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Chockfast Red Hardener

ITW POLYMERS AND FLUIDS


Chemwatch: 5141-60
Version No: 8.1.1.1
Safety Data Sheet according to WHS and ADG requirements

Issue Date: 26/05/2014


Print Date: 03/06/2014
Initial Date: Not Available
S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING


Product Identifier
Product name
Chemical Name
Proper shipping name
Chemical formula
Other means of identification
CAS number

Chockfast Red Hardener


Not Applicable
CORROSIVE LIQUID, N.O.S. (contains diethylenetriamine and tetraethylenepentamine)
Not Applicable
Not Available
Not Applicable

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Hardener or Part B of a 2 pack


epoxy system
Requires that the two parts be mixed by hand or mixer before use, in accordance with manufacturers directions. Mix only as much as is
required. Do not return the mixed material to the original containers
Use according to manufacturer's directions.
The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing.

Details of the supplier of the safety data sheet


Registered company name
Address
Telephone
Fax
Website

ITW POLYMERS AND FLUIDS


100 Hassall Street Wetherill Park NSW 2164
Australia
+61 2 9757 8800
+61 2 9757 3855
www.itwpf.com.au

Email

Not Available

Association / Organisation

Not Available

Emergency telephone numbers

1800 039 008

Emergency telephone number

Other emergency telephone numbers

+61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE


Primary Number

Alternative Number 1

Alternative Number 2

1800 039 008

+612 9186 1132

Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION


Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

Poisons Schedule
GHS Classification

[1]

Legend:

S5
Metal Corrosion Category 1, Skin Corrosion/Irritation Category 2, Eye Irrit. 2, Skin Sensitizer Category 1, Chronic Aquatic Hazard Category 3
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

GHS label elements

SIGNAL WORD

WARNING

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Chemwatch: 5141-60
Version No: 8.1.1.1

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Issue Date: 26/05/2014

Chockfast Red Hardener

Print Date: 03/06/2014

Hazard statement(s)
H290

May be corrosive to metals

H315

Causes skin irritation

H319

Causes serious eye irritation

H317

May cause an allergic skin reaction

H412

Harmful to aquatic life with long lasting effects

Precautionary statement(s): Prevention


P280

Wear protective gloves/protective clothing/eye protection/face protection.

P234

Keep only in original container.

P261

Avoid breathing dust/fume/gas/mist/vapours/spray.

P273

Avoid release to the environment.

Precautionary statement(s): Response


P321
P302+P352
P305+P351+P338
P333+P313

Specific treatment (see advice on this label).


IF ON SKIN: Wash with plenty of water and soap
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.

Precautionary statement(s): Storage


Not Applicable

Precautionary statement(s): Disposal


P501

Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS


Substances
See section below for composition of Mixtures

Mixtures
CAS No

%[weight]

Name

68513-05-3

>50

tall oil/ tetraethylenepentamine polyamides

112-57-2

<10

tetraethylenepentamine

111-40-0

<5

diethylenetriamine

SECTION 4 FIRST AID MEASURES


Description of first aid measures

Eye Contact

Skin Contact

If this product comes in contact with the eyes:


Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area.


Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
Transport to hospital, or doctor.

Ingestion

If swallowed do NOT induce vomiting.


If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent
aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.

Indication of any immediate medical attention and special treatment needed


Treat symptomatically.
For acute or short-term repeated exposures to highly alkaline materials:
Respiratory stress is uncommon but present occasionally because of soft tissue edema.
Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary.
Oxygen is given as indicated.
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Issue Date: 26/05/2014

Chockfast Red Hardener

Print Date: 03/06/2014

The presence of shock suggests perforation and mandates an intravenous line and fluid administration.
Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and solubilisation of proteins allow
deep penetration into the tissue.
Alkalis continue to cause damage after exposure.
INGESTION:
Milk and water are the preferred diluents
No more than 2 glasses of water should be given to an adult.
Neutralising agents should never be given since exothermic heat reaction may compound injury.
* Catharsis and emesis are absolutely contra-indicated.
* Activated charcoal does not absorb alkali.
* Gastric lavage should not be used.
Supportive care involves the following:
Withhold oral feedings initially.
If endoscopy confirms transmucosal injury start steroids only within the first 48 hours.
Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention.
Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia).
SKIN AND EYE:
Injury should be irrigated for 20-30 minutes.
Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology]

SECTION 5 FIREFIGHTING MEASURES


Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).

Special hazards arising from the substrate or mixture


Reacts with aluminium / zinc producing flammable, explosive hydrogen gas
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Fire Incompatibility

Advice for firefighters


Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Use fire fighting procedures suitable for surrounding area.

Fire Fighting

Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).

Fire/Explosion Hazard

SECTION 6 ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures

Minor Spills

Remove all ignition sources.


Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.

Major Spills

Clear area of personnel and move upwind.


Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE


Precautions for safe handling

Safe handling

Other information

DO NOT allow clothing wet with material to stay in contact with skin
DO NOT use aluminium, galvanised or tin-plated containers
DO NOT USE brass or copper containers / stirrers
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.

Conditions for safe storage, including any incompatibilities


Suitable container

Lined metal can, lined metal pail/ can.


Plastic pail.
Polyliner drum.
Continued...

Chemwatch: 5141-60
Version No: 8.1.1.1

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Issue Date: 26/05/2014

Chockfast Red Hardener

Print Date: 03/06/2014

Packing as recommended by manufacturer.


Storage incompatibility

Avoid contact with copper, aluminium and their alloys.


Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.
Avoid reaction with oxidising agents

PACKAGE MATERIAL INCOMPATIBILITIES


Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION


Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source

Ingredient

Material name

TWA

STEL

Peak

Notes

Australia Exposure Standards

diethylenetriamine

Diethylene triamine

4.2 mg/m3 / 1 ppm

Not Available

Not Available

Not Available

EMERGENCY LIMITS
Ingredient

TEEL-0

TEEL-1

TEEL-2

TEEL-3

tetraethylenepentamine

5 ppm

15 ppm

350 ppm

500 ppm

diethylenetriamine

1 ppm

1 ppm

1.25 ppm

100 ppm

Ingredient

Original IDLH

Revised IDLH

tall oil/ tetraethylenepentamine polyamides

Not Available

Not Available

tetraethylenepentamine

Not Available

Not Available

diethylenetriamine

Not Available

Not Available

Exposure controls

Appropriate engineering controls

Use in a well-ventilated area


General exhaust is adequate under normal operating conditions.
Refer also to protective measures for the other component used with the product. Read both MSDS before using; store and attach MSDS
together.

