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Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


1.

Which of the following has incorrect direction of I effect - 1.

I U -

CH!

CH!

(1)

(1)

CH!

CH!
O
C

O
OH

(2)

(2)

CH!

CH!
O
C

O
O

(3)

3.

4.

(3)

CH!

2.

OH

CH!

(4) CH3 C CH2CH3


O
How many equally stable resonating structure are possible 2.

(4) CH3 C CH2CH3


O
'tropylium'

for 'tropylium' -

U-

S U

(1) 2

(2) 4

(1) 2

(2) 4

(3) 5

(4) 7

(3) 5

(4) 7

The IUPAC name of the following compound is -

3.

IUPAC U -

(1) 3-Ethyl-4-Methyl hex-5-en-2-ol

(1) 3--4- U-5-U-2-

(2) 4-Ethyl-3-Methyl hex-1-en-5-ol

(2) 4--3- U-1-U-5-

(3) 3-Methyl-4-ethyl hex-1-en-5-ol

(3) 3--4- U-1-U-5-

(4) 4-Methyl-3-ethyl hex-5-en-2-ol

(4) 4--3- U-5-U-2-

The correct basic strength order of following anions is -

4.

U U U -

(1) CH3CH2 > NH2 > CH2=C H > CH C > HO > F

(1) CH3CH2 > NH2 > CH2=C H > CH C > HO > F

(2) NH2 > CH3 C H2 > CH2=C 0 > CH C > F > HO

(2) NH2 > CH3 C H2 > CH2=C 0 > CH C > F > HO

(3) CH3C H2 > CH2=C 0 > NH2 > CH C > HO > F

(3) CH3C 0 2 > CH2=C 0 > NH2 > CH C > HO > F

(4) F > HO > HC C > CH2=C 0 > NH2 > CH3C 02

(4) F > HO > HC C > CH2=C 0 > NH2 > CH3C 02

/+1

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Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


EE

5.

6.

EE

OH

EEE

HO
H

E

5.

HO
H

E

Find the order of reactivity labelled hydrogen with NaNH2

UUU NaNH2 U -

(1) I > II > III

(2) III > II > I

(1) I > II > III

(2) III > II > I

(3) III > I > II

(4) II > III > I

(3) III > I > II

(4) II > III > I

Which are not the tautomeric pairs -

6.

(1) Me2C=N OH and Me2CH NO


(2) CH2=CHNHCH3 and CH3CH=NCH3
C O

C=O and
H

(3)

7.

OH

EEE

U U (1) Me2C=N OH Me2CH NO


(2) CH2=CHNHCH3 CH3CH=NCH3
C=O
H

(3)

(4) CH3CH= C CH3 and CH3CH2 C CH3


O
OH
Select the decreasing order of relative basic strength of 7.

C O
H

(4) CH3CH= C CH3 CH3CH2 C CH3


O
OH

U U U U -

following species:
NH

NH

NH

8.

NH

NH

NH

NH

NH

NO

Cl

11

111

18

NH

NH

NH

NH

18

(3) III > IV > I > II

(4) II > I > IV > III

(4) II > I > IV > III

N
H

Cl

Cl

(3)

(4)

(4)

/+1

H
H

(2)

(3)

N
H H

NH

S U -

(1)

H
H

Cl

(3) III > IV > I > II

(2)

NH

111

(2) III > I > IV > II

N
H

NH

NO

(2) III > I > IV > II

(1)

11

(1) II > IV > I > III

8.

NH

NH

(1) II > IV > I > III

Which of the following ion will be most stable -

NH

N
H H

DTS (Daily Test Series) for Re-AIPMT- 2015

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure

SO!H NaHCO
!

9.

NO

SO!H NaHCO
!

9.

OH

NO
NaHCO!

OH
NaHCO!

