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You are on page 1of 13

DATE : 09/05/2015

TIME : 2 Hours

a) Speed (rate) of reaction

b) Concentration of the reactants

b) Pressure of the surroundings

d)Temperature

2)The time taken for the completion of of a first order reaction is

a)(2.303/k) log(3/4 )

b)(2.303/K) Log 4

c)(2.303/0.75)log k

d)(2.303/k)log 1/4

N2 (g) +3H2(g) -------- 2 NH3(g) ?

a)3d[H2]/dt =2d[N2]/dt

b)2d[N2]/dt=1/3d[H2]/dt

c) 2d[NH3]/dt= -3d[H2]/dt

d) 2d[NH3]/dt= -2d[H2]/dt

4)The activation energy for a simple chemical reaction A--B is Ea in forward direction .The

activation energy for the reverse reaction

a)is negative of Ea

5)A chemical reaction was carried out at 300k and 280k .The rate constants were found to be K 1

and K2 respectively.Then

a) K2=4 K1 b) K2=2 K1 c) K2=0.25 K1 d) K2=0.5 K1

6)The rate constant is given by the equation K=P.Ze -E/RT. which factor register a decrease for the

reaction to proceed more rapidly ?

a)T

b)Z

c)E

d)P

a)In K/x b)K/x

c)K+x d)K

8)A large increase in the rate constant with small rise in temperature for a gaseous reaction is

indicative of

a)Large number of collisions at higher temperature

b)High value of activation energy of the reaction

c)High value of the pre exponential factor

d)Increase in the average speed of molecules .

9)Which of the following formulae represents the first order reaction ?

a)k=2.303/t log [A]/[A]0

log(a/a+x)

[A]=[A 0]e-kt

c)

d) k=2.303/t

10) If a is the initial concentration of the reactant ,the time for completion of the reaction, if it is

of zero order,will be

a)a/k

b)a/2k

c)2a/k

d)k/a

a) mole litre s-1

b)mole-1 litre-1s-1

c) mole litre-1s-1

a)2N2O5 -----4NO2 +O2

d) 2NO+O2 ---2NO2

13)What is the order of a reaction which has a rate expression rate =k[A] 3/2[B]-1 ?

a)3/2

b)1/2 c)zero

d)none of these

14)The Arrhenius equation expressing the effect of temperature on the rate constant of the

reaction is

a)k=e-Ea/RT

b)k=Ea/RT

c)k=logeEa/RT d)k=Ae-Ea/RT

a) zero

b) 1

c) 2

d) 3

16)When concentration of reactant in reaction A--- B is increased by 8 times, the rate increase

only 2 times .The order of the reaction would be

A) 2

b) 1/3

c) 4

d)

17) For the first order reaction half life is 14 s .The time required for the initial concentration to

reduce to 1/8 th of its value is

A)28 s

b)42 s

c)(14) 3s

d) 14)2s

a) litre

1-n

mol1-n s-1

b) mol1-n litre

1-n

c) mol

1-n2

litren2 s-1

d) mol1-n litre

n-1

s-1

19)An endothermic reaction A--B has an activation energy as x kJmol-1 of A. If energy change of

the reaction is y kJ. The activation energy of the reverse reaction is

A) -X

b) x-y

c) x + y

d) y-x

a) L mol-1 s-1

b) mol L-1 s

-1

c) mol s-1

d) none of these

FUNCTIONs )

1)The value of a unit vector in the direction of vector A=5i-12j is

a)

i^

^

b) j

^

c) ( i

^j

)/13

d)

