Professional Documents
Culture Documents
.P889233498
1111111
11
1111111111
1111
11111111
United States
Environmental Protection
Agency
Research
Triangle
EPA;~j~0~82;013b-
,i
April1989
Park NC 27711
Air
Final
EIS
Fluid Catalytic
Cracking Unit
Regenerators
Background
Information
for
From u Igated
Standards
'
I
st
II
REPRODUCED
BY
U.S. DEPARTMENT
NATIONAL
TECHNICAL
SPRINGFIELD,
OF:.COMMERCE
INFORMATION
VA. 22161-
SERVICE
TECHNICAL
REPORT
DATA
~Ple~se reed 1,2srrucn'ons on the ~prcrsr before cornplerinpl
1Ek~i~TOrg-B2-013b n.
TITLE
AND
Sulfur
I~C~"-"~~"S'ag"s ,ns
SUBTITLE
Oxides
15.
Emissions
U'nit Regenerators
Promulgated
from
Fluid
- Background
Catalytic
Information
Cracking
for
16.PERFORMING
ORGANIZATION
CODE
18. PEAFORMING
.PERFORMING
ORGANIZATION
NAME
AND
ADDRESS
lo.
AGENCY
of
Air
and
Research
~6.
ABSTRACT
Park,
NO.
AND PERIOD
COVERED
Final
10. SPONSORINGAGENCYCODE
Protection
Triangle
SUPPLEMENT
REPORT
ECEMENTNO.
and Standards
Radiation
Environmental
II.
Planning
PROGRAM
ORGANIZATION
~1.CONTRACT/GRANT
NO.
DATE
1989
Standards
.AUTnOR(S)
U.S.
REPORT
I April
Agency
North Carolina
27711
EPA/2OO/04
NOTES
Standards
of performance
to control
emissions
of sulfur oxides (SOx) from new,
modified,
and reconstructed
fluid catalytic
cracking unit regenerators
are being
promulgated
under Section 111 of the Clean Air Act.
This document contains
a summary
I(EY
WORDS
nND
DESCRIPTORS
of Performance
processes
Petroleum
refineries
catalytic
Oxides
ANALYSIS
Air Pollution
I Sulfur
Oxides
Standards
Industrial
Fluid
DOCUMENT
b.lDENTIFIERSIOPEN
Air Pollution
Pollution
Control
Sulfur
standard.
Stationary
ENDEDTERMS
Control
13B
Sources
cracking
8. DISTRIBUTION STATEMENT
) i s. SE CUR IT v C~S~T~;iS~cporr7--rZ~7?J~5~?I
Unlimited
I Unclassified
?O. SECURITY
Unclassified
EP*
form
2220-1
(Re.
6-77)
p~rilevs
E51TION
15 OBSOLETE
22. PRICE
I ~Ao~
Sulfur
Oxides
Emissions
from
Standards
U.S. ENVIRONMENTAL
Division
PROTECTION
AGENCY
I-R
DISCLAIMER
This report
has been reviewed
by the Emission
Standards
Division,
Office
of Air Quality
Planning
and Standards,
Office
of Air and
Radiation,
Environmental
Protection
Agency,
and approved
for
publication.
constitute
charge
and
to
Mention
endorsement
Federal
non-profit
Library
Services
Research
Triangle
from the National
Road,
Springfield,
of company
by EPA.
employees,
or~aizations
or product
Copies
are
current
--
as
contractors
supplies
permit
-?
and grantees,
--
from
the
Office,
MD-35, Environmental
Protection
Agency,
Park NC 27711; or may be obtained,
for a fee,
Technical
Information
Services,
5285 Port Royal
Virginia
22161.
ii
ENVIRONMENTAL
PROTECTION
Background
Information
Environmental
Impact
for
Sulfur
Fluid
Oxides
AGENCY
and Final
Statement
Emissions
From
Catalytic
Cracking
Regenerators
repared
Unit
by:
~i~t~
k R.
Director,
U.S.
i.
/(Dat
Emission
Standards
Environmental
Research
Farmer
Triangle
Park,
-The emission
Agency
NC 27711
standards
new, modified,
at
111
will
limit
emissions
and reconstructed
regenerators
S~ction
Division
Protection
of
petroleum
the
Clean
fluid
Act
sulfur
catalytic
refineries.
Air
of
cracking
The standards
and
are
based
oxides
on
from
unit
implement
the
A~ninistra-
tor's
determination
of 3une 11, 1973 (38 FR 15380) that petroleum
refineries
contribute
significantly
to air pollution
which may
reasonably
be anticipated
to endanger public health or welfare.
2.
Copies of this
document
have been sent to the following
Federal
Departments:
Labor,
Health
and Human Services,
Defense,
Transportation,
Agriculture,
Cor~merce, Interior,
and Energy;
the National
Science
Foundation;
the Council
on Environmental
Quality;
members
of the State
and Territorial
AirPollution
Program Administrators;
the
Association
Regional
3.
For
of
Administrators;
additional
Mr. Robert
Standards
Copies
of
5285 Port
Springfield,
Pollution
and
other
Control
interested
contact:
L. qjax
Development
this
Technical
Royal
Branch
(MD-T3)
Protection
Agency
Park,
NC 27711
541-5578
document
Air
information
U.S. Environmental
Research
Triangle
telephone:
(919)
4.
Local
may be obtained
(MD-35)
Park, NC 27711
Information
Road
VA 22161
Service
from:
Officials;
parties.
EPA
TABLE
OF CONTENTS
Section
1.0
P age
SUMMARY
1.1
...................
.....
Summary of Changes
Definition
of Affected
1.1.2
Definition
of
1.1.3
Methods
1.1.4
Definition
1.1.5
Averaging
1.1.6
Clarification
for
1.1.7
Reduction
1.1.8
Minor
Summary of
1.2.1
1.2.3
Feed
of
Test
Method
...................
Energy
and
Action
...................
...
.....
.......
.....
....
.........,
Promulgated
of
Need
2.2
Regulated
2.3
Designation
2.4
Format
2.5
Level
2.5.1
2.5.2
for
t~e
Economic
Action
..,...
of Promulgated
1-6
............
of
1-6
and Irretrievable
Resources
.....
Environmental
and Energy Impacts
of Delayed Standards
.......
Com~ents
............
of
Standards
Standards
Standards
1-7
2-1
..............
2-5
Facility
.........
.~.
2-8
......
................
for
Add-on
Level
of
Standard
Controls
1-7
..............
......
Level
Add-on
1-6
. 2-1
of Affected
the
1-6
Promulgated
Impacts
Irreversible
Commitment
Pollutant
of
1-5
1-6
1-4
1-6
Considerations
Summary of Public
1-3
Calculation
Locations
r.
1-2
1-4
Requirements.
Impacts
Action
1-2
Pollutant
and Sampling
Impacts
1-1
Determinations.
in Reporting
1.2.3.2
......
..
1-1
....,....
of Regulated
Changes
Other
.........
Facility
Compliance
of
1.2.3.1
2.0
Fresh
Environmental
1.2.2
1.3
Proposal
1.1.1
Procedures
1.2
Since
1-1
Control
for
..............
2-11
2-16
Standard
FCCU's
.....
2-16
without
2-17
j Precedingpage blank
TABLEOF CONTENTS
(Continued)
Section
Page
2.5.3
2.6
3.0
4.0
5.0
6.0
7.0
Feed
Sulfur
Cutoff.............
Averagi ny Times
2-19
.................
2-19
3.1
SO, Scrubbers
...................
3.2
SO, Reduction
Catalysts
3.3
Low-Sulfur
Feedstocks
..
...
3-1
3-1
..
............
3-6
...............
3-7
ENVIRONMENTAL
AND ENERGYIMPACTS COMMENTS.......
4-1
4.1
Model Plants
4-1
4.~
Water
Impacts
4.3
Solid
Waste
4.4
Energy
4.5
Air
Used for
Impact
Analyses
. 4-2
Impacts
Impacts
Impacts
................
4-7
..................
4-10
...................
. 4-11
Scrubber
5.2
5.3
Economic
Costs
General
6.2
With
6.3
Without
6.4
Feed
..........
5-1
..,...............
Impact
COMPLIANCE TESTING
61
......
5-1
Costs .........,
Analysis
5-10
.........,....5-11
AND MONITORING
COMMENTS .......
...................
Add-On
Control
Add-On
Sulfur
COMPLIANCE
COMMENTS
7.1
Source
7.2
Compliance
7.3
Changing
..
Devices
Control
Cutoff
.........,
Devices
..........
6-15
6-29
..................
7-1
6-1
6-2
................
Compliance
6-1
Scrubbing
Method
............
.......
........
7-1
7-2
7-2
::
TABLE
OFCONTENTS
(Concludeh)
Section
Page
8.0
MODIFICATION/RECONSTRUCTION
COMMENTS ..........
8-1
9.0
RECORDKEEPJNG
AND REPORTING
COMMENTS
9-1
10.0
MISCELLANEOUS
COMMENTS
APPENDIX A - Control
..........
.................
Equipment
Costs
10-1
and Fifth
vii
Year
Impacts
LIST
OF TABLES
Table
1-1
A-i
A-2
Page
LIST OF COMMENTERSON PROPOSED STANDARDS
OF PERFORMANCEFOR SULFUR OXIDES EMISSIONS
FROMFCCU REGENERATORS
,,,,,,,........
1-8
A-i
,,,.,,,,,,
A-2
VENTURISCRUBBING
FOR 2,500 m3/sd MODELUNITS ...
A-4
A-3
VENTURISCRUBBING
FOR 8,000 m3/sd MODELUNITS ...
A-5
A-4
TREATMENT
FOR MODELUNITS ,-,
A-6
,.,......,
A-5
VENTURI
SCRUBBING
FOR2,500 m3/sd
MODEL UNITS
A-7
,.,,,.,.,..........
A-6
A-7
VENTURJ
SCRUBBING
FOR8,000 m3/sd
MODEL UNITS
A-8
,...,,.,......,...,
:i
....,....
A-8
.,,......
A-9
A-9
ELECTROSTATICPRECIPITATOR COSTS
A-IO
A-ii
A-ii
A-12
V111
,,..,,.,,.
On January
(EPA) proposed
sions
from fluid
refineries
Air
standards
catalytic
Public
revisions
sions
for
to the
included
FCCU's
a daily
tions,
and the
would
proposed
revisions
air
comments
the
1.1
EPA's
revisions
the
over
Public
companies.
CHANGES
The proposed
SINCE
standards
The primary
on
determinadeter-
on the
included
commenters
two
association,
State
an
summary of
serve
as the
proposal
basis
for
and promulgation.
PROPOSAL
were
changes
revised
were
as a result
made
in the
Definition
of Affected
Definition
of
Definition
Averaging
Clarification
Fresh
standard
compliance
This
comments
between
The revi-
Most of the
trade
individual.
standards
in
requested
commenters
to these
standards
of compliance
daily
an industry
and a private
Clean
compliance
were
petroleusi
111 of the
for the
responded.
Other
agencies,
responses
the
comments
at
(50 FR 46464).
daily
which
emis-
On November 8, 1985,
pollutant
making
times
made to the
SUMMARY OF
c omment s .
for
(SO,)
proposed
determination
and 12 commenters
company,
and
oxides
of Section
on the
regulated
the
Agency
(FCCU) regenerators
were proposed
controls,
be made.
control
engineering
unit
requested
in the
methods
refining
pollution
for sulfur
the authority
rule
averaging
minations
represented
proposed
the
Protection
add-on
basis,
Environmental
were
a change
with
U.S.
cracking
comments
SUMIARY
of performance
Act.
