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Name the following compounds:

CH3CH=CHCH3 , CHCCH2CH3, CH2=CHCCH,


CH3CCH, CHCH CHCl2CH2C(CH3)=CHCH3,
CH3Cl
C-3 HC with a single sp3 C, CH3CH=CH2
C-5 HC with 3 methyl groups,
C-5 HC with 4 methyl groups,

C-8 HC with 6 methyl groups,


C-4 HC with 2sp2 C and 2 methyl groups, CH3CH=CHCH3
C-4 HC with mol. Formula C4H6 , no sp2 C,
CHCCH2CH3
C-6 HC with 4 methyl groups and its isomers, CH3CH(CH3)CH(CH3)CH3
C-5 HC with 1 ethyl group, CH3CH(CH3)CH2CH3
C-5 alkyne with 1 ethyl group, CHC CH2CH2CH3
an isomer of n-hexane with 4 methyl groups, CH3CH(CH3)CH(CH3)CH3
an olefin isomer of butyne, CH2=CHCH=CH2
an alkyne with two acidic H, CHCH
an alkyne with one acidic H and 3 methyl groups, CHCC(CH3)3
an alkene reducible to 2-methyl propane,
CH3C(CH3)=CH2
an alkene produced from 2-bromopropane, CH3CH=CH2
a compound that can produce propyne,
CH3CHBrCH2Br
HC with a 3o C,
CHCC(CH3)3
C-4 HC with a 2o C, C H3CH(CH3)2
alkene with a 1o C, CH4
compound with a chiral C, CABXY
compound with geometrical isomer, ABC=CAB
compound with a tetrahedral structure, CH4
a planar compound, ABC=CAB
a linier compound, CHCH
a halogenated HC, CH3Cl
HC produced from acetone, CH3CH2CH3
HC produced through Wurtz reaction, CH3CH3
HC produced through Clemmensen reduction, CH3CH2CH3
HC produced from BuLi, BuH
C-4 HC with 2 sp2 C, CH3CH=CHCH3
C-5 HC with terminal 2 sp2 C, CH3 CH2 CH2CH=CH2
Write line structures for butane, 1-butene, and 1-butyne and structural formula for the following:
3-Heptyne, 4-methyl-2-hexyne, 2-Methylpropene, E-2-Butene, eclipsed ethane,
3-methyl-2-hexene, 3,3-dimethylhexane, 3-ethyl-2,4-dimethylhexane, 5,5-dichloro-4-methyl-2-pentyne,
staggered ethane, cis-2,3-dichloropentene-2.
Give examples of constitutional isomers and stereo isomers.
What type of compound will exhibit optical isomers?
Indicate the nature of hybridization involved in the following bonds:

C=C double bond, C


C triple bond and C
C single bond. Show a regio-selective addition reaction.
Mention Sytzef rule.
How could you prepare ethane, 2-Me butane, pentane, propene, 1-butyne, acetylene, 2-Me-2-butene, 2Bromo propane, propyl bromide, acetonitrile, acetaldehyde, ethylene glycol, acetone, acetophenone?
Give important methods of preparation of alkane, alkene and alkyne. Mention their important reactions.
Give an example of electrophilic addition reaction. When does such reaction takes place according to anti
Marcownicoffs rule? What will be the resultant product of such reaction according to Marcownicoffs
addition?
5
Give examples of stereospecific reaction with a diene. When does a compound exhibit geometrical
isomerism? Show the reagents to convert an ozonide to carbonyl compounds.
5
How are alkynes synthesized? How could you prove that the terminal CH of alkynes are acidic? How
could you reduce an alkyne selectively to an alkene? 5
Produce the involved reactions in the following:
i) 2-Butyne to cis-butene, ii) Benzoic acid to benzene, iii) 2-Methyl-2-butene from 2-bromo-2methylbutane.
What will be the resultant product of addition of HBr with propene according to Marcownicoffs
addition?
5
How could you produce acetone from an alkene and actophenone from phenyl acetylene?

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