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SINGLE CORRECT : 1.

(CH3)3CMgCl on reaction with D2O produces: (A) (CH3)3CD (B) (CH3)3OD (C) (CD3)3CD (D) (CD3)3OD 2. In the reaction p-chlorotoluene with KNH2 in liq. NH3, the major product is: (A) o-toluidine (B) m-toluidine (C) p-toluidine (D) p-chloroaniline. 3.

4.

MORE THAN ONE OPTION MAY BE CORRECT: 5.

6. The correct statement(s) about the compound given below is (are)

(A) The compound is optically active (B) The compound possesses centre of symmetry (C) The compound possesses plane of symmetry (D) The compound possesses axis of symmetry 7.

8. which of the following can differentiate between ethanol and ethanal? (A) I2/KOH (B) Lucas reagent (c) sodium metal (D) sodiumhydrogen sulphite 9. which of the following statement is/ are true? (A) Williamson ether synthesis is used to prepare symmetrical ethers only. (B) Base catalyzed hydrolysis of cyanide stops at the stage of amide . (C) Cholorobenzene can be identified by AgI . (D) Ozonolysis of 1,2-dimethyl benzene produces three types of product. MATCH THE COLUMN: 10. Column I Column II CH3–CHBr–CD3 on treatment with (a) alc. KOH gives CH2=CH-CD3 as a (p) E1 reaction major product. Ph – CHBr - CH3 reacts faster than (b) (q) E2 reaction Ph-CHBr-CD3. Ph-CH2-CH2Br on treatment with (c) C2H5OD/C2H5O−gives Ph-CD=CH2 (r) E1cb reaction as the major product. PhCH2CH2Br and PhCD2CH2Br react First order reaction (d) (s) with same rate. 11. Column I (a)

Column II Sodium fusion extract of the (p) compound gives Prussian blue colour with FeSO4 (q) Gives positive FeCl3 test (r) Gives white precipitate with AgNO3

(b) (c)

(d)

(s)

Reacts with aldehydes to form the corresponding hydrazone derivative

SUBJECTIVE QUESTIONS (give your answer to nearest integer): 12. Number of structural isomers of C3H9Nare ? 13.

What is the molecular weight of compound E. 14. How many cyclic alkenes (excluding stereoisomer)will produce methyl cyclo hexane on catalytic hydrogenation. 15. Which of the following is the correct method for synthesizing methyl-t-butyl ether and why? 1. (CH3)3CBr + NaOMe 2. CH3Br + NaO-t-Bu Give your answer as 1 or 2. 16. Give the sum of molecular weight of product and the number of oxygen atom in it is: 17. Give the number of stereoisomer of the product. 18. Most ordinarysoaps are sodiumsalt of long-chain fattyacids and are soluble inwater. Soaps of divalent cations such as Ca2+ are only slightly soluble and are often seen in the common soap is calciumpalmitate Ca[CH3(CH2)14COO]2.Ahand book lists the solubility of this soap as 0.0055 gm per 100ml at 25°C.If sufficient sodium soap is used to produce a final concentration of palmitate ion equal to 0.10Min a water sample having 40 ppmCa2+ initially. How many mg of calcium palmitate would precipitate in a bowl containing 10Lof this water sample ? 19.Give the molecular weight of smallest carbonyl compound which give the following tests: a. It gives yellow ppt. with I2/KOH b. It can be obtained by hydrolysis of alkyne. c. oxidation would give ethanoic acid .