Personal protection

Eye and face protection

Skin protection

Hands/feet protection

Body protection
Other protection
Thermal hazards

Chemical goggles.
Full face shield may be required for supplementary but never for primary protection of eyes.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the
wearing of lenses or restrictions on use, should be created for each workplace or task.
See Hand protection below
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
NOTE:
The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective
equipment, to avoid all possible skin contact.
Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
See Other protection below
Overalls.
P.V.C. apron.
Barrier cream.
Not Available

Recommended material(s)

Respiratory protection

GLOVE SELECTION INDEX


Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computergenerated selection:
Chockfast Red Hardener
Material

CPI

BUTYL

NEOPRENE

VITON

* CPI - Chemwatch Performance Index


A: Best Selection

Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI
Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone,


approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection
Factor

Half-Face
Respirator

Full-Face
Respirator

Powered Air
Respirator

Continued...

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Print Date: 03/06/2014

B: Satisfactory; may degrade after 4 hours continuous immersion


C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final
selection must be based on detailed observation. * Where the glove is to be used on a short term, casual or infrequent basis, factors such as
"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise
be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

up to 10 x ES

AK-AUS P2

AK-PAPR-AUS /
Class 1 P2

up to 50 x ES

AK-AUS /
Class 1 P2

up to 100 x ES

AK-2 P2

AK-PAPR-2 P2 ^

^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance
Physical state

Amber liquid with an ammoniacal odour; mixes with water.


Liquid

Relative density (Water = 1)

1.24

Odour

Not Available

Partition coefficient n-octanol / water

Not Available

Odour threshold

Not Available

Auto-ignition temperature (C)

Not Available

pH (as supplied)

>7

Decomposition temperature

Not Available

Viscosity (cSt)

Not Available

Melting point / freezing point (C)


Initial boiling point and boiling range
(C)
Flash point (C)

Not Available
>204
>94

Molecular weight (g/mol)

Not Applicable

Taste

Not Available

Evaporation rate

Not Available

Explosive properties

Not Available

Flammability

Not Available

Oxidising properties

Not Available

Upper Explosive Limit (%)

Not Available

Surface Tension (dyn/cm or mN/m)

Not Available

Lower Explosive Limit (%)

Not Available

Volatile Component (%vol)

Not Available

Vapour pressure (kPa)

Not Available

Gas group

Not Available

pH as a solution(1%)

Not Available

VOC g/L

Not Available

Solubility in water (g/L)

Miscible

Vapour density (Air = 1)

Not Available

SECTION 10 STABILITY AND REACTIVITY


Reactivity

Chemical stability

See section 7
Unstable in the presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.

Possibility of hazardous reactions

See section 7

Conditions to avoid

See section 7

Incompatible materials

See section 7

Hazardous decomposition products

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION


Information on toxicological effects

Inhaled

Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the
individual.
511hardamine
Inhalation of amine vapours may cause irritation of the mucous membranes of the nose and throat and lung irritation with respiratory distress and
cough. Single exposures to near lethal concentrations and repeated exposures to sublethal concentrations produces tracheitis, bronchitis,
pneumonitis and pulmonary oedema. Aliphatic and alicyclic amines are generally well absorbed from the respiratory tract.

Ingestion

Skin Contact

The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.
Ingestion of amine epoxy-curing agents (hardeners) may cause severe abdominal pain, nausea, vomiting or diarrhoea. The vomitus may contain
blood and mucous. If death does not occur within 24 hours there may be an improvement in the patients condition for 2-4 days only to be followed
by the sudden onset of abdominal pain, board-like abdominal rigidity or hypo-tension; this indicates that delayed gastric or oesophageal corrosive
damage has occurred.
Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.
511r38
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects.
Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Continued...

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Print Date: 03/06/2014

Amine epoxy-curing agents (hardeners) may produce primary skin irritation and sensitisation dermatitis in predisposed individuals.

Eye

Chronic

Chockfast Red Hardener

tall oil/ tetraethylenepentamine


polyamides

510r36
Vapours of volatile amines cause eye irritation with lachrymation, conjunctivitis and minor transient corneal oedema which results in "halos"
around lights (glaucopsia, "blue haze", or "blue-grey haze"). Vision may become misty and halos may appear several hours after workers are
exposed to the substance
This effect generally disappears spontaneously within a few hours of the end of exposure, and does not produce physiological after-effects.
However oedema of the corneal epithelium, which is primarily responsible for vision disturbances, may take more than one or more days to clear,
depending on the severity of exposure. Photophobia and discomfort from the roughness of the corneal surface also may occur after greater
exposures.
Practical experience shows that skin contact with the material is capable either of inducing a sensitisation reaction in a substantial number of
individuals, and/or of producing a positive response in experimental animals.

TOXICITY

IRRITATION

Not Available

Not Available

TOXICITY

IRRITATION

Oral (rat) LD50: >5000 mg/kg

Eyes (rabbit) (-) moderate


Skin (rabbit) (-) moderate

Not Available

tetraethylenepentamine

Not Available

TOXICITY

IRRITATION

Dermal (rabbit) LD50: 660 mg/kg

Eye (rabbit): 100 mg/24h moderate

Oral (rat) LD50: 3990 mg/kg

Eye (rabbit): 5 mg moderate


Skin (rabbit): 495 mg SEVERE
Skin (rabbit): 5 mg/24h SEVERE

diethylenetriamine

Not Available

Not Available

TOXICITY

IRRITATION

Dermal (rabbit) LD50: 1090 mg/kg

Skin (rabbit): 10 mg/24h - SEVERE

Intraperitoneal (Mouse) LD50: 71 mg/kg

Skin (rabbit):500 mg open moderate

Intraperitoneal (Rat) LD50: 74 mg/kg


Oral (rat) LD50: 1080 mg/kg
Not Available

Not Available

Not available. Refer to individual constituents.


TALL OIL/
TETRAETHYLENEPENTAMINE
POLYAMIDES,
TETRAETHYLENEPENTAMINE,
DIETHYLENETRIAMINE

The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of
contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact
urticaria, involve antibody-mediated immune reactions.