1.0
of reviewing
following
public
areas:
Facilitj,
Feed
of Regulated
Pol'lutant
Method
Calculation
Procedures
and Sampling
Lo ca t i o ns
Reductions
in Reporting
and
Compliance
Testing
Requirements
standards
identified
FCCU regenerator.
each regenerator
1-1
as the
affected
in and emitted
to incorporate
from
more
than
one regenerator.
that
identifying
each FCCU
regenerator
as the affected facility
for multiple regenerator configurations is unreasonable.
If only one regenerator in a multiple
regenerator
configuration
would be impossible
to isolate
in some multiple
regenerater.
minimize
the cost
unlikely
that
an
facility
is now defined
of Fresh
The standards
include
of
sulfur
possibility
cutoff
was
that
exists
is
that
by identifying
fractionator
of the
allowed
cutoff
a refiner
the
all
that
by including
specifically
from
the
could
it
is
config-
others.
Therefore,,
regenerators
serving
which limits
feed
circumvent
hydrocarbon
unit
because
Therefore,
these
to
the
the
an FCCU.
streams
recycled
units
definition
of
fresh
not
circumvent
the
would
as "fresh
feed
feed
The revised
derivatives
unit
from
are not a
the
The
feed sulfur
a refiner
identifies
"fresh
cutoff,
fresh
feed"
facility.
ens-ure
fractionator,
1.1.3
to include
in the
or gas recovery
to
definition
them
regenerator
without
a feed sulfur
unit,
Feed
as "fresh
affected
revised
sulfur
work on the
in a multiple
or reconstructed
Definition
amount
part
arrangements
reactor.
1.1.2
the
ducting
it
would be modified
FCCU
standards,
the affected
to the
regenerator
affected
uration
from the
as"recycle",
thus
FCCU,
excluding
feed."
required
to
a continuous
identify
excess
emission
emissions,
monitoring
which
were
system
(CEMS) was
defined,
for
the
standard
test.
The proposed
monitoring
standard
system only
specified
at the
control
the
use of a continuous
device
outlet.
as SO2 in excess
comments that
1-2
this
approach
(The
excess emissions,
oxygen on
would result
in
an
unreasonable
excess
concentrations
test.
changed
These comments,
eliminate
the
performance
daily
the
in part,
of the
for
add-on controls
rather
(90 percent
FCCU's
than using
test.
the
daily)
compliance
basis.
limit.
they
Assurance
for
daily
The
the
are
of the
for
to identify
is less
FCCU's
on a
the
stringent)
need
now
Emission
for
Monitoring
for
FCCU's
to
FCCU's with
consists
of
at
least
18 \/alid
consists
of
at
least
2 valid
the
EPA concluded
determinations
30 successive,
on January
standards
that
(i)
60 Appendix
Systems
without
compliF,
As~surance
Require-
Used for
Compliance
add-on
controls
compliancewith
now
the
add-on
control
devices,
They.require
rolling
hours
data
22.valid
calendar
days.
of
where
data,
minimum
days
A valid
a valid
day
hour
points.
of Regulated Pollutant
standard.
of
As proposed
is required
demonstrate
out
Definition
SO2 monitor
1 - Quality
of every
on a continual
to 40 CFR Part
Procedure
8 testing
standards
facility
S02 monitors
kg coke burn-off
requirements
all
on the
of compliance
continuous
of data
for
to
subject
standard
Method
9.8 kg SO,/1,000
1.1.4
performance
and
to comply specifically
Procedures,
Gas Continuous
De te rm i n a t i o n ."
of data
inlet
approach
controls
emissions
Only an outlet
determinations,
data
this
determination
status
Because
data
the
definition
add-on
or 50 vppm, whichever
50 vppm emissi`on
For
with
The standard
seeks
requires
during
emission
excess
ments
device
determine
"Quality
measured
excess
now require
reduction
identifies
continuous
ance
control
level
standards
basis,
(i;e.,
when
from the
dependence
for a compliance
to
limit
test.
Both
without
emissions
for
the
17, 1984,
FCCU's.
regulated
After
further
pollutant
resulted
above,
in requiring
for
the
both
inlet
1-3
standard
The reasons
change
pollutant
consideration,
for the
regulated
the
for
FCCU's
for this
to daily
compliance
and outlet
monitors;
available
for
S02;
(3)
add-on control
devices,
the
Agency concluded that the regulated pollutant should remain SO,, because
SO3 could constitute a significant portion of the total SO, emissions
from FCCUls using SO, reduction
included
in the
were received
revisions
proposed
These conclusions
on November 8, 1985.
were
No comments
pollutant
regarding
SO, as the
add-on controls,
regulated
catalysts,
pollutant
add-on controls.
No additional
data or information was obtained that was sufficient for the Agencyto
conclude
add-on
that
controls.
on control
devices
1.1.5
SO2 should
Thus,
devices
the
be the
the
regulated
pollutant
pollutant
regulated
pollutant
to
7 days.
to determine
considered
performance.
average
period
for
and
FCCU's
without
for
ration
the
normal
both
the
with
the
Clarification
compliance
and
FCCU's with
would
times
better
add-on
take
the
other
rolling
controls
into
7-day calendar
for
catalyst
of a I-day
averaging
scrubbers
on SOx reduction
The proposed
cutoff
for
performance
selection
for
controls
variability,
1.1.6
standards
add-on
results
in scrubber
indicatedthat
test
of process variability
The analysis
add-on control
the effect
add-
is SO,.
the
3 hours
to
regulated
conside-
averaging
FCCU's without
of Method 8 to determine
The proposed
calculation
standards
the
total
add-on
controls
SO, emissions
standards
sufficient
procedures
for determining
total
were
revised
to
include
and
determinhtions.
Locations
The standard
,.J
modifications
1-4
requires
the use
from affected
facilities..
information
SO, emissions.
to
the
regarding
The
calculation
procedures
specified
emissions
upstream
flue
dard
for
standards
of the
is unsafe
high
carbon
required
monoxide
to require
FCCU's
without
rulemaking
devices,
a standard
add-on
revised
The stanto
allow
For FCCU's
of the CO boiler.
Requirements
the
refiner
with a standard
for
control
devices,
the refiner
to demonstrate
due to the
location.
been
that
provides
Initially,
stated
manual sampling
has
an a\ternativestandard
without
cutoff.
One corrsnenter
at this
controls
`Reduction in Reporting
elect
SOx
to be conducted
control
of total
sampling
to conduct
and pressures
add-on
This
that
(CO) boiler.
personnel
gas temperatures
sampling either
1.1.7
calculation
as S02.
The proposed
it
in Method 8 to allow
add-on
and
may elect
at
compliance
with
one of the
in compliance
a later
time,
but also
devices,
content
compliance
the
refiner
alternative
objectives
add-on
sulfur
to demonstrate
and,
in this
control
a feed
standards
were developed,
for
may
standards,
r.efiner
to encourage
greater
the use of
hydrotreating
and SO, reduction catalysts.
The reporting and recordkeeping requirements for the proposed standards required that a refiner
give
a 90-day
different
prior
notification
standard
and'conduct
Since proposal,
of his
intent
a performance
to be subJect
test
with
each change.
This change
requires
to a
to require
an owner or operator
the standard
which the
owner or operator
seeks
to comply.
The 90-day
notification
significantly
reduces
a refiner's
flexibility
other
standards,
subject
identified
to the
regardless
Particular
without
in the
required quarterly,
next
compliance
Thereis not
of whether
standard
with
prior
significantly
increasing EPA's ability to enforce the standard.
fore, the regulation
has been changed so that prior notification
required
dai~y
the
owner or operator
previously.
report.
All changes
Compliance
reports
has been
must be
are
1-5
particular
quarter,
in whichcase semiannual reports may be submitted.
The proposal had not allowed semiannual reporting when there were
periods of no exceedances.
If an owner or operator elects to comply
with an alternative
SOx standard, a quarterly report with notification
of the change must be submitted to the Administrator in the quarter
following
1.1.8
such a change
even if no violations
of a standard
have occurred.
FljnorChanges
Several changes have been made to the SO, emission percent reduction equation and SO, emission rate equation such that direct results
from the
1.2
test
methods
SUMMARY
OF IMPACTSOF PROMULGATED
ACTION
1.2.1
49 FR 2058.
minimal
1.2.2
impacts
The revisions
effect'on
of the
proposed
standards
are described
to the
proposed
standards
will
of the
standards.
the environmental
impacts
in
have a
^7;
Chapters
and economic
of the
final
background
standards
The nationwide
are greater
cumulative
the
than
capital
(reported
if
scrubbers
all
sodium
above 0.30
are
percent
cost
dollars).
contents
are
described
information
used
by weight.
would
estimates
not
differ,
because
weight
percent
1.2.3
Other
1.2.3.1
Implementation
percent
need
to
therefore,
costs
are
control
not
included
in Fourth
units
install
processing
of
with
in
sulfur
1984 dollars),
sulfur
year
quarter
levels
nationwide
1984
These
presented
FCCU.'s
of these
feed sulfur
a scrubber.
those
feed
in fourth
impacts
at proposal.
year
fifth
would be at the
The costs
quarter
with
(reported
from
for
fifth
facilities
cracking
of 0.30 weight
in the
in
document
and economic
calculated
The corresponding
Fluid catalytic
therefore,
at
cost
those
costs
standards
annual
standards
impacts
(BID).
A-ii
?~
cutoff
and
nationwide
Tables
contents
cost
A-10
and
of
0.30
here.
Considerations
Irreversible
of these
and
standards
Irretrievable
will
1-6
Commitment
result
in the
of
use
of
Resources.
sodium-based
scrubbers
in many cases.
natural resources,
However,
the
compared
to national
"Sulfur
Oxides
lost
the
adverse
shown
waste,
from delaying
1.3
rate
water
regulatory
proposed
were
requests
their
for
This
a public
are
interested
parties
categorized,
of the
year
to
be small
proposal
impact
BID.
7-6
standards
or energy
air
The annual
represents
the
delayed.
No
are
impacts
given
18 correspondents
proposed
on the proposed
hearing
so none
are
expected
commenting
an the
in Table
A list
presented
to
standards.
to those
under
the
to
the
their
preamble
General
Comments (Section
Control
Technology
Environmental
Costs
Compliance Testing
Compliance
Modification/Reconstruction
Recordkeeping
Miscellaneous
Comments (Section
topics:
2)
Comments (Section
Impacts
3)
Comments (Section
Comments (Section
7)
Comments
1-7
10)
(Section
4)
5)
Comments (Section
and
and Energy
of commenters,
document.
pertaining
proposed
and from 12
There were no
assigned
of this
revisions.
numbers
1-1
comments
standards,
was held.
EPA docket
from the
and they
adversely
in Table
the
documentpresents
resulting
expected
would
column
each
from
and the
regulation
of
COMMENTS
commenting
correspondence
use
action.
and the
affiliations,
7-6
pollution,
received
standards
correspondents
is
standards
in Table
for
SUMMARY OF PUBLIC
Letters
additional
Reduction"
reductions
solid
resources
of these
Emissions
emission
the
use.
in implementation
at
necessitate
of these
Environmental
quality
will
especially
commitment
1.2.3.2
Delay
This
8)
9)
6)
TABLE I-i.
