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Safety Data Sheet

according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012

Page 1 of 9

Product code: 91070119

SECTION 1: Identification of the substance/mixture and of the company/undertaking


Product identifier

Furadur Liquid
Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture

Coatings and paints, fillers, putties, thinners


Uses advised against

The product is intended for professional use.


Details of the supplier of the safety data sheet

STEULER-KCH GmbH
Siershahn
Berggarten 1

Company name:
Street:
Place:
Post-office box:
Telephone:
e-mail:

D-56427 Siershahn
1163
D-56425 Siershahn
+49 2623 600 0
info@steuler-kch.de

Contact person:
e-mail:

Labor COS/RUL
msds@steuler-kch.de

Internet:
Responsible Department:

www.steuler-kch.de

Emergency telephone:

Telefax: +49 2623 600 513

+49 2624 13 507


+49 2623 600 535
(001) 352 32 33500

SECTION 2: Hazards identification


Classification of the substance or mixture

Indications of danger : Toxic, Harmful, Irritant


R-phrases:
Harmful in contact with skin and if swallowed.
Toxic by inhalation.
Irritating to eyes and respiratory system.
Limited evidence of a carcinogenic effect.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Label elements

Danger symbols:

T - Toxic

T - Toxic
Hazardous components which must be listed on the label
furfuryl alcohol
R phrases
21/22
23
36/37
Revision No: 1,00

Harmful in contact with skin and if swallowed.


Toxic by inhalation.
Irritating to eyes and respiratory system.
GB - EN

Revision date: 16.04.2012

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012

Product code: 91070119

40
48/20

Limited evidence of a carcinogenic effect.


Harmful: danger of serious damage to health by prolonged exposure through inhalation.

S phrases
23
26
45

60
36/37/39

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Do not breathe Do not breathe vapour. .


In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
This material and its container must be disposed of as hazardous waste.
Wear suitable protective clothing, gloves and eye/face protection.

Other hazards

No data available

SECTION 3: Composition/information on ingredients


Mixtures
Hazardous components
EC No
CAS No
Index No
REACH No

Quantity

Chemical name
Classification
GHS classification

40 - 50 %

202-626-1

furfuryl alcohol

98-00-0

Carc. Cat. 3, T, Xn, Xi R40-23-21/22-48/20-36/37

603-018-00-2

Carc. 2, Acute Tox. 3, Acute Tox. 4, Acute Tox. 4, STOT RE 2, Eye Irrit. 2, STOT SE
3; H351 H331 H312 H302 H373 ** H319 H335

Full text of R- and H-phrases: see section 16.

SECTION 4: First aid measures


Description of first aid measures
General information
First aid assistant: Pay attention to self-protection! Move victim out of danger zone.
In case of accident or if you feel unwell, seek medical advice immediately (show safety data sheet if
possible). Take off immediately all contaminated clothing.
After inhalation
Provide fresh air. In case of breathing difficulties administer oxygen. No mouth-to-mouth or
mouth-to-nose resuscitation.Use respiratory bag or oxygen resuscitation apparatus. Immediately get
medical attention.
After contact with skin
Wash with generous amount of water. Change contaminated clothing. Medical treatment necessary.
After contact with eyes
If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for
at least 5 minutes. Subsequently consult an ophthalmologist.
After ingestion
Rinse mouth immediately and drink large quantities of water. Make affected person vomit if
conscious. Medical treatment necessary.
Most important symptoms and effects, both acute and delayed
Following symptoms can occur: difficulties of breathing. Coughing. Headache.
Indication of any immediate medical attention and special treatment needed
Symptoms of poisoning may develop several hours following exposure. Victim should be under
medical observation for at least 48 hours after exposure. Treat symptomatically.
Revision No: 1,00

GB - EN

Revision date: 16.04.2012

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012

Page 3 of 9

Product code: 91070119

SECTION 5: Firefighting measures


Extinguishing media
Suitable extinguishing media
Carbon dioxide (CO2). Extinguishing powder. Foam. Water fog.
Extinguishing materials should be selected according to the surrounding area.
Extinguishing media which must not be used for safety reasons
High power water jet.
Special hazards arising from the substance or mixture
Combustible. Vapours may form explosive mixtures with air.
Advice for firefighters
Wear a self-contained breathing apparatus and chemical resistant suit.
Additional information
Use water spray/stream to protect personnel and to cool endangered containers. Use a water spray jet
to knock down vapours/gases/mists. Collect contaminated fire extinguishing water separately. Do not
allow entering drains or surface water.

SECTION 6: Accidental release measures


Personal precautions, protective equipment and emergency procedures
Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eye
and clothing. Wear personal protection equipment.
Environmental precautions
Do not empty into drains or the aquatic environment.
Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the assimilated material according to the section on waste disposal.
Reference to other sections
See protective measures under point 7 and 8.

