:

4079703001, 4079703002, 4079703003, 4079703004, 4079703005

809919

Parameter
Percent Moisture

Units
%

4079739003
Result
7.1

Dup
Result

Max
RPD

RPD
6.9

Qualifiers
10

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 56 of 63

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

QC Batch:

PMST/8585

Analysis Method:

ASTM D2974-87

QC Batch Method:

ASTM D2974-87

Analysis Description:

Dry Weight/Percent Moisture

Associated Lab Samples:


SAMPLE DUPLICATE:

4079703006, 4079703007, 4079703008, 4079703009, 4079703010, 4079703011, 4079703012, 4079703013,


4079703014, 4079703015, 4079703016, 4079703017

810007

Parameter
Percent Moisture

Units
%

4079739001
Result
7.2

Dup
Result

Max
RPD

RPD
7.2

Qualifiers
10

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 57 of 63

#=QL#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALIFIERS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-G

Pace Analytical Services - Green Bay

BATCH QUALIFIERS
Batch: MSV/20118
[M5]

A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.

Batch: MSSV/5759
Benzo(b)fluoranthene and benzo(k)fluoranthene were in the check standard but did not meet the resolution criteria in
[IP]
SW846 Method 8270C. Whereas sample results included are reported as individual isomers, the lab and the customer
must recognize them as an isomeric pair.
Batch: MSSV/5760
Benzo(b)fluoranthene and benzo(k)fluoranthene were in the check standard but did not meet the resolution criteria in
[IP]
SW846 Method 8270C. Whereas sample results included are reported as individual isomers, the lab and the customer
must recognize them as an isomeric pair.
ANALYTE QUALIFIERS
M0

Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.

S4

Surrogate recovery not evaluated against control limits due to sample dilution.

Non-detect results are reported on a wet weight basis.

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 58 of 63

#=CR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA CROSS REFERENCE TABLE


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab ID

Sample ID

QC Batch Method

QC Batch

Analytical Method

Analytical
Batch

4079703001
4079703002
4079703003
4079703004
4079703005

GP-1
GP-2
GP-3
GP-4
GP-5

EPA 3541
EPA 3541
EPA 3541
EPA 3541
EPA 3541

OEXT/18642
OEXT/18642
OEXT/18642
OEXT/18642
OEXT/18642

EPA 8082
EPA 8082
EPA 8082
EPA 8082
EPA 8082

GCSV/9725
GCSV/9725
GCSV/9725
GCSV/9725
GCSV/9725

4079703001
4079703002
4079703003
4079703004
4079703005
4079703011
4079703012
4079703013
4079703014
4079703015
4079703016

GP-1
GP-2
GP-3
GP-4
GP-5
GP-10
GP-11
GP-13
GP-14
GP-22
GP-26

EPA 3050
EPA 3050
EPA 3050
EPA 3050
EPA 3050
EPA 3050
EPA 3050
EPA 3050
EPA 3050
EPA 3050
EPA 3050

MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637
MPRP/8637

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010

ICP/7673
ICP/7673
ICP/7673
ICP/7673
ICP/7673
ICP/7673
ICP/7673
ICP/7673
ICP/7673
ICP/7673
ICP/7673

4079703001
4079703002
4079703003
4079703004
4079703005
4079703011
4079703012
4079703013
4079703014
4079703015
4079703016

GP-1
GP-2
GP-3
GP-4
GP-5
GP-10
GP-11
GP-13
GP-14
GP-22
GP-26

EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471

MERP/3700
MERP/3700
MERP/3700
MERP/3700
MERP/3700
MERP/3700
MERP/3700
MERP/3700
MERP/3700
MERP/3700
MERP/3700

EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471
EPA 7471

MERC/4611
MERC/4611
MERC/4611
MERC/4611
MERC/4611
MERC/4611
MERC/4611
MERC/4611
MERC/4611
MERC/4611
MERC/4611

4079703001
4079703002
4079703003
4079703004
4079703005
4079703006
4079703007
4079703008
4079703009