LIST OF COMMENTERSON PROPOSED
STANDARDS OF PERFORMANCEFOR SULFUR OXIDES
EMISSIONS
Docket
Flair
Item No.
IV-D-1
Management District
Drive
El Monte,
CA
91731
IV-D-2
2.
Mr.
J.J.
Moon
Ph ii ii ps Petroleum Company
704 Phillips
Building
Bartlesv.ille,
3.
Mr. Phillip
Conoco,
P.O.
IV-D-3
TX
77252
IV-D-4
Box 43596
Paul,
MN 55164
Oil
P.O.
Box
fulsa,
6.
L. Youngblood
Box 2197
P.O.
5.
74004
Incorporated
Houston,
4..
OK
Mr.
1650
OK
74102
William
American
IV-D-5
Company
F. O'Keefe
Petroleum
IV-D-6
Insti.tute
1220 L Street,
Northwest
Uashington,
D.C.
20005
7.
Mr,
Peter
W. McCallum
The Standard
IV-D-7
Oil Company
Midland
Building
Cleveland,
OH 44115-1098
8.
Mr. J.R.
Bowler
CITGO Petroleum
Lake
Box
Lake
9.
Charles
~~-D-8
Corporation
Operations
1562
Charles,
LA
70602
Gallows
Fairfax,
1V-D-9
Road
VA 22037
1-8
TABLE 1-1.
STANDARDS
LIST
OF COMMENTERS ON PROPOSED
OF PERFORMANCE
FOR SULFUR OXIDES
Commenter
10.
and
Mr. J.
Texaco,
Affiliation
Donald
U.S.A.
1050 17th
Washington,
Docket
Annett
Street,
D.C.
Item
IV-D-I0
N.W.
20036
JV-D-11
II.
Mr.
A.G.
Shell
Smith
Oil Company
P.O.
Box 4320
Houston,
TX 77210
12.
13.
14.
Box
KY
Mr.
Arnel
L.G.
Oil
Products
Box
2001
Houston,
TX
Mr.
Johnson
J.M.
U.S.A.
TX
Mr.
Johnson
A.R.
77001
IV-D-15
and Webster
Box
Boston,
25
IV-D-14
2180
Houston,
Mr.
Company
77252
Company,
Box
P.O.
17.
IV-D-13
P.O.
Stone
16.
41114
Gulf
P.O.
15.
391
Ashland,
Exxon
IV-D-12
Engineering
Corporation
2325
M~
02107
Franklyn
Isaacson
Summit
Court
Westfield,
NJ
IV-D-1~
07090
Mr.
Bill
Stewart
Texas
Air
Control
IV-D-18
Board
Mr.
3.G.
Amoco Oil
P.O.
Box
Chicago,
Huddle
IV-D-20
Company
6110A
IL
60680
1-9
No,
:r3
TABLE 1-I.
LIST
OF COMMENTERS ON PROPOSED
Commenter
19.
and Affiliation
Mr. Allan
Diamond
P.O.
A. Griggs
Item
No.
IV-K-1
Box 20267
TX
J.G.
78220-0267
Isaacson
1V-K-2.
Court
Westfield,
Mr.
Docket
Shamrock
San Antonio,
21.
NJ 07090~
Huddle
IV-K-3
Box 6110A
Chicago,
IL
60680
23.
Corporation
Gallows
Rd.
Fairfax,
VA 22037
Mr.
Wasil~a
N.J.
IV-K-4
IV-K-5
SOHIO
Midland
Building
Cleveland,
OH 44115-1098
24.
Mr.
J.
Donald
Annett
Texaco,
USA
1050 17th Street,
Washington,
D.C.
25.
Mr.
J.R.
IV-K-6
N.W.
20036
Bowler
IV-K-7
CITGO Petroleum
.Corporation
bake Charles
Operations
Box
1562
Lake
26.
Mr.
Charles,
James
Lyondell
LA
70602
H. O'Brien
Petrochemica~
IV-K-8
Company
1200
Lawndale
Box 24 51
27.
Houston,
TX
Mr.
Johnson
J.M.
Exxon
P.O.
Company,
Box
77252-2451
IV-K-9
U.S.A.
2180
HOvS~on,
TX77001
1-10
TABLE 1-I.
LIST
OF COMMENTERS ON PROPOSED
STANDARDSOF PERFORMANCE
FOR SULFURdXIDES
EMISSIONS
Commenter
28.
Mr.
and
B.F.
Affiliation
Mr.
Shell
3.A.
Oil
Docket
Ballard
Phillips
Petroleum
Bartlesville,
OK
29.
Item
IV-K-10
Company
74004
Eslick
IV-K-11
Company
One Shell
Plaza
P.O.
Box 4320
30.
Houston,
TX
Mr.
Kienle
Shell
R.R.
Oil
One
Shell
P.O.
Box
Houston,
77210
IV-K-12
Company
Plaza
4320
TX
77210
1-11
No.
2.0
2.1
NEED FOR
THE
GENERAL COMMENTS
STANDARDS
Comment:
Two commenters
(IV-D-7
represent
an unnecessary
fore,
standards
the
commenters
for
and
burden
should
stated
to the
of the
that
petroleum
be withdrawn.
withdrawal
the
industry
The reasons
standards
standards
are:
and,
cited
(1)
there-
by the
other
sources
of
emissions
emissions
emitted
in
IV-D-16)
the
insignificant
United
SO,
States.
Response:
Section
list
111
categories
of
a category
causes,
or contributes
Section
promulgate
demonstrated"
been
ities
as:
source
these
areas
sources.
evaluated
and
ranked
from
of
that
standards
of
new source
development
of growth
category;
pollution
list.
performance
and replacement
estimated
performance
performance
for
the
the
source
standards
already
that
source
of existing
2-1
the
these
such
might
factors
by
be
category;
facilities
incrementa~
were selected
of
required
Sources
using
for
amount of air
future
1977, or earlier,
prior-
pollutants
emit
involving
category.
attention
implementing
that
in a preselected
...
areas
actually
of control
for
and
assigning
specifies
are
any)
may
"best
of-EPAfor
(if
it
considerable
for
by a process
levels
c~ould be prevented
during
in this
categories
control
(2) estimated
source
the
of interest
Source
of emission
standards
strategy
shall
to propose
reflect
The approach
broad
"...
or welfare."
Administrator
of an approach
categories.
the
Often,
level
(3) projections
the
development
to
which
health
to the
are
pollution
public
sources
regulations;
required
the
endanger
directs
Administrator
in his judgement
air
(BDT) for
by stationary
State
to,
if
technology
by considering
(1) the
in such list
which
the
The Administrator
performance,
passage
pollutants
sources.
to
Ill(a)(l)
to various
emitted
directs
of
given
interest
Act
significantly
standards
Since
Air
of sources
be anticipated
Further,
has
Clean
of stationary
include
reasonably
the
year
for
by
which
or under
these
criteria;
"Petroleum Refineries,"
Section
now requires
Ill(f),
priority
list
was
EPA to list
major
source
categories.
Major source
1:
cate-
the significance
iip
17 units)
and reconstructed
year (a total
of
reflect
76,100 tonslyr;
the
intent
total
a significant'
of performance
of Section
emissions
by about
improvement.
from
Neither
the
negate
these
standards.
Comment:
questions
pertaining
emissions:
(1)
considerably
by the
technology
rules
stated
(2)
be withdrawn.
rules
should
ai those
through
for
necessary
the modeling
1-7)
show that
If not,
be reissued,
best
sulfur
results
unregulated
2-2
available
do the job,
the
with
to satisfy
should
proposed
PSD requirements
more than
control
the proposed
proposal
BID and
baseline
emissions
PSD BACT.
feedstock
(proposal
model plant
BID pages
is
7-4
II and
III
quality
standard
and
secondary
national
(NAAQS). Thus,
there
ambient
air
NSPS.
(3)
year
trigger
or
limit,
III
doesn't
this
BACT, regardless
of Class
I1
increment?
Response:
Congress
would also
clearly
be subject
applicability
of
discussed
listed
source
structed
will
unclassified
of the
ambient
that
specified
allowable
air
the
the
increase
are
on the
application
source
or major
After
that
date,
reduces,
by the
for
area.
that
The current
emission
limitation
the
III
after
August
40 CFR 52.21
modification
each
net
emissions
allowable
under
the
which
1977,
for
will
occurs
would
or
increase
that
area
be less
than
ambient
air
, the
cause
maximum
the
ambient
(pristine
concentration
on which
the
by a major
requirements
increase
by sources
helps
that
environment)
to the
source
2-3
as attain-
attainment
raise-the
that
is
specified
will
increase
the
unit
is designated
maximum allowable
emissions
the
emissions
increase
was submitted
subject
same amount,
if
thi s si tuation
7,
(i.e.,
or has a potential
of the
The baseline
are
or recon-
NAAQS. CNote:
areas.l
is
a new, modified,
is
I area
source"
a maximum allowable
an increase
in a Class
date
under
equal
to equal
noClass
earliest
III),
increase
If
as
to regula-
that
concentration
NAAQS.
will
or
specified
above
concentration
in an area
II,
the
subject
and if the
if
concentration
I,
NSPS'~s
needed,
stationary
to PSD requirements
area
baseline
not
which emits,
on the classification
(Class
air
NSPS is
Therefore,
area
the
to
BACT. Thus,
be subject
Depending
including
as a "major
not affect
subject
pollutants
in an S02 attainment
show that
(b)(l)(i)(a)
per year
FCCU would
located
many sources
refineries,
of air
100 tons
under the
not
Petroleum
in 40 CFR 52.21
to emit,
that
to PSD requirements,
PSD does
below.
a stationary
tion
understood
is
first
and
established
complete
stationary
of 40 CFR 52.21.
in the
emissions
determine
may operate;
no
that
area
increase
the
is,
the
source
will
be subject
emitted
an emission limitation
of each
pollutant
subject
the permitting
account
authority,
energy,
to regulation
on a case-by-case
basis,
and economic
processes
including
fuel
techniques
and available
cleaning
impacts
Several
and other
sions
the
source
unemployment
desire
will
conditions,
for that
etc.
After
industry),
all
to emit;
these
attractiveness
other
variables
are taken
no specified
levels
source
wanting
into
of
combustion
constraints
of the
sources
costs,
wi~l influence
be allowed
which
and techniques,
fuel
other constraints
Act
through application
or innovative
(the
are
area's
to locate
considderation,
in the
area,
BACT is then
determined.
There
dependent
are
on the
constraints
on a case-by-case
industry
locate
allowable
emissions
rather
lenient
States
are
relying
basis).
in its
within
the
and there
increase
upon the
(i.e.,
the
in having an
source
could
large
receive
to conduct
thorough
NSPS program.
At this
BACT investigations
point,
is
BACT is determined
was a substantially
available,
BACTdetermination.
not able
area
region
the
many
without.
NSPS program
the additional
determination
process.
BACTis developed.
stated
As such,
control
which will
established
exceed
the
pursuant
maximum
"...
could
NSPS provides
in no event
technology"
PSD/BACT requirements.do
the
that
in 40 CFR 169(3)
available
defines
constraints
result
emissions
to Sections
not
emission
application
that
2-4
need
for
BACT can
of "best
of any pollutants
by any applicable
the
from which
preclude
level
shall
baseline
in emissions
allowed
-"
into
this
facility,
taking
methods, systems,
or treatment
for control
under
environmental,
in 40 CFR
Act."
standard
In summary,
NSPS; rather,
allow.
