38 views

Uploaded by RezzaPutraSamudra

Computational Thermodynamics

- 20x20-myna
- Wacker LTC4L
- Runner 180 FXR 2T
- Microsoft Word - Tub Assembly Standard Options A.pdf
- Andrew HL4 50A
- Chapter7 Warf
- Inventure Surveillance Script February
- SBU-A Spec Sheet 2009_metric ROBBINS
- Spare Parts - Ovens
- list of Defaulters
- Manager
- Quaker STLE 1998
- Aquamatic 8T
- Spare Parts
- 3 - Pending at Reviewing Level 3
- Earthing and Grounding
- Design of Eurocode Columnxlsx
- 6082330 (1) swstick fabs.txt
- erte
- Aluminium Cans Market | Prices, Manufacturing Plant Report

You are on page 1of 30

Thermodynamics

LINA KJELLQVIST

Licentiate Thesis

Stockholm, Sweden 2006

**ISRN KTH/MSE−−06/15−−SE+THERM/AVH
**

ISBN 91-7178-318-0

KTH

SE-100 44 Stockholm

SWEDEN

**Akademisk avhandling som med tillst˚
**

and av Kungliga Tekniska h¨ogskolan framl¨agges

till offentlig granskning f¨

or avl¨

aggande av licentiatexamen tisdagen den 25 april

2006 kl 14.00 i Konferensrummet v˚

aning 4, Brinellv¨agen 23, Kungliga Tekniska

h¨ogskolan, Stockholm.

c Lina Kjellqvist, april 2006

Tryck: Universitetsservice US AB

Abstract

The main focus in the present work concerns calculations on steel/slag equilibria.

Thermodynamic software and databases are now powerful and accurate enough to

give reliable results when applied to complex metallurgical processes. One example

is the decarburization process of high alloyed steels. It is shown that using advanced

thermodynamic models, without a complicated kinetic description of the system,

reasonable agreement with experimental data is obtained. The calculations are

performed using the Thermo-Calc software.

Within this work a Java interface for Thermo-Calc has been implemented. Java

gives graphical possibilities and a graphical interface has been created that facilitates calculations that involve both metallic phases as well as oxides and make

them feasible also for an industrial user.

Keywords: steel/slag equilibria, thermodynamic modelling, thermodynamic assessment, CALPHAD, phase diagram, Thermo-Calc.

.

The following papers are included in the thesis: I Java interface for Thermo-Calc by Lina Kjellqvist II Users’ guide . Royal Institute of Technology.Interface for steel/slag/gas equilibria calculations by Lina Kjellqvist III Thermodynamic assessments of the Al2 O3 -TiO2 . CaO-TiO2 . Department of Material Science and Engineering. FeO-TiO2 .Preface The work presented in this thesis was carried out at the division of Computational Thermodynamics. Stockholm. MgO-TiO2 and MnO-TiO2 systems by Lina Kjellqvist. Malin Selleby and Bo Sundman IV Simulation of decarburization of a high alloyed liquid steel using a reactor model within Thermo-Calc by Lina Kjellqvist and Bo Sundman . Fe2 O3 -TiO2 . Sweden.

.

. 5 Concluding remarks 13 14 17 5. . . .1 Summary of appended papers . . . . . . . . . . 10 4 Decarburization of a stainless steel 4. . . . . . . . .2 Discussion and future work .3 Thermodynamic assessments of TiO2 binary systems . . . . . . . . . . . . .2 The cellular model . . . . . . . . 9 3. . 18 Bibliography 21 . . . . . . . 17 5. . . . . . . . . . . . . . . 6 3 Graphical interface for steel/slag calculations 9 3. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Simulation results . . . . . . . . . . . . . . . . . .Contents 1 Introduction 1 2 The CALPHAD technique 3 2. . . . . . . . . . . . . . . . . . . . . . .2 The steel/slag calculation interface . . . . . . . 4 2. . . . .1 Thermodynamic modelling . . . . . . . . . . . . . . 5 2.1 A Java interface for Thermo-Calc . . . .

.

