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JEE ADVANCED 2015 CHEMISTRY (PAPER 2)
SECTION - I
This section contains 8 questions. Each question, when worked
out will result in one integer from 0 to 9 (both inclusive).
1. Three moles of B2H6 are completely reacted with methanol.
The number of moles of boron containing product formed is
2. The molar conductivity of a solution of a weak acid HX (0.01
M) is 10 times smaller than the molar conductivity of a solution
of a weak acid HY (0.10 M). If
the difference in
l 0x – » l0y –

II.

III.

their pKa values, pKa(HX) – pKa (HY), is (consider degree of
ionization of both acids to be <<1)
3.

A closed vessel with rigid walls contains 1 mol of

238
92 U

1 mol of air at 298 K. Considering complete decay of
206
82 Pb,

4.

5.

and

238
92 U

7.

to

the ratio of the final pressure to the initial pressure of

the system at 298 K is
In dilute aqueous H2 SO 4 , the complex diaquodioxalatoferrate(II) is oxidized by MnO4 –. For this reaction, the
ratio of the rate of change of [H+] to the rate of change of
[MnO4–] is
The number of hydroxyl group(s) in Q is
H+

IV.

aqueous dilute KMnO (excess)

4
¾¾¾
® P ¾¾¾¾¾¾¾¾¾¾¾
®Q
heat
0° C

8.

H O

2
¾¾¾
®
100°C

H2
¾¾¾¾¾
®
Pd - BaSO
4

DIBAL –H
¾¾¾¾¾¾
®
Toluene,–78°C
H 2O

In
the
complex
acetylbromidodicarbonylbis
(triethylphosphine) iron (II), the number of Fe–C bond(s) is
Among the complex ions, [Co(NH2–CH2–CH2–NH2)2Cl2]+,
[CrCl2(C2O4)2]3–, [Fe(H2O)4(OH)2]+, [Fe(NH3)2(CN)4]–,
[Co(NH2–CH2–CH2–NH2)2(NH3)Cl]2+ and
[Co(NH3)4(H2O)Cl]2+, the number of complex ion(s) that
show(s) cis-trans isomerism is
SECTION - II

This section contains 8 multiple choice questions. Each question
has 4 choices (a), (b), (c) and (d) out of which ONE or MORE
THAN ONE are correct.
9.

The major product U in the following reactions is
CH =CH–CH , H+

6.

Among the following, the number of reaction(s) that
produce(s) benzaldehyde is

I.

2
3

¾¾¾¾¾¾¾¾
® T ¾¾¾¾¾¾¾¾
high pressure, heat

CO, HCl
¾¾¾¾¾¾¾¾
®
Anhydrous AlCl / CuCl
3

3

(a)