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Question1.
250mLofxMsolutionand500mLofyMsolutionofasolutearemixedanddilutedto2Ltoproduceatsolutionhavingconcentration1.6M.
Ifx:y=5:4,thenx+yis:
[A]
[B]
[C]
[D]

8.06
8.86
9.8
12.6

Question2.
Onelitreof
[A]
[B]

0.6litreCO
0.8litre

[C]
[D]

0.6litre

ispassedoverhotcoke.Thevolumebecomes1.4litre.Thepercentcompositionofproductsis:

and0.8litreCO

noneofthese

Question3.
Thepressureofarealgasislessthanthepressureofanidealgasbecauseof:
[A]
[B]
[C]
[D]

increaseinthenumberofcollisions
finitesizeofthemolecules
increaseinthekineticenergy
intermolecularforces

Question4.
Photoelectricemissionisobservedfromasurfaceforfrequencies

and

oftheincidentradiation

kineticenergiesofthephotoelectronsinthetwocasesareintheratio1:kthenthethresholdfrequency

Ifthemaximum
isgivenby:

[A]
[B]
[C]
[D]

Question5.
Ifproton,electronand

particlehaveequalkineticenergy,theirdeBrogliewavelengthswouldbeintheorder:

[A]
[B]
[C]
[D]

Question6.
Changeinentropyisnegativefor:
[A]
[B]

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[C]
[D]

Question7.
Inconversionoflimestonetolime,
thevalueof
and
are+179.1kJmol1and160.2J/Krespectivelyat298Kand1bar.Assumingthat
donotchangewithtemperature.Temperatureabovewhichconversionoflimestonetolimewillbespontaneousis:
[A]
[B]
[C]
[D]

and

1008K
1200K
845K
1118K

Question8.
atconstantpressureis18500calat25oC.Theheatofreactionat

Theheatofformationofmethane
constantvolumewouldbe:
[A]
[B]
[C]
[D]

19096cal
18798cal
18202cal
17904cal

Question9.
Lechatelier'sprincipleisnotapplicableto:
[A]
[B]
[C]
[D]

Question10.
WhichactsbothasLowryBronstedacidandbase?
[A]
[B]
[C]
[D]

Question11.
Theprecipitateof

isobtainedwhenequalvolumesofthefollowingaremixed:

[A]
[B]
[C]
[D]

Question12.
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If50mLof0.2MKOHisaddedto40mLof0.5MHCOOH,thepHoftheresultingsolutionis:
[A]
[B]
[C]
[D]

3.75
5.6
7.5
3.4

Question13.
AccordingtoMOtheory,
[A]

isparamagneticandbondordergreaterthanO 2

[B]

isparamagneticandbondorderlessthanO 2

[C]

isdiamagneticandbondorderislessthanO 2

[D]

isdiamagneticandbondorderismorethanO 2

Question14.
IdentifytheIUPACnameoffollowingcompound.

[A]
[B]
[C]
[D]

2Hydroxy4ketohexanoicacid
Hexan2ol4on1oicacid
3Keto5hydroxyhexan1oicacid
4Keto2hydroxyhexan1oicacid

Question15.
IdentifytheIUPACnameofthefollowingcompound:

[A]
[B]
[C]
[D]

Ethyl2methylpentanoate
Ethyl1methylbutanoate
2Methylethylpentanoate
Ethyl1methylpentanoate

Question16.
Whichrepresentsthedisproportionationreaction?
[A]
[B]
[C]
[D]

Allofthese

Question17.
Selectthecorrectstatements:
[A]
[B]
[C]
[D]

H2O 2isimmisciblewithH2O
InpurestateH2O 2isdeepbluecoloured
H2O 2hasanonplanarstructure
H2O 2canonlyactasanoxidizingagent.

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Question18.
WhichoffollowingcarbonateuponheatingwillgiveCO 2.
[A]
[B]
[C]
[D]

Li2CO 3
Na2CO 3
K2CO 3
CsCO 3

Question19.
Whichonerepresentsanimpossiblearrangement?
[A]
[B]
[C]
[D]

nlms
3221/2
4001/2
3231/2
5301/2

Question20.
Agasabsorbsaphotonof355nmandemitstwowavelengths.Ifoneoftheemissionisat680nm,theotherisat:
[A]
[B]
[C]
[D]

1035nm
325nm
743nm
518nm

Question21.
Fortheprocess,

(1bar,373K),thecorrectsetofthermodynamicparametersis:

