Mahatma Montessori CBSE School

Parent Teacher Road,Gopala Krishnan Nagar,

Madurai, Tamil Nadu, India-625007
Paper :

Chemistry

Course : Class XI Chemistry

Type : Objective

Name : ....................................

Time Duration : 30

Total Questions : 25

Enrollment No. : .......................

Max Marks : 25

Test Date : 9/7/2015

Marks Obtained : .....................

Instructions :
Answer all

Q. 1

Q. 2

Q. 3

Q. 4

Q. 5

Which of the following is a strong acid?

(Marks : 1)

(1) Methane

(2) Ethane

(3) Ethylene

(4) Acetylene

If the empirical formula for a compound is CH4, the ratio of carbon in the compound
is:
(Marks : 1)
(1) 25%

(2) 75%

(3) 40%

(4) 50%

In an experiment, it was found that 12 g of an organic compound contains 4 g of

carbon. What is the percentage of carbon in the compound?
(Marks : 1)
(1) 33.3%

(2) 20%

(3) 30%

(4) 40%

The number of sigma bonds in the molecule CH3-CH2-CH=CH-CH3 is:

(1) 14

(2) 10

(3) 15

(4) 13

Calculate the number of sigma and pi bond in ethyne?

(1) 2

,1

(2) 1

,1

(3) 1

,2

(4) 3

,2

(Marks : 1)

(Marks : 1)

Q. 6

The name of the given compound is :

(Marks : 1)

Q. 7

Q. 8

Q. 9

(1) 2,3 dimethyl pentane

(2) 2,3 dimethyl hexane

(3) Hexane

(4) 2,3 diethyl hexane

Which of the following pairs are not metamers?

(Marks : 1)

(1) Methoxy propane and ethoxy ethane

(2) 2 pentanone and 3 pentanone

(3) Methoxy propane and methoxy

isopropane

(4) Aniline and benzyl amine

In which of the following compounds, geometrical isomerism is not

possible?
(Marks : 1)
(1) 2-butene

(2) 1,2 Dichloro ethane

(3) 2-pentene

(4) 2-butane

Which of the following statements about tautomerism is incorrect?

(Marks : 1)

(1) There is a dynamic equilibrium

between equilibrium molecules.

(2) The relative stability of tautomeric

structures depends on external factors
like solvents and reagents.

(3) Tautomerism is a type of structural

isomerism.

(4) Tautomerism is possible in all organic

compounds.

Q. 10 Methyl amine is more basic than ammonia. This can be explained by :

(1) Inductive effect

(2) Mesomeric effect

(3) Photochemical reaction

(4) Hydration energy

(Marks : 1)

Q. 11 Which of the following groups attracts an electron by the -I effect and releases an
electron by the +M effect?
(Marks : 1)

(1) -NO2

(2) -NH2

(3) -Cl

(4) OH

Q. 12 Phenol is more acidic than ethanol. This can be explained by :

(Marks : 1)

(1) The + M effect of the OH group

(2) The -M effect of the OH group

(3) The +R effect of the OH group

(4) The -R effect of the OH group

Q. 13 Which of the following is the strongest acid?

(Marks : 1)

(1) o-chloro benzoic acid

(2) m-chloro benzoic acid

(3) p-chloro benzoic acid

(4) benzoic acid

Q. 14 Which of the following is not true about CH3o free radicals?

(Marks : 1)

(1) The carbon is sp3 hybridized.

(2) There is one unpaired electron on the

carbon.

(3) It is formed by homolytic fission.

(4) It is relatively stable.

Q. 15 The most reactive carbanion is:

(Marks : 1)

(1) CH3-

(2) CH3-CH2(4) (CH3)3-C-

(3)
Q. 16 The bond which is likely to generate free radicals is:

(Marks : 1)

(1) Cl-Cl bond

(2) H-Cl bond

(3) N-H bond

(4) C-N bond

Q. 17 In alkane's lower member are gases, those having carbon atom from 5 - 17 are
liquids whereas higher members are solids. Why?
(Marks : 1)
(1) Due to weak covalent bond

(2) Due to weak Vander Waals force

(3) Due to strong Vander Waals force

(4) Due to ionic bond

Q. 18 What do you mean by pyrolysis?

(Marks : 1)

(1) Decarboxylation

(2) Formation of higher alkane from

lower alkane

(3) Decomposition of higher alkane to

lower alkane

(4) Hydrolysis

Q. 19 In which projection the molecule is viewed from the molecular axis and then C-C
bond is drawn in central as straight line?
(Marks : 1)
(1) Newman projection

(2) Rotamer's

(3) In both the projections - Newman's

and Rotamer's

(4) Sawhorse projection

Q. 20 Arrange the following halogen acid in the correct order of reactivity towards alkenes.
HCl, HI, HBr
(Marks : 2)
(1) HCl > HI > HBr

(2) HCl > HBr > HI

(3) HCl < HI < HBr

(4) HI > HBr > HCl

Q. 21 Addition of HBr to alkenes in the absence of peroxide takes place according

to:
(Marks : 2)
(1) Markovnikov rule

(2) Substitution

(3) Anti-Markovnikov rule

(4) Elimination

Q. 22 Calculate the number of sigma and pi bond in ethyne?

(1) 2

,1

(2) 1

,1

(3) 1

,2

(4) 3

,2

(Marks : 2)

Q. 23 Arrange the following in the correct order of acidic strength.

Ethyne, Ethane, Ethene
(Marks : 2)
(1) Ethyne > Ethene > Ethane

(2) Ethyne < Ethane < Ethene

(3) Ethyne < Ethene < Ethane

(4) Ethyne > Ethane > Ethene

Q. 24 What is friedel crafts alkylation reaction?

(Marks : 2)

(1) Addition of alkyl group

(2) Formation of halogen

(3) Addition of oxygen

(4) Formation of benzene

Q. 25 What is friedel crafts acylation reaction?

(Marks : 2)

(1) Addition of alkyl group

(2) Addition of acyl group

(3) Addition of oxygen

(4) Addition of hydroxyl group