(5 i1 j)/13

2)Two vectors A and B lie in X-Y plane .The vector B is perpendicular to vector A if A=I + j, then B

may be

a) i j b i+ j c 2i+2 j d an y of the above

3) The two vector A=2i +j +3k

A)parallel

c) anti- parallel

b)perpendicular

d)none of these

A)tan-1 3/2

b) tan-1 2/3

c) sin-1 2/3

d) cos-1 3/2

5) A vector A points vertically upward and ,B points toward north The vector product A*B is

a) Along west

b) along east

c) zero

d) vertically downward

6) If A = B + C and the magnitudes A ,B , and C are 5,4 ,and 3 units ,the angle between A and C is

a)cos-1 (3/4)

b)cos-1 (4/5)

c) /2

a) <

B) < IF A<B

d) sin -1(3/4)

c) < if A>B

d) < if A =B

a)-I +j b) j +k

c) i +j -2k

9) The vectors a+ 5b -7 c

a)10

b)-10

c) 0

b=I + j + k

d) j + 3k + i

& -2a b + 14c are collinear ,then the value of is

d) 14

10) The position vectors of the points which divided internally &externally in ratio 3:4,the join of the points a+b , 2a b

respectively are

a)

10 a+b

& 2 a+7 b

7

c)

10 a2 b

4 a+7 b

7

10 ab

12 a+ 4 b

7

b)

d)

2 a+7

b10 a+b

7

11) Find the co ordinates of the terminal point of the vector AB where initial point has co-ordinates (5,6)

and whose components are -7i & 4j along x and y axis respectively

a)(2,10 )

12) If

c) (-2 ,0)

d)(10 ,10)

a) 8

13) If

b) (10 ,2)

b) 9

c) 10

d) 14

a)cos-1(3/4)

b) cos-1 (13/14)

c)cos-1(3/4)

d)cos-1(14/13)

14) Find the value of a so that the angle between the two vector

a)-4

b)(-4 ,0)

c) (-1 ,4 )

i j+ ak

0

i+k is 60

d) ( 0, 3)

15) What will be the angle between a & b if there is a set of there vectors a , b & c such that a+b+c =0 &|a| = 3 |b|=5

& |c| =7

a) =90

b )=40

c) =60

d) =30

a)6

b)7

d) 8

d)5

a) 5i -3 j k

5i

3j

k

18 ) The two vectors a=

a) Parallel

5i

3j

k

35 35 35

d)

12 i+ 16 j9 k

none of these

( 3 ,1 , 2 ) , ( 1,1 , 3 ) , ( 4 ,3 ,1 )( 6 ,3 , 0 ) is

a)21 sq unit

b) 14 sq unit

c) 15 sq unit

d) 27 sq unit

a)

|c +d|=|a+ d| b a+d=a+d

b)

a=c d d=b

21) Let A={1,2,3} then the number of equivalence relations containing (1, 2) is

a) 1

b) 2

c) 3

d) 4

a)reflexive and transitive

then R is

23) Let R be the root line .Consider the following subsets of the plane R*R

S=

T=

{( x , y ) : x y is aninteger }

a)T is an equivalence relation on R but S is not

24)Let W denotes the words in the English dictionary .Define the relation R by

R=

b) reflexive ,symmetric and transitive

c)reflexive , not symmetric and transitive

d)not reflexive ,symmetric and transitive

25)Let R1 and R2 be equivalence relations on a set A , then R1U R2 need not be

a) reflexive b) symmetric

c) transitive

d) none of these

a)

f ( x )=x

b)

f ( x )=x

+2

a)one one bt not onto

c)

f ( x )=2 x +1

f ( x )=( x1 ) ( x2 ) ( x 3 ) is

d)

f ( x )=x

+1

28)Let A={ x : -1 x 1

a) a bijection

then

is

then

is

29)Let function

f ( x )=x |x| ,

30)

f ( x )=

is rational

{0x,if, ifxxisirrational

}

g ( x ) = 0,if x is rational

x ,if x is irrational

and

then

f g is

PHYSICS ( ELECTROSTATICS )

1)

a)zero

b) 8 N

c) 4 N

d) 12 N

2)

A long string with a charge of per unit length passes through an imaginary cube of edge

a .the maximum flux of the electric field through the cube will be

a) a/ E

b) 2 a/ E

c) 6 a/ E

d) 3 a /E

3)