GP-1
GP-2
GP-3
GP-4
GP-5
GP-6(S)
GP-6(D)
GP-7
GP-8

EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546

OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628
OEXT/18628

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM

MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759
MSSV/5759

4079703010
4079703011
4079703012
4079703013
4079703014
4079703015
4079703016
4079703017

GP-9
GP-10
GP-11
GP-13
GP-14
GP-22
GP-26
GP-2(D)

EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546
EPA 3546

OEXT/18629
OEXT/18629
OEXT/18629
OEXT/18629
OEXT/18629
OEXT/18629
OEXT/18629
OEXT/18629

EPA 8270 by SIM


EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM
EPA 8270 by SIM

MSSV/5760
MSSV/5760
MSSV/5760
MSSV/5760
MSSV/5760
MSSV/5760
MSSV/5760
MSSV/5760

4079703006
4079703007

GP-6(S)
GP-6(D)

EPA 5035/5030B
EPA 5035/5030B

MSV/20116
MSV/20116

EPA 8260
EPA 8260

MSV/20118
MSV/20118

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 59 of 63

#=CR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA CROSS REFERENCE TABLE


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079703

Lab ID

Sample ID

QC Batch Method

QC Batch

Analytical Method

Analytical
Batch

4079703008
4079703009
4079703010
4079703016

GP-7
GP-8
GP-9
GP-26

EPA 5035/5030B
EPA 5035/5030B
EPA 5035/5030B
EPA 5035/5030B

MSV/20116
MSV/20116
MSV/20116
MSV/20116

EPA 8260
EPA 8260
EPA 8260
EPA 8260

MSV/20118
MSV/20118
MSV/20118
MSV/20118

4079703001
4079703002
4079703003
4079703004
4079703005

GP-1
GP-2
GP-3
GP-4
GP-5

ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87

PMST/8584
PMST/8584
PMST/8584
PMST/8584
PMST/8584

4079703006
4079703007
4079703008
4079703009
4079703010
4079703011
4079703012
4079703013
4079703014
4079703015
4079703016
4079703017

GP-6(S)
GP-6(D)
GP-7
GP-8
GP-9
GP-10
GP-11
GP-13
GP-14
GP-22
GP-26
GP-2(D)

ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87
ASTM D2974-87

PMST/8585
PMST/8585
PMST/8585
PMST/8585
PMST/8585
PMST/8585
PMST/8585
PMST/8585
PMST/8585
PMST/8585
PMST/8585
PMST/8585

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:45 PM

without the written consent of Pace Analytical Services, Inc..

Page 60 of 63

Page 61 of 63

Page 62 of 63

Page 63 of 63

#=CL#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

LIMS USE: FR - MITCHELL BANACH


LIMS OBJECT ID: 4079704

June 19, 2013

Mitchell Banach
Ayres & Associates, Inc.
3433 Oakwood Hills Parkway
Eau Claire, WI 547017698

RE: Project: 19-0291.20 DEPT OF ADMIN.


Pace Project No.: 4079704
Dear Mitchell Banach:
Enclosed are the analytical results for sample(s) received by the laboratory on June 15, 2013. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,

Steven Mleczko
steve.mleczko@pacelabs.com
Project Manager

Enclosures

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 1 of 19

#=CP#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

CERTIFICATIONS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Green Bay Certification IDs


1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334

New York Certification #: 11888


North Dakota Certification #: R-150
South Carolina Certification #: 83006001
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 2 of 19

#=SS#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE SUMMARY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Lab ID