C or Matlab. It is based on thermodynamic data assessed with the CALPHAD technique and minimization of Gibbs energy. Kaufman and Bernstein [2] summarized the general features of the calculation of phase diagrams. A graphical interface has been created that facilitates calculations that involve both metallic phases as well as oxides and make 1 . This progress will continue as model descriptions are improved and computational technology advances. Thermodynamic software and databases are now powerful and accurate enough to give reliable results when applied to complex metallurgical processes. It is possible to use Thermo-Calc in user-written programs through one of the Thermo-Calc programming interfaces. Fortran. The purpose of the present work is to incorporate thermodynamic models into metallurgical processes. The correlation between thermodynamics and phase equilibria was established in the 19th century by Gibbs [1]. Application programmers can retrieve thermodynamic data and calculate phase equilibria directly from within their own programs. thus laying the foundation for the CALPHAD [3] method. As a part of this work a software interface in Java has been implemented. written in e. which will be useful in the development of user-friendly application software with graphical facilities. Enormous progress has been made in the calculation of phase diagrams during the past 30 years. Mathematical modelling of thermodynamic properties is used to understand or predict reality. Thermo-Calc [4] is a software for thermodynamic calculations of phase equilibria in multicomponent systems. The main focus concerns calculations on steel/slag equilibria. Computer calculations are useful in the development of new materials as well as for controlling and improving metallurgical processes.Chapter 1 Introduction Experimental work is a time-consuming and costly task.g. The equilibrium state of a material is determined by the thermodynamic properties. and approximately 100 years later.

2 CHAPTER 1. . This kind of calculations can be a useful tool for controlling and improving metallurgical processes. INTRODUCTION them feasible also for an industrial user.

where experimental information is hard to find. For each phase in the system a model is chosen to describe the Gibbs energy as a function of temperature. To get as good description as possible of the properties it is necessary to use all experimental information simultaneously. and are becoming more and more important in thermodynamic modelling. The CALPHAD (CALculation of PHAse Diagrams) technique is used to describe the thermodynamics of materials. pressure and concentrations of the constituent components. 3 . Models and databases developed within the CALPHAD technique helps to improve the understanding of various industrial and technological processes. The experimental data is then used in an optimization procedure to fit the model parameters. has been developed to fit the model parameters to the experimental data by a least mean square method that minimizes the quadratic errors. To calculate the phase equilibria it is then necessary to minimize the total Gibbs energy of all phases taking part in the system. A computer program called PARROT [5]. both phase equilibrium data and thermo-chemical data can be used. The determination of the coefficients is frequently called assessment or optimization of a system. included in the Thermo-Calc software. Results from first-principle calculations can also be used as experiments. pressure and composition. A good model should also permit interpolation and extrapolation to compositions and temperatures not available in experimental studies and extrapolation into multicomponent systems. All available experimental information is collected and evaluated.Chapter 2 The CALPHAD technique Phase diagrams are visual representations of the state of a material as a function of temperature. Enthalpies of formation of stable compounds are routinely predicted by first-principles calculations.

e.g.1) The Gibbs energy of a phase should be described for the whole composition range. are used because there can be more constituents than components and the mole fractions are only defined for the components. The configurational entropy conf Sm is expressed by conf Sm = −R n X i=1 yi ln(yi ) (2.1 CHAPTER 2. even if no such phase is stable for the pure elements. Normally the pressure dependence in the system is ignored. can easily be derived. where SER denotes the reference state of the element. and not the mole fractions. The temperature dependence of Gibbs energy for a pure element can be described using an empirical formula and is expressed as G − H SER . THE CALPHAD TECHNIQUE Thermodynamic modelling In the CALPHAD technique the Gibbs energy is used as the modelled thermodynamic property. properties that are convenient to control in experiments. In this case the constituent fractions.15 K and 1 atm. The quantity phys Gm represent the contribution to the Gibbs energy due to physical models like the magnetic transitions. entropy or enthalpy. The superscript “conf” stands for the configurational entropy of the phase and is based on the number of possible arrangements of the constituents in the phase.. xi . From the Gibbs energy other thermodynamic quantities. the expression is only valid for atmospheric pressure.4 2.4) . and how the atoms of the pure elements mix. G − H SER = a + bT + cT lnT + dT 2 + eT 3 + f T −1 + . The surface of reference srf Gm for the Gibbs energy of a phase is expressed by srf Gm = n X yi o Gi (2. (2. The total Gibbs energy of a phase is expressed by Gm = srf Gm + phys Gm − T · conf Sm + E Gm (2..2) The superscript “srf” stands for “surface of reference” and represents the Gibbs energy of the components of the phase relative to their reference state. i. yi .3) i=1 where o Gi is the Gibbs energy of the component i. that is not included in the other terms. E Gm is the so-called excess Gibbs energy and describes the remaining part of the Gibbs energy. The choice of Gibbs energy as the minimizing function is due to the fact that Gibbs energy is a function of temperature and pressure.e. The phase is described for the pure elements. the stable state at 298.

