Unsaturated Polyester Nanya

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NAN YA UNSATURATED POLYESTER RESIN
Ensure total quality management to offer

customers utmost satisfaction of our products
CONTENTS
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BUTTON - B Series
1~2
CASTING - C Series
3~6
FURNITURE - F Series
7~8
GEL COAT - G Series
9~10
LAMINATING - L Series
11~12
SMC - M Series
13~14
SHIPPING - S Series
15~16
PULTRUSION - PT Series
17~18
Filament Winding
19~20
STORAGE
Catalyzed resin will remain stable for three
months if stored in the dark and at temperature
below 25C. Stocked cargo should be always away
from sun light or steam pipes .Opened drum must
be sealed tightly after each use in order to maintain the best quality of the resin.
BUTTON
B SERIES
GRADE
CHARACTERISTICS
APPLICATION
APPEARANCE
THIXOTROPIC
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/30C
Min/30C
6rpm/60rpm
25C
PROMOTER WAX
25C

B3A01
Excellent compatibility with
For centrifugal button fast cure
Pale Yellow
1.12-1.16
1300130
31
--

B4101
pearl and show gloss, easy to
For centrifugal button
Hazen 30
1.10-1.16
1300130
31
--

B4201
drill and dye.
For Rodmaker button
Pale Yellow
1.14-1.18
3500350(25C)
102
2.60.2

B4301
For centrifugal button
Hazen 30
1.10-1.16
1300130
31
--

B5101
For Perma button
Hazen 50
1.14-1.18
2500250
41
--

B6101
Soft grade
Hazen 50
1.10-1.15
1500200
41
--
O : With wax/promoter
X : Non-wax/non-promoter
CURING CONDITION

PROPERTIES OF THE CURED RESIN
1. Gel test : adds 0.5PHR Promoter NP-10,
1PHR MEKPO(55%).
Hardness, Barcol
2. These tests are based on JIS-6911,
Impact Strength,Kg-cm/cm
JIS-6901,CNS-9715.CNS-9716.
Casting(B4101)
45
2
Tensile Strength,Kg/mm
5.5
11.8
Flexural Modulus,Kg/mm
329
Elongation,%
2.5
Flexural Strength,Kg/mm
2.6
CASTING - ONYX
C2 SERIES
GRADE
CHARACTERISTICS APPLICATION
APPEARANCE
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/25C
Min/25C
6rpm/60rpm

Excellent wet-out properties.
C2P01
Artificial marble & onyx, and vanity top
THIXOTROPIC
25C
PROMOTER WAX
25C
Transparent-Blue
1.12-1.18
1100110
112
--

Higher filler content, good
C2P04
Transparent-Blue
1.12-1.18
85085
142
--

mechanical properties.
C2Q01
Transparent-Blue
1.12-1.18
1700170
142
--

C2Q02
Transparent-Blue
1.12-1.18
1700170
303
--
CURING CONDITION
1. Gel test : C2P adds 1PHR MEKPO(55%) .
2. These tests are based on
Hardness, Barcol
4.5
JIS-6911,JIS-6901,CNS-9715,
2.5
CNS-9716.
Tensile Strength,Kg/mm2
6.0
Casting
9.0
Flexural Modulus,Kg/mm2
310
CASTING
C3 SERIES
GRADE
APPEARANCE
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/25C
Min/25C
6rpm/60rpm

C3G01
1. With high or medium reactivity.
2. Possess good transparence, low

C3G02
shrinkage, non-cracking, easy

C3A01
defoaming, excellent wet-out
properties.

C3A02
THIXOTROPIC
25C
for medium & large
Light Red
1.11-1.12
size casting statue
Light Red
1.11-1.12
for medium & small
Light Red
1.11-1.12
size casting statue
Light Red
1.11-1.12
30030
51
35035(20C) 51(20C)
30030
51
35035(20C) 51(20C)
PROMOTER WAX
25C
--
--
--
--
CURING CONDITION
1. Gel test : adds 1PHR MEKPO (55%)
2. These tests are based on
JIS-6911,JIS-6901,CNS-9715,
CNS-9716.

Casting
C3A01
C3G01
C3A02
C3G02
48
42
2~3
2~3
4~5
4~5
10~12
11~13
Flexural Modulus,,Kg/mm 200~230
220~250
Hardness, Barcol
2
2
2
FURNITURE
F SERIES
GRADE
APPEARANCE
THIXOTROPIC
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/25C
Min/25C
6rpm/60rpm
25C
PROMOTER WAX
25C
F3401

1. With high reactivity
for PET film to be
Purple Red
1.12 - 1.15
35035
31
--
F3601

2. Good extensibility forfabrication,
molded on polyester
Purple Red
1.12 - 1.15
35035
41
--
F5401

excellent gloss and lightness.
plywood .
Purple Red
1.12 - 1.15
55055
31
--
F5601

Purple Red
1.12 - 1.15
55055
41
--
F7401

Purple Red
1.12 - 1.15
75075
31
--
F7601

Purple Red
1.12 - 1.15
75075
41
--
1100110
51
--
FA000

Transparent Yellow 1.12 - 1.15
FA001

Purple Red
1.12 - 1.15
1100110
51
FA002

Purple Red
1.12 - 1.15
1100110
41
--
FA003

1100110
41
--
FA400

1500150
41
--
FA401

Purple Red
1.12 - 1.15
1500150
41
--
FA402

Purple Red
1.12 - 1.15
1300130
41
--
1300130
41
--
FA403
FA601

Purple Red
1.12 - 1.15
1800180
51
--
FA602

Purple Red
1.12 - 1.15
1800180
41
--
CURING CONDITION
1. Gel test : Fa000, FA003, FA400, FA403, add 0.3
PHR promoter POBO and 1PHR MEKPO(55%).
Other adds 1 PHR MEKPO(55%).
JIS-6901,CNS-9715,CNS-9716.

CASTING
Hardness, Barcol
50
2
3.5
8
13
360
GEL COAT
G SERIES
GRADE
APPEARANCE
THIXOTROPIC
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/25C
Min/25C
6rpm/60rpm
25C
PROMOTER WAX
25C

GC101
1. With high or medium reactivity
For exterior application
Transparent-Yellow 1.11-1.20
1180118
82
--

GC202
2. Excellent compatibility with pig
of ship and FRP products
Transparent-Yellow 1.11-1.20
1800180
91
--

GC203
ment and show gloss
Pale Yellow
1.11-1.20
6000900
122
5.00.5

GC204
3. The chemical resistance and water
Purple Red
1.11-1.20
6000900
122
5.00.5
resistance:GCI is excellent, GC2 is

GC503
Purple Red
1.11-1.20
3000450
122
5.50.5
next, others are GC5, GC6 and GC7.