Acute Toxicity

Carcinogenicity

Skin Irritation/Corrosion

Reproductivity

Serious Eye Damage/Irritation

STOT - Single Exposure

Respiratory or Skin sensitisation

STOT - Repeated Exposure

Mutagenicity

Aspiration Hazard

CMR STATUS
SKIN

diethylenetriamine

Australia Exposure Standards - Skin

Sk

SECTION 12 ECOLOGICAL INFORMATION


Toxicity
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
DO NOT discharge into sewer or waterways.

Persistence and degradability


Ingredient

Persistence: Water/Soil

Persistence: Air

Not Available

Not Available

Not Available

Bioaccumulative potential
Ingredient

Bioaccumulation

Continued...

Chemwatch: 5141-60
Version No: 8.1.1.1

Not Available

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Issue Date: 26/05/2014

Chockfast Red Hardener

Print Date: 03/06/2014

Not Available

Mobility in soil
Ingredient

Mobility

Not Available

Not Available

SECTION 13 DISPOSAL CONSIDERATIONS


Waste treatment methods
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.

Product / Packaging disposal

SECTION 14 TRANSPORT INFORMATION


Labels Required

Marine Pollutant
HAZCHEM

NO
2X

Land transport (ADG)


UN number
Packing group
UN proper shipping name
Environmental hazard

1760
III
CORROSIVE LIQUID, N.O.S. (contains diethylenetriamine and tetraethylenepentamine)
No relevant data
Class

Transport hazard class(es)

Subrisk

Special precautions for user

Special provisions

223 274

Limited quantity

5L

Air transport (ICAO-IATA / DGR)


UN number
Packing group
UN proper shipping name
Environmental hazard

1760
III
Corrosive liquid, n.o.s. * (contains diethylenetriamine and tetraethylenepentamine)
No relevant data
ICAO/IATA Class

Transport hazard class(es)

ICAO / IATA Subrisk


ERG Code

Special precautions for user

8L

Special provisions

A3A803

Cargo Only Packing Instructions

856

Cargo Only Maximum Qty / Pack

60 L

Passenger and Cargo Packing Instructions

852

Passenger and Cargo Maximum Qty / Pack

5L

Passenger and Cargo Limited Quantity Packing Instructions

Y841

Passenger and Cargo Limited Maximum Qty / Pack

1L

Sea transport (IMDG-Code / GGVSee)


UN number
Packing group
UN proper shipping name

1760
III
CORROSIVE LIQUID, N.O.S. (contains diethylenetriamine and tetraethylenepentamine)

Environmental hazard

Continued...

Chemwatch: 5141-60
Version No: 8.1.1.1

Transport hazard class(es)

Special precautions for user

IMDG Class

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IMDG Subrisk
EMS Number

F-A,S-B

Special provisions

223 274

Limited Quantities

5L

SECTION 15 REGULATORY INFORMATION


Safety, health and environmental regulations / legislation specific for the substance or mixture

tall oil/ tetraethylenepentamine


polyamides(68513-05-3) is found on the
following regulatory lists

"International Maritime Dangerous Goods Requirements (IMDG Code)","International Maritime Dangerous Goods Requirements (IMDG
Code) - Substance Index","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia
Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","Australia Inventory of Chemical Substances (AICS)","OECD List of
High Production Volume (HPV) Chemicals","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International
Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","OSPAR National List of Candidates for
Substitution United Kingdom","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations
(Spanish)","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA)
Dangerous Goods Regulations"

tetraethylenepentamine(112-57-2) is
found on the following regulatory lists

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous
Goods Requirements (IMDG Code)","International Council of Chemical Associations (ICCA) - High Production Volume List","Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","International Maritime Dangerous Goods
Requirements (IMDG Code) - Substance Index","FisherTransport Information","Australia FAISD Handbook - First Aid Instructions, Warning
Statements, and General Safety Precautions","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations
(English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production Volume (HPV)
Chemicals","Australia Inventory of Chemical Substances (AICS)","OSPAR National List of Candidates for Substitution Norway","Belgium
Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A:
Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","OSPAR National List of Candidates for Substitution
United Kingdom","Sigma-AldrichTransport Information","United Nations Recommendations on the Transport of Dangerous Goods Model
Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List - GESAMP Hazard Profiles","Australia
Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Hazardous Substances Information System - Consolidated
Lists","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","International Air Transport
Association (IATA) Dangerous Goods Regulations","IMO IBC Code Chapter 17: Summary of minimum requirements"

diethylenetriamine(111-40-0) is found on
the following regulatory lists

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous
Goods Requirements (IMDG Code)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule
5","Australia Exposure Standards","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance Index","Australia FAISD
Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","United Nations Recommendations on the Transport of
Dangerous Goods Model Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action
Codes","Australia Inventory of Chemical Substances (AICS)","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List
of Candidates for Substitution Norway","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International
Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","OSPAR
National List of Candidates for Substitution United Kingdom","Sigma-AldrichTransport Information","United Nations Recommendations on the
Transport of Dangerous Goods Model Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List GESAMP Hazard Profiles","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Hazardous Substances
Information System - Consolidated Lists","International Air Transport Association (IATA) Dangerous Goods Regulations","Australia Standard
for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","IMO IBC Code Chapter 17: Summary of minimum
requirements"

SECTION 16 OTHER INFORMATION


Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any
process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

end of SDS

Chockfast Red Resin


ITW POLYMERS AND FLUIDS
Chemwatch: 5141-59
Version No: 8.1.1.1
Safety Data Sheet according to WHS and ADG requirements

Issue Date: 01/01/2013


Print Date: 03/06/2014
Initial Date: Not Available
S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING


Product Identifier
Product name
Chemical Name
Proper shipping name
Chemical formula
Other means of identification
CAS number

Chockfast Red Resin


Not Applicable
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains epoxy resin)
Not Applicable
Not Available
Not Applicable

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Use according to manufacturer's directions.


Requires that the two parts be mixed by hand or mixer before use, in accordance with manufacturers directions. Mix only as much as is
required. Do not return the mixed material to the original containers
The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing.

Details of the supplier of the safety data sheet


Registered company name
Address
Telephone
Fax
Website
Email

ITW POLYMERS AND FLUIDS


100 Hassall Street Wetherill Park NSW 2164
Australia
+61 2 9757 8800
+61 2 9757 3855
www.itwpf.com.au
Not Available

Emergency telephone number


Association / Organisation

Not Available

Emergency telephone numbers

1800 039 008

Other emergency telephone numbers

+61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE


Primary Number

Alternative Number 1

Alternative Number 2

1800 039 008

+612 9186 1132

Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION


Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
COMBUSTIBLE LIQUID, regulated for storage purposes only
Poisons Schedule
GHS Classification [1]
Legend:

S5
Flammable Liquid Category 4, Skin Corrosion/Irritation Category 2, Eye Irrit. 2, Skin Sensitizer Category 1, STOT - SE (Narcosis) Category 3,
Acute Aquatic Hazard Category 2, Chronic Aquatic Hazard Category 2
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

GHS label elements

SIGNAL WORD

WARNING

Continued...