g. SiO2 . [8] was developed to be used when there is a tendency for ionisation in the liquid. for example the associate solution model [9]. THE CELLULAR MODEL 5 A variety of models have been proposed for phases that deviate from the ideal behavior to describe the excess Gibbs energy. but can be justified by their ability to reproduce experimental data. The cells can be treated like constituents but one has to be careful about the number of atoms in the constituents. where the constituents would be (CaO. The cell model has a special form of the quasi-chemical entropy. It was first developed for oxide liquids. In this work the cellular model has been used. and the presentation here will be limited to oxides. The compound energy formalism was constructed in order to describe models of the thermodynamic properties of phases with two or more sublattices which show a variation in composition.2. i.e. A number of models have been proposed for the liquid phase besides the ionic two-sublattice liquid model. In the cell model one considers cells with one anion and two cations.2 The cellular model A binary cell model was proposed by Kapoor and Frohberg [12] and later extended to multicomponent systems by Gaye and Welfringer [13]. The mole fraction of the “component oxides”. 2. the cells with only one type of cation.6) i=1 j6=i where vj is oxygen stoichiometry of the oxygen in the component oxide of the cation M. Within the frame of the compound energy formalism. As an example one may use the system CaO-SiO2 .7) . (CaO)2 SiO2 ) and the quantities above would be yCaO + 2yCa2 SiO4 xCaO = Q ySiO2 + yCa2 SiO4 xSiO2 = Q Q = yCaO + ySiO2 + 3yCa2 SiO4 (2.5) xi = Q n n X X Q = (yi + vj yij ) (2. [13].2. are for n cations: Pn yi + j6=i vj yij (2. The general rule is that the same number of anions must be provided from both cations in the constituent with two different cations. liquid oxides and sulphides. the modified quasi-chemical model [10]. Models of this kind may be nonphysical. the ionic two-sublattice model [7]. e. but has later been extended to sulphides and fluorides. Mui Ovi . [11] and the cellular model [12]. The cells can have two identical or two different cations. A general formalism widely used in CALPHAD assessments of binary and higher order systems is the compound energy formalism [6].

4). Beside data for the oxides sulfide.3 Thermodynamic assessments of TiO2 binary systems One database suitable for calculations including oxides is the Thermo-Calc slag database. SLAG2 [14]. despite its simplicity. see section 2. 2. This database contains a liquid slag phase. One feature with this model is the use of binary interaction parameters only. as well as an Fe-rich liquid phase and many other phases that may appear in a steel/slag system. phosphate. silicate and fluoride species are also described in the slag phase. Equation (2. Therefore thermodynamic assessments of some binary TiO2 systems have been performed [15]. The model then introduces a sum over the component oxides.2) multiplied with their constituent fraction as in the ideal solution model.6 CHAPTER 2. The entropy expression of the cell model then is: conf Sm = R n−1 Di Di+1 ui X (Di ln( ) − Di+1 ln( )) − vi i=1 vi xi vi xi 2R n X i=1 vi xi ln( m X vi xi yj )−R yj ln( ) D1 D1 j=1 (2. By introducing Di the model attempts to account for the charged behavior of the cells. then the second highest charged on the remaining sites and so on. using the Kapoor-Frohberg-Gaye Quasichemical Cell Model. Thermodynamic data for the liquid slag phase within the Al2 O3 -CaO-CrO-Cr2 O3 FeO-Fe2 O3 -MgO-MnO-Na2 O-SiO2 system were critically assessed by IRSID. but with the possibility to use the model in a multicomponent system. Di defined as Di = n X vj xj (2. It turns out that the model provides a quite accurate estimation of the thermodynamic properties.8) j=i The important property of this sum is that the “component oxides” must be ordered in decreasing valency according to the cations. Equation (2. The intention of the assessments are not to .9). One important oxide missing in the description in the liquid slag phase is TiO2 . is in principle derived by first distributing the highest charged constituents on all possible sites. THE CALPHAD TECHNIQUE The Gibbs energy of formation of the “component oxides” as well as the cell with two different cations are simply introduced in the srf Gm part of Equation (2.9) The first two sums are over all component oxides but the last sum over j is made for all m constituents.2. The expression for the configurational entropy below.