GC603
Purple Red
1.11-1.20
3000450
222
5.50.5

GC703
Purple Red
1.11-1.20
6000900
122
5.00.5
CURING CONDITION
1. Gel test :
GC101 GC202 GC203 add 0.5PHR promoter
P040 and 1PHR MEKPO(55%) .
GC204 GC502 GC601 GC702 add 1PHR MEKPO
(55%).
2. These tests are based on JIS-6911 JIS-6901,
RETENTION OF PROPERTIES AGAINST CHEMICAL AGENT,%
Retention of Properties,% =
Casting
Hardness, Barcol
40-50
2
6-7
11-13
300-350
PRODUCT
CODE
Wet Value of Flexural Strength

X 100
GC1
Dry Value of Flexural Strength
Wet Value : Test specimens are immersed in GC2
GC5

chemical solution as following
GC6

for one month at 70C.
GC7
Flexural
Strength
Kg/mm2
12.58
13.46
12.20
11.87
11.3
Acetic
Acid
(50%)
48.5%
40.2%
15.5%
16.2%
10.4%
Sulfuric Hydrochloric NaOH

KOH Gasoline
Acid
Acid
(50%
(36%)
(10%)
(10%) (100%)
90.5% 67.2%
92.4% 94.0% 90.1%
87.6% 60.5%
83.1% 88.9% 88.2%
86.4% 52.8%
77.2% 73.4% 82.3%
80.2% 48.4%
75.6% 70.2% 77.4%
74.3% 40.6%
67.0% 68.3% 76.3%
Diesel
Oil
(100%)
92.2%
87.4%
85.4%
80.4%
79.3%
CNS-9715, CNS-9716.
10
LAMINATING
L SERIES
GRADE
APPEARANCE

L3A1H
1.With high or medium reactivity

L311H
2.Excellent non-sagging and wet out

L3B1K
properties, the products show

L321K
excellent mechanical properties.

L3B1Q

L321Q

L3C02

L3C05

L4B01

L4203

L4B02

L4204

L4B06

L4206

L4B07

L4207

L4B08

L4208

L4B10

L4210

L7S12

L4Y05
1.With medium reactivity

L4705
2.Excellent non-sagging and wet out

L4Y06
properties, the products show
excellent mechanical properties.

L4706
CURING CONDITION
1. Laminated pieces of 30% glass fiber mat.
2. Gel test adds 1PHR MEKPO(55%).
3. These tests are based on JIS-6911
JIS-6901,CNS-9715,CNS-9716.
11
For hand lay-up and

spray-up open mold
fabrication
For hand lay-up and

spray-up open mold
fabrication
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Ligth Grey
Light Grey
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Purple Red
Yellowish Green
Purple Red
Purple Red
Purple Red
Purple Red
THIXOTROPIC
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/ C
Min/25C
6rpm/60rpm
25C
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
1.07-1.11
40040/25C
40040/25C
35035/25C
35035/25C
32032/30C
35032/30C
32032/25C
32032/25C
40040/25C
40040/25C
40040/25C
40040/25C
55055/25C
55055/25C
55055/25C
55055/25C
40040/25C
40040/25C
45045/25C
45045/25C
90090/30C
35035/25C
35035/25C
35035/20C
35035/20C

Glass Mat

Casting Laminate
Hardness, Barcol
47
55
3.0
65
Tensile Strength,Kg/mm2
6.0
12
Flexural Strength,Kg/mm2
11
22
Flexural Modulus,Kg/mm2
450
1010
Elongation,%
2.5
2.0
71
71
162
162
162
162
162
162
112
112
162
162
182
182
162
162
112
112
162
162
51(30C)
122
122
122
122
PROMOTER WAX
25C
2.30.3
2.30.3
1.80.2
1.80.2
2.30.3
2.30.3
3.00.3
3.00.3
1.80.2
1.80.2
2.30.3
2.30.3
2.60.3
2.60.3
2.60.3
2.60.3
--
--
2.30.3
2.30.3
--
2.30.3
2.30.3
2.30.3
2.30.3
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o
12
SMC
M SERIES
GRADE
APPEARANCE

1.High reactivity

M5F01
General purpose

2.Low Shrinkage, good mechanical
THIXOTROPIC
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/25C
Min/80C
6rpm/60rpm
25C
PROMOTER WAX
25C
Transparent Yellow
1.1-1.2
1800150
233
--
Transparent Yellow
1.1-1.2
1900150
122
--

properties, moldability, paintability
M5S01

and pigmentability
For water-resistant
M5G01
Ortho type
General purpose
Transparent Yellow
1.1-1.2
900100
233
--
M5D01
High reactivity
Class A surface
Transparent Yellow
1.1-1.2
1900150
392
--
M5A03
ISO - NPG type
For water-resistant
Transparent Yellow
1.1-1.2
1000100
13.51.5
--
M5C01
ISO - Type low shrinkage
Autamotive grade
Transparent Yellow
1.1-1.2
1800150
232
--
santiary ware application
CURING CONDITION
1. Gel test adds 1PHR BPO(98%)
JIS-6901,CNS-9715,CNS-9716.

Casting
Hardness, Barcol
2
Tensile Strength, Kg/mm
M5F01
M5S01
M5G01
M5D01
M5A03
M5C01
40~50
40~50
40~50
45~55
40~50
40~50
4~5
5~6
4~5
4~5
5~6
5~7
200~250
150~250
150~250
200~300
250~350
10~11
9~10
9~10
10~12
10~12
300~350
300~350
300~350
300~400
300~400
Tensile Modulus, Kg/mm2 150~200

2
Flexural Strength, Kg/mm
9~10
Flexural Modulus, Kg/mm2 300~350
13
Heat Distortion Temp.C
80~90
80~90
80~90
90~100
75~85
75~85
Water Absorption,25C, 24hr.%
0.2~0.3
0.1~0.2
0.3~0.35
0.3~0.35
0.1~0.2
0.2~0.3
14
SHIPPING
S SERIES
GRADE
APPEARANCE
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/25C
Min/25C
6rpm/60rpm

1. With medium or low reactivity

S3B01
For fishing boat, yachts
THIXOTROPIC
25C
PROMOTER WAX
25C
Purple Red
1.07-1.11
35035
162
3.00.3
2. High impact, low Shrinkage and

S4B01
excellent wet-out properties
Purple Red
1.07-1.11
43043
202
3.00.3
3. Approved by DNV Register of Shipping.

S5E01
Purple Red
1.07-1.11
45045
383
3.00.3
R5E01
ISO type (Laminating)
Purple Red
1.07-1.11
50050
384
3.00.3
R4E01
ISO type (Laminating)
Purple Red
1.07-1.11
50050
384
3.00.3
R3F01
ISO type (Vacuum bag)
Purple Red
1.07-1.11
25030
555
1.0
CURING CONDITION
1. Laminated pieces of 30% glass fiber mat.
2. Gel test adds 1PHR MEKPO(55%).
JIS-6901,CNS-9715,CNS-9716.