NO

NO

B U -

A and B are gases -

(1) SO2, CO2

(1) SO2, CO2

(2) SO2, CO

(2) SO2, CO

(3) SO2, NO2

(3) SO2, NO2

(4) CO2, CO2

(4) CO2, CO2

10. Hyper conjugation involves overlap of the following orbitals- 10.

U U -

(1) -

(2) -p

(1) -

(2) -p

(3) p-p

(4) -

(3) p-p

(4) -

11.

11. Tautomerism does not exhibited by -

mUU U U -

CH=CH OH

CH=CH OH
(1)

(1)

(2)

(2)

(3)

(3)

O
O

(4)

12. Which one is most unstable compound -

12.

S U -

(1)

(1)

(2)

(2)

(3)

(3)

(4) All of the above

(4) UUQ

/+1

(4)

DTS (Daily Test Series) for Re-AIPMT- 2015

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


13. True for -

O
O

13.

OH

O
O
11

U O

O
111

OH

O
O
11

O
111

(A) I II S

(A) I and II are position isomers


(B) I and II are metamers
(C) I and III are functional isomers
(D) II and III are functional isomers
(1) (A) and (B)

(2) Only (C)

(3) (B) and (C)

(4) (B), (C) and (D)

14. Total number of position isomer of C6H3XYZ -

14.

U
(B) I II U
(C) I III U
(D) II III U
(1) (A) (B)
(2) (C)
(3) (B) (C)
(4) (B), (C) (D)
C6H3XYZ S U -

(1) 9

(1) 9

(2) 10

(2) 10

(3) 8

(3) 8

(4) 7

(4) 7

15. Which compound are shows geometrical isomerism -

15.

U -

(1)

(2)

(1)

(2)

(3)

(4) All of the above

(3)

(4) UUQ

16. The number of geometrical isomers in the following 16.

U -

compound CH3CH=CHCH=CHC2H5 is -

CH3CH=CHCH=CHC2H5

(1) 4

(2) 3

(1) 4

(2) 3

(3) 2

(4) 5

(3) 2

(4) 5

17. In the given conformer if C2 is rotated about C2C3 bond 17.


anticlockwise by an angle of 120, then the conformation

M C2 C2C3
120 U, M U -

obtained is "

"

(1) Staggered conformation

(2) U M

(3) Fully eclipsed conformation

(3)

/+1

H
H

(1) U

(2) Gauche conformation


(4) Partially eclipsed conformation

M
(4) M
DTS (Daily Test Series) for Re-AIPMT- 2015

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


18. The absolute configuration of the following -

18.

U -

CH!
Cl
H
CH!

H
Cl
(1) 2S, 3R

(1) 2S, 3R

(2) 2S, 3S

(2) 2S, 3S

(3) 2R, 3S

(3) 2R, 3S

(4) 2R, 3R

(4) 2R, 3R

19. The correct statement about the compound I, II & III is -

H
H

COOH
OH
OH
COOH
1

H
H

COOH
OH
OH
CHO
11

CH!
Cl
H
CH!

H
Cl

H
HO

19. I, II III U -

COOH
OH
H
CHO
111

H
H

COOH
OH
OH
COOH
1

H
H

COOH
OH
OH
CHO
11

(1) I and II are identical

(1) I II U

(2) II and III are diastereomers

(2) II III U U

(3) II and III are enantiomers

(3) II III U

(4) I and III are enantiomers

(4) I III U
20.

20. Which statement is wrong (1) Without prifix IUPAC name is possible
(2) Without root word IUPAC name is not possible
(3) Without suffix IUPAC name is not possible
(4) Without primary suffix IUPAC name is possible
21. Write the IUPAC name of Neo pentylchloride -

21.