If charge q is placed at the centre of the line joining two equal charges Q.The system of

three charges will be in equilibrium if q is

a) Q/2

b) Q/4

c) 4Q

d) +Q/2

There are two charges +1 c and +5 c . The ratio of the forces acting on them

4)

will be

a)1 : 1

b)1: 2

c)1 : 3

d)1:4

5)

Two spheres A and B of exactly same mass are given equal positive and negative charges

respectively .Their masses after charging

a)remain unaffected

can be said

6)

Two point charges repel each other with a force of 100N .One of the charges is increased by

10 %and other is reduced by 10 % .The new force of repulsion at the same distance would be

a)100N

b)121 N

c)99N

d)none of these

7)

Two electrons are separated by a distance r metre and have coulomb force F .Two alpha

particles separated by 2r metre will have a force equal to

a)2F

8)

b)3F

c)F/2

d)F

a)1 C2 N-1m-2

is

C)1/(9 x 109 ) C2 N-1m-2

D) 1/(4

x 9 x 109 ) C2 N-1m-

9)

A positively charged rod is brought near an uncharged conductor .if the rod is then suddenly

withdrawn, the charge left on the conductor will be

a)positive

10)

b)negative

c)zero

d)note sure

Two balls carrying charges +7 c and -5 c attract each other with a force F. if a

a)F

b)F/2

11)

line

d)zero

What is the angle between electric dipole moment and electric field due to it on the axial

a)00

12)

c)2F

b) 900

c)1800

13)

a) -3

b)- 2

c)- 1

d) 0

where n is

14)

Fig .12.28 given here is plot of lines of force due to two charges q 1 and q2 .The signs of

the two charges are

a)both positive

b)both negative

c)upper positive ,lower negative

d)upper negative ,lower positive

15)

infinite length

16)

a)zero

17)

b)positive

c)negative

d)infinite

a)2

18)

b)

/2

c)

/4

d)

a)

19)

/2

b)

c)

d)

and +6 C

of -4 C

a)zero

b)4N attractive

c)4N repulsive

d)12N attractive

20)

A charge particle q is placed at the centre O of a cube length L .Another same charge q is

placed at a distance L from O .The electric flux through the cube is

a) q /4 0L

b) q /

c)2 q /

d)zero

MECHANICS

1)

A particle is moving so that its displacement s is given as s=t 3 -6t2 +4 metre .Its velocity at

the instant when its acceleration is zero will be

a) 3 m/s

b) -12 m/s

c) 42 m/s

d) -9 m/s

2)

If y denotes the displacement and t denotes the time and displacement is given by y=a sin

wt ,the velocity of the particle is

a)a cos wt

b) a cos wt

c)aw cos wt

d) (a cos wt )/w

3)

The displacement x of a particle moving along a straight line is related to time by the

reaction t=x +3 ,The displacement of the particle when its velocity is zero is given by

a)0

b) -2

c)2

d) 1

4) The variation of velocity of a particle moving along straight line shown in figure .The distance

traversed by the body in 4 sec is

a)70 m

b)60 m

c) 40 m

d) 55 m

5)

a)

b)

6)

b)

d)

a)

b)

c)

d)

AB

BC

CD

DE

7) The adjoining curve represents the velocity- time graph of a particle ,its acceleration values along

OA,AB and BC in metre/sec 2 are respectively

a)1,0,0.5

b)1,0,0.5

c)1,1,0.5

d)1,0.5,0

8)

A particle, after starting from rest ,experiences, constant acceleration for 20 sec .if it

covers a distance of S1 in first 10 sec and distance S2 in next 10 sec ,then

a) S2= S1/2

b) S2= S1

c) S2= 2S1

d) S2= 3S1

9)