Glass Mat
Casting
Laminate
45
50
3.0
60
Hardness, Barcol
2
6.0
11
10
20
350
850
Elongation,%
2.0
2.0
15
16
PULTUSION
PT SERIES
GRADE
APPEARANCE
THIXOTROPIC
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/25C
Min/80C
6rpm/60rpm
25C
PROMOTER WAX
25C
ISO type, excellent mechanical

P5A01
properties, soft & good toughness
For Pultrusion application
Pale Yellow
1.07~1.11
50050
92
Pale Yellow
1.07~1.11
50050
92
Pale Yellow
1.02~1.06
500150
124
Ortho type, excellent wet-out

P5B01
properties, good gloss
Vinyl ester resin, resistant to a wide

V1A01
range of acids & bases,
good toughness
CURING CONDITION

P5A01
P5B01
V1A01
1. Gel test adds 1PHR BPO (98%).
Hardness, Barcol
40~50
40~50
32~38
Tensile Strength, Kg/mm2
6~7
5~6
7~8
Tensile Modulus, Kg/mm
200~250
200~250
250~300
Elongation, %
2.0~2.5
2.0~2.5
5~6
10~12
9~11
11~13
Flexural Modulus, Kg/mm2
300~350
300~350
300~350
70~80
70~80
100~110
JIS-6901, CNS-9715, CNS-9716.
Heat Distortion Temp,
17
18
FILAMENT WINDING

GRADE
APPEARANCE
THIXOTROPIC
SPECIFIC
VISCOSITY
GEL TIME
INDEX
GRAVITY
CPS/25C
Min/25C
6rpm/60rpm
25C
PROMOTER WAX
25C
ISO type, excellent mechanical

GC208
properties, resistant to acids &
Pipes, Tanks
Purple Red
1.07~1.11
30030
404
Purple Red
1.07~1.11
30030
404
Purple Red
1.02~1.06
500150
255
bases
Ortho type, easy of processing

GC708
Vinyl ester resin, superior acids

V1A03
& bases resistance, excellent
toughness
CURING CONDITION
1. Gel test GC208, GC708 add 1 PHR MEKPO (55%)
V1A03 add 1.2 PHR MEKPO (55%)
JIS-6901, CNS-9715, CNS-9716.

Hardness, Barcol
GC708
V1A03
40~50
40~50
32~38
6~7
5~6
7~8
Tensile Modulus, Kg/mm
250~300
200~250
250~300
Elongation, %
Tensile Strength, Kg/mm
1.5~2.0
1.5~2.0
5~6
11~13
10~12
11~13
300~350
250~300
300~350
70~80
70~80
100~110

Flexural Modulus, Kg/mm
Heat Distortion Temp,
19
GC208
20
21
22
23
24
........................................
NAN YA VINYL ESTER RESIN
Formosa Plastics Group Maoliao Industrial Park

CONTENTS
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Introduction
Chemistry
Product Family
Curing and Handling
Quality Control
Storage And Safety
Application
Chemical Resistance
ISO Certificate
26
Chemistry
...............................................
NAN YA vinyl ester resins are a family of liquid thermosetting resins developed for
production of fiber reinforced plastics.
NAN YA vinyl ester resins are epoxy-based, thermosetting resin that are cured by free
radical initiation of polymerization, which is similar to the curing mechanism of conventional
polyester resins.
There are numerous types of reactants that make up the vinyl esters, each polymer has
They combine the excellent thermal and mechanical properties of epoxy resins
its characteristic properties. However, the properties and chemistry can be typified by the most
with the ease of processing and rapid curing of unsaturated polyester resins but their
versatile of these resins. NAN YA vinyl ester is the reaction product a Bisphenol-A epoxy and
chemical resistance are much more excellent than epoxy and polyester resins.
methacrylic acid, the chemical structure is shown below:
They are an ideal choice for severe applications particularly in highly corrosive
environments. They possess outstanding resistance to corrosion by many different
chemicals , including both acids and alkalis , at room and elevated temperatures .
The high strength-to-weight ratio and excellent fatigue resistance of vinyl ester
based composites make NAN YA resins an good choice for automotive, military, aerospace, sporting and other applications.
NAN YA vinyl ester resins are designated by the prefix "V".
The terminal carbon to carbon double bonds are the reactive groups that enter into the
free radical polymerization or cure. In effect, this structure allows an epoxy to react like a
polyester. This by itself is very important since epoxy reactions in general are very sluggish
compared to the free-radical reactions. Another important feature of NAN YA vinylester resins
(1) V1 series - premium, high performance
is that they are diluted in styrene monomer. Since they are 1ow in viscosity, this makes the
(2) V4 series - for high-solvency solvents
resins easily worked in the reinforced plastic process. Epoxy resin, on the other hand, are high
viscosity materials and require more difficult and expensive processing methods.
Chemical attack on these types of resins occurs through hydrolysis of the ester group
or the splitting on unreacted unsaturated bonds through actions such as oxidation and
halogenation. In ortho & iso UP, ester linkages occur through the molecular chain, making
the chain more susceptible to attack by hydrolysis but for the NAN YA vinyl ester, the ester
linkages only exist at terminal , which is more less than polyester. These terminal ester groups
are made hydrolytically stable by the hindrance offered by methyl group.
In addition to ester linkage, carbon-to-carbon double also occur randomly through
the ortho & iso UP chain, and not all of those bonds react during polymerization. Those
unreacted double bonds are susceptible to chemical attack, particularly through oxidation
and halogenation. In NAN YA vinyl ester resins, the unsaturated double bonds are all at
the terminal, and easily cured. These react completely on curing polymerization, giving an
excellent chemical structure.
28
Figure 1. The comparative chemical structures of NAN YA vinylester

and polyesters
RESIN
(1)
CHEMICAL STRUCTURE
(ESTER)
UNSATURATED POLYESTER
Product Family
Repeated ester
V1A01-Premium, High performance

V1A01 resins are epoxy-modified vinyl esters designed to provide high corrosion
ORTHO
resistance, superior toughness and anti-fatigue properties.V1A01 resins are resistant to a
type
broad range of acids, base and salt solutions, commonly up to temperature of 100(212).
unsat
V1A01 resins can tolerate heavy design loads without causing failure from resin damage; their
ISO
toughness and anti-fatigue properties can also provide a broad safety factor for impact damage
type
from process upsets or during shipping and installation. V1A01 also demonstrates excellent
backbone
adhesive properties to metals and concrete.
Bisphenol
It is well-suited for use in fabricating tanks, pipes and process equipments; specifically
BISPHENOL
-A
type
for filament winding, hand lay-up and spray lay-up, pultrusion, tank linings and coatings
where premium corrosion resistance is required.
VINYLESTER
The standard type of V1A01 has a viscosity of 500cps and contains 40% styrene.
Different viscosity resins are available at different styrene levels, all of which have essentially
From the comparative structure, it is very obvious that the number and arrangement of polar
similar properties.
Related products:
groups on vinylest er resins make them much less polar than all polyester resins. Therefore, they are
V1A02: 35% styrene with 1000cps viscosity.
less susceptible to the effect of water on curing, and to hydrolysis.
V1A03: pre-promoted grade, fast westing V1A01.
The secondary hydroxyl groups on the backbone also have a benefit effect on the quality of
V1A04: thixotropic grade. especially suitable for making moulds of F.R.P.
laminate, which result from excellent glass fiber wetting and good adhesion for the higher strength
V1A04: thixotropic grade. especially suitable for making moulds of F.R.P.
obtained with laminates made of NAN YA vinylester resins.
V1A05: thixotropic, pre-promoted V1A01, especially suitable for making moulds of F.R.P.
Because the ether linkage on backbone and the cured vinylester resins contain only terminal cross
linking, the entire length of the molecular chain is available to elongate under stress and thus absorb more
mechanical shocks, which make it higher impactness, and the chemical structure of bisphenol-A can offer
NAN YA resin more heat-resistant.
Table 1: List of chemical resistance of thermosetting resins.