NSPS
'P
2.2
REGULATED POLL~TANT
In the proposed
change the
regulated
revisions
(50 FR 46464),
pollutant
add-on controls,
standard
without
add-on
proposed
decision
standard
without
responses
follow.
controls.
the
regulated
Comments
controls.
commenters
(IV-K-P,
Agency proposed
standard
pollutant
were
regulated
to
with
for the
received
only
pollutant
on the
for the
Agency's
Comment:
Several
use SO2 rather
than
SO, reduction
refinery~
lated
only
tested
contact
pollutant
only regulated
for
monitor
comnenter,
the
although
atmosphere,
and
monitor
could
the
the
continuous
for
regu-
standard
of SO3.
to acid mist
monitors
before
EPA
other
EPA usually
emissions
SO3 condenses
emissions
that
how an opacity
limit
that
to the
stack-mounted
regulated
an in-stack
with
occurs
are
SO2.
with
According
SO, as the
catalysts.
sources
approved
any atmospheric
upon
by EPA are
contact
In another
several
points
(1)
comment letter
pertaining
The Federal
is
only
Register
effect
(2)
oxygen drives
is
emissions.
in the
(3)
the
0.5
SO3 content
the
reaction
proposal
refining
of oxygen
gas:
oxygen content
of FCCU flue
to sulfur
content.
may
gas.
trioxide,
Thus,
it
the
linear.
is greater
This
claims that
the
power
lessthan
S03 typically
the
notice
increase
to
substantially
Although
(IV-D-16),
than 10 percent
statement
is
based
of the total
on test
comnenter's
data
SO,
reported
experience
in
industry.
SO, reduction
catalysts
work best
operates
to maximize the fraction
refineries
indicate
only an insignificant
same result
was also
SOx reduction
amount of SO3.
found without
catalyst
trials
have generally
contained
at one of
the
catalysts.)
that
pollutant (1) the same monitoring technique (pro;en S02 monitors) would
be used as is for add-on scrubber
consistency
and reliability
technology
would be gained.
This commenter also stated that emerging SO, reduction catalyst data
indicate -that S03 is unaffected by the catalysts; SO, reduction
catalysts
control
the percent,
the
SO, reduction
arguments
catalysts
presented
by the
do
commenters
SO, reduction
this
catalysts.
After
review,
regulated pollutant
catalysts
is SO,, not SO2
The Agency recontacted
SOx reduction
catalyst
SO, reduction
sulfate
catalysts
compound that
vendors to review
catalyst
preferentially
believes
than
the metal
sulfite
com-
balance is
~lf the rate
of S02 to SO3 is less than the rate of metal sulfate formation (SO3
plus metal oxide), then the SO3 percentage in the FCCU~emissions will
dec rease .
metal
sulfate
formation
rate,
then
th'is
S03 percentage
operate
a regenerator,
is faster
will
than the
increase.
to the extent
possible,
would
in such a manner
conditions
including
on this
that
submitted
in the
revised
be submitted.
by Corrsnenters
proposal
any data
Very little
2-6
that
that
were
The`data
that
base
remains
SO3 than
ever,
data
the earlier
that
there
very limited
generally
data.
the
is a potential
catalysts
control
agrees
with
uncondensed
determinations,
however,
plume opacity.
and maintenance
tion
is
available
suggest.,
S02 as the
how-
regulated
not necessarily
reflect
by SOx reduction
that
is affected
condensation
If
sufficient
may also
compliance
had been
the
of
opera-
higher
than
in-stack
limit
presented,
regulated
reading
Some informa-
of S03 and,
help
compliance
extent
emissions
data
on~this
then
pollutant
to the
the
for
of
possi-
Agency
FCCU's
would
without
determinations.
allow the
that
same monitoring
cost
savings
sampling.
likely
technique
be applied
technique
is
to
evaluated
other
EPA usually
regulated
for
to be used as for
controls
no need
IV-K-2 that
utant .woulld
be gained.
yield
S02 as the.regulated..poll
technique
not necessarily
There
appropriate
using
would
is
of a source
opacity
would
to show proper
device.
data
changing
add-on controls
intended
are burned.
it
Opacity
emissions
control
ability
transmissometers
visible
are
the
standard,
considered
stack.
by the condensation
bi ii ty .
in the
plume
fuels
affects
opacity
that
particulate
indicates
that
IV-KI2
made through
of the
opacity
(plume)
Commenter
are
is
still
of
S03 emissions
opacity
have
data
can be obtained
Transmissometers
tion
S03.
large
of SO, that
not measure
this
recent
by a standard
The Agency
the
for
Thus, regulating
potential
tendto
Some of the
pollutant.
and inconclusive.
on its
more consistent
that
standards.
own merit.
are
2-7
Agency
the
and reliable
Method 8
same monitoring
Each possible
regulated
is
and using
and using
The facts
the
add-on controls.
requirement
sources
However,
an SO, standard
alternative
refinery
this
or
add-an
raised
only for
monitoring
by Commenter
not
2.3
DESIGNATIONOF AFFECTEDFACILITY
Comment:
foran FCCU
reactor using multiple regenerators, the affected facility
should i nclude the reactor and all of the regenerators serving the
reactor, because it may be possible that SO, control systems used on
muitiple regenerator systems are more efficient.
Another commenter
(IV-0-16)recommended
that the affected facility shouldinclude the
FCCUreactor,
fractionator,
The commenter
sulfur cutoff,
a refiner
of the fe~d
feedstock.
Response:
Section
111 of the
Clean
Air
Act.
each FCCUregenerator
as the
because
the
refiner
the cost
and
downtimefor
revamping
workonthe unit, it is unlikelythat onlyone
2-8
regenerator
in
or
reconstructed
is
now defined
a multiple
regenerator
without
to
The proposed
those
petroleum
refiner
would
the
include
others.
all
of "fresh
derivatives
recycled
circumvent
the
would
Therefore,
regenerators
definition
not
configuration
serving
feed"
within
feed
the
be modified
affected
an FCCU reactor.
specifically
the
sulfur
facility
excluded
FCCU. To ensure
cutoff
by adding
that
low-
sulfur content recycle from the fractionator and gas recovery unit,
EPA has revised
the
definition
of "fresh
feed"
in the
regulation.
The
FCCU, fractionator,
excludes
them
from
and
the
gas
recovery
definition
of
unit
"fresh
as recycje,
and thus
feed."
Comment:
One commenter
(IV-D-12)
stated
that
the
proposed
not apply
IRCC) processes
Treatment
(ART) units.
justification
i.
The following
which
has
heavy
2.
The refining
different
metal
constituents,
content.
catalyst
high
Consequently,
design.
objective
employs
or Asphalt
carbon
residue,
and
may have a
(residual
distillate
an adsorbent
Resid~91
commenter's
ACC unif
(reduced crude),
RCC units
should
was provided:
AnFCCU processes
clean gas oils while the
processes
asphalt-containing
long residuum
higher sulfur
very different
standards
upgrading)
is
oils.
3.
rather
than
4.
a cracking
the feedstock
upgrading
process.
5.
residual
avoid
upgrading.
undesirable
and
operated
secondary
is accomplished
burn,
are
These units
reactions.
by multiple
catalyst
heat
under
stage
conditions
are designed
critical
and operated
Control
regeneration,
~o
to
of heat
release
limited
carbon
exchange.
Response:
To upgrade
distillate
residual
product
yields,
catalyst
feedstocks
new processes
termed
process
As in a conventional
regeneration.
and to increase
Emissions
gasoline
heavy oil
installed
residual
FCCU, emissions
and other
occur
and middle
cracking
at refineries.
heavy oil
as a result
be greater
of
from
of SO, emissions,
HOC units
showed that
control
the proposed
for HOCunits.
in Appendix
costs,
standards
for
The results
F of the proposal
of this
analysis
were
BID.
Emissions, emission control, and control costs for the ART process
were further evaluated by EPA (see Docket A-79-09, item IV-B-17).
The
differences
exist.
stated
by the commenter
inert
microspheric
between
an ART unit
contact
material'that
and an FCCU do
but rather
collects
uses
contaminants.
an
The
operating
Nevertheless,
important
operation,
and emissions
unit
the
under
material,
For
thereby
in regenerator
that
warrant
both
an
is performed
restoring
for
during
operation
are expected
emissions
(see
control
feasibility
Based on a scrubber
effectiveness
calculated
cost
effectiveness
expected
CO emissions,-if
be
item
for
IV-D-3O),
the
and
catalyst
in the unit.
the
regenerator
range of emissions
based
The EPA
on reported
that
of 90 percent,
is below
In addition,
particulate
Opacity
and determined
ART unit
or
those on HOC's.
was appl.icable
for FCCU's.
necessary,
a conv~ntional
SO, efficiency
cost
of an ART
and cost
Docket A-79-09,
reuse
including
cost.
and
to be within
regulation
ART unit
it
evaluated
the
configuration,
and emissions
normal
~,d
similarities
exist
FCCU NSPS.
FCCU, regeneration
contact
conditions
emissions
the scrubber
the
'range
costs
are
of
I:;I
to control
estimated
to
reasonable.
The similarity
ability
unit
of control
regenerator
objective
that
icant
subject
the
material
to
emissions
equipment
can meet
of the
reasons
in
the
FCCU NSPS.
the
the
regenerator
a reasonable
cost
FCCU standards.
is
different
regenerated
to support
the
at
ART process
being
from
is
contention
Therefore,
2-10
indicate
The facts
than
not
that
a catalyst
that
the
and the
proposed
that
that
of the
the
ART
the
FCCU as~d
are
an ART unit
avail-
not
signif-
should
standards
not
covered
be
both
and the
that
HOC, or any
an ART unit,
treatment
unit
promulgated
regenerator
other
achieve
standards
similar
the
continue
type
to require
of~fluidized
FCCU particulate,
bed
opacity,
CO,
FORMAT
OF THE
STANDARDS
Comment:
Several
commenters
(IV-D-3,
IV-D-1O,
IV-D-11,
IV-D-14,
and IV-K-12)
stated that EPA should establish a single SO, standard for FCCU's.
reasons cited by the commenters for setting a single standard are:
a single
standard
determining
the
(2) a single
would allow
refiners
most cost-effective
standard
the options
and flexibility
method of meeting
The
(1)
that
Ill(h)
of
limit;
and
rather
feasible
to
than
do
a work
practice
or equipment
standard,
where
so.