[A]
[B]
[C]
[D]

Question22.
TheheatsofneutralizationoffouracidsA,B,C,Dare19.7,9.4,11.2and12.4kcalrespectivelywhentheyareneutralizedbya
commonbase.Theacidiccharacterobeystheorder:
[A]
[B]
[C]
[D]

A>B>C>D
A>D>C>B
D>C>B>A
D>B>C>A

Question23.
Inwhichofthefollowingreactions,increaseinthepressureatconstanttemperaturedoesnotaffecttheequilibrium?
[A]
[B]
[C]
[D]

Question24.
Anequilibriummixtureofthereaction,
moleof

ina4litreflaskatconstanttemperature.Thevalueof

contains0.120moleof

moleofNOand0.640

forthereactionatthistemperatureis:

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[A]
[B]
[C]
[D]

QuestionRevision

14
24
7
28

Question25.
Whichcanactasbuffer?
[A]
[B]
[C]
[D]

40mLof0.1MNaCN+20mLof0.1MHCl
Allofthese

Question26.
Anacidbaseindicatorhas

Theacidformoftheindicatorisredandthebasicformisblue.ThepHchangerequired

tochangethecolourofsolutionfrom75%redto75%blueis:(log2=0.3,log3=0.47)
[A]
[B]
[C]
[D]

1.2
0.47
0.94
1.88

Question27.
Inthecompound

bonds(numberaccordingtoIUPAC)isof:

[A]
[B]
[C]
[D]

Question28.
AssumingthatHund'sruleisviolated,thebondorderandmagneticnatureofthediatomicmoleculeB2accordingtoMOTis:
[A]
[B]
[C]
[D]

1anddiamagnetic
0anddiamagnetic
1andparamagnetic
0andparamagnetic

Question29.
IdentifytheIUPACnameofthefollowingcompound:

[A]
[B]
[C]

Nhexylpentanamine
NpentylNhexylamine
N(
methylpentyl)hexanamine

[D]

N(

methylpentyl)heptanamine

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Question30.
ChoosethecorrectIUPACnameoffollowingcompound

[A]
[B]
[C]
[D]

Ethoxy2methylpropane
Propoxy2methylpropane
2Methylpropoxyethane
Ethoxy1methylpropane

Question31.
Thepositionvectorofaparticleis,
[A]
[B]
[C]
[D]

.Thevelocityoftheparticleis:

paralleltopositionvector
Perpendiculartopositionvector
directedtowardstheorigin
Directedawayfromtheorigin

Question32.
Inthesystemshowninfigure
accelerationofblockAis(

,and

.Thepulleysaremasslessandfrictionisabsenteverywhere.The

[A]
[B]
[C]
[D]

Question33.
Asmallsphereisgivenverticalvelocityofmagnitude
string.Theangle

anditswingsinaverticalplaneabouttheendofamassless

withtheverticalatwhichstringwillbreak,knowingthatitcanwithstandamaximumtensionequaltotwicethe

weightofthesphere,is:(

[A]

[B]
[C]
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[D]

Question34.
Apointmovesinxyplaneaccordingtothelawx=5sin(6t)andy=5(1
traversedbytheparticleint=4sis:
[A]
[B]
[C]
[D]

cos(6t)),wherexandyareinmeter.Thedistance

24m
48m
96m
120m

Question35.
Fourrodseachoflengthlhavebeenhingedtoformarhombus.VertexAisfixedtorigidsupport,vertexCisbeingmovedalongthex
axiswithaconstantvelocityvasshowninthefigure.TherateatwhichvertexBisapproachingthexaxisatthemomenttherhombusis
intheformofasquareis

[A]

[B]
[C]
[D]

Question36.
Thedistancerfromtheoriginofaparticlemovinginxyplanewithtimeas,r=2tandtheanglemadebytheradiusvectorwithpositive
xaxisis
.Here,tisinsecond,rinmetersand
inradian.Thespeedoftheparticleatt=1sis:
[A]
[B]
[C]
[D]

Question37.
AblockofmassMistiedtooneendofamasslessrope.Theotherendoftheropeisinthehandsofamanofmass2Masshownin
Figure.TheblockandthemanarerestingonaroughwedgeofmassM.Thewholesystemisrestingonasmoothhorizontalsurface.
Themanstartswalkingtowardsrightwhileholdingtheropeinhishands.Pulleyismasslessandfrictionless.Findthedisplacementofthe
wedgewhentheblockmeetsthepulley?Assumewedgeissufficientlylongsothatmandoesnotfalldown.