Inorganic
Acids
Organic
Acids
Oxidized
Chemical
Alkalines
Organic
Solvents
Ortho-type polyesters
ISO-type polyesters
Bisphenol-type polyesters
Epoxy room-temp curing
Epoxy high-temp curing
NAN YA vinylesters
Resin
:Excellent
Chemical
:Good
:Fair
:Poor
30
(2) V4A01: 42% styrene with 500cps viscosity, a tailor-made resin for
Table 3: Typical clear casting properties
high-solvency solvents like ketones, aromatic chemicals.
Table 2:Typical properties of liquid resins

Property
V1A01
V4A01
Non Volatilc(%)
582
582
Viscosity cps/25
500150
500150
Specific Gravity
1.040.02
1.070.01
Flash Point
30
30
205*
205*
Gel Time 25(min)

Stability Dark at 25(month)
*55% MEKPO:1.2%
6% Cobalt:0.4%
100% DMA:0.05%
**SPI gel time at 80

98%BPO=1.0%
32
Curing and Handeling

The ratio of MEKPO to CoNap(or CoOct) in this system is important to achieve optimum
(1). Room temperature curing system.

Catalysts are materials that cause the resin to cure. Promoters and accelerators are materials
used to speed up (and control) that cure. Retarders are materials used to extend the gel time.
results. A minimum ratio of 3/1(MEKPO/Co) is required. A maximum ration of 10/1 has proven
satisfactory. Proportions outsides the 3/110/1 range may result in poor cure, low hardness
Three types of catalysts are in general used with NAN YA resins:
and inadequate corrosion resistance protection. Use of DMA as an accelerator diminishes the
Methyl Ethyl Ketone Peroxide, MEKPO
sensitivity of the lower ratio.
Benzoyl Peroxide, BPO
Cumene Hydroperoxide, CHP
Thorough mixing is also necessary to get optimum results. It is important to mix the
MEKPO and CHP are normally used with promoters,typically

Cobalt Naphthalene, CoNAP
activators into the resin by the standard procedure:

Mix the CoNap(CoOct) and DMA into the resin thoroughly and then add MEKPO.
Cobalt Octoate, CoOCT
And accelerators typically

Dimethyl Aniline, DMA
MEKPO is marketed as a 30%60% active solution. Different brands behave very differently
Elevated Temperature Curing

The same catalysts that are used with polyesters at elevated temperature can be used with
when used with NAN YA resins. This varying reactivity is attributed to subtle differences in
NAN YA vinylester resins. Some common catalysts are:
monomer, dimmer and trimer content of the peroxide. Users should be thoroughly evaluated
Benzoyl Peroxide : BPO is commonly used for elevated temperature curing. Used at a level of 1~2%,
before using. Typical amounts of the most common activators used with NAN YA resins are:
the pot life is several days, yet rapid cures are obtained at temperature over 80.
Catalyst(55% MEKPO)
: 0.92.5%
Tertiary Butyl Peroxybenzoate (TBPB): TBPB are a liquid form catalyst, its half-life of
Promoter(6% CoNap or CoOct) : 0.20.5%

Accelerator(100% DMA)
reactivity is more longer than BPO, and the pot life of TBPB containing resins are also longer
: 0.00.2%
(When room temperature is low than 30, DMA is recommended to added.)
than that of BPO.

Other : other catalysts are commonly used at elevated temperature, for example: Bis(4-tbutylcyclohexyl) peroxydicarbonate, tertiary Butyl Peroxy-2- ethyl- hexanoate.......
Table 4:Typical gel time for NAN YA resins

Temperature
10~20
20~30
30
Gel time
Air Inhibition
Curing system
10~20mins
20~40mins
40~60mins
MEKPO
2.0%
1.5%
1.2%
Oxygen in the air may inhibit the complete cure of an exposed FRP surface. This inhibited
CoOCT
0.5%
0.4%
0.3%
surface may vary in depth, and may result in reduced chemical resistance. To eliminate this, a small
DMA
0.15%
0.1%
0.05%
MEKPO
1.5%
1.2%
1.0%
paraffin wax (0.20.4%) is used in the final top-coat. The small amount of wax is incorporated
CoOCT
0.4%
0.4%
0.3%
DMA
0.15%
0.05%
0.02%
MEKPO
1.2%
1.2%
1.0%
CoOCT
0.4%
0.3%
0.3%
DMA
0.05%
0.02%
0.00%
readily into the system by preparing a master-batch of 610% wax-styrene.
34
Storage and Safety

Quality Control
Storage:
Quality Assurance of raw materials and Quality control of processing and final products
have became an inevitable routine job for NAN YA. Our testing methods are according to
ASTM or CNS, mostly. Some important Q.C. items of our vinyl ester resins are:
Gel test: Gel test of each batch is basic by cup test for room temperature cure, and SPI gel
tests and DSC methods are tested for elevated temperature.
NAN YA vinylester resins are stable at ambient conditions, but if handled improperly,
they may slowly gel. At all times they must be maintained below 25, and keep away from
heat and light. (NOTE: It, which periodically re-fresh or aerate air into NAN YA resins will
extend the shelf-life.)
NAN YA vinylester resins are classified as flammable materials under NFPA 30,
Shelf life: Since vinyl ester resins are intrinsic unstable, shelf life is tested and monitored
so they must be stored and handled properly to prevent ignition. If a fire occurs, Fire can
batch-by-batch.
be extinguished by conventional means, including foam, dry powder and carbon dioxide.
Chemical resistance: NAN YA has established a set of accelerated testing methods for
However, water is not suitable for extinguishing fire.
detecting the chemical resistance of resins.

Mechanical properties: Mechanical properties of NAN YA vinyl ester resins are tested once
per three months for each commercial resins.
Other: Viscosity, appearance, acid value and epoxy equivalent weight of each batch are testing
routinely.
Safety and Health Considertions:

The base vinylester resins are low in toxicity and may be handled openly by observing
normal good house keeping practices. Since the styrene is a chemical volatile, it is
recommended that good ventilation be provided in working area to keep the styrene level in
the area below safety working limits for health and freedom from fire and exposition. If they
are accident swallowed, medical attention should be sought immediately, and the condition
should be treated symptomatically. Do not induce vomiting. If they accident get into eyes,
the eyes should be irrigated with low pressure flowing water continuously for at least 15
minutes, and medical attention should be sought promptly.
36
Application
NAN YA vinylester resin have superior chemical resistance for most chemicals
in many industries as shown in Table 5. They can successfully service in many chemical
facilities and equipments at both ambient and elevated temperature. Unlike metals or
their alloys, NAN YA resins corrosion, and highly resistant to PH extremes and chemical
solvents. In addition to corrosion protection from environment, the maintenance cost is
relatively low.
Table 6: The construction of Nan Ya on steel substratum
Table 5:NAN YA resins and their applications.