Response:
There
are three
(1) scrubbing
catalysts;
techniques
of FCCU regenerator
hydrotreating
and
method
of continuous
energy,
and nonair
emission
quality
techniques
consideration
and impacts
that
occurring
for controlling
associated
of FCCU applications,
effectively
and represent
FCCU-feedstocks
or processing
sources
that
without
the
establish
obtained
naturally
by either
occurring
can effectively
use
of
alternative
add-on
by feedstoek
oils.
of performance
that
reflect
for new,
the
costs,
The
best
environmental,
SO, emission
control
all
Upon thorough
reduction
techniques,
capability,
EPA determined
SO, emissions
from all
types
catalysts
low sulfur
high
crude
2-11
sulfur
oils.
reduce
EPA concluded
standards.
can be reduced
hydrotreating
and continuously
controls,
crude
effectively
SO, reduction
obtained
considering
systems
(2) using
impacts.
standards
of the availability,
scrubbing
standards
reduction,
health
low sulfur
FCCU regenerators
gases;
FCCU feedstocks
EPA to develop
reconstructed
to control
exhaust
low sulfur
or from naturally
applicable
it
feedstocks
For the
SO, emissions
is
reasonable
to
The standard
for
add-on
format
of add-on
controls
consistent
with
controls
reduction
was selected
for
all
Section
requires
it
to allow refiners
reduction
low sulfur
Although
SO, emissions
costs
or
believes
it
afforded
low sulfur
that
using
that
impacts
controls
to use SO,
a combination
effective
add-on
instead
SOx reduction
at reducing
feedstocks
of both
is reasonable
without
is
the standard
add-on
may be less
a standard
benefits
or
performance
This
that
by establishing
The percent
levels.
without
feedstocks,
environmental
reduction
refiner
nonair
control
the
the flexibility
techniques
than scrubbers
and smaller
scrubber.
these
sulfur
A standard
reflects
which requires
best
feed
Ill(a)(l),
the
in SO2 emissions.
because
expected
that
of
in
catalysts,
return
catalysts,
scrubbers.
:?
If
hydrotreating,
or
standard
install
without
add-on
and operate
reduction
an add-on
then
control
the
device
refiner
that
can
still
achieves
90 percent
of S02 emissions.
The standards
Section
111
nor the
standard
type
controls,
of
are
the
be operated
to
Clean
for
of controls
performance
Air
standards
Act.
Neither
FCCUls without
that
must
achieve
the
and are
the
add-on
be used
or
controls
exactly
consistent
add-on
with
control
standard
specifies
how the
the
controls
are
to
standard...
Comment:
Several~commenters
that
the
add-on
percent
controls
emission
limit
(IV-D-2,
reduction
should
format
be changed
standard
IV-D-3,
proposed
to
to control
SO, emissions
percent
reduction,
which
is
and IV-0-11)
by EPA for
an emission
would simplify
refiner
IV-D-10,
limit
compliance
to a specific
a moving
the
stated
standard
format.
with
An
level
rather
than
a
a
target.
Response:
Compliance
performance
device.
with
source
the
test
percent
at
that
both
reduction
the
inlet
an emission
format
requires
and outlet
limit
format
of the
for
conducting
control
the
standard
~y
source
testing
only
limit
could
the percent
percent
be
level
will
device.
using
is difficult
percent
reduction.
had no means
device.
than
emission
requirements
device
(see
results
continuous
a moving
Section
control
6.2).
device.
for
to
refiners
to
achieve.
the
coke
a control
outlet
S02 monitor,
reduction
the
requirements
and outlet
refiner
the
to
will
percent
reduction
calculated
becomes
achieved
monitoring
reduction,
thus
to
emission
to achieve
determine
results,
outlet
at the inlet
The percent
is
device
Consequently
available
monitoring
target
the
that
to the commenters'
percent
changed
specified
with
to the control
that
the
may perceive
level
the
acontrol
of monitoring
An emission
because
concentration
format
by scrubbers.
BDT.
Rather,
inlet
this
A refiner
no specific
to operate
S02 monitors
by the
the
represents
outlet.
monitoring
it
monitoring
achieved
achievable
control
the
is
on the
control
have
there
vary depending
and continuous
the
However,
to be a "moving target"
device
refiner
by the
of control
control
that
constant
outlet.
greateremissions.
format
The proposed
opinion
device
reduction
in
format
the
device outlet
the
result
reduction
at
control
90 percent
reduction
achieved
the
As discussed
format
at
a fixed
by
rather
Comment:
Three
commenters
standard
One commenter
allows
no
discourage
while
latitude
perhaps
sulfur
scale
was considered
allowable
that
this
format
burn-off
was
recorded
format,
the
yields
the
format
of light
will
suggested
stated
development
that
because
coke
2-13
uses
a format
who
products
be reduced,
that
EPA
in coke
the
of the
(SCAQMD)Rule 1105,
inappropriate
will
refiners
for variation
(IV-D-1)
by
inappropri-
and
penalizes
emissions
allows
during
is
content
The commenter
Management District
a coke
format
sulfur
increase
level.
proposed
cokeburn-off
The format
that
format
add-on controls
coke
A second commenter
format
concluded
in
content.
burn-off
of
variation
improvements
a sliding
burn-off
statedthat-the
to an unachievable
consider
rates
(IV-D-9)
improvements.
process
reducing
that
process
implement
stated
coke
South
but it
was
burn-off
instead
expressed
in
terms
of kilograms
barrels
of feed.
-A third
com-
--a
rather
than
a nonflexible
limit
of
sulfur
on coke.
Response:
Based on a sensitivity
proposal
analysis
that
presented
in Appendix F of the
format
relates
1'7
that
can be burned
reduce
the
off
coke
in the
make rate
regenerator.
are
Process
made to allow
the
refiner
to process more feed through the unit until the unit is again
limited
in the
amount of coke it
improvement that
results
An exampleof a process
to the
throughput
until
within
the
standard
offers
greater
basis.
on coke.
the
unit
Thus,
is again
even though
refining
The commenters
provided
the
refiner
coke burn-off
emissions
flexibility
-I_:
could
are
increase
limited
and still
would increase.
This
to refute
be
format
of feed
this
conclusion.
A sliding
content
would
scale
that
be difficult
coke on catalyst
considers
format
is not
a sliding
scale
to.enforce
readily
format
catalyst
for
variation
because
the
obtainable.
reduction
content
reason,
sulfur
of the
EPA
format
for the
standard
for
FCCU emissions
a percent
reduction
SO, concentration
sulfur
For this
to reduce
With'SO, reduction
in coke
unreasonable.
a percent
allows
percentage.
The
catalysts,
to measure.
by a set
there
Thus,
::I
con-
is no uncontrolled
it would be impossible
to
by SO, reduction
SO, emissions.
catalysts
using EPA's correlation
However, EPA's correlation
represents
2-14
an average
useful
for
all
for analyzing
the overall
While the
correlation
is
inlet
SO,
for
a specific
be used
on a case-by-case
separate
correlation
dards
unreasonable,
is
tion
select
The
EPA
direct
coke
particulate
standard;
and would
2.5
2.5.1
burn-off
method
use
for
stan-
of a correla-
is not
determining
catalysts,
format
the
reasonable
sulfur-on-coke
identical
the
be readily
LEVEL
coke
to the
is
by the
SO, emissions
a practical
format.
the
relationship
correlation
develop
that
reduction
format
to
EPA concluded
not
the
uncontrolled
is
Thus,
The cost
each feedstock
there
considers
burn-off
basis.
potential
concentration
a percent
feedstock,
Therefore,
Because
SO, inlet
its
for
for determining
practical.
FCCU and
to
coke
the
relationship.
format
burn-off
because
rate
The
selected
can
of
for
the
be recorded
NSPS
reasonably
available,
OF STANDARDS
Level
for
Add-On
Control
Standard
Comment:
Two commenters
(IV-D-2
standard
for
add-on
controls.
standard
for
add-on
controls
commenter
should
(IV-D-2)
and JV-D-4)
One commenter
is
excessively
that
the
than
50 vppm.because
equivalent
applications.
IV-D-18)
In contrast,
stated
that
the
standard
BDT for
is
stated
reduction
options
proposed
standards
are
industry
processing
(IV-D-4)
for
realistic
Another
for
achieving
when analyzed
and emission
control
of the
stated
that
the
Another
add-on
a.300
controls
vppm standard
is
reasonable.
add-on controls
provided
level
SO, reduction
three'commenters
(IV-D-11)
that
that
standard
to a 90 percent
the
stringent,
stated
approximately
stated
questioned
One commenter
at
90 percent
commenter
(IV-D-18)
compliance
in terms
by weight
with
the
of existing
practices,
Response:
The standard
are
reduced
The
standard
for
add-on
by 90 percent
is
based
controls
requires
that
or to 50 vppm, whichever
on test
data
that
2-15
demonstrate
less
that
stringent.
scrubbers
can
The 50 vppm
that
level
90 percent
reductions
processing
feedstocks
with sulfur
contents
is equivalent
to
:1
:,j
by application
level
2.5.2
In summary, 4300
achievable
the
standard
for
the
Level
vppm standard
of BDTand, therefore,
standard
of Standard
for
for
add-on
FCCU's
reduction
the
in
level
as
controls.
Vithout
`3
Add-On Controls
Comment:
IV-D-10)
controls
stated
that
the
standard
for
FCCU's
without
add-on
because:
impact
by SO, reduction
on ambient
catalysts
air
quality;
(2) 80 percent
by the
limited
reductions
commercial
tests cited by EPA; and (3) a 13 kg S0,/1,0O0 kg coke burn-off emission limit would allow more refiners
to use the catalysts
rather than
add-on controls since SO, reduction catalysts are the only costeffective
and environmentally
commenters
limit
tant
should
and IV-D-10)
the
Phase Ii
dard.
control
added that
be made to account
supported
that
(IV-D-6
acceptable
for the
In contrast,
an increase
change
proposed
of the
that
One commenter
SO, reduction
II of the
rule.
stated
that
reduction
required
tially
equivalent
the
emission
to the
level
Two
in the
in the
levels
Control
alternative.
emission
controlled
pollu-
by EPA.
of control
(IV-D-1)
catalysts
Another
by the
required
FCCUSO, emissions.
2-16
i.
than
reported
the stan-
are expected
commenter
(IV-0-18)
standard
is essen-
Response:
and environmentally
energy,
and nonair
control
to using
SO, reduction
quality
SO, reduction
acceptable
considering
health
costs,
impacts,
and are
that
BDT.
catalysts,
control
environmentai,
scrubbers
Furthermore,
refiners
catalysts
effectively
as an alternative
or low
to allow
with
further
stocks,
of the
best
standard
(9.8
refiners
flexibility
currently
development
especially
reduction
those
needed
80 percent.
to
lower
the
For example,
to~use
catalyst
with
achieve
available
of the
and to encourage
technology.
sulfur
level
content,
of
a feedstock
the
with
0.5
reduction
achieve
standard.
In response
of the
contacted
a number of companies
catalysts
to request
ability
updated
of developmental
SO, reduction
catalyst
catalyst
data
test
SO, emissions
developers
show catalyst
continues
a wide
to
achieve
level
of
reasonable.
standard
The
determination
consideration
increase
primary
and
for
purpose
scrubbers
of
of the benefits
in SO,-emissions
of the
can
FCCU's
the
standards
achieve
to the
this
2-17
points
catalyst
of
feedstocks.
EPA believes
controls
is
standard
included
and the
BDT of scrubbing.
emission
FCCU
technology
catalysts
future
of
by~the
tests,
add-on
is to reduce
cost-effective
the
catalyst
of
reduce
some data
range
of SO, reduction
compared
to
As the
a greater
level
and avail-
SO, reduction
reported
to use
without
EPA
Based on a survey
90 percent.
for
to
SO, reduction
performance
data
be able
standard
sulfur
comments,
performance;
of SO, reduction
the
to the
developers
The test
will
than
in SOx emissions
by the
as
less
percent
commercial
of catalyst
refiners
results
weight
on the
current
as high
the
is
catalysts.
reported
range
develop,
Based on the
the
developers,
performance
to
technology
information
by 65 to 75 percent.
span
emission
known to be developing
SO, reduction
havebeen
the
standard
50 percent
level
SO, reduction
performance,
would needapproximately
the
kg
Because the
reductions,
EPA
concluded that
emissions
it is not reasonable
by raising
the
level
to further
of the
increase
allowable
::1
standard.
total
FCCUSO, emissions
because S03 can comprise a substantial portion of the FCCUSO, emissions when SO, reduction catalysts are used, and the potential SO,
emissions from FCCUregenerators can be significant.