[A]

1/2mtowardsright

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[B]
[C]
[D]

QuestionRevision

1/2mtowardsleft
thewedgedoesnotmoveatall
1mtowardsleft

Question38.
Ingravityfreespace,aparticleisincontactwiththeinnersurfaceofahollowverticalcylinderandmovesinahorizontalcircularpath
alongthesurface.Thereissomefrictionbetweentheparticleandthesurface.Theretardationoftheparticleis:
[A]
[B]
[C]
[D]

zero
independentofitsvelocity
proportionaltoitsvelocity
proportionaltothesquareofitsvelocity

Question39.
A20gbulletpiercesthroughaplateofmassM1=1kgandthencomestorestinsideasecondplateofmassM2=2.98kgasshownin
Figure.Itisfoundthatthetwoplates,initiallyatrest,nowmovewithequalvelocities.Findthepercentagelossintheinitialvelocityofthe
bulletwhenitisbetweenM1andM2.Neglectanylossofmaterialoftheplatesduetotheactionofbullet:

[A]
[B]
[C]
[D]

Question40.
ArodABofmassMandlengthLislyingonahorizontalfrictionlesssurface.Aparticleofmassmtravellingalongthesurfacehitsthe
endAoftherodwithavelocityv 0inadirectionperpendiculartoAB.Thecollisioniscompletelyelastic.Afterthecollisiontheparticle
comestorest.Findratio
[A]
[B]
[C]
[D]

1:3
1:5
1:6
1:4

Question41.
Aflywheelrotatesaboutanaxis.Duetofrictionattheaxis,itexperiencesanangularretardationproportionaltoitsangularvelocity.Ifits
angularvelocityfallstohalfwhileitmakesnrotations,howmanymorerotationswillitmakebeforecomingtorest?
[A]
[B]
[C]
[D]

2n
n
n/2
n/3

Question42.
AdiscofmassMandradiusRisrollingpurelywithcentre'svelocityv 0onaflathorizontalfloorwhenithitsastepinthefloorofheight
R/4.Thecornerofthestepissufficientlyroughtopreventanyslippingofthediscagainstitself.Whatisthevelocityofthecentreofthe
discjustafterimpact?(Thediscdoesnotbounce)

[A]
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[B]
[C]
[D]

Noneofthese

Question43.

AblockXofmass0.5kgisheldbyalongmasslessstringonafrictionlessinclinedplaneofinclination
tothehorizontal.The
stringiswoundonauniformsolidcylindricaldrumYofmass2kgandofradius0.2masshowninfigure.Thedrumisgivenaninitial
angularvelocitysuchthatblockXstartsmovinguptheplane.Findthetensioninthestringduringthemotion.
[A]
[B]
[C]
[D]

1.63N
2.30N
0.93N
1.93N

Question44.
Thereidenticalparticleseachofmassmareplacedatthecornersofanequilateraltriangleofsidel.Theworkdonebyexternalforceto
increasethesideoftrianglefromlto2lis:
[A]

[B]

[C]

[D]

Question45.
Aparticleisthrownverticallyupwardsfromthesurfaceofearthanditreachestoamaximumheightequaltotheradiusofearth.Theratio
ofthevelocityofprojectiontotheescapevelocityonthesurfaceofearthis
[A]

[B]
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[C]

[D]

Question46.
Thedistancemovedbyaparticleinsimpleharmonicmotioninonetimeperiodis.
[A]
[B]
[C]
[D]

A
2A
4A
zero

Question47.
AparticlemoveontheXaxisaccordingtotheequation
[A]
[B]
[C]

.Themotionissimpleharmonicwithamplitude

A
B
A+B

[D]

Question48.
AparticlemovesintheXYplaneaccordingtotheequation

Themotionoftheparticleis.

