You are on page 1of 12



Time: 15 minutes

Marks: 15

1. Electrophiles are electron seeking species. Which of the following groups contain
only electrophiles?
(i) BF3, NH3, H2O
(ii) AlCl3, SO3, NO+2
(iii) NO+2, CH3+, CH3−C+=O
(iv) C2H+5, C2+H5, C2H+5
(ii) and (iii)
(i) and (iv)
(i) and (ii)
(i) and (iii)

2. What does the following diagram showing Lewis structures depict?

metamerism in nitromethane (CH3NO2)
inductive effect in nitromethane (CH3NO2)
electron displacement effects in nitromethane (CH3NO2)
resonance structures of nitromethane (CH3NO2)
3. In the four compounds below, which of the following pairs are position isomers?
(i) I and II
(ii) II and III
(iii) II and IV
(iv) III and IV


weebly.noimurrahman. 5. II IV 1. Which is incorrect representation? . When CH3Cl undergoes hemolytic bond-fission: (a) Carbon undergoes a geometric change from tetrahedral to planar (b) Hybridisation changes from sp3 + sp2 (c) Both of the above take place (d) None of the above takes place. Select the incorrect statement: (a) is called Carbonium ion (b) In carbon is even more electron deficient than that in a radical (c) In there is sharing of eight electrons among five bonds (d) are called carbenium ions based on IUPAC nomenclature 4. Which has maximum stability (a) (b) (c) (d) 2.www. Select correct statement(s) about carbene: (a) It is obtained by photolysis of diazomethane or ketene (b) It can be inserted into alkene forming cycloalkane (c) It can exist as single or triplet (d) All the statements are true.

Which is not the electrophile? . Select incorrect comparison as nucleophile: (a) (b) (c) (d) 9. 8.noimurrahman. Which of the following compounds can react with the Lewis base Cl – in a Lewis acid-base reaction? (a) CH4 (b) AlCl3 (c) OH– (d) CH3– (a) (b) (c) (d) 6. In the following reaction: (a) I is a Lewis acid and II is a Lewis base (b) I is a Lewis base and II is a Lewis acid (c) Both are Lewis acids (d) Both are Lewis bases.weebly.www.

Select incorrect statement: (a) Homolytic fission results in the formation of free radicals (b) Heterolytic fission results in the formation of Lewis acid and Lewis base (c) Completion of the octet provides a major driving force for the Lewis acid-base reaction (d) Steric bulky group increases (a) (b) (c) BF3 (d) SO3 10.weebly. Which is most stable carbocation? (a) (b) (c) (d) 12. Which comparison is not correct as indicated? (a) (b) (c) . 11.noimurrahman.www.

www. Select incorrect statement(s): (a) Electron-withdrawing inductive effect to the carbonyl group in —COOH group weakens the O — H bond and favours ionisation of a carboxylic acid compared with an alcohol (b) Inductive effect of the chlorine destabilizes the acid and stabilises the conjugate base (c) Aniline is a weaker base than ammonia (d) Phenol is a weaker acid than water 16. Which is maximum acidic? (a) (b) (c) (d) (d) 13. Increasing order of pK a values (pKa = –log Ka) of H2O. CH3OH and C6H5OH is: (a) H2O < CH3OH < C6H5OH (b) CH3OH < H2O < C6H5OH (c) C6H5OH < H2O < CH3OH (d) C6H5OH < CH3OH < H2O 15.weebly.noimurrahman. Which has maximum stabilization energy as a result of resonance? .

noimurrahman. The bond between carbon atom (1) and carbon atom (2) in compound Involves the hybridization as (a) sp2 and sp2 (b) (c) sp and sp2 (d) sp and sp [1987] 2. Amongst the following. the most basic compound is (a) Benzylamine . The number of sigma and pi-bonds in 1-butene 3-yne are (a) 5 sigma and 5 pi (b) 7 sigma and 3 pi (c) 8 sigma and 2 pi (d) 6 sigma and 4 pi [1989] (a) (b) (c) (d) 1.weebly.www.

Among the following compounds.www. What is the decreasing order of strength of the bases? (a) (b) (c) (d) [1989] 6. The hybridization of carbon atoms in C—C single bond (a) (b) (c) (d) [1991] 5. the strongest acid is .com (b) Aniline (c) Acetanilide (d) p-nitroaniline [1990] 4.noimurrahman.weebly.

3-hexanedione [2000] 8.www. 4-hexanedione (c) (a) (b) (c) (d) [1998] 7.weebly. Among the following the strongest base is (a) (b) (c) (d) [2000] 9. has the most acidic hydrogen? (a) 3-hexanone (b) 2. 5-hexanedione (d) 2. Which of the following.noimurrahman. Which of the following hydrocarbons has the lowest dipole moment? (a) cis-2-butene (b) 2-butyne .

com (c) 1-butyne (d) [2002] 10. Identify the correct order of boiling points of the following compounds (a) 1>2>3 (b) 3>1>2 (c) 3>1>2 (d) 3>2>1 [2002] 11.www.noimurrahman. Which of the following acids has the smallest dissociation constant? (a) (b) (c) (d) [2002] 12. For 1-methoxy-1 3-butadiene.weebly. which of the following resonating structure is least stable? .

] (a) (b) (c) (d) [2005] 13. H/CH3 that is most likely to migrate to the positively charged carbon is . When benzene sulphonic acid and p-nitrophenol are treated with NaHCO3. In the following carbocation.www.weebly. Hyperconjugation involves overlap of the overlap of the following orbitals (a) – (b) –p (c) p–p (d) – [2008. the gases released respectively are (a) (b) (c) (d) [2006] 14.

Among the following compounds. acid (d) p-toluic acid [2011] 18. Which of the following represent the hydridisation sp2— sp2—sp—sp from left to righ? given monde of (a) (b) H at C-4 (c) CH3 at C-2 (d) H at C-2 [2009] 16. the most acidic is (a) p-nitrophenol (b) p-hydroxybenzoic acid (c) o-hydroxybenzoic.www.noimurrahman. The correct stability order of the following resonance structure is (a) (I) > (II) > (IV) > (III) (b) (I) > (III) > (II) > (IV) (c) (II) > (I) > (III) > (IV) (d) (III) > (I) > (IV) > (II) [2009] 17.

the molecule with the highest dipole moment is (a) CH3Cl (b) CH2Cl2 (c) CH2Cl2 (d) CCl4 [2003] 20. Among the following. Arrange in order of increasing acidic strength (a) X>Z>Y (b) Z<X>Y (c) X>Y>Z (d) Z>X>Y .com (a) (b) (c) (d) [2003] 19.weebly.www.noimurrahman.