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Version No: 8.1.1.1

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Chockfast Red Resin

Print Date: 03/06/2014

Hazard statement(s)
H227

Combustible liquid

H315

Causes skin irritation

H319

Causes serious eye irritation

H317

May cause an allergic skin reaction

H336

May cause drowsiness or dizziness

H401

Toxic to aquatic life

H411

Toxic to aquatic life with long lasting effects

Precautionary statement(s): Prevention


P210

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P271

Use only outdoors or in a well-ventilated area.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P261

Avoid breathing dust/fume/gas/mist/vapours/spray.

Precautionary statement(s): Response


P321

Specific treatment (see advice on this label).

P370+P378

In case of fire: Use to extinguish.

P302+P352

IF ON SKIN: Wash with plenty of water and soap

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Precautionary statement(s): Storage


P403+P235
P405
P403+P233

Store in a well-ventilated place. Keep cool.


Store locked up.
Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s): Disposal


P501

Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS


Substances
See section below for composition of Mixtures

Mixtures
CAS No

%[weight]

Name

25068-38-6

>60

bisphenol A/ epichlorohydrin resin

1330-20-7

1-10

xylene

SECTION 4 FIRST AID MEASURES


Description of first aid measures

Eye Contact

Skin Contact

If this product comes in contact with the eyes:


Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area.


Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
Transport to hospital, or doctor.

Ingestion

If swallowed do NOT induce vomiting.


If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent
aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.

Indication of any immediate medical attention and special treatment needed


Continued...

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Version No: 8.1.1.1

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Issue Date: 01/01/2013

Chockfast Red Resin

Print Date: 03/06/2014

Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES


Extinguishing media
Water spray or fog.
Alcohol stable foam.
Dry chemical powder.
Carbon dioxide.

Special hazards arising from the substrate or mixture


Fire Incompatibility

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters


Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.

Fire Fighting

Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).

Fire/Explosion Hazard

SECTION 6 ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures

Minor Spills

Environmental hazard - contain spillage.


Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.

Major Spills

Environmental hazard - contain spillage.


Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE


Precautions for safe handling

Safe handling

Other information

DO NOT allow clothing wet with material to stay in contact with skin
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.

Conditions for safe storage, including any incompatibilities


Suitable container
Storage incompatibility

Metal can or drum


Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Avoid reaction with oxidising agents

PACKAGE MATERIAL INCOMPATIBILITIES


Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION


Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source

Ingredient

Material name

TWA

STEL

Peak

Notes

Australia Exposure Standards

xylene

Xylene (o-, m-, p- isomers)

350 mg/m3 / 80 ppm

655 mg/m3 / 150 ppm

Not Available

Not Available

EMERGENCY LIMITS
Ingredient

TEEL-0

TEEL-1

TEEL-2

TEEL-3
Continued...

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Chockfast Red Resin

Print Date: 03/06/2014

bisphenol A/ epichlorohydrin resin

125 / 4 / 50 ppm

150 / 350 / 12.5 ppm

500 / 100 ppm

500 ppm

xylene

100 ppm

130 ppm

920 ppm

2500 ppm

Ingredient

Original IDLH

Revised IDLH

bisphenol A/ epichlorohydrin resin

Not Available

Not Available

xylene

1,000 ppm

900 ppm

Exposure controls

Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls
can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
"adds" and "removes" air in the work environment.

Personal protection

Eye and face protection

Skin protection

Hands/feet protection

Body protection
Other protection
Thermal hazards

Safety glasses with side shields.


Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the
wearing of lenses or restrictions on use, should be created for each workplace or task.
See Hand protection below
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to
manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when
making a final choice.
Suitability and durability of glove type is dependent on usage.
See Other protection below
Overalls.
P.V.C. apron.
Barrier cream.
Not Available

Recommended material(s)

Respiratory protection

GLOVE SELECTION INDEX


Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computergenerated selection:
Chockfast Red Resin
Material

CPI

PE/EVAL/PE

PVA

TEFLON

VITON

* CPI - Chemwatch Performance Index


A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final
selection must be based on detailed observation. * Where the glove is to be used on a short term, casual or infrequent basis, factors such as
"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise
be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88
or national equivalent)

Where the concentration of gas/particulates in the breathing zone,


approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection
Factor

Half-Face
Respirator

up to 10 x ES

A-AUS / Class
1

A-PAPR-AUS /
Class 1

up to 50 x ES

Air-line*

up to 100 x ES

A-3

100+ x ES

Air-line**

Full-Face
Respirator

Powered Air
Respirator

* - Continuous-flow; ** - Continuous-flow or positive pressure


demand
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES


Information on basic physical and chemical properties
Continued...

Chemwatch: 5141-59
Version No: 8.1.1.1

Appearance
Physical state

Page 5 of 8

Issue Date: 01/01/2013

Chockfast Red Resin

Print Date: 03/06/2014

Clear to yellow liquid with a very slight odour; not miscible with water.
Liquid

Relative density (Water = 1)

1.15

Odour

Not Available

Partition coefficient n-octanol / water

Not Available

Odour threshold

Not Available

Auto-ignition temperature (C)

Not Available

pH (as supplied)

Not Available

Decomposition temperature

Not Available

Melting point / freezing point (C)

Not Available

Viscosity (cSt)

Not Available

Initial boiling point and boiling range


(C)
Flash point (C)

>120

Molecular weight (g/mol)

65

Not Applicable

Taste

Not Available

Evaporation rate

Not Available

Explosive properties

Not Available

Flammability

Combustible.

Oxidising properties

Not Available

Upper Explosive Limit (%)

Not Available

Surface Tension (dyn/cm or mN/m)

Not Available

Lower Explosive Limit (%)

Not Available

Volatile Component (%vol)

Not Available

Vapour pressure (kPa)

Not Available

Gas group

Not Available

pH as a solution(1%)

Not Available

VOC g/L

Not Available

Solubility in water (g/L)

Immiscible

Vapour density (Air = 1)

Not Available

SECTION 10 STABILITY AND REACTIVITY


Reactivity

Chemical stability

See section 7
Unstable in the presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.