Sample ID

Matrix

Date Collected

Date Received

4079704001

GP-1

Water

06/14/13 00:00

06/15/13 12:01

4079704002

GP-2

Water

06/14/13 00:00

06/15/13 12:01

4079704003

GP-3

Water

06/14/13 00:00

06/15/13 12:01

4079704004

GP-4

Water

06/14/13 00:00

06/15/13 12:01

4079704005

GP-6

Water

06/14/13 00:00

06/15/13 12:01

4079704006

GP-17

Water

06/14/13 00:00

06/15/13 12:01

4079704007

GP-18

Water

06/14/13 00:00

06/15/13 12:01

4079704008

GP-19

Water

06/14/13 00:00

06/15/13 12:01

4079704009

GP-26

Water

06/14/13 00:00

06/15/13 12:01

4079704010

TRIP BLANK

Water

06/14/13 00:00

06/15/13 12:01

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 3 of 19

#=SA#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

SAMPLE ANALYTE COUNT


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Lab ID

Sample ID

4079704001

GP-1

4079704002

4079704003

4079704004

GP-2

GP-3

GP-4

Analytes
Reported

Method

Analysts

Laboratory

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7470

CMS

PASI-G

EPA 8270 by HVI

RJN

20

PASI-G

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7470

CMS

PASI-G

EPA 8270 by HVI

RJN

20

PASI-G

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7470

CMS

PASI-G

EPA 8270 by HVI

RJN

20

PASI-G

EPA 8082

BLM

10

PASI-G

EPA 6010

DLB

PASI-G

EPA 7470

CMS

PASI-G

EPA 8270 by HVI

RJN

20

PASI-G

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 4 of 19

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079704001

GP-1

EPA 6010
EPA 6010
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Barium, Dissolved
Chromium, Dissolved
Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene

4079704002

GP-2

EPA 6010
EPA 6010
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Arsenic, Dissolved
Barium, Dissolved
Acenaphthylene
Fluorene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene

4079704003

GP-3

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 7470
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Mercury, Dissolved
Acenaphthene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene

Units

Report Limit

Analyzed

62.5
2.9J
0.0095J
0.016J
0.029J
0.027J
0.026J
0.020J
0.022J
0.035J
0.0078J
0.077
0.0096J
0.016J
0.011J
0.015J
0.049J
0.069
0.074

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

5.0
5.0
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049

06/18/13 12:11
06/18/13 12:11
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33

5.0J
61.8
0.0037J
0.0056J
0.015J
0.021J
0.072
0.013J

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

20.0
5.0
0.045
0.045
0.045
0.045
0.045
0.045

06/18/13 12:14
06/18/13 12:14
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51

69.7
596
4.6J
184
81.0
0.34
0.0060J
0.011J
0.034J
0.031J
0.032J
0.023J
0.031J
0.041J
0.079
0.0054J
0.018J

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

20.0
5.0
5.0
5.0
7.5
0.20
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048

06/18/13 12:16
06/18/13 12:16
06/18/13 12:16
06/18/13 12:16
06/18/13 12:16
06/17/13 14:21
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 5 of 19

#=HO#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

HITS ONLY
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Lab Sample ID

Client Sample ID

Method

Parameters

Result

4079704003

GP-3

EPA 8270 by HVI


EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene

4079704004

GP-4

EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 6010
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Selenium, Dissolved
Silver, Dissolved
Acenaphthylene
Fluoranthene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene

Units

Report Limit

Analyzed

0.0093J
0.014J
0.049
0.062
0.081

ug/L
ug/L
ug/L
ug/L
ug/L

0.048
0.048
0.048
0.048
0.048

06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09

11.2J
160
1.2J
36.5
15.1
6.7J
3.0J
0.0051J
0.0065J
0.015J
0.029J
0.095
0.0095J
0.0081J

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

20.0
5.0
5.0
5.0
7.5
20.0
10.0
0.049
0.049
0.049
0.049
0.049
0.049
0.049

06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27

Qualifiers

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Page 6 of 19

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Sample: GP-1
Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP, Dissolved
Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Selenium, Dissolved
Silver, Dissolved
7470 Mercury, Dissolved
Mercury, Dissolved