2000 1800 1700 1600 1500 1200 0 20 FeO.1. . THERMODYNAMIC ASSESSMENTS OF TIO2 BINARY SYSTEMS 7 fit all experimental data perfectly.1: The calculated phase diagram of the FeO-TiO2 system according to the present work. The solid intermediary phases were all treated as stoichiometric and their descriptions were taken from SSUB3 when possible.2. The thermodynamic descriptions of the pure oxides were taken from the SGTE Substance database.2TiO2 1300 FeO. The CALPHAD approach was applied and the optimization of the thermodynamic parameters was carried out using the PARROT module of the Thermo-Calc software [4].TiO2 TEMPERATURE. oC 1900 40 60 MASS-% TIO2 80 100 Figure 2. and some of them were assessed. SSUB3 [16]. (solid oxides) and the SLAG2 database [14] (liquid oxides). with experimental points for the liquidus.TiO2 1400 2FeO. rather a reasonable and quick description with not so many model parameters.3. namely the FeO-TiO2 system. As an example on an assessed phase diagram. see Figure 2.

.

The Java Interface uses the TC-API. This interface uses the so-called Java Native Interface (JNI). and in the development of new steel grades. a number of software interfaces have been developed. with an intermediate layer written in C followed by a part written in Java. A new software interface written in JAVA has been implemented in the Thermo-Calc software within the present work. for example in the ladle furnace. In order to provide a good thermodynamic basis for simulations of materials.1 A Java interface for Thermo-Calc There is an intensive development of software applications in materials science. Java applications call native methods 9 . 3. The Thermo-Calc Java Interface uses the Thermo-Calc Application Programming Interface (TC-API). Applications that uses the JNI can integrate Java applications with native code written in programming languages such as C.Chapter 3 Graphical interface for steel/slag calculations The command line based user interface in Thermo-Calc Classic requires frequent use otherwise the user may not remember the way to perform a calculation. The aim with the implementation of a software interface in Java and the design of a graphical interface for steel/slag calculations was to overcome this difficulty by creating an interface that is easy to use and suitable for the steel industry. JNI is a feature of the JavaT M platform. and the TC-API makes it possible to access Thermo-Calc from applications written in the C programming language. The Thermo-Calc software is written in FORTRAN. Such an interface could be a useful tool for controlling metallurgical processes. that is useful for the development of user-friendly applications.

10 CHAPTER 3. GRAPHICAL INTERFACE FOR STEEL/SLAG CALCULATIONS in the same way that they call methods implemented in the Java programming language. as a Java-applet and can be accessed through the Internet. . see Figure 3. 3. The interface. Within the present work a graphical interface has been developed that facilitates such calculations and make them feasible also for an industrial user. using the Java interface for Thermo-Calc described above.1: Main window together with the result window.1. consequently the programmer uses this new “Thermo-Calc class” in the same way as any build-in Java class. is written in the Java programming language.2 The steel/slag calculation interface It has been realized for a long time that thermodynamic calculations that involve both metallic phases as well as oxides are difficult to perform for the not so frequent user. Figure 3.

basicity.5% MgO. Al C Cr Mn S Si Measured start composition 0. 2% S. Fe. To demonstrate the database and the interface two calculations have been performed. Cr2 O3 .028 % 0.4 % 0.055 % 1% 1. the properties of the slag.287 % The second example is measurements on a stainless steel.3 % 0. 0. 6.3% Mn. where the aim is to lower the sulphurcontent in the steel by the addition of a slag. to be used together with this interface.4% Cr.028% S.28 % Calculated final composition 0. neither. the values are not changed from the original steel composition.024 % 1% 1.3 % 0. After the ladle furnace the steel composition remains almost constant. 0. e.g. 6.g.2. The result is seen in Table 3. O. The first example regards a ladle furnace. The difference between measured and calculated values is only 0.1: Measured and calculated steel composition for a low alloyed steel. Si. SiO2 . Cr. The measured compositions of the steel and slag respectively: . sulfide distribution ratio.007 % 0. 0. and the composition of the slag is given in terms of component oxides.28% Si • 1000 kg slag: 32% Al2 O3 .1. one for a low alloyed steel and one for a high alloyed steel.4 % 0. Cr and Mn no difference at all can be seen.5% SiO2 The question of interest is how the composition of the steel is changed after addition of the slag. e.025 % 1% 1. The overall temperature of the system must be given and the interface will then present the result. Table 3.3.28 % Measured final composition 0. The sample is taken in the ladle furnace just before the continuous casting. 1% C. 53% CaO. through the combination of existing databases.3 % 0. Beside composition of each phase. e.006 % 0. As new descriptions get available the interface can use those new databases without any difficulties.055% Al. For C. 1.g. sulphide capacity. the composition of the liquid metal is given in terms of elements. THE STEEL/SLAG CALCULATION INTERFACE 11 For the users convenience.4 % 0. FeO. and activities are presented. A new database was created.001% for Al and S and slightly higher regarding Si. The start compositions of the steel and slag respectively: • 100 tons of steel: 0.

