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JEE ADVANCED 2015 CHEMISTRY (PAPER 2)
SECTION - I
This section contains 8 questions. Each question, when worked
out will result in one integer from 0 to 9 (both inclusive).
1. Three moles of B2H6 are completely reacted with methanol.
The number of moles of boron containing product formed is
2. The molar conductivity of a solution of a weak acid HX (0.01
M) is 10 times smaller than the molar conductivity of a solution
of a weak acid HY (0.10 M). If
the difference in
l 0x – » l0y –

II.

III.

their pKa values, pKa(HX) – pKa (HY), is (consider degree of
ionization of both acids to be <<1)
3.

A closed vessel with rigid walls contains 1 mol of

238
92 U

1 mol of air at 298 K. Considering complete decay of
206
82 Pb,

4.

5.

and

238
92 U

7.

to

the ratio of the final pressure to the initial pressure of

the system at 298 K is
In dilute aqueous H2 SO 4 , the complex diaquodioxalatoferrate(II) is oxidized by MnO4 –. For this reaction, the
ratio of the rate of change of [H+] to the rate of change of
[MnO4–] is
The number of hydroxyl group(s) in Q is
H+

IV.

aqueous dilute KMnO (excess)

4
¾¾¾
® P ¾¾¾¾¾¾¾¾¾¾¾
®Q
heat
0° C

8.

H O

2
¾¾¾
®
100°C

H2
¾¾¾¾¾
®
Pd - BaSO
4

DIBAL –H
¾¾¾¾¾¾
®
Toluene,–78°C
H 2O

In
the
complex
acetylbromidodicarbonylbis
(triethylphosphine) iron (II), the number of Fe–C bond(s) is
Among the complex ions, [Co(NH2–CH2–CH2–NH2)2Cl2]+,
[CrCl2(C2O4)2]3–, [Fe(H2O)4(OH)2]+, [Fe(NH3)2(CN)4]–,
[Co(NH2–CH2–CH2–NH2)2(NH3)Cl]2+ and
[Co(NH3)4(H2O)Cl]2+, the number of complex ion(s) that
show(s) cis-trans isomerism is
SECTION - II

This section contains 8 multiple choice questions. Each question
has 4 choices (a), (b), (c) and (d) out of which ONE or MORE
THAN ONE are correct.
9.

The major product U in the following reactions is
CH =CH–CH , H+

6.

Among the following, the number of reaction(s) that
produce(s) benzaldehyde is

I.

radical, initiator, O

2
3

¾¾¾¾¾¾¾¾
® T ¾¾¾¾¾¾¾¾
high pressure, heat

CO, HCl
¾¾¾¾¾¾¾¾
®
Anhydrous AlCl / CuCl
3

3

(a)

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2 (b) (b) The number of lone pairs of electrons on Cl in (ii) and (iii) together is three (c) The hybridization of Cl in (iv) is sp3 (d) Amongst (i) to (iv). the compounds used for preparation of linear polymer and for chain termination. is(are) (a) (c) The number of Cl=O bonds in (ii) and (iii) together is two Buy books : http://www. the major product W is NaNO2 . When O2 is adsorbed on a metallic surface.dishapublication. One mole of a monoatomic real gas satisfies the equation p(V – b) = RT where b is a constant. The correct statement(s) regarding. the strongest acid is (i) 12. NaOH (b) Heat is released (c) * Occupancy of p2r of O2 is increased (d) Bond length of O2 is increased 0°C (a) (a) 15. Fe3+ (c) Cu2+. Pb2+ (d) Hg2+.html . are (c) (d) 10. respectively. electron transfer occurs from the metal to O2. The pair(s) of ions where BOTH the ions are precipitated upon passing H2S gas in presence of dilute HCl. (ii) HClO2. In the following reactions.com/entrance-exams-books/engineering-exams. (i) HClO. Zn2+ (b) Bi3+. Bi3+ 13. (iii) HClO3 and (iv) HClO4. Under hydrolytic conditions. is(are) Ba2+. The relationship of interatomic potential V(r) and interatomic distance r for the gas is given by OH OH (b) N=N (a) OH (c) N=N (b) (d) N=N 11. The true statement(s) regarding this adsorption is(are) OH (a) O2 is physisorbed . HCl N=N (a) CH3SiCl3 and Si(CH3)4 (b) (CH3)2SiCl2 and (CH3)3SiCl (c) (CH3)2SiCl2 and CH3SiCl3 (d) SiCl4 and (CH3)3SiCl 14.