COOH
OH
H
CHO
111

U (1) IUPAC U
(2) IUPAC U U
(3) IUPAC U U
(4) IUPAC U
Neo pentylchloride IUPAC U -

(1) 2, 3-dimethylpentane

(1) 2, 3-dimethylpentane

(2) 2,3-dimethyl-1-chloro-propane

(2) 2,3-dimethyl-1-chloro-propane

(3) 1-chloro-2,2-dimethyl propane

(3) 1-chloro-2,2-dimethyl propane

(4) 1-chloro-1,1-dimethyl pentane

(4) 1-chloro-1,1-dimethyl pentane

22. How many carbon atom are in same plane of following 22.

H
HO

U U -

compound -

(1) 10

(1) 10

(2) 12

(2) 12

(3) 11

(3) 11

(4) 6

(4) 6

/+1

DTS (Daily Test Series) for Re-AIPMT- 2015

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


23. The IUPAC name of COOH

23. COOH

COOH

COOH

IUPAC U -

(1) Oxalic acid

(1) Oxalic acid

(2) Ethan carboxylic acid

(2) Ethan carboxylic acid

(3) Ethanedioic acid

(3) Ethanedioic acid

(4) Carboxy methanoic acid

(4) Carboxy methanoic acid


24. iso octane IUPAC

24. IUPAC name of iso octane is -

U -

(1) 2,2,4-trimethyl octane

(1) 2,2,4-trimethyl octane

(2) 2,2-dimethyl octane

(2) 2,2-dimethyl octane

(3) 2,2,4-trimethyl pentane

(3) 2,2,4-trimethyl pentane

(4) 2,2,4,4-tetramethyl butane

(4) 2,2,4,4-tetramethyl butane


25.

25. Which of the following statement is correct (1) Metamerism belongs to the category of structural

U (1) U U U

isomerism.
(2) Tautomeric structures are the resonating structures of

(2)

U U U U

a molecule.
(3) Keto form is always more stable than enol form.
(4) Geometrical isomerism is shown only by alkenes.
26. Observe the following diagram for relative boiling points 26.
of different alkanes. Identify the hydrocarbons X, Y, Z,

(3) U

M U M S U U
(4) mUU U
-
X, Y, Z, W, R UUU U -

W, R.
Z

W
X

Y
B .P.

B .P.

A lkan es

A lkan es

(X )

(Y )

(Z )

(W )

(X )

(R )

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

/+1

(Y )

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(Z )

(W )

(R )

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure

How many monochlorination products are possible from P.

P(C9H18) UUU U
U U UUU U U U, P
U U U -

(1) 1

(1) 1

(2) 2

(2) 2

(3) 3

(3) 3

(4) 4

(4) 4

27. An organic compound P(C9H18) has only primary hydrogen 27.


atoms. All hydrgoen atoms are chemically alike (similar).

28. How many dichloro derivatives are possible for the following 28.

UUU U -

compound -

(1) 2

(2) 4

(1) 2

(2) 4

(3) 5

(4) 7

(3) 5

(4) 7

29. In which of the following organic compound all effects (i.e. 29.
mesomeric effect, hyperconjugation effect and inductive

( U
, U ) US U -

effect) are present (1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

30. Identify the correct order of stability of carbocation -

30.

S U U -

(i)

(ii)

(i)

(ii)

(iii)

(iv)

(iii)

(iv)

(1) i > ii > iii > iv

(2) ii > i > iv > iii

(1) i > ii > iii > iv

(2) ii > i > iv > iii

(3) i > iii > ii > iv

(4) i > ii > iv > iii

(3) i > iii > ii > iv

(4) i > ii > iv > iii

/+1

DTS (Daily Test Series) for Re-AIPMT- 2015

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


resonance is present -

U (SIR)
US U -

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

31. Identify the compound in which steric inhibition effect in 31.

32. How many secondary amine are possible with molecular 32.

C4H11N mU U -

formula C4H11N (1) 4

(1) 4

(2) 3

(2) 3

(3) 2

(3) 2

(4) 1

(4) 1

33. Which of the following compound is most acidic -

33.

U -

(1)

(2)

(1)

(2)

(3)

(4)

(3)

(4)

34. Calculate double bond equivalent in following compound - 34.

mU -

(1) 10

(1) 10

(2) 11

(2) 11

(3) 12

(3) 12

(4) 13

(4) 13

/+1

DTS (Daily Test Series) for Re-AIPMT- 2015

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


35. Consider the following anions -

35.