Lab ID: 4079704001


Results

Units

Collected: 06/14/13 00:00


LOQ

LOD

Received: 06/15/13 12:01

DF

Prepared

Matrix: Water

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3510


<0.29
<0.29
<0.29
<0.29
<0.29
<0.29
<0.29
<0.29

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

76 %
94 %

0.58
0.58
0.58
0.58
0.58
0.58
0.58
0.58

0.29
0.29
0.29
0.29
0.29
0.29
0.29
0.29

37-130
34-130

1
1
1
1
1
1
1
1

06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08

06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49
06/18/13 13:49

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/17/13 08:08 06/18/13 13:49 877-09-8


06/17/13 08:08 06/18/13 13:49 2051-24-3

P2

L2

Analytical Method: EPA 6010 Preparation Method: EPA 3010


<4.2
62.5
<0.48
2.9J
<2.7
<5.2
<1.7

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

20.0
5.0
5.0
5.0
7.5
20.0
10.0

4.2
1.1
0.48
1.4
2.7
5.2
1.7

1
1
1
1
1
1
1

06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00

06/18/13 12:11
06/18/13 12:11
06/18/13 12:11
06/18/13 12:11
06/18/13 12:11
06/18/13 12:11
06/18/13 12:11

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7470 Preparation Method: EPA 7470


<0.10 ug/L

0.20

0.10

06/17/13 10:06 06/17/13 14:17 7439-97-6

8270 MSSV PAH by HVI

Analytical Method: EPA 8270 by HVI Preparation Method: EPA 3510

Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

0.0095J
<0.0038
0.016J
0.029J
0.027J
0.026J
0.020J
0.022J
0.035J
0.0078J
0.077
0.0096J
0.016J
0.011J
0.015J
0.049J
0.069
0.074

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

74 %
107 %

0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
39-130
73-155

0.0042
0.0038
0.0053
0.0052
0.0054
0.0074
0.0088
0.011
0.0068
0.0060
0.0057
0.0042
0.0064
0.0039
0.0067
0.0036
0.0042
0.0058

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44

06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33
06/19/13 09:33

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:44 06/19/13 09:33 321-60-8


06/18/13 07:44 06/19/13 09:33 1718-51-0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 7 of 19

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Sample: GP-2
Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP, Dissolved
Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Selenium, Dissolved
Silver, Dissolved
7470 Mercury, Dissolved
Mercury, Dissolved

Lab ID: 4079704002


Results

Units

Collected: 06/14/13 00:00


LOQ

LOD

Received: 06/15/13 12:01

DF

Prepared

Matrix: Water

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3510


<0.28
<0.28
<0.28
<0.28
<0.28
<0.28
<0.28
<0.28

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

79 %
90 %

0.56
0.56
0.56
0.56
0.56
0.56
0.56
0.56

0.28
0.28
0.28
0.28
0.28
0.28
0.28
0.28

37-130
34-130

1
1
1
1
1
1
1
1

06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08

06/18/13 14:06
06/18/13 14:06
06/18/13 14:06
06/18/13 14:06
06/18/13 14:06
06/18/13 14:06
06/18/13 14:06
06/18/13 14:06

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/17/13 08:08 06/18/13 14:06 877-09-8


06/17/13 08:08 06/18/13 14:06 2051-24-3

P2

L2

Analytical Method: EPA 6010 Preparation Method: EPA 3010


5.0J
61.8
<0.48
<1.4
<2.7
<5.2
<1.7

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

20.0
5.0
5.0
5.0
7.5
20.0
10.0

4.2
1.1
0.48
1.4
2.7
5.2
1.7

1
1
1
1
1
1
1

06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00

06/18/13 12:14
06/18/13 12:14
06/18/13 12:14
06/18/13 12:14
06/18/13 12:14
06/18/13 12:14
06/18/13 12:14

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7470 Preparation Method: EPA 7470


<0.10 ug/L

0.20

0.10

06/17/13 10:06 06/17/13 14:19 7439-97-6

8270 MSSV PAH by HVI

Analytical Method: EPA 8270 by HVI Preparation Method: EPA 3510

Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

<0.0039
0.0037J
<0.0049
<0.0048
<0.0050
<0.0068
<0.0081
<0.010
<0.0062
<0.0055
<0.0052
0.0056J
<0.0059
0.015J
0.021J
0.072
0.013J
<0.0053