Possibility of hazardous reactions

See section 7

Conditions to avoid

See section 7

Incompatible materials

See section 7

Hazardous decomposition products

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION


Information on toxicological effects

Inhaled

Ingestion

Skin Contact

Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by narcosis, reduced alertness, loss of reflexes, lack of
coordination and vertigo.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death.
Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful.
Accidental ingestion of the material may be damaging to the health of the individual.
Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal discomfort and may be
harmful if swallowed. Ingestion may result in nausea, pain and vomiting.
Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.
The material produces moderate skin irritation; evidence exists, or practical experience predicts, that the material either
produces moderate inflammation of the skin in a substantial number of individuals following direct contact, and/or
produces significant, but moderate, inflammation when applied to the healthy intact skin of animals (for up to four hours), such inflammation
being present twenty-four hours or more after the end of the exposure period.
Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The
dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis.

Eye

Evidence exists, or practical experience predicts, that the material may cause severe eye irritation in a substantial number of individuals and/or
may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals. Eye
contact may cause significant inflammation with pain. Corneal injury may occur; permanent impairment of vision may result unless treatment is
prompt and adequate. Repeated or prolonged exposure to irritants may cause inflammation characterised by a temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.

Chronic

On the basis, primarily, of animal experiments, concern has been expressed that the material may produce carcinogenic or mutagenic effects; in
respect of the available information, however, there presently exists inadequate data for making a satisfactory assessment.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or
biochemical systems.
Limited evidence shows that inhalation of the material is capable of inducing a sensitisation reaction in a significant number of individuals at a
greater frequency than would be expected from the response of a normal population.
Pulmonary sensitisation, resulting in hyperactive airway dysfunction and pulmonary allergy may be accompanied by fatigue, malaise and aching.

Chockfast Red Resin

bisphenol A/ epichlorohydrin resin

TOXICITY

IRRITATION

Not Available

Not Available

TOXICITY

IRRITATION

Intraperitoneal (mouse) LD50: 4000 mg/kg

Eye (rabbit): 100 mg - mild

Intraperitoneal (rat) LD50: 2400 mg/kg

Nil reported

Oral (mouse) LD50: 15600 mg/kg


Continued...

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Version No: 8.1.1.1

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Issue Date: 01/01/2013

Chockfast Red Resin

Print Date: 03/06/2014

Oral (rat) LD50: 11400 mg/kg


Oral (rat) LD50: 13600 mg/kg
Not Available

xylene

Not Available

TOXICITY

IRRITATION

Inhalation (rat) LC50: 5000 ppm/4h

Eye (human): 200 ppm irritant

Intraperitoneal (Mouse) LD50: 1548 mg/kg

Eye (rabbit): 5 mg/24h SEVERE

Intraperitoneal (Rat) LD50: 2459 mg/kg

Eye (rabbit): 87 mg mild

Oral (Mouse) LD50: 2119 mg/kg

Skin (rabbit):500 mg/24h moderate

Oral (rat) LD50: 4300 mg/kg


Subcutaneous (Rat) LD50: 1700 mg/kg
Not Available

Not Available

* Value obtained from manufacturer's msds


unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
BISPHENOL A/ EPICHLOROHYDRIN
RESIN

XYLENE

Chockfast Red Resin, BISPHENOL A/


EPICHLOROHYDRIN RESIN

for RTECS No: SL 6475000: (liquid grade) Equivocal tumourigen by RTECS criteria Somnolence, dyspnea, peritonitis

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may
produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of
dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.
Reproductive effector in rats
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of
contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact
urticaria, involve antibody-mediated immune reactions.

Acute Toxicity

Carcinogenicity

Skin Irritation/Corrosion

Reproductivity

Serious Eye Damage/Irritation

STOT - Single Exposure

Respiratory or Skin sensitisation

STOT - Repeated Exposure

Mutagenicity

Aspiration Hazard

CMR STATUS
Not Applicable

SECTION 12 ECOLOGICAL INFORMATION


Toxicity
Toxic to aquatic organisms.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment
wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.

Persistence and degradability


Ingredient

Persistence: Water/Soil

Persistence: Air

Not Available

Not Available

Not Available

Bioaccumulative potential
Ingredient

Bioaccumulation

Not Available

Not Available

Mobility in soil
Ingredient

Mobility

Not Available

Not Available

SECTION 13 DISPOSAL CONSIDERATIONS


Waste treatment methods
Product / Packaging disposal

Recycle wherever possible or consult manufacturer for recycling options.


Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Continued...

Chemwatch: 5141-59
Version No: 8.1.1.1

Page 7 of 8

Issue Date: 01/01/2013

Chockfast Red Resin

Print Date: 03/06/2014

Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 TRANSPORT INFORMATION


Labels Required

Marine Pollutant

HAZCHEM

3Z

UN number

3082

Land transport (ADG)

Packing group
UN proper shipping name
Environmental hazard

III
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains epoxy resin)
No relevant data
Class

Transport hazard class(es)

Subrisk

Special precautions for user

Special provisions

179 274 331 335 AU01

Limited quantity

5L

Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082


are not subject to this Code when transported by road or rail in;
(a) packagings;
(b) IBCs; or
(c) any other receptacle not exceeding 500 kg(L).
- Australian Special Provisions (SP AU01) - ADG Code 7th Ed.

Air transport (ICAO-IATA / DGR)


UN number
Packing group
UN proper shipping name
Environmental hazard

3082
III
Environmentally hazardous substance, liquid, n.o.s. * (contains epoxy resin)
No relevant data
ICAO/IATA Class

Transport hazard class(es)

ICAO / IATA Subrisk


ERG Code

Special precautions for user

9L

Special provisions

A97A158

Cargo Only Packing Instructions

964

Cargo Only Maximum Qty / Pack

450 L

Passenger and Cargo Packing Instructions

964

Passenger and Cargo Maximum Qty / Pack

450 L

Passenger and Cargo Limited Quantity Packing Instructions

Y964

Passenger and Cargo Limited Maximum Qty / Pack

30 kg G

Sea transport (IMDG-Code / GGVSee)


UN number
Packing group
UN proper shipping name

3082
III
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains epoxy resin)

Environmental hazard

Transport hazard class(es)

Special precautions for user

IMDG Class

IMDG Subrisk
EMS Number

F-A,S-F

Special provisions

274 335
Continued...