Both SO2and
SO3 are emitted
tests
indicate
catalyst
additives,
SO, emissions.
portion
or
(up to 60
data
used by EPAto select the level of the standard are reported in terms
of total
SO, emissions.
of 302.
2.5.3
Feed
Sulfur
Cutoff
Comme
nt :
Two commenters (IV-0-4 and IV-D-11) stated
sulfur
cutoff
of 0.30 weight
percent
sulfur
that
an arbitrary
feed
is too restrictive.
One
kg coke burn-off
accomplished
should
by developing
be established.
a correlation
using
test
This would be
between
feed sulfur
content
data.
Response:
The selection
percent
proposed
standards,
consideration
emissions
sulfur
feed
levels
refiners
to use naturally
level
cutoff
of 0.30 weight
in the
level
preamble
to the
was selected
based
low sulfur
feedstocks,
and the
occurring
on
low sulfur
feed-
if they
feed or to hydrotreat
high
feeds.
is presented
on test
on p. 3-18 of the
data
for
a large
sulfur
A correlation
based
the
cutoff
As was discussed
stock sulfur
elect
kg coke burn-off
proposal
BID.
content
The correlation
is
types.
an FCCU
SO, emission level of 9.8 kg SO,/
corresponds
to a feed sulfur
2-18
level
of
approximately
0.3
weight
percent.
Thus,
the
feed
sulfur
cutoff
level
without
determine,
sulfur
2.6
add-on
controls.
on a case-by-case
content
There
basis,
is
no
need
for
a correlation
each
refiner
between
to
feed
AVERAGING
TIMES
Comment:
Commenters
IV-D-EO) stated
i nc reased .
IV-D-11)
appropriate
that
averaging
the
of these
that
averaging
controls
commenters
(IV-0-3,
for
for the
(2) no process
control
(IV-D-2)
device
stated
add-on
lengthened
to
7 days
commenters
(IV-0-11)
determinations
with
the
excess
for
the
stated
should
hours
that
1,000
the
averaging
kg coke burn-off
Response:
Upon evaluation
commenters
foe
that
FCCU's with
the
period
standards
of the
averaging
for
feed
in a 3-hour
catalysts;
concentrations
commenter
times
should
reasons.
be
One of the
period
daily
the
for
peaks
compliance
not.exceeding
the
should
add-on
control
be a rolling
time
for
add-on
long-term
variability
compliance
controls
and 9.8
30-day
comments on variability,
and without
would be
FCCU's
time
Another
averaging
with
and
(1) a 7-day
not.
averaging
7 days
and for
in S02 inlet
same variability
the
be
for compliance
averaging
would
and
IV-0-1O,
can be adjusted
emissions
at
1V-D-6,
that
be set
IV-0-11,
standardsshould
reasons:
for variation
3
IV-D-10,
controls
the
variables
whereas
that
period
following
SO2 emissions
for the
cutoff;
1V-D-6,
time
standards
period to regulate
to
1V-D-4,
a 7-day averaging
for the
add-on
sulfur
IV-D-3,
Several
stated
without
(IV-D-2,
.period.
EPA agreed
with
should
the
kg/
with t~e
standards
be lengthened.
by statistically
analyzing
the
pointed
in scrubber
and feedstocks.
to this
inlet
study
as an example of the
conditions
The hourly
due to variability
percent
2-19
reductions
potential
vari-
in FCCU operaachieved
by the
scrubber
averaging times.
estimated
once
to compare various
in
10 years.
The results
ensure
analysis
that
analysis
exceedances
variability.
of
However,
performance
of the
of this
level
the
standard
with a 7-day
estimated
standard.
showed that
3 hours
would
rolling
not
This result
indicates
occur
average,
once in 10 years
is too short
due
normal
the minimum
was greater
that
to
to
than
the
level
developmental
stages,
for long-term
anal ys i s .
after
such
there
and
would
for
longer
the
be
changes
time
standard
as to
for
because
due
a different
the
feedstock,
standards
controls.
normal
The
included
a revision
7 days.
Six commenters
IV-K-10)
all
variatidn.
(IV-K-1,
add-on
EPA did
with
IV-K-5,
EPA's revision.
process
whereas
for
averaging
1V-K-3,
to use
vari-
3 hours
a 7-day averaging
The revised
of the compliance
in the
not
to
agreed
still
were appropriate
both
add-on
is
Therefore,
without
that
reasonable
FCCU's
technology
were no tests
a reasonable
catalyst
controls
choose
exceedances
proposed
time
IV-K-9,
No commenters
of
standards
from 3 hours
IV-K-6,
:T:
to
and
disagreed.
Comment:
Two commenters
period
for the
(IV-D-4
feed sulfur
and IV-D-20)
cutoff
pe ri od .
a 30-day
rolling
generator
average
period
stated
should
period
that
be a 30-day
the averaging
rolling
would be appropriate
isused
for the
fossil
average
because
fuel-fired
steam
NSPS.
Response:
Whenever
an individual
practical,
source
EPA determines
category
30-day
rolling
average
simply
to copy
the
period
fossil
basis.
for
NSPS regulatory
It
is not appropriate
fuel-fired
steam
requirements
sulfur
generator
cutoff
NSPS.
on
to use a
standard
The
of a range
of averaging
2-20
periods.
A daily
averaging
time
in selecting
the FCCUfeedstock
mix.
However,
increasing the averaging time beyond a 7-day period would allow feddstocks with sulfur
contents
significantly
greater
to the refiner
2-21
3.0
3.1
CONTROL
TECHNOLOGY
COMMENTS
SO, SCRUBBERS
Comment:
Two commenters
the
performance
proposed
data
of scrubbers
standard
for
that
scrubber
base;
feeds
(2 percent
(IV-D-9)
feeds
wrote
as applied
add-on
constituents
efficiencies.
Thus,
high
sulfur
coal
differs
high
sulfur
feedstocks.
They stated
should
be confirmed.
scrubber
tLe
higher
sulfur
among scrubber
sulfur
that
performance
from scrubber
that
One commenter
differences
containing
of
upon an insufficient
on FCCU's processing
can be subtle
and chemical
removal
is founded
performance
there
EPA's assessment
to FCCU's.
controls
or more sulfur)
that
challenged
for
performance
affect
scrubber
boilers
for
firing
FCCU's processin~
Response:
Scrubber
SO, control
between
liquor.
as those
However,
high
scrubber
exhaust
coal
Therefore,
high
lower
con~ustion
off the
for
flue
for
ities
between
process
that
exhaust
gases
A comparison
between
take
place
in the
are similar
boilers
FCCU regenerator
3-1
deri.ved
exhaust
material
the
similar
The catalyst
Given the
fuels,
air
to
to the
similar-
combustion
is expected
to yield
from coal-fired
gases
to,
showed that
similar
in boilers.
to those
if the
by adding
is thus
FCCU regenerator
of FCCU
is applicable
boilers.
regeneration
solid
confirm
the composition
This comparison
process
as
gas streams.
by EPA to
industrial
during
to
to FCCU's processing
is a carbonaceous
place
that
sorbent
applied
to determine
industrial
fuel-fired
catalyst
that
catalyst
takes
scrubbers
testing
gases
feedstocks.
The regeneration
processes
liquor
SO,-containing
EPA compared
boiler
sulfur
used in solid
regenerator.
judgment,
was available
of sodium scrubbers
coke is burned
the
to
to the
flue
to industrial
FCCU's processing
the
none
performance.
performance
scrubbing
SO,-containing
applied
scrubbers
feeds,
gases
the
of the
scrubbers
because
sulfur
a function
Based on engineering
higher SD,-containing
well
is
and industrial
boilers,
boiler flue gases was presented in fable 4-3 in the proposal BID. The
comparison showed that
of most FCCUregen-
erator exhaust gas constituents ~nitrogen (N2), oxygen (02), 002, SOx,
nitrous
to the boiler
of regenerator
of fly ash.
particulate
Catalyst
emissions.
In an industrial
boiler application,
(refer
upstream
from the
scrubber.
According
to scrubber
control
the scrubber
of the application.
regardless
vendors
that pass
the design of
fines are no more erosive than fly ash and neither type of particu7ate
would interfere
particuiates
reaction.
in
low solubi7ity
scrubber
of hydrocarbons
operation
or perfon~ance.
in the aqueous
scrubbing
liquor, the hydrocarbons will not be absorbed but pass through the
scrubber to the atmosphere. .Other differences
in gas compositions are
minor and are not expected
systems
for
industrial
II-B-21)
in flue
boilers
and consideration
conclusion
that
applicable
to
applied
the applicability
of scrubber
FCCU regenerators.
The similarities
between
to invalidate
industrial
FCCU's.
to an industrial
and characteristics
of their
boiler
Source
boiler
to Docket A-79-09,
differences
sodium scrubber
test
results
burning
for
a high
item
performance
a sodium
sulfur
is
scrubber
fuel
show that
II-A-11).
a reasonable
Therefore,
EPA has
reached
3-2
conclusion
that
the
FCCU standard
expected
is achievable
range
and that
of FCCU regenerator
The commenter
did
not
scrubbers
exhaust
provide
gas
performance
for
industrial
boilers
scrubber
performance
for
FCCU's.
Therefore,
mentioned
expect
to
that
similarities,
scrubber
applicable
sulfur
for
to show that
would
be different
than
in consideration
EPA believes
performance
over the
concentrations.
any information
scrubber
above
are
that
it
industrial
is
of the
reasonable
boilers
to
is applicable
FCCU's.
Conanent:
One commenter
scrubber
system
SO, removal
(1V-D-16)
currently
As discussed
applied
below,
90 percent
to achieve
Research
and Engineering
applied
high
the
of 95 percent
A-79-09,
items
1I-D-41
concentrations
bers
vendors
in
tower
reported
(see
should
Docket
that
of all
sodium scrubbers
achieved
SO, control
A-79-09,
items
efficiencies
and
11-1-50).
90 percent
companies
However,
ERE scrubber
II-I-42
of
refining
Exxon
for the
efficiencies
other
for
(see
ERE states
the
Docket
that
at
low
Docket A-79-09,
sodium
items
tower
scrubber
non-venturi
at least
item
scrubber
Due
concentration
II-B-10
vendors
and performance
type
at a location
achieve
reduction.
licensor
II-D-95j.
other
or tray
A-79-09,
Docket
scrubbers
of
and II-D-50)
standard.
applicability
FCCUSO, emissions
device
the
fluctuation,
(see
contacted
the
(spray
and
and process
EPA
regarding
90 percent
of SO, emission
for
(less
50 vppm is reasonable
The
sodium
be guaranteed.
