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ISSN: 2455-9024
Research Department of Physics, Holy Cross College (Autonomous), Nagercoil, Tamil Nadu, India-629004
Email address: 2priyadharshini065@gmail.com
Abstract NiO has a wide bandgap value ranging from 3.6 to 4.0 eV
and exhibits low p-type conductivity. The structural and optical
properties of NiO-based nanoparticles can be modified by doping
with lithium (Li) for suitable applications in the field of
photocatalysis and sensors. In this present work, sol-gel method is
used to produce the pure NiO nanoparticles and Li doped NiO
nanoparticles at two different concentrations 0.01 M and 0.09 M. All
the samples exhibit cubic structure as confirmed from the JCPDS
File No.: 89-5881. The absence of impurity peaks reveals that the
pure and Li doped NiO nanoparticles exhibit high crystalline quality.
From PXRD and FESEM, it is observed that crystallinity and
average grain size of the NiO nanoparticles increases with increase
in the Li doping concentration. PL studies show a blue shift for the
pure and Li doped NiO nanoparticles.
I.
EXPERIMENTAL TECHNIQUES
INTRODUCTION
55
S. Irudaya Sahaya Lancy, M. Priya Dharshini, V. Shally, and Sr. Gerardin Jayam, Effect of lithium doping concentration on the structural,
morphological and optical properties of NiO nanoparticles, International Research Journal of Advanced Engineering and Science, Volume
1, Issue 2, pp. 55-58, 2016.
200
The PXRD pattern for the pure NiO nanoparticles with the
high intensity peaks observed at 2= 43.16o along the (4 0 0)
hkl plane, 2= 62.61o along the (4 4 0) hkl plane and 2=
37.01 o along the (2 2 2) hkl plane are presented in figure 1.
(222)
250
140
(440)
120
100
(622)
Intensity (counts)
160
80
(440)
300
60
40
(622)
Intensity(counts)
180
(400)
350
(400)
(222)
III.
200
20
10
30
40
50
60
70
80
100
50
10
20
30
40
50
60
70
TABLE I. Average grain size and dislocation density of pure and Li doped
NiO nanoparticles
Average
Dislocation
Nanopowder
S. No.
Grain Size
Density (1015)
Samples
(nm)
(lines/m2)
1.
Pure NiO
4.7294
0.04471
2.
0.01 M Li doped NiO
7.1940
0.01932
3.
0.09 M Li doped NiO
13.3609
0.00560
80
(degree)
100
(4 0 0 )
90
70
(4 4 0)
(2 2 2)
80
Intensity(counts)
20
(degree)
150
60
50
40
30
20
10
10
20
30
40
50
60
70
80
2(degree)
56
S. Irudaya Sahaya Lancy, M. Priya Dharshini, V. Shally, and Sr. Gerardin Jayam, Effect of lithium doping concentration on the structural,
morphological and optical properties of NiO nanoparticles, International Research Journal of Advanced Engineering and Science, Volume
1, Issue 2, pp. 55-58, 2016.
57
S. Irudaya Sahaya Lancy, M. Priya Dharshini, V. Shally, and Sr. Gerardin Jayam, Effect of lithium doping concentration on the structural,
morphological and optical properties of NiO nanoparticles, International Research Journal of Advanced Engineering and Science, Volume
1, Issue 2, pp. 55-58, 2016.
[7]
[8]
IV.
CONCLUSION
[9]
[10]
[11]
[12]
[13]
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S. Irudaya Sahaya Lancy, M. Priya Dharshini, V. Shally, and Sr. Gerardin Jayam, Effect of lithium doping concentration on the structural,
morphological and optical properties of NiO nanoparticles, International Research Journal of Advanced Engineering and Science, Volume
1, Issue 2, pp. 55-58, 2016.