0 M NaOH (under identical conditions to Expt. Compound X is (a) (b) (c) (d) (c) 20. Enthalpy of dissociation (in from the Expt. four questions related to the two paragraphs with two questions on each paragraph.0 (c) 24. each describing theory. H 2 O H2O (a) HgSO 4 .6 °C was measured. In the following reactions.0 (d) 7. Each question has one or more than one correct answer(s) among the four given options (a).0 (d) 51.dishapublication.5 kJ mol–1) of acetic acid obtained (b) 10.H 2SO 4 C8 H 8 O (b) (i) EtMgBr. (b) PARAGRAPH 1 (c) When 100 mL of 1.3 17. data etc. H2 O ¾¾ ¾ ¾ ¾® Y (ii) H + .2 J g–1 K–1 and density of all solutions as 1. In a second experiment (Expt.0 × 10–5) was mixed with 100 mL of 1.0 16.0 g mL–1) Buy books : http://www. this experiment could be used to measure the calorimeter constant.1).7 (c) 5.8 (b) 4.0 M NaOH in an insulated beaker at constant pressure.III (a) This section contains 2 paragraphs. the product S is PARAGRAPH 2 In the following reactions C8 H6 Pd . 1) where a temperature rise of 5.com/entrance-exams-books/engineering-exams. heat 19. NaOH.BaSO 4 H2 C8 H8 (i) B2 H6 ¾¾¾¾¾¾¾ ®X (ii)H 2 O 2 . The major compound Y is (d) SECTION . (d) (Consider heat capacity of all solutions as 4. Because the enthalpy of neutralization of a strong acid with a strong base is a constant (–57. 100 mL of 2.0 M acetic acid (Ka = 2.0 M HCl was mixed with 100 mL of 1. The pH of the solution after Expt. (b).html .7 °C was measured for the beaker and its contents (Expt.4 18. a temperature increase of 5.0 kJ mol–1).2 is (a) 1. experiments. (c) and (d). 2 is (d) (a) 2. 2).

2– Methyl Shift + –H + + OH CH CH 3 3 aq.dishapublication. at start (ni) = 1 Now number of moles in gas phase.01( l m ) HX 0.4 1.com/entrance-exams-books/engineering-exams.1 PF n 9 = F = =9 Pin n in 1 ( lm ) 2 HY (l°m ) æ ( l m ) HX ö = 0. HCl Anhyd AlCl3 /CuCl OH (Gatterman Koch Reaction) OH CHCl 2 CHO CH H2O OH 100°C COCl H2 Pd–BaSO 4 COOMe – H 2O CHO (Rosenmund Reduction) CHO DIBAL–H Toluene. (4) CO.1 ç ÷ = 10–3 è 10 ø Hence.01 \ K a1 Ka 2 ( ) 0.1ç ÷ è ( l m ) HY ø Number of moles in gas phase.1( l m )HY 2 = 0. 2. dilute KMnO4excess 0°C OH OH OH CHO 6. SOLUTIONS (6) (3) 3B2H6 + 18CH3OH ® 6B(OCH3)3 + 18H2 1 ® HX 2 ® HY a1 = ( l m )HX a2 = l°m K a1 = C1a12 ( = 0. –78°C H2O Buy books : http://www. after decomposition (n F) = 1 + 8 = 9 mole at constant temperature and pressure l °m ) 2 l m HX 2 l°m (9) 206 4 0 238 92 U ®82 Pb + 82 He + 6 – b ( l m )HY K a 2 = C2a 22 2 = 3. (8) 8H+ + 5[Fe(H2O)2(OX)2]2– + MnO4– ® Mn2+ + + 5 [Fe(H2O)2(OX)2]– + 4H2O 2 d[MnO 4– ] 1 d[H + ] =– dt 8 dt Rate = 2 æ 1ö = 0.html . K a1 pKa(HX) – pKa(HY) = –log K = –log10–3 = 3 rate of [H + ]decay rate of [MnO 4– ] decay =8 a2 H 5. (4) H + – H2O D 1. 2 4.