When attached to sp3-hybridized carbon, their leaving group


ability in nucleophilic substitution reaction decreases in the

sp3 U U U, SU S
UU U U U -

order (1) I > II > III > IV

(1) I > II > III > IV

(2) I > II > IV > III

(2) I > II > IV > III

(3) IV > I > II > III

(3) IV > I > II > III

(4) IV > III > II > I

(4) IV > III > II > I

36. The angular momentum of an electron present in the excited 36. H


state of H is

1.5h
. The electron is present in

ijek.kq ds fdlh mksftr voLFkk eas bysDVkWu dk dksf.k; laosx

1.5h
gS]

rks bysDVkWu mifLFkr gksxk -

(1) 3rd orbit

(1) 3rd orbit

(2) 2nd orbit

(2) 2nd orbit

(3) 4th orbit

(3) 4th orbit

(4) 5th orbit

(4) 5th orbit

37. Which of the following is correct for second line of Balmer 37.

fuEu eas ls ckej Js.kh dh f}rh;d js[kk ds fy, lgh dFku gksxk -

series (1) 4 2

(1) 4 2

(2) 2 4

(2) 2 4

(3) 3 1

(3) 3 1

(4) 5 2

(4) 5 2

38. Which of the following is not a legal set of quantum numbers 38.

fuEu esa ls dkSu lk Dok.Ve la[;kvksa dk leqPp; lgh ugha gS ?

for an electron in an atom?


(1) n = 5, l = 3, ml = 2, ms = 1/2

(1) n = 5, l = 3, ml = 2, ms = 1/2

(2) n = 3, l = 2, ml = 3, ms = 1/2

(2) n = 3, l = 2, ml = 3, ms = 1/2

(3) n = 2, l = 1, ml = 0, ms = 1/2

(3) n = 2, l = 1, ml = 0, ms = 1/2

(4) n = 6, l = 3, ml = 3, ms = 1/2

(4) n = 6, l = 3, ml = 3, ms = 1/2

o 2p eas f=T; uksM dh la[;k e'k% gksxh (1) 2 rFkk 0


(2) 0 rFkk 2
(3) 1 rFkk 2
(4) 2 rFkk 1

39. The number of radial nodes in 3s and 2p respectively are - 39. 3s


(1) 2 and 0
(2) 0 and 2
(3) 1 and 2
(4) 2 and 1

/+1

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Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


40. What possible can be the ratio of the de-Broglie wavelengths 40.

nks bysDVkWu ftudh izkjafHkd tkZ 'kwU; gS dks ;fn e'k%

for two electrons having zero initial energy and accelerated

200 volts

through 50 volts and 200 volts -

vuqikr gksxk -

(1) 3 : 10

(1) 3 : 10

(2) 10 : 3

(2) 10 : 3

(3) 1 : 2

(3) 1 : 2

(4) 2 : 1

(4) 2 : 1

41. The difference in angular momentum associated with the 41.

50 rFkk

ls Rofjr fd;k tk, rks mudh Mh&czksfXy rjaxnS/;Z dk

nks ekxr d{kdksa ds fy, dks.kh; laosx dk varj gksxk &

electron in two successive orbits of hydrogen atom is (1) h /

(1) h /

(2) h/2

(2) h/2

(3) h / 2

(3) h / 2

(4) (n1)h / 2

(4) (n1)h / 2

42. The circumference of first Bohr's orbit of hydrogen atom is 42.


how many times the circumference of second Bohr's orbit

gkbMkstu ijek.kq dh izFke d{kk dh ifjf/k


dh ifjf/k dh fdrus xquk gS

He+

dh f}rh; d{kk

of He+ (1) Two times

(1)

(2) Half

(2) vk/kh

(3) Equal

(3) leku

(4) None

(4)

