IIT - JEE 2005 Chemistry Solution (Screening)

1 Sol: Ans. B
D - glucopyranose is cyclic form of glucose. Around C - 1 (Newly formed chiral centre, due to cycle formation)
two isomers are observed. They are called as α and β - anomers.
2 Sol: Ans. A

OH
H 3P O 4

H 3 P O 4 a cts a s d e h yd ra tin g a g e n t

3 Sol: Ans. B

1
PbO 2 + 2HNO 3 → Pb( NO 3 )3 + H 2 O + O 2
2
4 Sol: Ans. C

CH3
N a O H , I2
H 3C H 3C COOH
H+
O

Iodoform test.
5 Sol: Ans. B
PhMgBr + Me3COH → Ph - H + Me3COMgBr
6 Sol: Ans. B
V4+ and Cu2+ both have one unpaired electron available.
7 Sol: Ans. C
Work done against constant external pressure = Pext (V2 - V1)
In adiabatic condition ∆q = 0 therefore w = ∆u

∴ − Pext (V2 − V1 ) = R (T2 − T1 ) [Expansion work is negative]

3
2

2
On solving, T2 = T1 − .
3 × 0.0821
8 Sol: Ans. B

Bi +3 + KI → BiI3 ↓
Black

BiI3 + KI → K[BiI 4 ]
Orange solution

9 Sol: Ans. C
Chalocopyrite (CuFeS2)

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10 Sol: Ans. D
It is an intramolecular Wurtz reaction.

Br

Cl

11 Sol: Ans. A
SN1 and SN2, both reactions are possible due to aqueous acetone solution.

12. Sol: Ans. B

1
2H+ + O + 2e- → H2O; E0 = +1.23 V
2 2
Fe+2 + 2e- → Fe(s) ; E0 = -0.44 V
1
Fe(s) + 2H+ + O → Fe+2 + H2O; E 0cell = 1.67 V
2 2

∆G 0 = − n F E 0cell = − 2 × 96.500 × 1.67 = − 322 kJ

13. Sol: Ans. B
⊕
CH3NH2 + HCl → CH 3 N H 3 + Cl −
Initially 0.1 0.08-
In solution 0.02 - 0.08

[CH 3 NH 2 ]
[OH − ] = K b
[CH 3 NH 3+ ]

5 × 10 −4 × 0.02 5
[OH − ] = = × 10 − 4
0.08 4

K W 10−14 × 4
[H + ] = −
= −4
= 8 ×10−11
[OH ] 5 × 10
14 Sol: Ans. A
Number of radial nodes = n - l - 1, so, for 3s: 3 - 0 - 1 = 2
For 2p: 2 - 1 - 1 = 0
15 Sol: Ans. C
Ph
p - MeO - Ph - CHO + (AcO)2O CH
3 → p - M e O
COONa
COOH

16 Sol: Ans. D
Order of reaction is determined experimentally. It may be fractional.
17 Sol: Ans. C
 13.44 1000 
∆Tb = i × K b × m = 3 × 0.52 ×  ×  = 0.16
 134.4 1000 
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Kochi Branch: Bldg.No.41/352, Mulloth Ambady Lane, Chittoor Road, Kochi - 011, (: 0484 - 2370094,9388465944
Note: Based on the memory
18 Sol: Ans. C

CH3 S O 3H + C H 3C O O N a CH3 S O 3N a + C H 3C O O H
(W e a k a cid )
(S tro n g a cid )

Above reaction is acid base reaction.

19 Sol: Ans. A

O
(S h e e t stru ctu re )
O
O O

20 Sol. Ans. B
0
NO + NO 2 30
 C
→ N 2O3
Pale blue colour

21 Sol: Ans. A

rHe 16
= = 2 :1
rCH 4 4

22 Sol: Ans. A
[Co(NH3)4(Br)2]Cl can show both Geometrical and Ionisation isomerism.
23 Sol: Ans. D

O
Fe Fe
O C l- O (N o lo n e p a ir) Xe (T w o lo n e p a ir)
Fe Fe

F
F
S (O n e lo n e pa ir) (T h re e lo n e p a ir)
F

24 Sol: Ans. D
Lyophilic solutions are solvent loving in nature. Due to this property, such kind of solutions are self stabilised.
25 Sol: Ans. C
Point of difference is nature of carbanion 20 carbanions are less stable than 10 carbanions generally.
26 Sol: Ans. C
Due to layered structure in Black Phosphorous, it is most stable.
27 Sol: Ans. B
In ZnS, Anions (S-2) are placed in fcc manner and cations (Zn+2) are placed in alternate tetrahedral voids.
28 Sol: Ans. C
KMnO4 can’t be oxidised by any oxidising agents. Mn is in maximum possible oxidation state of VI.

Tvm Branch: T.C.No: 5/1703/30, Golf Links Road, H.B. Clony, Kowdiar Gardens, Trivandrum, (: 0471-2438271 3
Kochi Branch: Bldg.No.41/352, Mulloth Ambady Lane, Chittoor Road, Kochi - 011, (: 0484 - 2370094,9388465944
Note: Based on the memory