Chemwatch: 5141-59
Version No: 8.1.1.1

Limited Quantities

Page 8 of 8

Issue Date: 01/01/2013

Chockfast Red Resin

Print Date: 03/06/2014

5L

SECTION 15 REGULATORY INFORMATION


Safety, health and environmental regulations / legislation specific for the substance or mixture

bisphenol A/ epichlorohydrin
resin(25068-38-6) is found on the
following regulatory lists

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous
Goods Requirements (IMDG Code)","Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard
Facilities (And Their Threshold Quantity) Table 2","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) Schedule 5","WHO Model List of Essential Medicines - Adults","International Maritime Dangerous Goods Requirements (IMDG Code) Substance Index","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","United Nations
Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List
of Emergency Action Codes","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances
(AICS)","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by
Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","United Nations Recommendations on the Transport of Dangerous
Goods Model Regulations (Spanish)","OECD Existing Chemicals Database","Australia Dangerous Goods Code (ADG Code) - Dangerous
Goods List","Australia Hazardous Substances Information System - Consolidated Lists","International Air Transport Association (IATA)
Dangerous Goods Regulations","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part
2)","Australia - New South Wales Protection of the Environment Operations (Waste) Regulation 2005 - Characteristics of trackable wastes"

xylene(1330-20-7) is found on the


following regulatory lists

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous
Goods Requirements (IMDG Code)","International Council of Chemical Associations (ICCA) - High Production Volume List","Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","OSPAR List of Chemicals for Priority
Action","Australia Exposure Standards","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance
Index","FisherTransport Information","IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing at least
99% by weight of components already assessed by IMO, presenting safety hazards","Australia FAISD Handbook - First Aid Instructions,
Warning Statements, and General Safety Precautions","United Nations Recommendations on the Transport of Dangerous Goods Model
Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production
Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Australia Drinking Water Guideline Values For Physical and
Chemical Characteristics","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix I","Belgium Federal Public Service Mobility and Transport,
Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013
(Dutch)","UNECE - Kiev Protocol on Pollutant Release and Transfer Registers - Annex II","Australia National Pollutant Inventory","Australia Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm - Domestic
water supply quality","Australia High Volume Industrial Chemical List (HVICL)","WHO Guidelines for Drinking-water Quality - Guideline values
for chemicals that are of health significance in drinking-water","United Nations Recommendations on the Transport of Dangerous Goods Model
Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List - GESAMP Hazard Profiles","Australia
Dangerous Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA) Dangerous Goods
Regulations","Australia Hazardous Substances Information System - Consolidated Lists","Australia Standard for the Uniform Scheduling of
Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambient
environmental standards (Domestic water supply - organic compounds)","IMO IBC Code Chapter 17: Summary of minimum
requirements","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 7","International Fragrance
Association (IFRA) Survey: Transparency List","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule
6"

SECTION 16 OTHER INFORMATION


Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any
process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

end of SDS

Chockfast Red Aggregate


ITW POLYMERS AND FLUIDS
Chemwatch: 5141-61
Version No: 8.1.1.1
Safety Data Sheet according to WHS and ADG requirements

Issue Date: 01/01/2013


Print Date: 03/06/2014
Initial Date: Not Available
S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING


Product Identifier
Product name

Chockfast Red Aggregate

Chemical Name

Not Applicable

Proper shipping name

Not Applicable

Chemical formula

Not Applicable

Other means of identification


CAS number

Not Available
Not Applicable

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses

Mixed with Chockfast resin and hardener to form epoxy grouting compound..

Details of the supplier of the safety data sheet


Registered company name
Address
Telephone
Fax
Website

ITW POLYMERS AND FLUIDS


100 Hassall Street Wetherill Park NSW 2164
Australia
+61 2 9757 8800
+61 2 9757 3855
www.itwpf.com.au

Email

Not Available

Association / Organisation

Not Available

Emergency telephone numbers

1800 039 008

Emergency telephone number

Other emergency telephone numbers

+61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE


Primary Number

Alternative Number 1

Alternative Number 2

1800 039 008

+612 9186 1132

Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION


Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

Poisons Schedule
GHS Classification

[1]

Legend:

Not Applicable
STOT - RE Category 2
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

GHS label elements

SIGNAL WORD

WARNING

Hazard statement(s)
H373

May cause damage to organs through prolonged or repeated exposure

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Precautionary statement(s): Prevention


P260

Do not breathe dust/fume/gas/mist/vapours/spray.

Precautionary statement(s): Response


P314

Get medical advice/attention if you feel unwell.

Precautionary statement(s): Storage


Not Applicable

Precautionary statement(s): Disposal


P501

Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS


Substances
See section below for composition of Mixtures

Mixtures
CAS No

%[weight]

Name

14808-60-7

60-90

silica crystalline - quartz

65997-17-3

1-20

glass, oxide

70657-70-4

<1

propylene glycol monomethyl ether acetate, beta-isomer

Not Available

<1

hydrotreated distillate, light

Not Available

<1

polyether modified methalkyl polysiloxane copolymer

SECTION 4 FIRST AID MEASURES


Description of first aid measures

Eye Contact

Skin Contact

If this product comes in contact with the eyes:


Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area.


Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
Transport to hospital, or doctor.

Ingestion

Immediately give a glass of water.


First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Indication of any immediate medical attention and special treatment needed


Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES


Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.

Special hazards arising from the substrate or mixture


Fire Incompatibility

None known

Advice for firefighters

Fire Fighting

Fire/Explosion Hazard

Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Non combustible.
Not considered a significant fire risk, however containers may burn.

SECTION 6 ACCIDENTAL RELEASE MEASURES


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Personal precautions, protective equipment and emergency procedures

Minor Spills

Clean up all spills immediately.


Avoid contact with skin and eyes.
Wear impervious gloves and safety glasses.
Use dry clean up procedures and avoid generating dust.

Major Spills

Clear area of personnel and move upwind.


Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment and dust respirator.
Prevent spillage from entering drains, sewers or water courses.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE


Precautions for safe handling

Safe handling

Other information

Limit all unnecessary personal contact.


Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Avoid contact with incompatible materials.
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.

Conditions for safe storage, including any incompatibilities


Suitable container

Polyethylene or polypropylene container.


Check all containers are clearly labelled and free from leaks.