heat Cumene. c) Cl Cl–O–H O (i) Cl Cl OH O (ii) O OH (iii) O O OH (iv) Number of Cl = O bonds in (ii) and (iii) together is 3 Number of lone pairs on Cl in (ii) and (iii) together is 3 Hybridisation of Cl in all the four is sp3 Strongest acid is HClO4 (iv) Buy books : http://www. HO 2 en Cl Cl .5 CO Et3P O 7. O 2 High Pressure. (3) CH3– C – Fe +2 Et3P 8. (a) O 11. (b.H (b) en Co + CN Fe CN CN NC CN NC NH3 Fe NH3 CN CN (Co(NH3)4(H2O)Cl]2+ NH3 NH3 Cl NH3 Co NH3 NH3 H3N NH3 H3N OH2 Co Cl NH3 NH3 Radical. (6) – Br CO All the complexes given show cis-trans isomerism [Co (NH2 — CH2 — CH2 — NH2) Cl2] + [CrCl2(C2O4)2]3– Cl en Cl ox en Co en en Co ox Cr ox ox Cr Cl Cl Cl Cl [Fe(H2O)4(OH)2]+ HO 2 HO 2 OH Fe OH OH2 OH2 [Fe(NH3)2(CN)4]– OH HO 2 OH HN 3 Fe HO 2 OH2 OH2 HN 3 [Co(NH2–CH2–CH2–NH2)2(NH3)Cl]2+ en en Co Cl 9.com/entrance-exams-books/engineering-exams.html . initiator. T Cumene hydroperoxide.dishapublication. U – NH 2 10.

7 Þ (C + 200 × 4. c. This means. H2O Pd-BaSO4 C8 H 6 H2 O 20.com/entrance-exams-books/engineering-exams.1 = 4.6 = 5600 J. Overall.7 0. Þ DHneutralization of CH3COOH = 57 – 56 = 1 KJ/mol (b) Final solution contain 0.dishapublication.7 × 1000 = (C + 200 × 4. B 2H6 ii. H+. 1 = 0.7 × 1000 = (C + 200 + 4. 16.1 3 18.2) × 5. H 2O –2H2O 17. 1 = 0. repulsive tendencies will be dominant when interatomic distance are small.7 KJ = 5. This means . Hence it is a buffer solution.1 = – 56000 J/mol = – 56 KJ/mol.7 × 1000 J Þ 5. nNaOH = – 0.2) J/K Moles of acid. H2 O2 .1 × 57 = 5.1 × 1 = 0.1 mol of CH3COOH undergo neutralization. (b) (CH3)2SiCl2 form linear polymer on hydrolysis and (CH3)3SiCl is a chain terminator. base neutralised in expt.1 Buy books : http://www. d) Only group II cations precipitate as sulphide with H2S in acidic medium that is (Cu2+. interatomic potential is never negative but becomes positive at small interatomic distances. 5. (a) PV Pb = +1 RT RT Z =1+ NH 3 (i) O3 (ii) Zn. NaOH. H2O ii. only 0. Mass of aqueous content in expt. Et MgBr. 14. pH = pKa log 19.1 mole of CH3COOH and CH3COONa each. (b. –5600 Þ DHneutralization of CH3COOH = 0. Pb2+) and (Hg2+. Þ – ® O2– O2 + e – ¾¾ This is an example of chemisorption. (c) OH i.] [CH3COOH] = 5–log 2 + log 0. d) Reaction on metal surface + ®M + e M ¾¾ 15.2) × D´T. (c) P(V–b) = RT Þ PV – Pb = RT Þ Pb RT Hence Z > 1 at all pressures. Total mass of aqueous content = 200 g Þ Total heat capacity = (C + 200 × 4. (a) Let the heat capacity of insulated beaker be C. (c. 1 = (100 + 100) × 1 = 200 g Þ ± Total heat capacity = (C + 200 × 4.1 Þ Heat released in expt.2) = 1000 In second experiment. Heat Y [CH3COO. Bi3+) 13.2.html . nCH COOH = 0.6 12.2) = 1000 Þ Heat released = 1000 × 5. H2SO4 i. (d) C8H6 H2O HgSO4 .