The initialvelocity of a particle is 10 m/s and its retardation is 2 m/sec 2 .The distance

covered in the fifth second of the motion will be

a) 1m

b) 19 m

c) 50 m

d) 75 m

10) A moving train is stopped by applying brakes .it stops after travelling 80 m .if the speed of

the train is doubled and retardation remains the same .it will cover a distance

A) Same as earlier

b) double the distance covered earlier

c) Four times the distance covered earlier d) half the distance covered earlier

11) A body starts from rest ,the ratio of distances travelled by the body during 3 rd and 4th

seconds is

a)7/5

b) 5/7

c) 7/3

d) 3

12) Which of the following equations represent the motion of a body with finite constant

acceleration . in these equations y denotes the position of the body at time t and a, b ,and c are

constant of the motion

a)y=a/t =bt

b) y=at

c) y = at +bt 2

d) y = at +bt2 +ct3

13) A rocket is projected vertically upwards and its time-velocity graph is shown in the

figure.the maximum height attained by the rocket is

a)

b)

c)

d)

1 km

10km

100km

60km

14) An object is released from some height .Exactly after one second ,another is release from

the same height The distance between the two objects exactly after 2 seconds of the release of

second object will be

a) 4.9 m

b) 9.8 m

c)19.6 m

d) 24.5m

15) A stone is thrown vertically upwards from the top of a tower with a velocity u an it reaches

the ground with a velocity 3u .the height of the tower is

a) 3u2/g

b)4 u2/g

c) 6u2/g

d)9 u2/g

16) A ball is thrown from the ground with a velocity of 80 ft/sec .Then the ball will be at a height

of 96feet above the ground after time

a)2 and 3 sec

b) only 3 sec

c) only 2 sec

d) 1 and 2 sec

17) A stone is dropped from a bridge and it reaches the ground in 4 seconds .the height of the

bridge is

a) 78.4m

b)64

c)260m

d)2000m

18) A rocket is launched from the earth surface so that it has an acceleration of 19.6 m/s 2 .if its

engine is switched off after 5 seconds of its launch,then the maximum height attained by rocket

will be

a)245m

b) 490

c)980m

d) 735m

19) Two bodies of different masses ma and mb are dropped from two different heights viz a and

b .the ratio of times taken by the two to drop through these distances is

a)a:b

b) ma/ mb

c) a:b

d)a2/b2

20) A body thrown up with a finite speed is caught back after 4 sec .the speed of the body with

which it is thrown up is

a)10 m/s

b) 20 m/s

c) 30 m/s

d) 40 m/s

21)

A ball is dropped from certain height on a glass floor so that it rebounds elastically to the

same height .if the process continues the velocity time graph for such a motion would be

22) In the following velocity-time graph of a body .the distance and displacement travelled by

the body in 5 second in meters will be

a)70,110

b)110,70

c)40,70

d)90,50

23) The following figures show some velocity v versus time t curves but only some of these can

be realized in practice .This are

a)a ,b ,d

b) a ,b ,c

c) b , c

d) all of them

24) a girl walks along an east-wst street and a graph of her displacement from home is as

shown in figure.Her average velocity for the whole time interval is

a)

b)

c)

d)

Zero

6m/min

11m/min

15 m/min

represented by

a)

b)

B)

D)

26) Adjacent graph shown the variation of velocity of a rocket with time .Find the time of

burning of fuel from the graph

a)10 sec

b)110sec

c)120sec

d) cannot be estimated from the graph

27) A particle moves from the position of rest and attains a velocity of 30m/sec after10 sec

.The acceleration will be

a)9 m/sec2

28)

b)18 m/sec2

c)3 m/sec 2

d)4 m/sec 2

29) A bal is thrown upwards with a speed V from a height h above the ground .The time taken

by the ball to hit the ground is

a)(2h/g )

b) (gh/g)

d) V/g +(2h/g)

30)

A car accelerates from rest at a constant rate for some time ,after which is

deaccelerates at a constant rate and comes to rest .IF the tota time elapsed in t ,then the

maximum velocity acquired by the car is

A)(2 + 2 /)/t

b) (2 - 2 /)/t

c) ( + )t /

d)t/+

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