[A]
[B]
[C]
[D]

(i),(iii)
(i),(iii),(iv)
(ii),(iii),(iv)
(i),(iv)

Question49.
Asquaregateofsize
ishingedattopmostpoint.Afluidofdensity
fromlowestpointwhichcanholdthegatestationaryis.

fillsthespaceleftofit.Theforcewhichacting1m

[A]
[B]
[C]

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[D]

Question50.
Aninvertedtubebarometeriskeptonaliftwhichismovingdownwardwithadecelerationa.Thedensityofmercuryis
accelerationduetogravityisg.IftheatmosphericpressurebyP0then:
[A]

heightofthemercurycolumnintheliftwillbe

[B]

heightofthemercurycolumnintheliftwillbe

[C]

heightofthemercurycolumnintheliftwillbe

[D]

heightofthemercurycolumnintheliftwillbe

and

Question51.
Asoapbubbleisbeingblownonatubeofradius1cm.Thesurfacetensionofthesoapsolutionis0.05N/mandthebubblemakesan
angleof
withthetubeasshown.Theexcessofpressureovertheatmosphericpressureinthetubeis:

[A]
[B]
[C]
[D]

5Pa
1Pa
10Pa
20Pa

Question52.
Asurveyor's30msteeltapeiscorrectatatemperatureof
daywhenthetemperatureis
[A]
[B]
[C]
[D]

.Thedistancebetweentwopoints,asmeasuredbythistapeona

,is26m.Whatisthetruedistancebetweenthepoint?

26.00468
26.00268
26.00168
26.00368

Question53.
Thespecificheatofasubstancevarieswithtemperature

Theheatrequiredtoraisethetemperatureof2gofsubstanceby
[A]
[B]
[C]
[D]

as

willbe.

55.25cal
56.25cal
89.25cal
88.25cal

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Question54.
Hotwatercoolsfrom

inthefirst10minandto

inthenext10min.Thetemperatureofthesurroundingis.

[A]
[B]
[C]
[D]

Question55.
Thelengthofametalwireisl1whenthetensioninitisT1andisl2whenthetensionisT2.Thenaturallengthofthewireis.
[A]
[B]
[C]

[D]

Question56.
TwowiresAandBaremadeofsamematerial.ThewireAhasalengthlanddiameterrwhilethewireBhasalength2landdiameterr/2.
Ifthetwowiresarestretchedbythesameforce,theelongationinAdividedbytheelongationinBis:
[A]
[B]
[C]
[D]

1/8
1/4
4
8

Question57.
Asphericalballisdroppedinalongcolumnofaviscousliquid.Thespeedoftheballasafunctionoftimemaybebestrepresentedbythe
graph.

[A]
[B]
[C]
[D]

A
B
C
D

Question58.
Theintensityleveloftwosoundsare100dBand50dB.Whatistheratiooftheirintensities?
[A]
[B]
[C]
[D]

101
103
105
1010

Question59.
Asonometerwireoflengthlvibratesinfundamentalmodewhenexcitedbyatuningforkoffrequency416Hz.Ifthelengthisdoubled
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keepingotherthingssame,thestringwill.
[A]
[B]
[C]
[D]

vibratewithafrequencyof416Hz
vibratewithfrequencyof208Hz
vibratewithafrequencyof832Hz
stopvibrating

Question60.
Theequationofdisplacementoftwowavesaregivenas

Thenwhatistheratiooftheiramplitudes
[A]
[B]
[C]
[D]

1:2
2:1
1:1
Noneofthese

Question61.
If
[A]
[B]

,then

0
,wherenismultipleof3

[C]
[D]

(wherenisapositiveinteger)maynotbeequalto:

22

Question62.
LetsetAhasnelementsandP(A)denotesthepowersetofA.FindthenumberofwaysofselectingtwoelementsfromP(A),suchthat
theyhaveexactlymelementsincommon(m<n).
[A]
[B]
[C]
[D]

Question63.
If

[A]

arethecoefficientsoftheexpansionsof

,thenthevalueof

is:

[B]

[C]
[D]

Noneofthese

Question64.
isequalto:
[A]

[B]
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[C]
[D]

QuestionRevision

3
9

Question65.
If

and

aretwosequencesgivenby

and

forall

.Then,

isequalto:
[A]
[B]

[C]

[D]

Question66.
If

isanoddfunctioninRand

,thendefinitionof

in

is:

[A]

[B]

[C]

[D]

Question67.
InthisquestioncontainstwoStatements:Statement1(Assertion)andStatement2(Reason).Eachofthesequestionsalsohasfour
alternativechoices,onlyoneofwhichisthecorrectanswer.Youhavetoselectamongoneofthecodes(A),(B),(C)and(D)given
below.
Let

Statement1:

Statement2:
[A]
[B]
[C]
[D]

Statement1isfalse,Statement2istrue
Statement1istrue,Statement2istrueStatement2isacorrectexplanationforStatement1
Statement1istrue,Statement2istrueStatement2isnotacorrectexplanationforStatement1
Statement1istrue,Statement2isfalse