2 % 6.003 % 0. and it should then be remembered that the total amount of steel is 95000 kg.095 % 0.011% Ti • 2500 kg slag: 1.46 % 0.1 % S SiO2 TiO2 0.33 % 0.0% CaO.3 % 49. If we for example look at the titanium we see that the difference in steel composition gives approximately 5 kg difference between measured and calculated values.3 % 48.006 % Slag Al2 O3 Measured 1.3% SiO2 .095% Cr2 O3 .22 % 0.72% Al2 O3 .2: Measured and calculated steel and slag composition for a stainless steel.2.072 % 8.0009 % 0.0005 % 0. 8. 1.68% MgO.2% FeO. 0. FeO and Ti/TiO2 . the calculated compositions should be the same as the input values.75% Mn.046 % 0. 25. 0.3 % 1. 0. The result is seen in Table 3. The agreement between measured and calculated values is satisfactory.072 % 8.e.75 % 0.021% C.3% CaF2 . GRAPHICAL INTERFACE FOR STEEL/SLAG CALCULATIONS 12 • 95 tons of steel: 0.021 % Calculated 0. 0. Steel Al C Measured 0.37 % Mn Mo N Ni S Si Ti 1.37 % 18. 0. 6.0 % 0.3 % 1. 0.90 % CaF2 CaO Cr2 O3 FeO MgO MnO 15.011 % 1.9 % 0.1 % 15. 1.001% S. Differences are noticed for Al/Al2 O3 . i.22% Ni.46 % 0.75 % 0. 0.CHAPTER 3. 0.1% MnO.001 % 0. 18.72 % Calculated 1.62 % .37% Cr.33 % 0.003% Al.072% N. Table 3.67 % 0. 49.31 % 0. 0. Cr2 O3 .46% Mo. 0.28 % 25.28% S.027 % 6.68 % 0.33% Si.28 % 25. 15. but they are small.021 % Cr 18.22 % 0.31% TiO2 The analysis of the steel and slag compositions are done when the system is in equilibrium.

The AOD converter is used primarily to remove carbon from the hot metal transferred from the electric arc furnace. especially if thermodynamic equilibria should be calculated in all grid points. there is an extra cost in terms of consumption of resources such as oxygen. especially the carbon content. The non-isothermal reactor model by Eriksson and Johansson [18] was used to simulate the decarburization process. Detailed studies of the AOD converter. such as chromium. On the other hand. Being able to accurate estimate the metal analysis. the simulation time will decrease significantly and give an accurate prediction of the final steel composition. will also be oxidized and form a top slag on the metal surface. Carbon will react with oxygen. If simulations can be performed using only a few grid points without reducing the accuracy too much. This work uses a detailed description of the thermodynamics and a very simplified description of the kinetics to simulate the decarburization process in an Argon Oxygen Decarburization (AOD) converter. energy and production time if the final carbon content is made unnecessarily low. Species formed at one level will flow for further reaction 13 . To do this a mixture of oxygen and argon is blown into the converter through nozzles located on the sides near the bottom. The main quality measure of the final product is the carbon content. Other elements in the metal. On one hand. In the reactor raw material and energy can be supplied at any level. have been performed for example by Tilliander [17]. metallurgical processes can be described with thermodynamics and kinetics. is important for ensuring the quality of the steel. if the process is ended to early and must be repeated it is very time consuming. forming mainly carbon monoxide. silicon and manganese. using Computational Fluid Dynamics (CFD).Chapter 4 Decarburization of a stainless steel Somewhat simplified. A major drawback of the CFD calculations is the amount of time required to carry out accurate simulations.

