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Part 2 CCT Overview

Environmental Protection Technologies (Flue Gas Treatment and Gas Cleaning Technologies)

5B1. SOx Reduction Technology
Technology overview

1. Background
Sulfur oxides (SOx, mainly SO2) are regulated by a "K-value"

and lower costs have been ongoing. At present, most pulverized

control, which uses exhaust heights and regional coefficients to

coal-fired thermal power plants are equipped with wet limestone

limit SOx emissions. "Total amount control" is a term used in

and gypsum-based desulfurization systems. Furthermore, a wet

Japan to define the total emissions from the whole of a region.

desulfurization process requiring no wastewater treatment is now

To comply with these regulations, flue gas desulfurizers were

under development.

commercialized in 1973. Efforts to improve their performance

2. Technology
(1) Wet limestone-gypsum process

The overall reaction is as follows:

Research and development: Mitsubishi Heavy Industries, Ltd.;
Babcock Hitachi K.K.; Ishikawajima-Harima Heavy Industries Co., Ltd.;
Chiyoda Corporation; Kawasaki Heavy Industries, Ltd.; others

CaSO3-0.5H2O+0.5O2+1.5H2O

CaCO3+SO2+0.5H2O

CaSO3-0.5H2O+CO2
CaSO4-2H2O

There are two types of absorption towers, as shown in Figure 1: a

Overview

CaSO3-0.5H2O separate tower oxidation system and a

There are two limestone-gypsum processes; a soot-separation

comprehensive single tower oxidation system. At present, single

process, in which a dust (cooling) tower is installed upstream for

tower oxidation systems are less expensive to install and operate

dust collection and HCI/HF removal and cooling, and a soot-

and their use is increasing annually. There are several methods to

mixed process without such a dust (cooling) tower. The soot-

have recycled absorption liquid come into contact with SO2 in the

separation process is used when high-purity gypsum containing

absorption tower section; the "spray method," which sprays the

no soot or dust is desired. At present, however, more and more

absorption liquid, the "grid method," which spreads absorption

systems employing the soot-mixed process, which is less

liquid on the surface of a grid-like pad, the "jet-bubbling method,"

expensive to install, are being installed since high-performance

which blows exhaust gas into the absorption liquid, and the

dust collection devices, such as an advanced low-temperature

"water-column method," in which absorption liquid flows in the

electrostatic precipitator, which lowers soot/dust concentrations,

absorption tower.

have been developed.

For developing countries, a simple desulfurizer installable in the

In the absorption tower, on the other hand, a water-mixed

flue gas duct or at the lower part of a smoke stack has also been

limestone slurry is reacted with SO2 within the exhaust gas for

commercialized.

the recovery of sulfur contents as gypsum (CaSO4-2H2O).

Oxidation tower-separated type

In-absorption tower oxidation type

Absorption tower
Sulfuric
acid

Absorption tower
Oxidation
tower

Basic flow
Gypsum
Gas

Gas

Air
Limestone

Limestone

Absorption tank

Gypsum
Absorption tower tank

Air

Fig. 1 Limestone-gypsum process-based desulfurizers

85

1 unit (350MW). causing the following reaction to CaCO3+SO2 CaSO3+CO2 References 1) "Introductory Course: Environmental Preservation Technology/Equipment for Thermal Power Plants IV Desulfurization Equipment.. Limestone to be used for desulfurization is mixed and but SO2 is removed in accordance with the following reaction: combusted with the coal. By using the Conveyor newly produced absorbent. Institute of Electric Engineers. The desulfurization Clean gas Desulfurization fan Scale Steam Primary absorption agent technologies developed to make effective use of coal ash. 1997). which is sprayed into a spray dryer. Inc." Thermal/Electronic Power Generation. fluidized-bed boilers. and to be removed. 3) "Coal Ash-Based Dry Flue Gas Desulfurizer" pamphlet. J-POWER. operation and attained a 70% desulfurization rate in verification Within the dryer. 4 unit (210MW) in Qingdao. 1990. Vol. as part of the "Green Aid Plan.. Ltd. (4) Furnace desulfurization process remove SO2 at a furnace temperature of 760-860oC: Research and development: Hokkaido Electric Power Co. Kyushu Electric Power’s New Kanda thermal power plant. The process can Fig. Temperatures are maintained between 100-200oC. Inc. SOx is removed from the flue gas.. Kyushu Electric Power Co. 911.." Thermal/Electronic Power Generation Vol. 1990. Hitachi. 2 Coal ash-based dry desulfurization process also remove dust and NOx. limestone does boilers. the technology had been installed at Hokkaido Electric Power’s Tomatoh-Atsuma Thermal power plant No... causing the plant No. 4) General View of Thermal Power Generation. No. China. Mitsubishi Heavy Industries.. "Coal Ash-Based Dry Desulfurizer Development. 2 unit normal-pressure fluidized-bed boilers as well as the pressurized fluidized-bed boilers of Hokkaido Electric Power’s Tomatoh-Atsuma thermal power plant.5H2O).. where the equipment is being used to treat one- Spent desulfurization agent Boiler Exhaust gas Water Kneader Drier Hot air is a process to produce a new absorbent from limestone." where dryer desulfurizer with an exhaust gas treatment capacity of water is added to burned lime (CaO) to make a slack lime 300Km3N/h (one-half of total exhaust) at the Huangdao power (CaSO4-H2O) and calcium sulfite (CaSO3-0. Ltd.. giving a particle mixture of gypsum Research and development: The Electric Power Development Company. Inc.. Inc. By 2003. Project type: Voluntary CaCO3 CaO+CO2 CaO+SO2 CaSO3 At present. and Chugoku Electric Power’s Osaki thermal power plant. Mitsubishi Heavy Industries. 86 not . this process is employed at J-POWER’s Takehara thermal power plant No. 2002. J-POWER. moreover. Hokkaido Electric Power. Conveyor Extruder Mixer calcium hydroxide (Ca(OH)2) and spent absorbent.. Since this Overview waste.. 7. Project type: Subsidized development of oil-alternative energy-related technology for commercialization Development period: 1986-1989 more. Chugoku Electric Power Co. These process is not adequate for good-quality gypsum and. where an SOx removal Spent desulfurization agent Breaker efficiency of 90% or greater can be attained. 41 No.." installed a spray The spray dryer process is a so-called "semi-dry process. Ltd. desulfurized particles are disposed of as (Ca(OH)2) slurry. Ltd. Project type: Voluntary under the Green Aid Plan particles are recovered at a down-stream precipitator. Babcock Hitachi K. It is currently in SO2 in the flue gas to react with Ca(OH)2. This Pre-absorption agent The coal ash-based dry desulfurization process was one of the Desulfurization silo Overview Slack lime Coal ash half of the flue gas. Ltd. In Overview pressurized The furnace desulfurization process is used for fluidized-bed breakdown into CaO due to the high partial pressure of CO2. 7. the desulfurization reaction and limestone drying tests (Oct. Kawasaki Heavy Industries. 911. ash remains in the mix. 1994 through Oct. Ishikawajima-Harima Heavy Industries Co. which also includes a Scale stage to manufacture the absorption agent. Hokkaido Electric Power Co. Figure 2 shows an outline of this process.. Screen Steam generator reaction allows Ca(OH)2 to remove SO2. with a NOx removal efficiency of (3) Spray dryer process take place simultaneously. 2) Kudo et al.Clean Coal Technologies in Japan (2) Coal ash-based dry desulfurization process approximately 20% and a dust collection efficiency of 96% or Research and development: Hokkaido Electric Power Co.. Inc. 41.K.