RESIN
V1A01
V4A01
FEATURES
APPLICATION
Superior toughness
Resistant to a wide range of
chemicals, acids, bases, and
bleaches.
Fatigue resistance
Suitable for F.R.P., lining, and
flake compounds
Comply with FDA regulation
21 CFR 177.2420
Fabrication methods are versatile:

Hand-lay up
Spray-up
Filament winding
EMatched metal die
EF.R.P. lining
Flake lining
Pultrusion
Centrifugal casting
Resin transfer molding
Superior solvent resistance

Superior high temperature properties
Excellent resistant to oxidizing acids
Comply with FDA regulation
21 CFR 177.2420
Fabrication methods are same as V1A01

High temperature service
Gas collection equipment
Ducks, Scrubber
Tanks, pipes for organic solvents
38
Application
Table 7: The construction of Nan Ya on concrete substratum
14
40
Chemical Resistance
Table 8: Maximun service temperature and chemical enviroment
of NAN YA resins
This section lists chemical resistance of NAN YA vinylester resins. It gives the
maximum service temperature at different chemicals according to ASTM C581-87, and the
justified standardization is :
CHEMICAL
The known maximum temperature at which equipments made with NAN YA vinylester
resins
has given goodservice.
to use under eachchemical conditions. If the retention after 6 months is higher than 60%,
and then maintain above 50% afterone year, it is allowed to use under such condition.
If exposure or contact is intermittent or is to fumes or spills only, it is possible to get
good service at temperatures considerably high than those shown.
Some related products of V1A01V4A01 are unlisted in the table but the given
values apply to all members of the related products. In the following table 7 a blank
indicates that no full data are available or under test. "NR" means "Not Recommended", and
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
V4A01
A
Acetaldehyde
Each retention of Barcol hardness, Flexural strength and modulus is applied to use, or not
CONCENTRATION
(% by weight)
All
NR
NR
0-25
99/210
99/210
25-50
82/180
99/210
50-75
65/150
82/180
Acetic Anhydride
All
NR
38/100
Acetone
100
NR
NR
Acrylic Acid
25
38/100
38/100
Alcohol,Buryl
All
49/120
49/120
Alcohol,Ethyl
10
65/150
65/150
100
27/80
38/100
10
65/150
65/150
100
49/120
49/100
10
65/150
65/150
Acetic Acid
Alcohol,lsopropyl
"ALL" means the chemical is 100% concentration.

Alcohol,Methyl
100
NR
38/100
Alcohol, Mehtyl Isobutyl
10
65/150
65/150
Alcohol, Secondary Butyl
10
65/150
65/150
Allyl Chloride
All
27/80
27/80
Alum
All
99/210
121/250
Aluminum Chloride
All
99/210
121/250
Aluminum Fluoride
All
27/80
27/80
Aluminum Hydroxide
All
82/180
93/200
Aluminum Nitrate
All
82/180
82/180
Aluminum Potassium Sulfate
All
99210
121250
0-20
65/150
65/150
38/100
65/150
Ammonia Aqueous
Ammonia Gas
Ammonia Liquid
Ammonium Acetate
Ammonium Bicarbonate
NR
NR
65
27/80
27/80
0-50
71/160
71/160
Ammonium Bisulfite
All
65/150
65/150
Ammonium Carbonate
All
65/150
65/150
Ammonium Chloride
All
99/210
99/210
Ammonium Citrate
All
65/150
65/150
Ammonium Fluoride
All
65/150
65/150
82/180
82/180
10
65/150
65/150
20
65/150
65/150
29
38/100
38/100
Ammonium Nitrate
All
99/210
121/250
Ammonium Persulfate
All
82/180
82/180
Ammonium Phosphate
All
99/210
99/210
Ammonium Sulfate
All
99/210
121/250
Amyl Acetate
100
NR
49/120
Ammonium Hydroxide
15
16
42
CHEMICAL
CONCENTRATION
(% by weight)
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
Aniline
All
NR
Aniline Hydrochloride
All
82/180
CONCENTRATION
(% by weight)
CHEMICAL
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
Calcium Hydroxide
V4A01
All
71/160
82/180
21/70
Calcium Nitrate
All
99/210
99/210
82/180
Calcium Sulfate
All
99/210
121/250
V4A01
Aniline Sulfate
All
99/210
99/210
Calcium sulfite
All
82/180
82/180
Aesenious Acid
All
82/180
82/180
Cane Sugar Liquor
All
82/180
82/180
Caprylic Acid
100
82/180
99/210
99/210
171/340
B
Barium Acetate
Barium Carbonate
Barium Chloride
Barium Hydroxide
All
82/180
All
99/210
121/252
Carbon Disulfide
All
99/210
99/210
Carbon Monoxide
0-10
65/150
65/150
Carbon Tetrachloride
Barium Sulfate
All
99/210
Barium Sulfide
All
82/180
Benzene
100
5% Benzene in Kerosene
Benzene Sulfonic Acid
Carbon Dioxide
82/180
50
NR
NR
99/210
171/340
65/150
82/180
Carbon Acid
65/150
65/150
82/180
Carbowax(PEG)
65/150
82/180
99/210
99/210
65/150
65/150
121/250
100
38/100
Castor Oil
99/210
99/210
Carboxy Methyl Cellulose
65/150
65/150
Chlorinated Brine Liquors

All
82/180
82/180
15
93/200
93/200
NR
10
88/190
O-Benzoyl Benzoic Acid
All
99/210
99/210
Chlorinated Wax
Benzoic Acid
All
99/210
99/210
Chlorine Dioxide/Air
38/100
Chlorine Dioxide,Wet Gas
Satd.
82/180
82/180
100
99/210
121/250
100
99/210
121/250
NR
NR
Benzyl Alcohol
Benzyl Chloride
100
NR
100
NR
27/80
Chlorine Dry Gas
163/325
204/400
Chlorine Wet Gas
Black Liquor Recovery(Furnace gasses)

Brass Plating Solution:
82/180
82/180
(3% Copper Cyanide6% Sodium Cyanide

1% Zinc Cyanide 3% Sodium Carbonate)
Bromine, Liquid
Bromine Water
NR
NR
82/180
88/190
Chlorine Liquid
Chlorine Water
All
82/180
99/210
Chlorosulfonic Acid
25
49/120
65/150
50
38/100
49/120
Con
NR
NR
Chlorobenzene
100
NR
38/100
(4% copper Cyanide5% Sodium Cyanide
Chloroform
100
NR
NR
3% Sodium Carbonate4.5% Rochelle Salts)
Chlorosulfonic Acid
100
NR
NR
49/120
65/150
20
49/120
65/150
30
NR
49/120
Bronze Plating solution:
Butyl Acetate
82/180
100
NR
88/190
27/80
Chrome Plating Bath:
050
99/210
99/210
(19% Chromic Acid Sodium
100
27/80
49/120
Fluorosillicate Sulfate)
100
82/180
99/210
Chromic Acid
Butyl Carbitol BC
100
38/100
38/100
Butyl Cellosolve BCS
100
27/80
38/100
Chromium sulfate
All
65/150
82/180
82/180
Citric Acid
All
99/210
99/210
99/210
99/210
Butyric Acid
Butyl benzyl phthalate BBP
Butylene Glycol BG
100
71/160
Coconut Oil
Cadmium Chloride
82/180
82/180
Copper chloride
All
99/210
121/250
82/180
93/200
Copper cyanide
All
99/210
99/210
(Plating Solution:3% Cadmium Oxide
Copper Fluoride
All
99/210
99/210
10% Sodium Cyanide1% Caustic Sode)
Copper Nitrate
All
99/210
99/210
71/160
88/190
All
Cadmium Cyanide
Calcium Bisulfite
All
Calcium Carbonate
All
Calcium Chlorate
All
82/180
Copper Plating Solutions:
82/180
82/180
(Copper Cyanide10.5% Copper
99/210
121/250
14% Sodium Cyanide