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

78 %
108 %

0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
0.045
39-130
73-155

0.0039
0.0035
0.0049
0.0048
0.0050
0.0068
0.0081
0.010
0.0062
0.0055
0.0052
0.0039
0.0059
0.0036
0.0061
0.0033
0.0039
0.0053

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44

06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51
06/19/13 09:51

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:44 06/19/13 09:51 321-60-8


06/18/13 07:44 06/19/13 09:51 1718-51-0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 8 of 19

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Sample: GP-3
Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP, Dissolved
Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Selenium, Dissolved
Silver, Dissolved
7470 Mercury, Dissolved
Mercury, Dissolved

Lab ID: 4079704003


Results

Units

Collected: 06/14/13 00:00


LOQ

LOD

Received: 06/15/13 12:01

DF

Prepared

Matrix: Water

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3510


<0.27
<0.27
<0.27
<0.27
<0.27
<0.27
<0.27
<0.27

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

82 %
77 %

0.54
0.54
0.54
0.54
0.54
0.54
0.54
0.54

0.27
0.27
0.27
0.27
0.27
0.27
0.27
0.27

37-130
34-130

1
1
1
1
1
1
1
1

06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08

06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23
06/18/13 14:23

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/17/13 08:08 06/18/13 14:23 877-09-8


06/17/13 08:08 06/18/13 14:23 2051-24-3

P2

L2

Analytical Method: EPA 6010 Preparation Method: EPA 3010


69.7
596
4.6J
184
81.0
<5.2
<1.7

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

20.0
5.0
5.0
5.0
7.5
20.0
10.0

4.2
1.1
0.48
1.4
2.7
5.2
1.7

1
1
1
1
1
1
1

06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00

06/18/13 12:16
06/18/13 12:16
06/18/13 12:16
06/18/13 12:16
06/18/13 12:16
06/18/13 12:16
06/18/13 12:16

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7470 Preparation Method: EPA 7470


0.34 ug/L

0.20

0.10

06/17/13 10:06 06/17/13 14:21 7439-97-6

8270 MSSV PAH by HVI

Analytical Method: EPA 8270 by HVI Preparation Method: EPA 3510

Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

0.0060J
<0.0038
0.011J
0.034J
0.031J
0.032J
0.023J
0.031J
0.041J
<0.0059
0.079
0.0054J
0.018J
0.0093J
0.014J
0.049
0.062
0.081

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

70 %
90 %

0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
0.048
39-130
73-155

0.0041
0.0038
0.0052
0.0051
0.0053
0.0072
0.0087
0.011
0.0066
0.0059
0.0056
0.0041
0.0062
0.0038
0.0065
0.0036
0.0041
0.0057

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44

06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09
06/19/13 10:09

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:44 06/19/13 10:09 321-60-8


06/18/13 07:44 06/19/13 10:09 1718-51-0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 9 of 19

#=AR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

ANALYTICAL RESULTS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Sample: GP-4
Parameters
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
PCB, Total
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
6010 MET ICP, Dissolved
Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Selenium, Dissolved
Silver, Dissolved
7470 Mercury, Dissolved
Mercury, Dissolved

Lab ID: 4079704004


Results

Units

Collected: 06/14/13 00:00


LOQ

LOD

Received: 06/15/13 12:01

DF

Prepared

Matrix: Water

Analyzed

CAS No.