between the segments. 4. The amounts and temperatures of these species are predicted by dividing the reactor into a number of segments and by assuming that the chemical reactions proceeding within each segment reach their chemical and thermal equilibrium states. or parts of a phase (liquid in the figure).1 Simulation results By assuming that an AOD converter can be discretized using the reactor model. i. Not only material flows between the segments. heat is generated. . The oxidation process is exothermic. see Figure 4. Thermodynamic equilibrium is calculated using a thermodynamic software and a suitable database. could be moved. gas slag liquid gas heat liquid 20% gas slag liquid 80% heat liquid 20% gas slag liquid 20% heat liquid 20% gas slag liquid 20% heat O2 / Ar Figure 4. The converter is divided into two segments.1: An example of a reactor model for an AOD converter. DECARBURIZATION OF A STAINLESS STEEL at other levels or may leave the reactor. it is possible to construct a thermodynamic model of the converter and do simulations of the decarburization process.14 CHAPTER 4. The entire phase from a segment (gas and slag in the figure). with mainly liquid slag and various oxides in the top segment and liquid steel in the bottom segment. received from the equilibrium calculation. There is an interaction between the slag and the steel. A stainless steel (Fe-C-Cr-Mn-Mo-Ni-Si) has been used as a test case for verification of the model. Energy losses is simulated by a withdrawal of enthalpy throughout the simulation. Flow of materials inside the reactor is simulated by moving the stable phases.e. with different distribution factors for the different phases. but energy as well.1.

Silicon is an efficient deoxidant for slag reduction to fully recover any oxidized metallics. SIMULATION RESULTS 15 simulated by a transport of liquid steel from the bottom to the top segment. have been performed. AOD ELECTRIC ARC FURNACE MEASUREMENT OF STEEL COMPOSITION PREALLOYING: Cr Mn Ni LADLE FURNACE SLAG FORMING AGENTS: CaO MgO CONTINUOUS CASTING DECARBURIZATION: O2/Ar SLAG REDUCTION: CrSi FeSi Figure 4.3(b). The reason for the drastic change in chromium content and slag composition seen in Figures 4. A mixture of argon and oxygen gas is blown into the lower part of the converter.4 at the end of the process is the recovery of metals from the slag as a result of the addition of silicon. From the electric arc furnace the liquid steel is tapped into a ladle and transported to the AOD converter.3(a) and 4. Figures 4. Simulations of the AOD process.3(b). in this case MgO and CaO. .2: Processes simulated within the AOD converter. and this kind of calculations could be a tool for controlling and improving metallurgical processes. Initial composition.2.3-4. prealloying and addition of slag forming agents are taken into account and a start composition for the iteration process can now easily be calculated using the Thermo-Calc software. the argon/oxygen ratio and the amount of gas are changed. and also addition of slag forming agents.4. see Figure 4. When the carbon content has reached a satisfactory low level. where a measurement of the steel composition is made. It is seen that this simple model for the decarburization process gives an accurate prediction of the final steel composition. or the amount and composition of the top slag. but also the composition of other alloying elements. such as chromium: 2Cr2 O3 + 3Si → 4Cr + 3SiO2 (4. manganese and nickel. see Figures 4.4(b). During the decarburization process.1) There are a number of interesting properties to study regarding the decarburization process. recovery of desirable metals from the slag is necessary before the steel is transfered to the ladle furnace. see Figure 4.4(a) and 4. Figure 4. The most interesting one is perhaps the carbon content in the steel.3(a).1. Based on that measurement the steel is prealloyed with mainly chromium.

DECARBURIZATION OF A STAINLESS STEEL 1.6 0.16 CHAPTER 4.3: Example of steel properties.2 0 17.8 mass−% Cr mass−% C 1 0. Figure 4. Figure 4. 0 5 10 15 20 25 time [min] 30 35 40 45 (b) Chromium content in the liquid steel.4 17.2 calculated composition experimental composition 18.4 18. 40 45 . 35 40 45 0 0 5 10 15 20 25 time [min] 30 35 (b) Composition of top slag.5 calculated composition experimental composition 1. 60 3000 50 2500 40 mass−% slag slag [kg] 3500 2000 1500 MgO Cr2O3 FeO CaO MnO SiO2 30 20 1000 10 500 0 0 5 10 15 20 25 time [min] 30 (a) Amount of top slag.5 17.25 18 0.75 0 5 10 15 20 25 time [min] 30 35 40 17 45 (a) Carbon content in the liquid steel.25 0.4: Example of slag properties.

