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District level midterm Examination, November 2015
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Time :3.15 Hours

Inetructions :

1) The question paper has four parts

zlod epoddd,: : 70
Max. Marks :70

[341

A, B, c & D all parts are compulsory.

2) Write balanced chemical equations & draw labeled diagram wherever reguired.

PART.A

Answer all tirc following questions.


l. Defineunitceli.

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What is osmotic pressure.


What is secondary cell.
Name the process employed for the purification ofnickel.

Identifytheproduct"A" inthe foilorlixrereaction.


xeF6 + 3HrO ----)A + 6HF.

10.

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6. Writethe structureofhlpochlorousacid. \
7. Giveanexampleforallylichalides. \
8. WritethelUpACnameof(CH3)rCH-CHO. t'\.
9. Name the oxidising agent used in hydrobo ation oxidation ofalkene

g.

2.
3.
4.
5.

10X1:10

Give an exanple for non-reducing sugar.

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PART - B

Answer anyFive of the following.

lL

defect. \

i3.

write the anode and cathode reaction of dry cell or leclanche cell,

14.

Explain froath flotation process.

5.

5
'-

2:10

'

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12.

Give any two differencess between schottky defect and frenkel


Whatare non-Ideal solutions? Give an example.

How does PCl, reacts with water? Give equations.


What is wurE-fitting reaction? Give an example.

PART - C

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III.

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16.
17. How do you prepare phenol from diazonium salts.
18. what is lanthanoid contraction? Mention one of it's consequences.
Answer any tr'ive of the following.
1

9.

5X3:15

Explain the extaction of alluminium by hall heroult process.

20. Describe the manufacture ofNitricacidby osfwald process with equations.


21. Explain the manufacture of concentrted HrSoo by contactprocess.
22. Giv e any three anomalous behavior of fluorine.
23. Complete the following equations.
(i)

3Mg+N,4

(ii) 2KClo,

-d+zrct +:0,

(iii) Cl, H2 O,,+ HrSO4,."6--)

24.
25

, * FIz SO4 + 11 HrO

Give the equations for the reactions involved in the preparation ofpotassium dichromate from chtoriteore.
(i) Give any two reasons for the formation of complex compound of tansirion metals.

(ii)AmongZn2* and Cn2*which is the coloured ion.

26. (i)Action

ofheat on KMnO4? Write equation

(ii) Explain the oxidising property of acidifi

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KMno4 with oxalate ion.

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PART - D

IV.

Answer any Three of the


27

following.

3X5

15

a) Calculate the packing efficiency in bcc unit cell.

b) Wlat are -b- type semiconductor? Give an example.

29

ofparticals in FCC unit cell,


b) (i) Statehenry's law. Write it's mathe matical formula.
(ii) What is the effect oftemperature on the solubility of gases in liquids.
a) Calculate the number

a) When 39 of solute in 50g ofbenzene the boiling point of solution was higher than that of benzene by 0.9K.

Kb value forbenzene is 2.53K Kg mot'. Calculate the Molarmass ofthe solate.


b) Whatis rererce osmosis? Mentionone of it's application.
b) Calculate the emf ofthe cell Fe/ Fe'?. (0.6M)/Sn2+
Given Eoo.z-/r. -0.44v and Eor,z*1s":0.14V

31.

[0.2M]pn

a) Explain the construction and working of standard hydrogen elecftode or SHE.

b) Calculate the standard freenergy change for the reaction

ib

Zrr1,y+ 2Ag-,*,F- Zfi*


6"t+ 2Ag*r
tro
1
v and
.rru IF
Lt +I 96.500C
56V
Mol
zv'Jvv \ tYrvr-'
- c"ll - r 'Jv
.

*ART

Answer any Four of the following.

32.

a)Explain SN2Mechanisfi't.
c) What are

33

ofAlkyl halides. Explain wift

4 X 5 = 20

an exanple.

b) What is dehlldro halogrnation

-E

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V.

g.

a) State faradays second law ofelecholysis.

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30.

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28.

"rrurlo*".r.

a) Explain the nitration of chlorobenzene

with equations.

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b) What is swartz reaction? Give an general equation.


c) Give an example for a grignard reagent.

to ethane.

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34. a) Write the mechanism of dehydration of ethanol

b) Give the classification of alcohols on the basis ofNerfber of -04 groups.


35

a) How do you convert phenol to salicylaldehyde? Name the reaction and write equations.

6.

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b) Explain william son's ether synthasis.


a) Explain cannizzaro's reaction by taking benzaldelyde as an example.

b) Write the equation for

(i) Clemmenson's reduction and wolflkishner reduction.


c) How do you conrent acehcacid to acetanide.

a) Write the Haworth structure of cr-D(+) maltose.


b) What are amiso acidl? Write it's general formula.

37

c) What is denaturation ofprotein?

t*t+r,<'t

X<*+*:1.

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