Qual

Analytical Method: EPA 8082 Preparation Method: EPA 3510


<0.31
<0.31
<0.31
<0.31
<0.31
<0.31
<0.31
<0.31

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

73 %
83 %

0.62
0.62
0.62
0.62
0.62
0.62
0.62
0.62

0.31
0.31
0.31
0.31
0.31
0.31
0.31
0.31

37-130
34-130

1
1
1
1
1
1
1
1

06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08
06/17/13 08:08

06/18/13 14:40
06/18/13 14:40
06/18/13 14:40
06/18/13 14:40
06/18/13 14:40
06/18/13 14:40
06/18/13 14:40
06/18/13 14:40

12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
1336-36-3

1
1

06/17/13 08:08 06/18/13 14:40 877-09-8


06/17/13 08:08 06/18/13 14:40 2051-24-3

P2

L2

Analytical Method: EPA 6010 Preparation Method: EPA 3010


11.2J
160
1.2J
36.5
15.1
6.7J
3.0J

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

20.0
5.0
5.0
5.0
7.5
20.0
10.0

4.2
1.1
0.48
1.4
2.7
5.2
1.7

1
1
1
1
1
1
1

06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00
06/17/13 09:00

06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/18/13 12:22
06/18/13 12:22

7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7782-49-2
7440-22-4

Analytical Method: EPA 7470 Preparation Method: EPA 7470


<0.10 ug/L

0.20

0.10

06/17/13 10:06 06/17/13 14:23 7439-97-6

8270 MSSV PAH by HVI

Analytical Method: EPA 8270 by HVI Preparation Method: EPA 3510

Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogates
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

<0.0042
0.0051J
<0.0052
<0.0051
<0.0053
<0.0073
<0.0087
<0.011
<0.0067
<0.0059
0.0065J
<0.0042
<0.0063
0.015J
0.029J
0.095
0.0095J
0.0081J

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

60 %
91 %

0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
0.049
39-130
73-155

0.0042
0.0038
0.0052
0.0051
0.0053
0.0073
0.0087
0.011
0.0067
0.0059
0.0056
0.0042
0.0063
0.0039
0.0066
0.0036
0.0042
0.0057

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44
06/18/13 07:44

06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27
06/19/13 10:27

83-32-9
208-96-8
120-12-7
56-55-3
50-32-8
205-99-2
191-24-2
207-08-9
218-01-9
53-70-3
206-44-0
86-73-7
193-39-5
90-12-0
91-57-6
91-20-3
85-01-8
129-00-0

1
1

06/18/13 07:44 06/19/13 10:27 321-60-8


06/18/13 07:44 06/19/13 10:27 1718-51-0

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 10 of 19

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

QC Batch:

MERP/3699

Analysis Method:

EPA 7470

QC Batch Method:

EPA 7470

Analysis Description:

7470 Mercury Dissolved

Associated Lab Samples:


METHOD BLANK:

4079704001, 4079704002, 4079704003, 4079704004

809199

Associated Lab Samples:


Parameter

Matrix: Water
4079704001, 4079704002, 4079704003, 4079704004
Blank
Reporting
Units
Result
Limit

Mercury, Dissolved

ug/L

LABORATORY CONTROL SAMPLE:

809200

Parameter

<0.10

Mercury, Dissolved

ug/L

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
Mercury, Dissolved

Spike
Conc.

Units

Units
ug/L

0.20

LCS
Result
5

4079685014
Result

Qualifiers

06/17/13 14:00

LCS
% Rec
4.9

809201

Analyzed

% Rec
Limits
97

Qualifiers

85-115

809202
MS
Spike
Conc.

MSD
Spike
Conc.

MS
Result
4.9

MSD
Result

MS
% Rec

5.0

MSD
% Rec

% Rec
Limits

Max
RPD RPD
2

Qual

20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 11 of 19

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

QC Batch:

MPRP/8636

Analysis Method:

EPA 6010

QC Batch Method:

EPA 3010

Analysis Description:

6010 MET Dissolved

Associated Lab Samples:


METHOD BLANK:

4079704001, 4079704002, 4079704003, 4079704004

809163

Associated Lab Samples:


Parameter

Matrix: Water
4079704001, 4079704002, 4079704003, 4079704004
Blank
Reporting
Units
Result
Limit

Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Selenium, Dissolved
Silver, Dissolved

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

LABORATORY CONTROL SAMPLE:

809164

Parameter

<4.2
<1.1
<0.48
<1.4
<2.7
<5.2
<1.7

Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Selenium, Dissolved
Silver, Dissolved

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

Parameter
Arsenic, Dissolved
Barium, Dissolved
Cadmium, Dissolved
Chromium, Dissolved
Lead, Dissolved
Selenium, Dissolved
Silver, Dissolved

Spike
Conc.