Rochelle Salts)
82/180
Calcium Chloride
All
99/210
121/250
Calcium Hydroxide
All
82/180
99/210
17
6%
18
44
CHEMICAL
CONCENTRATION
(% by weight)
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
CHEMICAL
V4A01
CONCENTRATION
(% by weight)
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
V4A01
Copper Brite Plating Caustic-Cyanide
71/160
88/190
Copper Plating Solution:
DMA 4 Weed Killer
82/180
93/200
100
49/120
65/150
DMA 6 Weed Killer
100
49/120
65/150
100
65/150
82/180
(45% Copper Fluoroborate 19% Copper
Dodeeyl Alcohol
Sulfate 8% Sulfuric Acid)

Copper Matte Dipping Bath:
82/180
93/200
(30% Ferric Chloride 19% Hydrochloric)

Copper Pickling Bath:10% Ferric Sulfate
Copper Sulfate
All
Corn Oil
Electrosol (Antistatic Agent)
65/150
65/150
Epichlorohydrin
100
NR
NR
Epoxidized Soybean Oil
93/200
93/00
99/210
121/250
100
65/150
65/150
Esters Fatty Acids
82/210
99/210
100
82/180
82/180
Ethly Acetate EAC
Corn Starch
Slurry
99/210
99/210
100
NR
21/70
Corn Sugar
Ethly Acrylate EA
All
99/210
99/210
100
NR
NR
Ethly Benzene
99/210
99/210
100
27/80
49/120
Ethly Bromide
100
NR
NR
Ethly Chloride
100
NR
NR
Cottonseed Oil
Cresylice Acid
100
NR
NR
Crude Oil, Sour
100
99/210
121/250
Crude Oiil, Sweet
Ethly Ether
100
99/210
121/250
100
NR
NR
Cyclohexane
Ethlyene Chlorohydrin
100
49/120
65/150
100
38/100
38/100
Ethly Glycol(EG)
49/120
65/150
All
99/210
99/210
Ethly Glycol Monobutyl Ehter (BCS)
100
38/100
38/100
Ehtyl Sulfate
100
27/80
38/100
Cyclohexanone
D
Detergents, Sulfonated
All
99/210
99/210
Diallyl Phthalate(DAP)
All
71/160
82/180
Fatty Acids
65
99/210
99/210
All
99/210
121/250
Dibromophenol
Ferric Chloride
100
NR
38/100
All
99/210
99/210
Dibutyl Ether
Ferric Nitrate
100
65/150
82/180
All
99/210
99/210
Dichloro Benzene
Ferric Sulfate
100
NR
49/120
All
99/210
99/210
Dichloroethylene
Ferrous Chloride
100
NR
NR
All
99/210
99/210
Dichloromonomethane
Ferrous Nitrate
100
NR
NR
All
99/210
99/210
Dichloropropane
Ferrous Sulfate
100
NR
38/100
All
99/210
99/210
Dichloropropene
8-8-8 Fertilizer
100
NR
27/81
49/120
49/120
Disesl Fuel
100
82/180
9/2003
Diethanol Amine
Flue Gas
100
49/120
49/120
Diethyl Amine
Fluoboric Acid
100
NR
NR
Diethyl Benzene
Fluosilisic Acid
100
38/100
65/150
Diethyl Carbonate
100
NR
38/100
Diethylene Glycol
Frmaldehyde
100
82/180
93/200
Frmic Acid
20
82/180
82/180
Diethyl Sulfate
100
38/100
49/120
Diisobutylene
Freon
100
38/100
65/150
Diisobutyl Phthalate(DIBP)
Fuel Oil
100
54/130
65/150
Diisopropanol Amine
Furfural
100
49/120
65
Dimethyl Formamide DMF
100
NR
NR
Dimethyl Morpholine
100
NR
49/120
Dimethyl Phthalate(DMP)
100
65/150
82/180
Dioctyl Phthalate (DOP)
100
65/150
99/210
Dipropylene Glycol
100
82/180
99/210
Di-Ammonium Phosphate
Diethylhexyl Phosphoric Acid(in Kerosene)
19
Fertillizer-Urea Amminium Nitrate
49/120
49/120
163/325
204/400
All
82/180
99/210
10
82/180
82/180
20
49/120
49/120
All
65/150
65/150
10
82/180
82/180
All
38/100
38/100
38/100
38/100
100
82/180
99/210
49/120
65/150
10
38/100
49/120
100
NR
NR
Gas,Natural
99/210
99/210
Gasoline,Auto
82/180
82/180
Gasoline,Aviation
82/180
82/180
46
CHEMICAL
CONCENTRATION
(% by weight)
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
Gasoline,Ethyl
100
Gasoline,Sour
CHEMICAL
V4A01
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
V4A01
82/180
82/180
Isopropyl Amine
ALL
38/100
49/120
100
99/210
110/230
82/180
82/180
82/180
82/180
ALL
99/210
99/210
NR
49/120
ALL
49/120
49/120
49/120
82/180
82/180
Isopropyl Palmitate
Gluconic Acid
50
82/180
82/180
Glucose
All
99/210
121/250
Glutaric Acid
50
49/120
49/120
Glycerine
All
99/210
99/210
Kerosene
Glycolic Acid
10
82/180
93/200
70
38/100
38/100
Lactic Acid
Glyoxal
40
38/100
38/100
Lasso (50%Chlorobenzene)
82/180
82/180
Latex
Gold Plating Solution:
CONCENTRATION
(% by weight)
Jet Fuel
63% Potassium Ferrocyanide
Lauroyl Chloride
100
38/100
0.2% Potassium Gold Cyanide
Lauric Acid
ALL
99/210
99/210
0.8% Sodium Cyanide
Lead Acetate
ALL
99/210
104/220
Lead Nitrate
ALL
99/210
99/210
82/180
82/180
99/210
110/230
99/210
110/230
H
Heeptame
82/180
82/180
Lead Plating Solution:
Hexane
65/150
65/150
(8%Lead0.8%Fluorboric Acid0.4% Boric Acid)
Hexylene Glycol
65/150
65/150
Levulinic Acid
171/340
204400
Linseed Oil
99/210
99/210
Lithium Bromide
ALL
99/210
121/250
NR
NR
Lithium Sulfate
ALL
99/210
99/210
Hot Stack Gas

