452 Thermodynamics and Thermochemistry

1.

The internal energy change when a system goes from state

A to B is 40 kJ/mole. If the system goes from A to B by a
reversible path and returns to state A by an irreversible path
what would be the net change in internal energy

8.

[BHU 1998; Pb. PET 2000; MP PET 2002]

[CBSE PMT 2003]

2.

(a) 40 kJ

(b) > 0 kJ

(c) < 40 kJ

(d) Zero

The correct relationship is

(a) H PV V
(c)

3.

4.

E nRT P

[DPMT 2002]

9.

(c) Entropy

(d) Free energy

Which of the following statements is true

(d) None of these

(b) E is always less than H

For CaCO 3 (s) CaO(s) CO2(g) at 977 C ; H 176 kJ

(c)

mol, then E is

(d) E is always proportional to H

[BVP 2003]

(a) 180 kJ

(b) 186.4 kJ

(c) 165.6 kJ

(d) 160 kJ

10.

Reaction

H (kJ mol )

+98.0

+14.8

II

55.5

84.6

III

+28.3

17.0

IV

40.5

+24.6

+ 34.7

0.0

S (JK

(a) Reaction I

(b) Reaction II

(c) Reaction III

(d) Reaction IV

(a) Zero
(c)

40.45 kJ K 1mol 1

E may be lesser or greater or equal to H

Mass and energy are conserved is demonstrated by

(a) First law of thermodynamics

mol )

(b) Law of conservation of energy

(c) Law of conservation of mass
(d) Modified form of Ist law of thermodynamics
11.

The enthalpy of the reaction,

H 2 (g )

1
O2 (g) H 2 O(g) is H1 and that of
2

H 2 (g )

1
O2 (g) H 2 O(l) is H 2 . Then
2

(a) H1 H 2
(c)

Molar heat capacity of water in equilibrium with ice at

constant pressure is
[IIT JEE 1997]

[KCET 2002]

[MH CET 2002]

Values of H and S for five different reactions are given

below.

(e) Reaction V
12.

[KCET 2004]

(b) H1 H 2 0

H1 H 2

(d) H1 H 2

A reaction occurs spontaneously if

[MP PET 2002; CBSE PMT 2005]

(b) Infinity ()

(a) TS H and both H and S are +ve

(d) 75.48 J K 1

(b) TS H and both H and S are +ve

Internal energy does not include

[AIIMS 1999; CPMT 2000]

(c) TS H and both H and S are +ve

(a) Nuclear energy

(d) TS H and H is +ve and S is ve

(b) Rotational energy

13.

(c) Vibrational energy

(d) Energy arising by gravitational pull
7.

(b) Enthalpy

(a) E is always greater than H

[Kerala PMT 2004; KCET 1988,90]

6.

(a) Internal energy

(b) H nRT E

On the basis of these values predict which one of these will

be spontaneous at all tempeature

5.

Heat exchanged in a chemical reaction at constant

temperature and constant pressure is called as

Two moles of an ideal gas expand spontaneously into a

vacuum. The work done is
[AMU 2000]
(a) 2 Joule

(b) 4 Joule

(c) Zero

(d) Infinite

Which expression is correct for the work done in adiabatic

reversible expansion of an ideal gas
[AMU 2002]
(a) W nRT ln

(c) W PV

V2
V1

(b) W ne ln

T2
T1

(d) W PdV
1

Thermodynamics and Thermochemistry

14.

If an endothermic reaction is non-spontaneous at freezing

point of water and becomes feasible at its boiling point, then

20.

[AIEEE 2002]

(a) H is ve , S is +ve

(c)

(c)

H and S both are ve

21.

(d) H is +ve, S is ve
15.

JK 1 mol 1

What is the entropy change (in

mol 1 at 0 o C )

) when one mole

(b) 20.13

(c) 2.013

(d) 2.198

17.

(c) Temperature T

22.

(c) 28.8 K

(d) 28800 K

The

enthalpy

(H)

change

N 2 H 4 (g) 2N(g) 4 H(g)

in

. The melting

for

the

1724 KJ mol

process

23.

(a) 160 KJ mol 1

(b) 391 KJ mol 1

(c) 1173 KJ mol 1

(d) 320 KJ mol 1

e
(b) K p

RT

(d) K p e

Go
RT

The standard enthalpy or the decomposition of N 2 O5 to

176.7 J / K . The standard free energy change for this

. What

reaction at 25 o C is

24.