Units

Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

20.0
5.0
5.0
5.0
7.5
20.0
10.0

LCS
Result

500
500
500
500
500
500
250

4079685014
Result

Qualifiers

06/18/13 11:59
06/18/13 11:59
06/18/13 11:59
06/18/13 11:59
06/18/13 11:59
06/18/13 11:59
06/18/13 11:59

LCS
% Rec
492
508
494
507
495
487
243

809165

Analyzed

% Rec
Limits
98
102
99
101
99
97
97

Qualifiers

80-120
80-120
80-120
80-120
80-120
80-120
80-120

809166
MS
Spike
Conc.

MSD
Spike
Conc.

MS
Result
495
553
491
504
497
495
245

MSD
Result

MS
% Rec

502
554
493
509
497
499
248

MSD
% Rec

% Rec
Limits

Max
RPD RPD
1
0
0
1
0
1
1

Qual

20
20
20
20
20
20
20

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 12 of 19

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

QC Batch:

OEXT/18613

Analysis Method:

EPA 8082

QC Batch Method:

EPA 3510

Analysis Description:

8082 GCS PCB

Associated Lab Samples:


METHOD BLANK:

4079704001, 4079704002, 4079704003, 4079704004

809133

Associated Lab Samples:


Parameter
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)

Matrix: Water
4079704001, 4079704002, 4079704003, 4079704004
Blank
Reporting
Units
Result
Limit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)

<0.12
<0.12
<0.12
<0.12
<0.12
<0.12
<0.12
97
77

809134
Units

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%

0.25
0.25
0.25
0.25
0.25
0.25
0.25
34-130
37-130

Analyzed

Qualifiers

06/18/13 11:30
06/18/13 11:30
06/18/13 11:30
06/18/13 11:30
06/18/13 11:30
06/18/13 11:30
06/18/13 11:30
06/18/13 11:30
06/18/13 11:30

809135
Spike
Conc.

2.5

LCS
Result
<0.12
<0.12
<0.12
<0.12
<0.12
<0.12
2.7

LCSD
Result
<0.12
<0.12
<0.12
<0.12
<0.12
<0.12
1.6

LCS LCSD
% Rec % Rec

108
101
93

63
57
46

% Rec
Limits

70-130
34-130
37-130

Max
RPD

RPD

52

Qualifiers

20
20
20
20
20
20
20 L0,R1

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 13 of 19

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

QC Batch:

OEXT/18634

Analysis Method:

EPA 8270 by HVI

QC Batch Method:

EPA 3510

Analysis Description:

8270 Water PAH by HVI

Associated Lab Samples:


METHOD BLANK:

4079704001, 4079704002, 4079704003, 4079704004

809563

Associated Lab Samples:


Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

Matrix: Water
4079704001, 4079704002, 4079704003, 4079704004
Blank
Reporting
Units
Result
Limit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene

<0.0040
<0.0068
<0.0043
<0.0039
<0.0054
<0.0053
<0.0055
<0.0075
<0.0090
<0.012
<0.0069
<0.0061
<0.0058
<0.0043
<0.0065
<0.0037
<0.0043
<0.0059
69
116

809564
Units

ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L

0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
39-130
73-155

Analyzed

Qualifiers

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809565
LCS
Result

Spike
Conc.
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2
.2

0.11
0.11
0.15
0.15
0.17
0.21
0.19
0.20
0.19
0.21
0.21
0.19
0.19
0.15
0.19
0.14
0.17

LCSD
Result
0.11
0.11
0.15
0.15
0.18
0.20
0.19
0.20
0.19
0.21
0.21
0.19
0.19
0.15
0.19
0.12
0.17