CaO-TiO2 . CaO-TiO2 . Users’ guide . It is based on thermodynamic data assessed with the CALPHAD technique and minimization of Gibbs energy. MgO-TiO2 and MnO-TiO2 systems have been performed. Fe2 O3 -TiO2 . MgO-TiO2 and MnO-TiO2 systems One important component missing in the description of the slag phase is TiO.Chapter 5 Concluding remarks 5. rather a reasonable and quick description with not so many model parameters. This document describes the Java interface developed for the Thermo-Calc software. 17 . It is possible to use Thermo-Calc in user-written programs through one of the Thermo-Calc programming interfaces. Thermodynamic assessments of the Al2 O3 -TiO2 . Application programmers can retrieve thermodynamic data and calculate phase equilibria directly from within their own programs.Interface for steel/slag/gas equilibria calculations It has been realized for a long time that thermodynamic calculations that involve both metallic phases as well as oxides are difficult to perform for the not so frequent user. The intention of the assessments are not to fit all experimental data perfectly. The optimization of the thermodynamic parameters was carried out using the PARROT module of the Thermo-Calc software. Therefor thermodynamic assessments of the Al2 O3 -TiO2 . Therefore an interface is created that facilitates such calculations and make them feasible also for an industrial user. FeO-TiO2 .1 Summary of appended papers Java interface for Thermo-Calc Thermo-Calc is a software for thermodynamic calculations of phase equilibria in multicomponent systems. The graphical interface is written in the Java programming language as a Java-applet and is accessed through the Internet. Fe2 O3 -TiO2 . FeO-TiO2 .

multicomponent. This work will contribute to the development of a larger slag database able to treat high alloyed steels. The Fe-Cr-Ni-O system will be the core system in the study. A reactor model together with the Thermo-Calc software makes it possible to simulate the reduction of carbon in a liquid high alloyed steel by a mixture with oxygen and inert gases. multiphase systems and despite that the deviation from experimental data is remarkably low.2 Discussion and future work In this work we can conclude that the models used for steel/slag equilibria is reasonable good. It shows good agreement in the calculations performed with the steel/slag calculation interface and adequate results using the reactor model. liquid and slag phases are distributed between them. For the future the work will continue to focus on oxide systems of relevance for stainless steels. It has been shown that this simple model for the decarburization process gives an accurate prediction of the final steel composition.18 CHAPTER 5. In the case with the reactor model it should be remembered that it is a significant simplification to consider an AOD converter to be almost in equilibrium. It should also be pointed out that the used systems are commercial. which we do when we divide the process into just a few segments. 5. . The solid part is of interest for example to describe the formation of oxide layers on stainless steels and the liquid part regarding steel/slag calculations in a metallurgical context. CONCLUDING REMARKS Simulation of decarburization of a high alloyed liquid steel using a reactor model within Thermo-Calc Thermodynamic software and databases are now powerful and accurate enough to give reliable results when applied to complex processes like the decarburization of liquid steels. The liquid will be described using the ionic two-sublattice model. A test case using a stainless steel is compared to experimental data. and this kind of calculations could be a tool for controlling and improving metallurgical processes. The process is divided into a small number of local equilibria and the gas. both the solid and the liquid parts of the system will be described using the CALPHAD technique.

Dr. many thanks to all my other friends and family. I also want to thank all other people at the Department of Materials Science and Engineering. Lars H¨ oglund for always being able to solve my problems. and of course to David. Malin Selleby is gratefully acknowledged for showing interest in my work and reading manuscripts and Dr.Acknowledgments First of all I would like to thank Prof. The Swedish Steel Producers Association is acknowledged for financial support and the Centre of Computational Thermodynamics for giving me feedback on part of the work and for providing me with experimental data. especially Johan Jeppsson and Jenny Strandh for all your support. 19 . Finally. Bo Sundman for giving me the opportunity to perform this work.

.

Sommer. T. Metall. pages 281–294. Sundman.. page 17. Trans Conn Acad III. Gaye and J. Sundman.D.D. [5] B. Z. Doctoral Thesis. Calphad.. 26:273–312. Calphad (Calculation of Phase Diagrams): A Comprehensive Guide. and J. 2002. Bernstein. 2001. pages 357–375. Metallurgical Soc of AIME. Pelton and M. Kaufman and H. [12] M. Hillert. Miodownik. Proc. 21 . [7] M. ˚ Agren. [11] A. Jansson. 2002. [10] A. B. 1982. 1985. M. B. B. Hillert. L. Sundman. 1984. 1971. 1991. [6] M. 15:109–119. Fe-containing slag database. pages 108–245.0.M. 1986. Proceedings of the Second International Symposium on Metallurgical Slags and Fluxes.P. [4] J-O. Trans. [15] L. Metall. Saunders and A. [9] F. Selleby. v2. Sundman. H¨ oglund. 320:161–176. P. Kapoor and G. Computer calculation of phase diagrams: With special reference to refractory metals. 1876. Pelton and M. Kjellqvist. Gibbs. Shi. 73:72–76. and B. Journal of Alloys and Compounds. [14] SLAG2. Helander. Metallkd. Royal Institute of Technology. Blander. 1998. Chemical Metallurgy of Iron and Steel. Trans. [2] L. 1970. 2006. Blander. and B. Welfringer. Frohberg. Unpublished work. Symp. [3] N. Andersson. Jansson. Provided by Thermo-Calc Software. 1984.Bibliography [1] J. [13] H. Calphad. 16A:261– 266.L.W. [8] B. 1984. 17B:805–815.