Question68.
InthisquestioncontainstwoStatements:Statement1(Assertion)andStatement2(Reason).Eachofthesequestionsalsohasfour
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alternativechoices,onlyoneofwhichisthecorrectanswer.Youhavetoselectamongoneofthecodes(A),(B),(C)and(D)given
below.
Statement1:Ifbothrootsoftheequation
Statement2:If
[A]
[B]
[C]
[D]

,
,then

lieintheinterval
and

,then

Statement1isfalse,Statement2istrue
Statement1istrue,Statement2istrueStatement2isacorrectexplanationforStatement1
Statement1istrue,Statement2istrueStatement2isnotacorrectexplanationforStatement1
Statement1istrue,Statement2isfalse

Question69.
If

,thenthevalueof

is:

[A]
[B]
[C]
[D]

Question70.
Areaofatrianglewithvertices

and

,where

areinGPwithcommonratiorandb,

areinGPwithcommonratios,isgivenby:
[A]
[B]
[C]
[D]

Noneoftheabove

Question71.
If

and

,where

doesnotlieinthethirdquadrantand

liesin3rdquadrant,then

isequalto:

[A]
[B]
[C]
[D]

Question72.
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If

QuestionRevision

,where

,then

isequalto:

[A]
[B]
[C]
[D]

Question73.
Thevalueofxinthegivenequation

is:

[A]
[B]
[C]
[D]

Question74.
Thetotalnumberofpermutationsofndifferentthingstakennotmorethanratatime,whereeachthingmayberepeatedanynumberof
times,is:
[A]

[B]

[C]

[D]

Question75.
Thelocusofthemiddlepointofthechordsofthecircle

whichsubtendarightangleatthecentre,is:

[A]
[B]
[C]
[D]

Question76.
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ThesumofntermsofthreeAP'swhosefirsttermis1andcommondifferencesare1,2and3are

and

,respectively.

Thetruerelationis:
[A]
[B]
[C]
[D]

Question77.
Equationofthelinewhichpassesthroughthepoint

andtheportionofthelineinterceptedbetweentheaxesisdivided

internallyintheratio5:3bythepoint,is:
[A]
[B]
[C]
[D]

Noneofthese

Question78.
If

areinAP,whosecommondifferenceis

,thenthevalueof
isequalto:

[A]

[B]
[C]
[D]

Question79.
Theequationofthecircleanditschordsarerespectively

and

.Theequationofthecircle

ofwhichthischordisadiameter,is:
[A]
[B]
[C]
[D]

Noneofthese

Question80.
Inhowmanyways10personstakeseatsinarowof24fixedseatssothatnopersontakesconsecutiveseats.
[A]

[B]

[C]
[D]

Noneofthese

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Question81.
If

andtheequation

(where[x]denotesthegreatestinteger

)hasnointegral

solution,thenallpossiblevaluesofalieintheinterval:
[A]
[B]

(1,2)

[C]
[D]

Question82.
If

,thenkbelongsto:

[A]
[B]
[C]
[D]

Question83.
Ifthecoefficientsofrth,(r+1)thand(r+2)thtermsinthebinomialexpansionof

areinAP,thenmandrsatisfytheequation

[A]
[B]
[C]
[D]

Question84.
If
[A]
[B]
[C]
[D]

,then

isequalto

110
115
120
135

Question85.
TheeccentricityofthehyperbolawhoseLatusrectumis8andconjugateaxisisequaltohalfofthedistancebetweenthefociis:
[A]

[B]

[C]
[D]

Noneofthese

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Question86.
Theequationoftheellipse,whosefocusis

,directrixistheline

andeccentricityequalsto

willbe:

[A]
[B]
[C]
[D]

Noneofthese

Question87.
Theequationoftheellipsehavingfoci

andminoraxisoflength1is:

[A]

[B]

[C]
[D]

Noneofthese

Question88.
Thelocusofthepointofintersectionoflines
[A]
[B]
[C]
[D]

and

fordifferentvaluesofkisa:

Ellipse
Parabola
Hyperbola
Noneofthese

Question89.
Theequationofthesetofallpointswhosedistancesfrom
[A]
[B]
[C]
[D]

are

oftheirdistancesfromtheline

is:

Straightline
Parabola
Ellipse
Hyperbola

Question90.
Apointequidistantfromthelines

and

is:

[A]
[B]
[C]
[D]

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