LCS LCSD
% Rec % Rec
54
54
75
75
87
103
93
99
94
107
104
93
95
76
93
69
87

54
53
74
73
89
101
95
100
94
106
106
93
93
77
93
61
86

% Rec
Limits
23-130
22-130
31-130
31-130
26-130
47-130
41-130
37-130
37-130
51-130
50-130
34-130
49-130
30-130
36-130
24-130
39-130

Max
RPD

RPD
1
1
1
2
2
2
3
2
0
1
2
0
2
1
1
11
0

Qualifiers

49
50
34
37
35
27
28
27
29
26
26
30
26
34
29
40
30

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 14 of 19

#=QC#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

LABORATORY CONTROL SAMPLE & LCSD:


Parameter
Pyrene
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)

809564
Units

ug/L
%
%

809565
Spike
Conc.

LCS
Result
.2

0.22

LCSD
Result
0.21

LCS LCSD
% Rec % Rec
108
68
101

106
66
101

% Rec
Limits
47-130
39-130
73-155

Max
RPD

RPD
2

Qualifiers

25

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 15 of 19

#=QL#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALIFIERS
Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-G

Pace Analytical Services - Green Bay

BATCH QUALIFIERS
Batch: GCSV/9716
[M5]

A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.

Batch: MSSV/5762
[M5]

A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.

ANALYTE QUALIFIERS
L0

Analyte recovery in the laboratory control sample (LCS) was outside QC limits.

L2

Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results may be biased low.

P2

Re-extraction or re-analysis could not be performed due to insufficient sample amount.

R1

RPD value was outside control limits.

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 16 of 19

#=CR#

Pace Analytical Services, Inc.


1241 Bellevue Street - Suite 9
Green Bay, WI 54302
(920)469-2436

QUALITY CONTROL DATA CROSS REFERENCE TABLE


Project:

19-0291.20 DEPT OF ADMIN.

Pace Project No.:

4079704

Lab ID

Sample ID

QC Batch Method

QC Batch

Analytical Method

Analytical
Batch

4079704001
4079704002
4079704003
4079704004

GP-1
GP-2
GP-3
GP-4

EPA 3510
EPA 3510
EPA 3510
EPA 3510

OEXT/18613
OEXT/18613
OEXT/18613
OEXT/18613

EPA 8082
EPA 8082
EPA 8082
EPA 8082

GCSV/9716
GCSV/9716
GCSV/9716
GCSV/9716

4079704001
4079704002
4079704003
4079704004

GP-1
GP-2
GP-3
GP-4

EPA 3010
EPA 3010
EPA 3010
EPA 3010

MPRP/8636
MPRP/8636
MPRP/8636
MPRP/8636

EPA 6010
EPA 6010
EPA 6010
EPA 6010

ICP/7675
ICP/7675
ICP/7675
ICP/7675

4079704001
4079704002
4079704003
4079704004

GP-1
GP-2
GP-3
GP-4

EPA 7470
EPA 7470
EPA 7470
EPA 7470

MERP/3699
MERP/3699
MERP/3699
MERP/3699

EPA 7470
EPA 7470
EPA 7470
EPA 7470

MERC/4609
MERC/4609
MERC/4609
MERC/4609

4079704001
4079704002
4079704003
4079704004

GP-1
GP-2
GP-3
GP-4

EPA 3510
EPA 3510
EPA 3510
EPA 3510

OEXT/18634
OEXT/18634
OEXT/18634
OEXT/18634

EPA 8270 by HVI


EPA 8270 by HVI
EPA 8270 by HVI
EPA 8270 by HVI

MSSV/5762
MSSV/5762
MSSV/5762
MSSV/5762

REPORT OF LABORATORY ANALYSIS


This report shall not be reproduced, except in full,

Date: 06/19/2013 03:26 PM

without the written consent of Pace Analytical Services, Inc..

Page 17 of 19

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