43. The ratio of the difference in energy between the first and 43.
second Bohr orbit to that between second and third Bohr

nks xquk

dksbZ ugha

gkbMkstu ijek.kq eas izFke vkSj f}rh; cksgj d{k dh rFkk f}rh; vkSj
r`rh; cksgj d{k dh tkZ ds varj dk vuqikr gS -

orbit in H-atom is (1) 4/9

(1) 4/9

(2) 1/3

(2) 1/3

(3) 27/5

(3) 27/5

(4) 1/2

(4) 1/2

44. How many photons of light having a wave length of 4000 44. 1J tkZ

iznku djus ds fy, 4000 rjaxnS/;Z ds izdk'k ds fdrus

are necessary to provide 1 J of energy ?

QksVksuks dh vko';drk gksxh ?

(1) 4.97 1019

(1) 4.97 1019

(2) 2 1016

(2) 2 1016

(3) 2 1028

(3) 2 1028

(4) 2 1018

(4) 2 1018

/+1

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10

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


45. Consider three electron jumps described below for the 45.

gkbMkstu ijek.kq ds fy, bysDVkWu ds rhu lae.k nh xbZ gS

hydrogen atom x : n = 3 to n = 1

x : n = 3 to n = 1

y : n = 4 to n = 2

y : n = 4 to n = 2

z : n = 5 to n = 3

z : n = 5 to n = 3

for which transition will the electron experience the longest

fdl lae.k ds fy, bysDVkWu dh d{k f=T;k esa vf/kdre ifjorZu

change in orbit radius ?

gksxk ?

(1) x

(1) x

(2) y

(2) y

(3) z

(3) z

(4) All have same change

(4) lHkh

46. Which of the following statements is incorrect regarding 46. Cl2O

esa leku ifjorZu

v.kq ds lanHkZ esa fuEu esa ls dkSulk dFku xyr gS&

Cl2O molecule (1) The molecule is planar

(1) v.kq

leryh; gS

(2) The shape of the molecule is bent

(2) v.kq

dh vkd`fr fod`r (bent) gS

(3) The hybridization of the central atom is sp3

(3)

(4) The molecules is non-planar

(4)

47. Which of the following pairs is iso-structural -

47.

U U sp3 U

U U

2
(1) BO3
3 and SO3

(1) BO3
3

SO2
3

(2) NO2+ and CO2

(2) NO2+

(3) HCN and SnCl2

(3) HCN SnCl2

(4) SnCl3 and SO3

(4) SnCl3 SO3

CO2

48. Which of the following statements is correct for the two 48. C6H6 B3N3H6 U Umolecules, C6H6 and B3N3H6 ?
(1) CH bond length is identical with NH and BH bond

(1) CH

U NH BH U U

lengths
(2) The nature of double bond is perfectly identical in both

(2) mU

(3) Both the molecules are planar

(3)

(4) C6H6 is non-polar while B3N3H6 is polar

(4) C6H6 U, B3N3H6 U

/+1

DTS (Daily Test Series) for Re-AIPMT- 2015

11

Class XIII (Spartan Batch)

C-2 : IUPAC, Isomerism, GOC, Chemical Bonding, Atomic Structure


49. Which of the following species has the same number of 49.
XOX linkages, where X = S or P ?
(I) S4O

2
6

(II) S3O9

(III) S2O

XOX U U X = S
P?

2
5

(IV) P3O

3
9

(I) S4O62

(1) II and IV

(1) II IV

(2) II and III

(2) II III

(3) I and III

(3) I III

(4) I and IV

(4) I IV

50. In which of the following processes, the value of magnetic 50.

(II) S3O9

(III) S2O52

(IV) P3O93

U U U U-

moment does not change (1) N2 N2

(1) N2 N2

(2) N2 N2+

(2) N2 N2+

(3) O2 O2+

(3) O2 O2+

(4) O2+ O2

(4) O2+ O2

/+1

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12