Hydraulic Fluid
Hydrazine
Hydrobromic Acid
Hydrochloric Acid
ALL
0-25
82/180
82/180
25-60
38/100
65/150
Magnesium Bisulfite
ALL
82/180
82/180
Magnesium Carbonate
ALL
82/180
82/180
Magnesium Chloride
ALL
99/210
110/230
Magnesium Hydroxide
ALL
99/210
110/230
0-20
99/210
110/230
20-37
71/160
82/180
30
82/180
110/230
Hydrocyanic Acid
ALL
99/210
99/210
Magnesium Sulfate
ALL
99/210
110/230
Hydrofluroic Acid
10
65/150
65/150
Maleic Acid
ALL
99/210
121/250
20
38/100
38/100
Mercuric Chloride
ALL
99/210
99/210
10
82/180
82/180
Mercurous Chloride
ALL
99/210
99/210
Hydrogen Bromide, Wet Gas
100
82/180
82/180
Methylene Chloride
100
NR
NR
Hydrogen Chloride, Dry Gas
100
99/210
177/350
Methyl Ethyl Ketone MEK
100
NR
21/70
Hydrogen Peroxide
0-30
65/150
65/150
Methyl Isobutyl Carbitol
100
NR
NR
Hydrogen Sulfide, Dry
ALL
99/210
99/210
Methyl Isobutyl Ketone (MIBK)
100
NR
NR
Hydrogen Sulfide, Aqueous Hydrogen
ALL
82/180
99/210
Methyl Styrene
100
NR
38/100
Fluoride, Vapor
82/180
82/180
Mineral Oils
99
121/250
Hydrosulfite Bleach
82/180
82/180
Molybdenum Disulfide
100
93
93/200
10
82/180
82/180
Monochloro Acetic Acid
100
NR
NR
20
65/1502
65/150
Monoethynolamine
100
Hydrochloric Acid Saturated
Hydrofluosilicic Acid
Hypochlorous Acid
I
Iron Plating Solution
(45%FeCl2:15%CaCl2
(9% Hydrochloric 23% Sulfuric)
NR
110/230
100
99/210
110/230
Naphtha
100
82/180
99/210
Naphthalene
100
82/180
93/200
Nickrl Chloride
ALL
99/210
99/210
Myristic Acid
82/180
99/210
82/180
99/210
20%FeSO4:11%(NH4)2SO4)
Iron and Steel Cleaning Bath:
NR
99/210
Motor Oil
N
22
48
CHEMICAL
CONCENTRATION
(% by weight)
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
Nickel Nitrate
ALL
Nickel Plating
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
V4A01
V4A01
99/210
99/210
Potassium
82/180
82/180
Potassium Chloride
All
99/210
99/210
Potassium Dichromate
All
99/210
99/210
Potassium Ferricyanide
All
99/210
99/210
(8% Lead 0.8% Fluoboric Aicd 0.4%Boric Acid)
Nickel Plating
CHEMICAL
CONCENTRATION
(% by weight)
82/180
82/180
(11%Nickel Sulfate 2%Nickel Chloride 1%Boric Acid)
Potassium Ferrocyanide
Nickel Plating
Potassium Hydroxide
82/180
82/180
ALL
65/150
65/150
All
99/210
99/210
0-25
65/150
65/150
(44% Nickel Sulfate 4%Ammonium
Potassium Nitrate
All
99/210
99/210
Chloride 4% Borie Acid)
Potassium Permanganate
All
99/210
99/210
99/210
Potassium Persulfate
All
99/210
99/210
82/180
Potassium Sulfate
All
99/210
99/210
Propionic Acid
20
93/200
93/200
Nickel Sulfate
ALL
Nitric Acid
65/150
20
49/120
60/140
52
NR
NR
50
82/180
82/180
71/160
82/180
100
NR
38/100
NR
38/100
All
99/210
99/210
82/180
82/180
NR
NR
65/150
65/150
Nitric Acid Fumes

Nitrobenzene
99/210
100
Propylene Glycol
Pulp Paper Mill Effluent
O
Oakite Rust Stripper
82/180
82/180
Pyridine
100
Octanoic Acid
100
82/180
99/210
Oil,Sour Crude
100
99/210
99/210
Rayon Spin Bath
Oil, Sweet Crude
100
99/210
99/210
Oleic Acid
ALL
99/210
99/210
Salicylic Acid
All
60/140
71/160
NR
NR
Sebacic Aicd
All
99/210
99/210
All
99/210
99/210
All
99/210
99/210
93/200
93/200
Oleum (Fuming Sulfuric)

Olive Oil
100
99/210
121/250
Selenius Acid
Oxzlic Acid
ALL
99/210
99/210
Silver Nitrate
Silver Plating Solution:
Perchlorethylene
100
27/80
49/120
(4% Silver Cyanide 7% Potassium Cyanide
Perchloric Acid
10
65/150
65/150
5% Sodium Cyanide 2% Potassium Carbonate)
30
38/100
38/100
Soaps
All
99/210
99/210
99/210
99/210
Sodium Acetate
All
99/210
99/210
NR
Sodium Aluminate
All
49/120
49/20
Sodium Alkyl Aryl Sulfonates
All
65/150
65/150
Sodium Benzoate
100
82/180
99/210
Sodium Bicarbonate
100
82/180
82/180
Peroxide Bleach
Phenol
100
NR
Phenol Sulfonic Acid
100
NR
NR
Phosphoric Acid
ALL
99/210
99/210
Phosphoric Acid Fumes

Phosphorous Pentoxide
0-54
99/210
104/220
99/210
99/210
Sodium Bifluoride
All
49/120
49/120
All
99/210
99/210
Phosphorous Trichloride
100
NR
NR
Sodium Bisulfate
Phthalic Acid
ALL
99/210
99/210
Sodium Bisulfite
All
99/210
99/210
99/210
Sodium Bromate
10
60/140
65/150
All
99/210
99/210
0-25
82/180
82/180
35
71/160
82/180
Sodium Chlorate
All
99/210
99/210
49/120
Sodium Chloride
All
99/210
99/210
121/250
Sodium Chlorite
15
65/150
65/150
65/150
Sodium Chromate
50
99/210
99/210
99/120
Sodium Cyanide
All
99/210
99/210
Pickling Acids, Sulfluric And Hydrochloric

Picric Acid, Alcoholic
Polyvinyl Acetate Latex PVAC
Polyvinyl Alcohol(PVA)
99210
10
NR
38/100
Sodium Bromide
ALL
99/210
99/210
Sodium Carbonate
100
49/120
49/120
Polyvinyl Chloride Latex

With 35 parts DOP
Potassium Alum Sulfate
Potassium Bicarbonate1
Potassium Bromidee
49/120
ALL
0-50
ALL
23
99/210
65/150
99/100
24
50
CHEMICAL
CONCENTRATION
(% by weight)
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
V4A01
Sodium Dichromate
All
99/210
99/210
Sodium Diphosphate
All
99/210
99/210
Sodium Ferricyanide
All
99/210
99/210
Sodium Ferrocyanide
All
99/210
99/210
Sodium Fluoride
All
82/180
82/180
Sodium Fluoro Silicate
All
49/120
49/120
Sodium Hexametaphosphates
10
49/120
49/120
82/180
65/150
10
82/180
65/150
25
82/180
82/180
50
99/210
91/200
Sodium Hydrosulfide
All
99/210
99/210
Sodium Hypochlorite
0-5
65/150
82/180
5-15
82/180
82/180
Sodium Lauryl Sulfate (SLS)
All
82/180
82/180
Sodium Mono-Phosphate
All
99/210
99/210
Sodium Nitrate
All
99/210
99/210
Sodium Nitrite
All
99/210
99/210
Sodium Persulfate
20
54/130
54/130
Sodium Silicate
All
99/210
99/210
Sodium Sulfate
All
99/210
99/210
Sodium Sulfide
All
99/210
99/210
Sodium Sulfite
All
99/210
99/210
Sodium Tetra Borate
All
93/200
93/200
Sodium Thiocyanate
57
82/180
82/180
Sodium Thiosulfate
All
82/180
82/180
Sodium Tripolyphosphate
All
99/210
99/210
Sodium Xylene Sulfonate
All
82/180
82/180
Sorbitol Solutions
All
71/160
82/180
Sour Crude Oil
100
99/210
121/250
Soya Oil
All
99/210
99/210
Stannic Chloride
All
99/210
99/210
Stannous Chloride
All
99/210
99/210
Stearic Aicd
All
99/210
99/210
Styrene
100
27/80
49/120
Succinonitrile
All
27/80
38/100
Sugar,Beet and Cane Liquor
All
82/180
82/180
Sugar, Sucrose
All
99/210
99/210
Sulfamic Acid
0-25
99/210
99/210
Sulfanilic Acid
All
99/210
99/210
Sulfated Detergents
All
99/210
99/210
99/210
121/250
99/210
149/300
Sodium Hydroxide
Sulfur Dioxide, Dry or Wet SO2