[DCE 2004]

(a) 5.38 kJ

(b) 5.38 kJ

(c) 5.38 kJ

(d) 538 kJ

For the equilibrium H 2 O(l) H 2 O(g) at 1 atm and 298 K

[AIIMS 2004]

Liquid ammonia is used in refrigeration because of its

(a) Standard free energy change is equal to zero (Go 0)

[DCE 2003]

(a) High dipole moment

(b) Free energy change is less than zero (G 0)

(b) High heat of vaporisation

(c) Standard free energy change is less than zero

(c) High basicity

(Go 0)

(d) All of these

A cylinder of gas supplied by Bharat Petroleum is assumed
14 kg
to contain
of butane. It a normal family requires
20,000 kJ
of energy per day for cooking, butane gas in the
cylinder last for . Days
[Kerala PMT 2004]
( Hc of C4 H10 2658KJ per mole )
(a) 15 days

(b) 20 days

(c) 50 days

(d) 40 days

(e) 32 days

Go

NO 2 is 58.04 kJ and standard entropy of this reaction is

. If the bond

[MP PMT 2004]

19.

G o
(c) K p
RT

391 KJ mol
energy of N H bond in ammonia is
N H
is the bond energy of N N bond is 2 4

18.

The standard Gibbs free energy change Go is related to

equilibrium constant K p as
[MP PET/PMT 1998]
(a) K p RT ln G

[DPMT 2004]

(b) 30.5 K

Equilibrium constant of a reaction is related to

(d) None

28.8 JK 1

(a) 1059 K

(d) 43.8 kJ mol 1

(b) Free energy change G

30.5 kJ
One mole of NaCl (s) on melting absorbed
of heat

and its entropy is increased by

point of NaCl is

68.0 kJ mol 1

(a) Standard free energy change Go

[CBSE PMT 2003]

(a) 21.98

(b) 43.8 kJ mol 1

[AIIMS 1991]

o
of ice is converted into water at 0 C
(The enthalpy
change for the conversion of ice to liquid water is 6.0 kJ

16.

The heat of neutralization of HCl by NaOH under certain

condition is 55.9 kJ and that of HCN by NaOH is 12.1
kJ. the heat of ionization of HCN is
[MP PET 2001]
(a) 68.0 kJ mol 1

(b) H and S both are +ve

453

(d) Standard free energy change is greater than zero

(Go 0)
25.

For reaction Ag 2 O(s) 2 Ag(s) (1 / 2)O2 (g) the value of

H 30.56 kJ mol 1

and

S 0.066 kJK 1 mol 1 .

Temperature at which free energy change for reaction will

be zero, is
[MH CET 1999]
(a) 373 K

(b) 413 K

(c) 463 K

(d) 493 K

454 Thermodynamics and Thermochemistry

(SET -10)
1.

16.

40
(d) A
B

(a)

Given that : H 30.5 KJ mol 1

40
A
B

S 28.8 JK 1 28.8 10 3 KJ K 1

H 40 40 0 .
2.

(b) H E nRT .

3.

(c)

By using S

n 1 0 1

E H nRT
E 176 1

4.

5.

8.314
1240 165.6 kJ .
1000

17.

30.5
1059 K
28.8 10 3
|

means their energy 391 4 1564

(d) A spontaneous process is accompanied by decrease in

enthalpy and increase in entropy means H is
negative and S is positive.

H
(b) CP
, At equilibrium T is constant i.e. T 0,
T P

(a) H N N H (So, 4 N H bond present)

so the bond energy of N N in N 2 H 4

1724 1564 160KJ / mol

18.

(b) Ammonia has high heat of vaporisation hence is used

in refrigeration.

19.

(e) Calorific value of butane

H c
2658

45.8 KJ / gm
mol. wt.
58

(d) E Eele. Enucl. Echemical Epotential

Ekinetic (Et Ev Er ) .

7.

H
T

H H

thus CP .
6.

NaCl (s) NaCl (l)

Cylinder consist 14 Kg of butane means 14000 gm of

(c) An ideal gas under going expansion in vacuum shows,

E 0,W 0 and q 0 .

butane
1gm gives

45.8 KJ

8.

(b) H q p .

14000 gm gives

14000 45.8

9.

(c)

10.
11.

E may be greater or lesser or equal to H .

641200 KJ

H E PV E nRT.

Family need 20,000 KJ / day

(d) It is a modified form of Ist law of thermodynamics. It is

a conservation law of mass and energy.

So, H1 H 2
(b) For spontaneous reaction G should be negative
G H TS (ve) T(ve)
If TS H then G will be negative and reaction will
be spontaneous.
13.

(b) W PV .

14.

(b) H and S
spontaneous.

15.

641200
32.06 days
20,000

(a) for reaction (i) n1 0.5

for reaction (ii) n2 1.5

12.

So gas full fill the requirement for

20.

(d)

21.

(a) Go 2.303 log k.

22.

(d) K p e G

23.

(d)

24.

(b) For reaction H 2O(l) H 2 O(g)

/ RT

n 1 means positive
so when n is positive then G 0 .

both are +ve than reaction is

25.

(c)

G H TS

G 0 at equilibrium

q
6000
21.98 JK 1mol 1
(a) S rev
T
273

H TS or 30.56 T 0.066
T 463 K .

***