Doctoral Thesis. 2002 & 2004. SGTE substance database. Johansson. Provided by ThermoCalc Software. Royal Institute of Technology. 7:264–270. [17] A. Tilliander. . 2003. 1978.22 BIBLIOGRAPHY [16] SSUB3. [18] G. Eriksson and T. Scandinavian Journal of Metallurgy. v3.2.

- 20x20-mynaUploaded byKatherine Kim
- Wacker LTC4LUploaded byAjans Victor
- Runner 180 FXR 2TUploaded byJorge Vale Pues
- Microsoft Word - Tub Assembly Standard Options A.pdfUploaded byADSD
- Andrew HL4 50AUploaded bysfynks
- Chapter7 WarfUploaded byabhi16
- Inventure Surveillance Script FebruaryUploaded byshrikant thombre
- SBU-A Spec Sheet 2009_metric ROBBINSUploaded byALP69
- Spare Parts - OvensUploaded byIulian12345
- list of DefaultersUploaded bysuresh
- ManagerUploaded byapi-78099343
- Quaker STLE 1998Uploaded byho-fa
- Aquamatic 8TUploaded byAlexiaKat
- Spare PartsUploaded byNestAdánMoRenö
- 3 - Pending at Reviewing Level 3Uploaded byPooja Tripathi
- Earthing and GroundingUploaded byLechluj Ollitsac
- Design of Eurocode ColumnxlsxUploaded bylibanpires
- 6082330 (1) swstick fabs.txtUploaded byManjunath Gowda
- erteUploaded bymuhd_ridhwan91
- Aluminium Cans Market | Prices, Manufacturing Plant ReportUploaded byMelissa Mejia
- 11_Hardware.pdfUploaded bygeneric829820

- Paper 2 Porayette Et Al. (2009) J Biol ChemUploaded byformtic
- Review QuestionsUploaded byAndrew George H
- Audit de Marketing Si AuditareaUploaded byAndreea Stefanescu
- rms-1316-ugUploaded byMonica Fernandez
- 15-5 The RhythmUploaded byBotinesteanu Radu
- Catzoc TableUploaded byxoox25
- Tnpsc Study Materials for Group 1 2 4 8Uploaded byjayabalpd001
- SPINAL CORD DISORDERS yared.pptUploaded byBethelhem Berhanu
- 7 Habbit FinalUploaded byhitkan2003
- Pinnacle HfxUploaded bygeorgesways247
- The effects of diabetes medications on post-operative long bone Giannoudis Simpson2015.pdfUploaded byKlaus
- 37003363 the History of ChinaUploaded bymukeshbansal001
- AMPA- No ConfidenceUploaded byanon_158426693
- Impact Mag vol42_no02Uploaded byImapct Magazine
- 5988-8519ENUploaded bymitsuosakamoto
- 4_Indias External RelationsUploaded byajaiximb
- Second Law Analysis of Solid Oxide Fuel CellsUploaded byहरिओम हरी
- Mitosis y MeiosisUploaded byYarabi Chavez
- AHT Job DescriptionUploaded bystretfordhigh
- Corporation Accounting and Corporation LawUploaded byJanina
- Launcher Rocket 3.5-Inch m20a1Uploaded byarmy3005
- About ExtjsUploaded byTanaya Kulkarni
- Nano Hornet ORG1411 Datasheet2Uploaded byJohnnattan Vargas
- Mca i and II Sem(Rest Paper)Uploaded byVikas Mishra
- Exercise on Movement of Substance Across the Plasma MembraneUploaded byNorliyana Ali
- Polyatomic Molecular Orbital TheoryUploaded byShamila Hussain
- GS+-+India+Financials+27Jul11Uploaded byPranjay
- SAIC-P-3010 REV 0.pdfUploaded byTehman Alam
- 04_1_G130&G150_PW-BLOCK_CLUploaded byANDRES CISTERNAS
- Jewish Art - An Illustrated History (Art eBook)Uploaded bySed