SECTION 7: Handling and storage


Precautions for safe handling
Advice on safe handling
Keep container tightly closed in a cool, well-ventilated place. Provide adequate ventilation. Wear
personal protection equipment. Do no eat, drink or smoke when using this product.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking.
Further information on handling
Avoid contact with skin and eyes. Do not eat, drink, smoke or sneeze at the workplace.
Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Floors should be impenetrable, resistant to liquids and easy to clean. Keep container tightly closed.
Keep locked up. Store in a place accessible only to authorized persons. Provide for sufficient
ventilation and punctiform suction at critical points.
Advice on storage compatibility
Do not store together with: Oxidizing agents. Strong acid
Further information on storage conditions
Storage class:
Specific end use(s)
Revision No: 1,00

GB - EN

Revision date: 16.04.2012

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012

Page 4 of 9

Product code: 91070119

Restricted to professional users. Observe technical data sheet.

SECTION 8: Exposure controls/personal protection


Control parameters
Exposure limits (EH40)
CAS No

Chemical name

ml/m

mg/m

98-00-0 Furfuryl alcohol

F/ml

Category

Origin

TWA (8 h)

CHAN

STEL (15 min)

CHAN

Exposure controls
Occupational exposure controls
In case of open handling equipment with built-in suction must be used. Do not breathe
gas/fumes/vapour/spray.
Protective and hygiene measures
Take off immediately all contaminated clothing. Protect skin by using skin protective cream. After
work, wash hands and face. When using do not eat or drink.
Respiratory protection

Respiratory protection required in case of: insufficient ventilation. insufficient absorbtion.


Suitable respiratory protective equipment: Filter respirator (DIN EN 147). A 2
Only use breathing apparatus with CE-label including the four-digit identification number.
Hand protection
Tested protective gloves are to be worn: Butyl rubber. FKM (fluororubber).
Before using check leak tightness / impermeability. Breakthrough times and swelling characteristics of
the material must be taken into consideration. When handling chemical substances, chemical
protective gloves must be worn with CE label including a four digit code.
Eye protection
Suitable eye protection: Tightly sealed safety glasses.
Skin protection
Suitable protection of the body: Single-use suit.
Environmental exposure controls
refer to chapter 7. No further action is necessary.

SECTION 9: Physical and chemical properties


Information on basic physical and chemical properties

Physical state:
Colour:
Odour:

liquid
dark brown
characteristic
Test method

4,5

pH-Value (at 20 C):


Changes in the physical state

No data available

Melting point:

171 C DIN 53171

Boiling point:
Sublimation point:

not determined

Softening point:

not determined
75 C DIN EN ISO 2719

Flash point:

Revision No: 1,00

GB - EN

Revision date: 16.04.2012

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012

Page 5 of 9

Product code: 91070119

Explosive properties
In use may form flammable/explosive vapour-air mixture.

Lower explosion limits:


Upper explosion limits:

1,8 vol. %
16,3 vol. %
390 C DIN 51794

Ignition temperature:
Oxidizing properties
Not oxidizing.

Vapour pressure:
0,53 hPa
(at 20 C)
Vapour pressure:
4,5 hPa
(at 50 C)
Density (at 20 C):
1,15 g/cm
not applicable
Bulk density:
Water solubility:
400 g/L
(at 20 C)
Solubility in other solvents
mixable with most organic solvent cleaners
Partition coefficient:
There are no data available on the mixture
itself.
Viscosity / dynamic:
(at 20 C)

900 - 1300 mPas DIN 53018


48,08 %

Solvent content:
Other information

ca. 45 %

Solid content:
none/none

SECTION 10: Stability and reactivity


Reactivity

Exothermic reactions with: Oxidizing agents, strong. Alkalis (alkalis). Strong acid Acid halides.
Chemical stability
No ignition, explosion, self-heating or visible decomposition.
Possibility of hazardous reactions
Exothermic polymerization
Conditions to avoid
Keep away from heat.
Incompatible materials
Oxidizing agents, strong. Strong acid, strong alkalis. Peroxides.
Hazardous decomposition products
Can be released in case of fire: Carbon monoxide. Carbon dioxide (CO2). Pyrolysis products, toxic.

SECTION 11: Toxicological information


Information on toxicological effects
Acute toxicity
Toxic. Acute toxicity, oral. Acute toxicity, inhalant. Acute toxicity, dermal.

Revision No: 1,00

GB - EN

Revision date: 16.04.2012

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012
CAS No

Chemical name
Exposure routes

98-00-0

Page 6 of 9

Product code: 91070119

Method

Dose

Species

Source

RTECS

furfuryl alcohol
oral

LD50
mg/kg

177 - 275

Rat.

dermal

LD50
mg/kg

400 - 657

Rabbit.

Irritation and corrosivity


Irritating to eyes. Following inhalation: Lung irritation. Coughing. shortage of breath.
Sensitising effects
May cause sensitization by skin contact.
Severe effects after repeated or prolonged exposure
Danger of serious damage to health by prolonged exposure.
Carcinogenic/mutagenic/toxic effects for reproduction
May cause cancer.
Additional information on tests
The classification was undertaken in accordance with the calculation method governed by the
Preparations Directive (1999/45/EC).