SO, control
has installed
included
levels
(see
it
to sampling
poliutant
(ERE) is the
scrubbers
is
guarantee
scrubbershave
and
to FCCU's will
to FCCU's.
show that
inlet
of the
would similarly
designed
in excess
the
SO, reduction
Sodium scrubbers.applied
system
licensor
the regulated
S02 removal
currently
if
Response:
Since proposal,
and thus
asked
for
information
of non-venturi
designs)
scrubbers
type
to FCCU's.
installed
IV-3-6).
Based
3-3
reductions
on these
These
to control
scrub-
control
in SOx emissions
responses,
EPA
vendors will
guarantee
Comment:
issue
an NSPS because
emissions
that
no add-on
control
device
demonstrated.
for
sulfur
oxide
that
exceedances
of the proposed
system
standard
variability,"
then
tests
emissio ns .
data
for sulfur
dura-
in the
BID Appendix
to lower~FCCUSO, emissions,
C are
for short
since
"all
periods."
Response:
Since the standards
the regulated
if
the
sion
pollutant
regulated
still
proposed,
pollutantfor
the
standard
for
add-on
Even
controls
were
SO,, the pgency disagrees that the lack of long-term SO, emisreduction
data
been adequately
contain
that
were originally
ability
supports
reduction
period
refinery
gives
scrubber
to attain
performance
over a 7-day
to attain
period,
and adjust
process
with
and believes
are adequately
conclusion,
demonstrated
because
variables,
does not.
commenter's
at
have
in each
SOx emission
least
90 percent
a 7-day averaging
scrubbers
operators
scrubbers
and maintained
a scrubber's
SO, emission
that
CAppendix C does
of well-operated
tests
a conclusion
of the short-term
reduction
to support
demonstrated
long-term
the
fails
minor problems
in
such as feedstock
add-on
controls
Comment:
One commenter
scrubbers
for
added that
request,
f.ired
the
that
steam
(IV-K-12)
effective
stated
SQ3 reduction
indicate
generators
that
that
at
available
SOg percent
gas
The co~8nenter
production
3-4
on flue
is not warranted.
data,
a western
EPA's reliance
field
is
very
'"
oxide
of this
due
on oillow,
while
:-~7
SOp percent
removal
scrubbers
are
although
they
is much higher.
known to
are
be less
efficient
According
effective
for
to the.:commenter,
submicron
for
the
concerns
particulates,
removal.
Response:
The Agency
that
flue
appreciates
gas scrubbers
controlling
This appears
from
scrubbers
S03 removal.
resolved
to differences
indicated
in scrubber
by the
portion
Thus, the
this
steam
commenter for
out,
generators
showing
of total
potential
this
it
possibly
regenerators,
adverse
environmental
the
apparent
although
Although
all
(80 to 99
as pointed
rulemaking,
design.
in
on FCCU regenerators
can be substantial
to contradict,
for
of SO3 emissions.
be as effective
by scrubbers
on oil-fired
commenter
to.be
small
S02.
on SO3 removal
by the
for control
may not
percent).
needs
systems
S03 as in controlling
irdicate
data
scrubber
expressed
commenter's
"very
low"
contradiction
is
likely
not
as
due
low as
S03 constitutes
using
impact,
add-on
even.jf
controls.
scrubber
efficiency
for S03 removal is actually "very low," will be very small.
Thus, the Agency believes that the decision to use SO2 as the regulated
pollirtant
for
regenerators
with
add-on
controls
is still
appropriate.
Comment:
One commenter
systems
(i.e.,
would result
(IV-D-7)
scrubbers)
stated
and the
flue
gas desulfurization
in more frequent
profitability
that
FCCU shutdowns,
nation's
refining
Scrubber
reducing
(FGD)
shutdowns
refinery
capacity.
Response:
At proposal,
sodium scrubbing
at
processing
other
capacity.
scrubbers
There
sodium
scrubbers
or reduced
is
represent
refinery
to control
11 percent
increased
to
SO, emissions.
the
FCCU shutdowns,
operation
reduced
of these
refinery
FCCU
show that
profitability.
applied
of nationwide
no information
has
refineries
Since proposal,
controlling
tion.
five
systems
applied
capacity,
no data
to
an effective
3.2
SO, REDUCTION
CATALYSTS
Comment:
.:j
CaTimenters (IV-D-2,
that
SO, reduction
catalysts
80 percent reductions
in SO, emissions.
and cannot
achieve
a variety
ii
T~
of feedstocks.
catalyst
inventory
will
reduce contact
nega-
is not addressed
by any existing
corrtmercial test
data;
and
catalyst
effectiveness
impede applicability
of the
catalysts
recognized,
at moderate
and
feedstock
levels.
Response:
The EPA considers SO, reduction catalysts
to be an emerging
technology.
The standards allow for their use and thereby encourage
their
further
development.
Current
catalysts
developers,
catalysts
can achieve SOx emission reductions of 65 to 75 percent (see
Section 2.5.2).
Concerns and uncertainties
about catalyst
performance
remain
because
the
technology
is not fully
developed
at this
time.
--3
operating
standard
lysts
restrictions
for
only.
may prevent
FCCU's without
In these
using hydrotreated
cases,
Thus, it is possible
some refiners
add-on
controls
the refiner
or low sulfur
from achieving
using
SO, reduction
that
the
cata-
feedstocks,
either
by
alone or in
or by scrubbing.
Comment:
that
recently
completed studies
show
that SO, reduction catalysts are capable of achieving the necessary SO,
reductions
such that
FCCU's operating
California
can achieve
Phase
at refineries
located
in Southern
SCAQMDregulations
add-on controls
for FCCU's
indication
catalysts
3.3
LOW-SULFUR
FEEDSTOCKS
Comment:
One commenter
(IV-D-16)
stated
that
the
proposal
the
standards
be reevaluated
with consideration
given
to whether
the proposed standards will have any impact because of the probable
diversion
of low-sulfur
feedstocks
to affected
low sulfur
facilities.
The com-
FCCU feedstocks.
3-7
Response:
_I
low sulfur
feedstocks
would be a cost-effective
alternative
to
improvedand crude oil prices have significantly declined from the peak
1980 prices, but not all refiners will choose to limit FCCUprocessing
to low sulfur virgin feedstocks.
Many refiners
exists
that.refiners..will
be processing
are currently
proces-
Furthermore, the
higher sulfur
content
crude oils within the next 5 years. Therefore, EPAexpects that most
refiners will use SO, reduction catalysts, hydrotreating, or scrubbers
to
achieve
these
standards.
3-8
:I
4.0
4.1
ENVIRONMENTAL
AND ENERGY
IMPACTS
COMMENTS
Comment:
One commenter
is less
(IV-D-16)
today than
January
using
showing
the
reduced
FCCU fresh
the
estimates
energy,
capacity
to
Response:
According
IV-J-2),
FCCU capacity
has
that
of the
cited
the
size
data
impacts
his
(see
claims.
1980 to
However,
also
period,a
modified
or reconstructed,
FCCU
and
New
existing
construction
units
are reported
(see
Docket A-79-09,
that
12 new FCCU's
were undergoing
1984.
Based
estimates
that
on this
provided
standards
reconstructed
reasonable
were
modification
A review
undergoing
construction
reconstruction
of this
EPA still
proposal
7 modified
information
5 years.
data
that
Table
be subject
new, modified,
the.growth
FCCU's would
of the
units
shows
and 14 existing
believes
or reconstructed
of
"Boxscores"
in the
on these
and
1980.
FCCU's were
in Hydrocarbon Processing
FCCU's projected
based
since
number of existing
information,
within
IV-J-3).
expansion
10 new and
these
item
item
1984 by 21,450
refineries
this
be
of new
Docket A-79-09,
from
of
should
andnumber
of FCCU's at unprofitable
during
capacity
and economic
from the
support
decreased
feed
environmental,
The commenter
decreasing
total
the
that
analyzing
are incorrect.
reevaluated
stated
A-10 for
and
BID also
estimated
to.
appear
sizes).
Comment:
One commenter
(IV-D-16)
stated
that
percent
sulfur
because
reflect
The commenter
that
cited
sulfur
a "Davison
model doesnot
Catalagram
FCCU processed
4-1
66" (1982)
feed
with
industry
practice.
which stated
a sulfur
content
above
2 percent
0.6
and that
sulfur
content
was
percent.
Response:
refining
trends
in the
impact
analyses.
Comment:
impacts
proposal
BID.
for
calcium-based
scrubbers
energy,
were omitted
and
from the
Response:
The analysis
of the
proposal
of various
BID was not
scrubbing
meant
to
systems presented
be all
inclusive.
in Chapter 4
The environ-
in the-proposal
system.
scrubber
to
4.2
achieve
However, a refiner
these
choose
touse
a calcium-based
standards.
WATER IMPACTS
Comment:
(IV-D-16)
a permit
scrubbers.
shown by the
This
commenter
requested
discharge
permits
need to
install
replacement
presented
no inland
of waste
that
rivers
could
under
Federal
not
discharge
additional
that
have
refineries
The
of water
treatment
a Wellman-Lord
receive
(IV-D-5)
would
systems
to
the costs
scrubber
for
used at a
used
commenter
bodies
wastewater
settling
been
could
Another
large
to
from sodium
scrubbers
inland
BID.
would be able
proposal
near
levels.
and stated
liquids
regulations.
located
fn;the
refiner
sodium
expensive
power plant,
scrutiny
that
refineries
meet permitted
that
noted
or large
commenter
that
stated
where oceans
stated
analysis
to receive
Response:
The EPA agrees
application
that
that
the waste
and operated
at
or other
reasonable
apply
to all
wastes
are
wastewater
treated
with
these
the
separately
system,
regulate
them.
sodium
about 6 percent
sul fates.
dissolved
There
scrubber
associated
with
then
limitations
refinery
control
accounted
are
under
processed,
treated,
wastewater
collection,
wastestream
solids
by weight,
are
currently
of
basis,
would
is
its
the
sodium
high
scrubber
of the Federal
a discharge
and still
comply with
standa rds .
discharged
solids
or
content,
of sodium
applicable
wastestream.
outside
the
419 regula-
of the
primarily
regulations
on whether
the
treatment,
dissolved
where appropriate,
accommodate
or
characteristic
solids,
be based
Part
far
would be made to
wt~ich consists
no Federal
discharged
The costs
the
determinations
when these
or are
system.
for
locations.
devices
wastewater
treatment
case-by-case
on dissolved
on a case-by-case
guidelines
the
are
can be installed
at inland
pollution
main
systems
refineries
from air
wastes
solids'content
limitations
Such
effluent
wastewater
wastes
of scrubber
for
disposal
treated
types
costs
tions.
aspects
sodium scrubbers
treatment
disposal
to the
Instead,
would be developed
effluent
guidelines.
receiving
a State's
water
water
body
can
quality
a maximum
~irJolve~
rolidr
content
at500.9/1
Infrerh
uarer.lodiu.
icrub~er ~3
wastes are produced at the rate of 0.19 to 0.38 m3 per minute.
Unless
sodium scrubber
discharge
point.
the
sodium scrubber
wastewater
would constitute
may be within
acceptable
levels-.
refinery
dissolved
solids
sufficient
i~
total
are diluted
to acceptable
levels.
located
at
emissions
coastal
from FCCU's.
locations.
Since
to saltor
brackish
water.
to the Agency's
discharges
proposal,
All
At least
No requirements
one of these
exist
for the
or salt
to all refiners
the proposal
discharge
water
in inland
preamble.
to surface
or discharge
locations.
to a sewer will
Disposal
not be available
Where permits
waters or sewers,
are unavailable
other.wastewater
for direct
disposal
deep-well
injection,
and recycle.
