CH3CCH, CHCH CHCl2CH2C(CH3)=CHCH3, CH3Cl C-3 HC with a single sp3 C, CH3CH=CH2 C-5 HC with 3 methyl groups, C-5 HC with 4 methyl groups,
C-8 HC with 6 methyl groups,
C-4 HC with 2sp2 C and 2 methyl groups, CH3CH=CHCH3 C-4 HC with mol. Formula C4H6 , no sp2 C, CHCCH2CH3 C-6 HC with 4 methyl groups and its isomers, CH3CH(CH3)CH(CH3)CH3 C-5 HC with 1 ethyl group, CH3CH(CH3)CH2CH3 C-5 alkyne with 1 ethyl group, CHC CH2CH2CH3 an isomer of n-hexane with 4 methyl groups, CH3CH(CH3)CH(CH3)CH3 an olefin isomer of butyne, CH2=CHCH=CH2 an alkyne with two acidic H, CHCH an alkyne with one acidic H and 3 methyl groups, CHCC(CH3)3 an alkene reducible to 2-methyl propane, CH3C(CH3)=CH2 an alkene produced from 2-bromopropane, CH3CH=CH2 a compound that can produce propyne, CH3CHBrCH2Br HC with a 3o C, CHCC(CH3)3 C-4 HC with a 2o C, C H3CH(CH3)2 alkene with a 1o C, CH4 compound with a chiral C, CABXY compound with geometrical isomer, ABC=CAB compound with a tetrahedral structure, CH4 a planar compound, ABC=CAB a linier compound, CHCH a halogenated HC, CH3Cl HC produced from acetone, CH3CH2CH3 HC produced through Wurtz reaction, CH3CH3 HC produced through Clemmensen reduction, CH3CH2CH3 HC produced from BuLi, BuH C-4 HC with 2 sp2 C, CH3CH=CHCH3 C-5 HC with terminal 2 sp2 C, CH3 CH2 CH2CH=CH2 Write line structures for butane, 1-butene, and 1-butyne and structural formula for the following: 3-Heptyne, 4-methyl-2-hexyne, 2-Methylpropene, E-2-Butene, eclipsed ethane, 3-methyl-2-hexene, 3,3-dimethylhexane, 3-ethyl-2,4-dimethylhexane, 5,5-dichloro-4-methyl-2-pentyne, staggered ethane, cis-2,3-dichloropentene-2. Give examples of constitutional isomers and stereo isomers. What type of compound will exhibit optical isomers? Indicate the nature of hybridization involved in the following bonds:
C=C double bond, C
C triple bond and C C single bond. Show a regio-selective addition reaction. Mention Sytzef rule. How could you prepare ethane, 2-Me butane, pentane, propene, 1-butyne, acetylene, 2-Me-2-butene, 2Bromo propane, propyl bromide, acetonitrile, acetaldehyde, ethylene glycol, acetone, acetophenone? Give important methods of preparation of alkane, alkene and alkyne. Mention their important reactions. Give an example of electrophilic addition reaction. When does such reaction takes place according to anti Marcownicoffs rule? What will be the resultant product of such reaction according to Marcownicoffs addition? 5 Give examples of stereospecific reaction with a diene. When does a compound exhibit geometrical isomerism? Show the reagents to convert an ozonide to carbonyl compounds. 5 How are alkynes synthesized? How could you prove that the terminal CH of alkynes are acidic? How could you reduce an alkyne selectively to an alkene? 5 Produce the involved reactions in the following: i) 2-Butyne to cis-butene, ii) Benzoic acid to benzene, iii) 2-Methyl-2-butene from 2-bromo-2methylbutane. What will be the resultant product of addition of HBr with propene according to Marcownicoffs addition? 5 How could you produce acetone from an alkene and actophenone from phenyl acetylene?