Sulfur Trioxide /Air SO3
All
25
CHEMICAL
CONCENTRATION
(% by weight)
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
V4A01
0-50
99/210
99/210
50-70
82/180
82/180
75
49/120
49/120
Over 75
NR
NR
10
49/120
49/120
105
99/210
99/210
93/200
104/220
All
99/210
99/210
Tartaric Acid
All
99/210
99/210
Tetrachloroethylene
100
27/80
38/100
All
49/120
49/120
Sulfluric Acid
Sulfurous Acid
Superphosphoric Acid
T
Tall Oil
Tannic Acid
Tetrasodium Ethylene-diaminetertra
acetic Acid
Textone-50% Aqueous Sodium Chlorate
99/210
99/210
10
27/80
38/100
100
NR
NR
93/200
93/200
Thioglycolie Acid
Thionyl Chloride
Tin Plating
(18%Stannous Fluoroborate 7% Tin
9% Fluorboric Acid 2% Boric Acid)
Toluene
100
27/80
Toluene Sulfonic Acid(PTSA)
All
99/210
49/120
99/210
149/300
Transformer Oils :
99/210
Mineral Oil Types

Chloro-Phenyl Types
NR
NR
50
99/210
99/210
Trichloroethane
100
38/100
54/130
Trichloroethylene
100
NR
NR
Trichloromonofluoro-Methane
100
27/80
38/100
Trichlorophenol
100
NR
NR
Tricresyl Phosphate (TCP)
100
71/160
71/160
Tridecylbenzene Sulfonate
All
99/210
99/210
Triethanolamine
100
49/120
49/120
Trimethylene Chlorobromide
100
NR
NR
Trisodium Phosphate
All
99/210
99/210
Turpentine
100
65/150
82/180
Tween Surfactant
All
65/150
82/180
0-50
65/150
65/150
99/210
99/210
Trichloro Acetic Acid
U
Urea
V
Vegtable Oils
Vinegar
99/210
99/210
Vinyl Acetate VAC
100
NR
NR
Vinyl Toluene
100
27/80
49/120
26
52
Certificate
CHEMICAL
CONCENTRATION
(% by weight)
100
MAXIMUM RECOMMENDED
TEMPERATURE (/)
V1A01
V4A01
W
Water
Deionized
99/210
99/210
Demineralized
99/210
99/210
Distilled
99/210
99/210
Fresh
99/210
99/210
99/210
99/210
Sea
99/210
99/210
White Liquor(Pulp Mill)
82/180
82/180
ALL
Salt
X
Xylene
100
27/80
49/120
Zinc Chlorate
ALL
99/210
149/300
Zinc Nitrate
ALL
99/210
99/210
82/180
82/180
93/200
93/200
99/210
99/210
Zinc Plating Solution:

9% Zinc Cyanide
4% Sodium Cyanide
9% Sodium Hydroxide
Zine Plating Solution:
49% Zinc Fluoborate
5% Ammonium Chloride
6%Ammonium Fluoroborate
ALL
Zinc Sulfate
27
54
PLASTICS 3RD DIVISION

ENGINEERING PLASTICS DEPT.
(2013.03. 300.38)
TAIPEI OFFICE : 201 TUN HWA N. POAD, TAIPEI, TAIWAN.

CABLE : "NAN YA TAIPEI"
TELEX : 11246 PLASTICORP TAIPEI
TEL : 886-2-27122211 EXT.5813~5814
FAX : 886-2-27138248
E-mail : 24030@ npc. com. tw

Unsaturated Polyester Nanya

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NAN YA UNSATURATED POLYESTER RESIN

Ensure total quality management to offer

GEL COAT - G Series

NAN YA UNSATURATED POLYESTER RESIN

For centrifugal button fast cure

For centrifugal button

For Rodmaker button

For centrifugal button

For Perma button

PROPERTIES OF THE CURED RESIN

1. Gel test : adds 0.5PHR Promoter NP-10,

2. These tests are based on JIS-6911,

NAN YA UNSATURATED POLYESTER RESIN

Artificial marble & onyx, and vanity top

PROPERTIES OF THE CURED RESIN

1. Gel test : C2P adds 1PHR MEKPO(55%) .

2. These tests are based on

NAN YA UNSATURATED POLYESTER RESIN

for medium & large

size casting statue

for medium & small

size casting statue

PROPERTIES OF THE CURED RESIN

Flexural Modulus,,Kg/mm 200~230

NAN YA UNSATURATED POLYESTER RESIN

NAN YA UNSATURATED POLYESTER RESIN

for PET film to be

Transparent Yellow 1.12 - 1.15

Transparent Yellow 1.12 - 1.15

Transparent Yellow 1.12 - 1.15

Transparent Yellow 1.12 - 1.15

PROPERTIES OF THE CURED RESIN

NAN YA UNSATURATED POLYESTER RESIN

For exterior application

of ship and FRP products

resistance:GCI is excellent, GC2 is

next, others are GC5, GC6 and GC7.

PROPERTIES OF THE CURED RESIN

RETENTION OF PROPERTIES AGAINST CHEMICAL AGENT,%

Sulfuric Hydrochloric NaOH

NAN YA UNSATURATED POLYESTER RESIN

For hand lay-up and

For hand lay-up and

PROPERTIES OF THE CURED RESIN

NAN YA UNSATURATED POLYESTER RESIN

santiary ware application

PROPERTIES OF THE CURED RESIN

Tensile Strength, Kg/mm

Tensile Modulus, Kg/mm2 150~200

Flexural Strength, Kg/mm

Flexural Modulus, Kg/mm2 300~350

Heat Distortion Temp.C

Water Absorption,25C, 24hr.%

NAN YA UNSATURATED POLYESTER RESIN

For fishing boat, yachts

2. High impact, low Shrinkage and

3. Approved by DNV Register of Shipping.

ISO type (Laminating)

ISO type (Laminating)

ISO type (Vacuum bag)

PROPERTIES OF THE CURED RESIN

NAN YA UNSATURATED POLYESTER RESIN

ISO type, excellent mechanical