Storage incompatibility

No known incompatibility with normal range of industrial materials

PACKAGE MATERIAL INCOMPATIBILITIES


Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION


Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source

Ingredient

Material name

TWA

STEL

Peak

Notes

Australia Exposure Standards

silica crystalline quartz

Quartz (respirable dust) / Silica Crystalline Quartz (respirable dust)

0.1
mg/m3

Not
Available

Not
Available

(see Silica - Crystalline) /


(see Chapter 14)

EMERGENCY LIMITS
Ingredient

TEEL-0

TEEL-1

TEEL-2

TEEL-3

silica crystalline - quartz

0.3 ppm

0.3 ppm

0.3 ppm

50 ppm

glass, oxide

5 ppm

15 ppm

60 ppm

500 ppm

Ingredient

Original IDLH

Revised IDLH

silica crystalline - quartz

N.E. mg/m3N.E. ppm

50 mg/m3

glass, oxide

Not Available

Not Available

propylene glycol monomethyl ether acetate,


beta-isomer

Not Available

Not Available

hydrotreated distillate, light

Not Available

Not Available

polyether modified methalkyl polysiloxane


copolymer

Not Available

Not Available

Exposure controls

Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls
can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
"adds" and "removes" air in the work environment.

Personal protection

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Eye and face protection

Skin protection

Hands/feet protection

Body protection
Other protection
Thermal hazards

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Safety glasses with side shields; or as required,


Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the
wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and
adsorption for the class of chemicals in use and an account of injury experience.
See Hand protection below
Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive
particles are not present.
polychloroprene.
nitrile rubber.
butyl rubber.
See Other protection below
Overalls.
P.V.C. apron.
Barrier cream.
Not Available

Recommended material(s)

Respiratory protection

GLOVE SELECTION INDEX


Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computergenerated selection:
Chockfast Red Aggregate Not Available
Material

Type AX-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI
Z88 or national equivalent)

Required
Half-Face
Minimum
Respirator
Protection Factor

CPI

* CPI - Chemwatch Performance Index


A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final
selection must be based on detailed observation. * Where the glove is to be used on a short term, casual or infrequent basis, factors such as
"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise
be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

Full-Face
Respirator

Powered Air
Respirator

up to 10 x ES

AX P1
Air-line*

AX PAPR-P1
-

up to 50 x ES

Air-line**

AX P2

AX PAPR-P2

up to 100 x ES

AX P3

Air-line*

Air-line**

AX PAPR-P3

100+ x ES

* - Negative pressure demand ** - Continuous flow


A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES


Information on basic physical and chemical properties
Appearance

Red coloured sand granules with no odour; insoluble in water. Slightly wetted to inhibit dusting.

Physical state

Divided Solid

Relative density (Water = 1)

Odour

Not Available

Partition coefficient n-octanol / water

Odour threshold

Not Available

Auto-ignition temperature (C)

pH (as supplied)

Not Applicable

Decomposition temperature

2.57
Not Available
Not Applicable
Not Available

Melting point / freezing point (C)

1710

Viscosity (cSt)

Not Applicable

Initial boiling point and boiling range


(C)

2330

Molecular weight (g/mol)

Not Applicable

Flash point (C)


Evaporation rate
Flammability

Not Available
Not Applicable

Not Available
Not Available

Oxidising properties

Not Available

Upper Explosive Limit (%)

Not Applicable

Surface Tension (dyn/cm or mN/m)

Not Available

Lower Explosive Limit (%)

Not Applicable

Volatile Component (%vol)

Vapour pressure (kPa)

Not Available

Taste
Explosive properties

Not Applicable

Solubility in water (g/L)

Immiscible

Vapour density (Air = 1)

Not Applicable

Not Applicable

Gas group

Not Available

pH as a solution(1%)

7 (5% slurry)

VOC g/L

Not Available

SECTION 10 STABILITY AND REACTIVITY


Reactivity
Chemical stability

See section 7
Product is considered stable and hazardous polymerisation will not occur.
Continued...

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Possibility of hazardous reactions

See section 7

Conditions to avoid

See section 7

Incompatible materials

See section 7

Hazardous decomposition products

See section 5

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SECTION 11 TOXICOLOGICAL INFORMATION


Information on toxicological effects

Inhaled

Limited evidence or practical experience suggests that the material may produce irritation of the respiratory system, in a significant number of
individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first removing or neutralising the
irritant and then repairing the damage. The repair process, which initially evolved to protect mammalian lungs from foreign matter and antigens,
may however, produce further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory tract
irritation often results in an inflammatory response involving the recruitment and activation of many cell types, mainly derived from the vascular
system.

Ingestion

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of
corroborating animal or human evidence. The material may still be damaging to the health of the individual, following ingestion, especially where
pre-existing organ (e.g liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses
producing mortality rather than those producing morbidity (disease, ill-health).

Skin Contact

Eye

Chronic

Chockfast Red Aggregate

Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial number of
individuals following direct contact, and/or produces significant inflammation when applied to the healthy intact skin of animals, for up to four
hours, such inflammation being present twenty-four hours or more after the end of the exposure period. Skin irritation may also be present after
prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by skin
redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. At the
microscopic level there may be intercellular oedema of the spongy layer of the skin (spongiosis) and intracellular oedema of the epidermis.
Limited evidence exists, or practical experience suggests, that the material may cause eye irritation in a substantial number of individuals and/or
is expected to produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental
animals. Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva
(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Serious damage (clear functional disturbance or morphological change which may have toxicological significance) is likely to be caused by
repeated or prolonged exposure. As a rule the material produces, or contains a substance which produces severe lesions. Such damage may
become apparent following direct application in subchronic (90 day) toxicity studies or following sub-acute (28 day) or chronic (two-year) toxicity
tests.

TOXICITY

IRRITATION

Not Available

Not Available

TOXICITY
silica crystalline - quartz

glass, oxide

propylene glycol monomethyl ether


acetate, beta-isomer

IRRITATION
Y

Not Available

Not Available

TOXICITY

IRRITATION

Not Available

Not Available

TOXICITY

IRRITATION

Dermal (rabbit) LD50: >5000 mg/kg*

[CCINFO]*

Inhalation (rat) LC50: 4345 ppm/6h


Oral (rat) LD50: 8532 mg/kg
Not Available

Not Available

Not available. Refer to individual constituents.