SECTION 12: Ecological information


Toxicity
CAS No

Chemical name
Aquatic toxicity

98-00-0

Dose

Method

h Species

Source

furfuryl alcohol
Acute fish toxicity

LC50

32 mg/l

96 Pimephales promelas

Persistence and degradability


Some of the components are biodegradable.
Bioaccumulative potential
On the basis of existing data about disposal/decomposition and bio-accumulation potential, long term
environmental damage is unlikely.
Partition coefficient n-octanol/water
CAS No
98-00-0

Chemical name

Log Pow

furfuryl alcohol

0,28

Mobility in soil

No data available
Results of PBT and vPvB assessment
This substance does not meet the criteria for classification as PBT or vPvB.
Other adverse effects
There are no data available on the preparation/mixture itself.
Further information
The classification was undertaken in accordance with the calculation method governed by the
Preparations Directive (1999/45/EC).

SECTION 13: Disposal considerations

Revision No: 1,00

GB - EN

Revision date: 16.04.2012

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012

Page 7 of 9

Product code: 91070119

Waste treatment methods


Advice on disposal
Waste disposal according to official state regulations. Evidence for disposal must be provided.
Waste disposal number of waste from residues/unused products
070208
WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic
rubber and man-made fibres; other still bottoms and reaction residues
Classified as hazardous waste.
Waste disposal number of contaminated packaging
150110
WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal
packaging waste); packaging containing residues of or contaminated by dangerous substances
Classified as hazardous waste.
Contaminated packaging
Handle contaminated packaging in the same way as the substance itself.

SECTION 14: Transport information


Land transport (ADR/RID)
UN number:

UN2810

UN proper shipping name:

TOXIC LIQUID, ORGANIC, N.O.S. (Furfuryl alcohol)

Transport hazard class(es):

6.1

Packing group:

III

Hazard label:
Classification code:
Special Provisions:
Limited quantity:
Transport category:
Hazard No:
Tunnel restriction code:

6.1
T1
274 614
5L
2
60
E

Other applicable information (land transport)


E1
Inland waterways transport
UN number:

UN2810

UN proper shipping name:

TOXIC LIQUID, ORGANIC, N.O.S. (Furfuryl alcohol)

Transport hazard class(es):


Packing group:

6.1
III

Hazard label:
Classification code:
Special Provisions:
Limited quantity:

6.1
T1
274 614 802
5L

Other applicable information (inland waterways transport)


E1
Marine transport
UN number:

UN2810

UN proper shipping name:

TOXIC LIQUID, ORGANIC, N.O.S. (Furfuryl alcohol-Mixture)

Transport hazard class(es):

6.1

Packing group:

III

Revision No: 1,00

GB - EN

Revision date: 16.04.2012

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012
Hazard label:
Special Provisions:
Limited quantity:
EmS:

Page 8 of 9

Product code: 91070119


6.1
223, 274
5L
F-A, S-A

Other applicable information (marine transport)


E1
Air transport
UN/ID number:

UN2810

UN proper shipping name:

TOXIC LIQUID, ORGANIC, N.O.S. (Furfuryl alcohol-Mixture)

Transport hazard class(es):

6.1

Packing group:

III

Hazard label:
Special Provisions:
Limited quantity Passenger:

6.1
A3 A4 A137
2L
655
60 L
663
220 L

IATA-packing instructions - Passenger:


IATA-max. quantity - Passenger:
IATA-packing instructions - Cargo:
IATA-max. quantity - Cargo:
Other applicable information (air transport)
E1
Passenger-LQ: Y642
Environmental hazards

Dangerous for the environment:

no

Special precautions for user


Keep away from food, drink and animal feedingstuffs. Store in a place accessible only to authorized
persons.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not classified for this carrier.

SECTION 15: Regulatory information


Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information

1999/13/EC (VOC):

48,081 % (552,93 g/l)

National regulatory information

Employment restrictions:
Water contaminating class (D):
Skin resorption/Sensitization:

Observe employment restrictions for young people.


1 - slightly water contaminating
Causes allergic hypersensitivity reactions.

Additional information
621
Chemical Safety Assessment

For this substance a chemical safety assessment has not been carried out.

SECTION 16: Other information


Abbreviations and acronyms
ADR: Accord europen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Rglement international concernant le transport des marchandises dangereuses par chemin de
Revision No: 1,00

GB - EN

Revision date: 16.04.2012

Safety Data Sheet


according to Regulation (EC) No 1907/2006

Furadur Liquid
Print date: 08.05.2012

Page 9 of 9

Product code: 91070119

fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
Full text of R-phrases referred to under sections 2 and 3
21/22
Harmful in contact with skin and if swallowed.
23
Toxic by inhalation.
36/37
Irritating to eyes and respiratory system.
40
Limited evidence of a carcinogenic effect.
48/20
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Full text of H-Statements referred to under sections 2 and 3
H302
Harmful if swallowed.
H311
Toxic in contact with skin.
H312
Harmful in contact with skin.
H319
Causes serious eye irritation.
H331
Toxic if inhaled.
H335
May cause respiratory irritation.
H351
Suspected of causing cancer.
H373
May cause damage to organs through prolonged or repeated exposure.
Further Information
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The
information cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily valid
for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)

Revision No: 1,00

GB - EN

Revision date: 16.04.2012