WARNING: For inhalation exposure ONLY: This substance has been classified by the IARC as Group 1: CARCINOGENIC TO HUMANS

SILICA CRYSTALLINE - QUARTZ

GLASS, OXIDE

The International Agency for Research on Cancer (IARC) has classified occupational exposures to respirable (<5 um) crystalline silica as
being carcinogenic to humans . This classification is based on what IARC considered sufficient evidence from epidemiological studies of
humans for the carcinogenicity of inhaled silica in the forms of quartz and cristobalite. Crystalline silica is also known to cause silicosis, a
non-cancerous lung disease.
Intermittent exposure produces; focal fibrosis, (pneumoconiosis), cough, dyspnoea, liver tumours.
No significant acute toxicological data identified in literature search.
A similar spherical glass powder was nontoxic to rats at 5,000 mg/kg. All animals survived, gained weight and appeared active and healthy.
There were no signs of gross toxicity, adverse pharmacologic effects or abnormal behavior. There are no known reports of subchronic
toxicity of nonfibrous glass. There are no known reports of carcinogenicity of nonfibrous glass When tested for primary irritation potential, a
similar material caused minimal irritation to eyes and was non-irritating to skin. Dust in excess of recommended exposure limits may result in
irritation to the respiratory tract

Continued...

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PROPYLENE GLYCOL MONOMETHYL


ETHER ACETATE, BETA-ISOMER

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Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic
condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating
compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with
abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern,
on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal
lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.
No data for material. Data for isomer only as its alpha isomer; propylene glycol monomethyl ether acetate:

Acute Toxicity

Carcinogenicity

Skin Irritation/Corrosion

Reproductivity

Serious Eye Damage/Irritation

STOT - Single Exposure

Respiratory or Skin sensitisation

STOT - Repeated Exposure

Mutagenicity

Aspiration Hazard

CMR STATUS
Not Applicable

SECTION 12 ECOLOGICAL INFORMATION


Toxicity
DO NOT discharge into sewer or waterways.

Persistence and degradability


Ingredient

Persistence: Water/Soil

Persistence: Air

Not Available

Not Available

Not Available

Bioaccumulative potential
Ingredient

Bioaccumulation

Not Available

Not Available

Mobility in soil
Ingredient

Mobility

Not Available

Not Available

SECTION 13 DISPOSAL CONSIDERATIONS


Waste treatment methods
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Management Authority for disposal.
Bury residue in an authorised landfill.
Recycle containers if possible, or dispose of in an authorised landfill.

Product / Packaging disposal

SECTION 14 TRANSPORT INFORMATION


Labels Required

Marine Pollutant
HAZCHEM

NO
Not Applicable

Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS


Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

SECTION 15 REGULATORY INFORMATION


Safety, health and environmental regulations / legislation specific for the substance or mixture

silica crystalline - quartz(14808-60-7) is


found on the following regulatory lists

"Australia Hazardous Substances Requiring Health Surveillance","Australia - Tasmania - Work Health and Safety Regulations 2012 Restricted hazardous chemicals","Australia Exposure Standards","Australia - Western Australia Hazardous Substances Requiring Health
Surveillance","Australia - Northern Territories Work Health and Safety National Uniform Legislation Regulations- Requirements for health
monitoring - Hazardous chemicals (other than lead) requiring health monitoring","FisherTransport Information","Australia - Tasmania
Hazardous Substances Requiring Health Surveillance","United Nations Consolidated List of Products Whose Consumption and/or Sale Have
Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments","Australia - Northern Territories Work Health and Safety
National Uniform Legislation Regulations- Restricted hazardous chemicals","Australia - Tasmania Hazardous Substances Prohibited for
Continued...

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Specified Uses","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Australia Queensland Work Health and Safety Regulation - Restricted hazardous chemicals","Australia - South Australia - Work Health and Safety
Regulations 2012 - Restricted hazardous chemicals","Australia - Western Australia Hazardous Substances Prohibited for Specified Uses or
Methods of Handling","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Australia
Occupational Health and Safety (Commonwealth Employment) (National Standards) Regulations 1994 - Hazardous Substances Requiring
Health Surveillance","Australia - South Australia - Work Health and Safety Regulations 2012 - Requirements for health monitoring - Hazardous
chemicals (other than lead) requiring health monitoring","Australia - Queensland Work Health and Safety Regulation - Hazardous chemicals
(other than lead) requiring health monitoring","Sigma-AldrichTransport Information","Australia - New South Wales - Work Health and Safety
Regulation 2011 - Requirements for health monitoring -Hazardous chemicals (other than lead) requiring health monitoring","Australia High
Volume Industrial Chemical List (HVICL)","Australia Work Health and Safety Regulations 2011 - Hazardous chemicals (other than lead)
requiring health monitoring","OECD Existing Chemicals Database","Australia - New South Wales - Work Health and Safety Regulation 2011
Restricted hazardous chemicals","Australia Hazardous Substances Information System - Consolidated Lists","Australia - New South Wales
Hazardous Substances Requiring Health Surveillance","Australia Work Health and Safety Regulations 2011 - Restricted hazardous
chemicals","Australia - Tasmania - Work Health and Safety Regulations 2012 - Requirements for Health Monitoring - Hazardous chemicals
(other than lead) requiring health monitoring","Australia - South Australia - Hazardous Substances Requiring Health Surveillance","Australia New South Wales Hazardous Substances Prohibited for Specific Uses"
glass, oxide(65997-17-3) is found on the
following regulatory lists

propylene glycol monomethyl ether


acetate, beta-isomer(70657-70-4) is
found on the following regulatory lists

"FisherTransport Information","Australia Inventory of Chemical Substances (AICS)","OECD List of High Production Volume (HPV)
Chemicals","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Sigma-AldrichTransport
Information","Australia Hazardous Substances Information System - Consolidated Lists"
"International Maritime Dangerous Goods Requirements (IMDG Code)","International Maritime Dangerous Goods Requirements (IMDG
Code) - Substance Index","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia
Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production Volume (HPV) Chemicals","Australia
Inventory of Chemical Substances (AICS)","OSPAR National List of Candidates for Substitution Norway","Belgium Federal Public Service
Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID
2013 (Dutch)","International Chemical Secretariat (ChemSec) SIN List (*Substitute It Now!)","Australia National Pollutant Inventory","United
Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Spanish)","Australia Dangerous Goods Code (ADG
Code) - Dangerous Goods List","Australia Hazardous Substances Information System - Consolidated Lists","International Air Transport
Association (IATA) Dangerous Goods Regulations"

SECTION 16 OTHER INFORMATION


Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any
process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

end of SDS