Evaporative
pending is
contamination
refiner
elects
to
charge
permit,
in many parts
install
he will
a sodium
of
scrubber
the
but
United
cannot
disposal
States.
obtain
If
a dis-
methods.
The
added cost of these disposal methods would be greater than the disposal
cost used fcr- EeA's cost estimates.
Ho~ipver, other scrubber systems,
such
controls
as dual
at
alkali,
reasonable
are
available
to meet
cost.
4-4
the
standard
for
add-on
11~
Sodium
control
scrubbers
have
SO, emissions
of 47 sodium
charge
deep-well
either
it
to
water
is
sewers,
possible
for
a permit
to
As mentioned
wastewater
to
dual
strated
removal
efficiencies
BID, Chapter
and FCCU flue
systems
these
are
gases
to these
comments (see
dual
alkali
the
refiner
Table
catalysts,
have
no significant
add-on
The costs
by EPA in the
and again
for dual
Appendix
developed
or by complying
with the
wastes
and
have
demon-
boilers
between
3.2),
(see
industrial
these
scrubbing
preamble
in response
volume
proposal,
to
provides
Alternatively,
with the
hydrotreating
feed sulfur
of
(see
scrubbers
IV-B-15)
compliance
by using
or Wellman-L~s~
systems
to this
since
to demonstrate
controls
item
wastes.
cost.
on industrial
in Section
Docket A-79-09,
may choose
liquid
wastes;
scrubbing
(discussed
surface
which have no
liquid
similarities
to
with minimal
solid
Due to the
costs
wastes
scrubbing,
produce
These
A-8 in the
scrubbing
FCCU's without
drying
instead
were evaluated
8),
location
of the
systems
7 use
wastestream.
to FCCU's at a reasonable
to FCCU's.
BID, Chapter
be reasonable.
SO, scrubber
5 dis-
refinery
scrubber
to
population
pending,
of the
to dispose
of 90 percent
4).
proposal
sodium
means
product.
applicable
scrubbers
another
~hich
sulfur
boiler
an inland
but
a salable
proposal
at
discharge
locations
boilers,
23 use
a refiner
other
produce
water,
dispose
wastes
scrubbing,
industrial
to
and spray
and
to
inland
From a total
recycle
alkali
liquid
at
boilers.
surface
are applicable
significant
citrate
use
above,
impacts
include
to
and I uses
or
extensively
applied
9 discharge
obtain
or
These
currently
injection,
Therefore,
used
from industrial
scrubbers
to a sewer,
been
standard
for
or SOx reduction
cutoff
using
low sulfur
feedstocks.
The sodium
scrubber
wastewater
wastestream
would
la nd fi 1 1 .
Currently,
(ESPls)
of in landfills.
will
be
wet
in
be removed
precipitators
and
exhaust
gas.
a settling
from
the
catalyst
include
fines,
fines
these
pondanddisposed
are
collected
FCCU particulate
4-5
sodium
salts
are removed
catalyst
of
in a
in electrostatic
NSPS, and are disposed
dissolved
removed
fines
Eventually,
settling
fines
catalyst
These catalyst
pond.
to meet the
Catalyst
will
contains
such
settling
as
sodium
pond,
Therefore,
selected
for disposal
catalyst
fines
of catalyst
settling
fines.
not affect
Thus,
under
it
the method'
is doubtful
that
RCRA.
Comment:
availability
in inland
refinery
locations
.sodium scrubber
blow-down on refinery
such a high
seriously
of total
solids
in the
necessitate
the
solids
installation
solids
of the activated
receiving
waters.
alkali
where water
In support of this,
quality,
and stated
impacts on receiving
of dual
scrubbers
wastewater
dissolved
high dissolved
that
level
alkali
or areas
single
waters would
scrubbers.
Response:
will
not negatively
affect
a refinery's
wastewater
plant.
include
aeration
bas.iri to reduce
By using these
stream
a settling
wastewater
chemical
treatment
treatment plant.
wastewater
treatment
the refinery's
wastewater
If the treated
facility
treatment
plant
will
the
mixed
treatment
not
4-6
the
refinery's
effluent
is
main wastewater
fines and an
scrubber
waste-
main wastewater
with
the
plant,
be affected.
treated
effluent
the refinery's
from
main
4.3
SOLID
WASTE IMPACTS
Comment:
One commenter
the
preamble
impacts.
cost
to the
impacts
for
scrubber
costs
water,
should
increase
disposal
costs
water
Another
According
the
would rise
solid
would
have
by weight.
that
address
Since
waste
scrubber
accordingly,
if disposal
systems that
are currently
no added
that
waste
disposal
sol'id
generated
waste
the
(IV-D-7)
the
in
states
the waste
to the commenter,
amount of solid
to
preamble
commenter
do notadequately
systems.
greatly
scrubbers
50 percent
much.
standards
of scrubber
disposal
presented
pertained
be twiceas
proposed
that
why sodium
waste
is
two statements
standards
asked
solid
waste
is 50 percent
questioned
proposed
The commenter
sodium
the
(IV-D-16)
wrote
that
waste
impacts
systems
could
by a refinery
locations
and
are available.
R~sponse:
both particulate
of scrubber,
required
to
an additional
achieve
particulate
emissions
the
With this
control
current
particulate
standard-.
(primarily
catalyst
to FCCU's
particulate
the
emissions
applied
increase
by a dry particulatecontrol
amount of particulates
"chargeable"
would
volume.
It
a scrubber
device,
collected
be wet
will
cost
and,
thus,
more
to
to~ a landfill
transport
than
dry
and
scrubber
is
included
costs.
as a conservative
scrubber
waste
In order
the water
to date,
estimate
to the
to
the
none of the
of the
costs
(see
Section
the
additional
in settled
percent
solids
settling
waste''
more
and encompass
in a
a larger
solids
collected
The increase;due
cost
analysis
disposal
to dispose
sodiurn
was added
liquid
document).
waste
disposal
(sludge),
content
of the
scrubber`solids.
the
of
cost
treated
5.1 of this
solid
to
in
in the
waste"
Therefore,
collected
solids
cost
due to
it was necessary
sodium scrubbers
over
are not
scrubber
Thus,
of FCCU
waste
sodium scrubbers
is "chargeable"
a ''liquid
sewer
determine
contained
to determine
as a "solid
In addition,
of solid
and dispose
solids.
Control
by a sodium scrubber
However, solids
weigh
would not be
such as an ESP.
by the
scrubber
fines)
device
However,
applied
regarding
the
waste generated
by a refinery,
sodium scrubbers.
from an FCCUprocessing
sulfur
feedstock
will
waste disposal
consider
control
not be possible,
techniques
that
the refiner
would need to
waste.
These
Wellman-Lord or
catalysts,
feedstocks.
Comment:
and produce
of raw materials
surface and
contaminant.
Response:
of sulfur.
The~standard
control
technologies,
refinery
sulfur
add-on
is eventually
plant.
4-8
controls
With both
_i
The amount
approximately
through
scrubber.
tants
resulting
these
impacts
impacts
sodium
hydroxide
1.15 times
the
discharge
of
are
are
the
application
reasonable.
discussed
in
discussed
in
by sodiumscrubbers
from
are
the
consumed
the
scrubbers
The water
impacts
Section
Section
4.2
5.1
of this
of
gas stream
impacts
of
this
is
passing
of secondary
pollu-
and determined
of scrubber
document,
that
wastewater
and the
cost
document.
Comment:
One commenter
SO, reduction
(IV-D-16)
catalysts
By dividing
the
by the
commenter determined
fifth-year
reported
that
FCCU solid
that
according
nationwide
(820 millionlyr)
increase
stated
the
waste
to have a solid
cost
cost
to the
for
waste
SO, reduction
of the catalysts
by 11,000
preamble,
impact.
catalysts
(81,8O0/M9),
catalysts
the
would
Mglyr.
Response:
The EPA does not believe
would
result
that
in a significant
increase
in FCCU solid
catalysts
waste
for
the.
replace
catalyst
inventory
One of the
their
than
may result
the
tests
formulations
because
produce
would
increasing
a softer
makeup rate
are
would
one.
rate
total
of time.
particulate
for the
much
be in the
quantity
In this
emissions
or solid
4-9
that
increases
than
earlier
catalyst
because
of
catalyst
likely
as a constituent
interest
formulation
cost
catalyst
waste.
to
of the cracking
without
used in the
SO, reduction
less
formulations
can be accomplished
catalyst
less
formulations.
a harder
most
this
Based
developers
developed
of cracking
case,
reported
waste
and therefore,
SO, control
of
is greater
harder
catalyst
softness
of up to 40 percent.
solid
Other recently
and consequently,
the
waste
catalyst
over a period
increase
its
The developer
circulating
and IV-D-24).
tan additive),
developer,
makeup
JI-D-57
to the
inso~id
it
items
of the
due
reduction
a lower
incorporate
catalyst
that
10 percent
that,
catalyst.
these
a harder
have
use than
cracking
stated
are anticipated
catalyst
by another
5 percent
5 and up to
Docket A-79-09,
in an increase
on recent
than
developers
SO, reduction
for
less
(see
catalyst
that
than
from
catalysts
FCCU
would not
In summary, whether
the
SOx reduction
tuent
of the
cracking
SO, reduction
solid
waste
4.4
catalyst
ENERGY
catalyst,
catalyst
over
is unlikely
formulations
current
that
or aconsti-
would significantly
increase
FCCU
levels.
IMPACTS
Comment:
presented
2 percent
in the
increase
menter stated
that
proposal
to control
stated
that
too low.
Instead
estimated
of the
by ERA, the
0.2 to
in electric
consumption
an increase
wouldbe morerealistic.
system
BID are
requirecom-
Thecommenter
operates a Wellman-lord
scrubbing
SO, emissions
from a utility
boiler.
The commenter
is 10 MWcompared to the
the
Wellman-Lord
flue
gas
scrubber,
in order
especially
blowers necessary
through
the
a CO boiler.
Response:
The EPA reevaluated
requirements
its
estimate
of the electrical
of Wellman-Lord
scrubber
systems.
the FCCUregenerator
boiler.
gas through
less
energy
is required
a Wellman-Lord
system
trial
should
or utility
requirements
be lower for
boiler
in
with
high
temperature
the
to operate
high temperature
believes
with
that
Wellman-Lord
the
majority
the estimate
scrubber
system
requirements
sodium scrubbers
applied
and
regeneration.
presented
are the
based
modified,
energy
in the
rather
only scrubber
are the
systems
4-10
for
than
an indus-
system energy
on an FCCU
of a CO boiler.
reconstructed
FCCU's
Consequently,
EPA
requirements
proposal
in the proposal
of sodium scrubbers
because
than
instead
of the electrical
BID are
regeneration
new,
system
The Wellman-Lord
proposal
of
scrubber
an FCCU application
application.
presented
operating
leaves
or other
As a result,
exhaust
energy
of
BID is reasonable.
than
Wellman-Lord
systems
EPA expects
that
systems
have been
most refiners
to
install
to
provided
achieve
the
standard
no information
Therefore,
EPA did
revise
chooses
to
4.5
AIR
use
add-on
regarding
not
a Wellman-Lord
for
sodium scrubber
the
that
energy
impact
commenter
energy
of
requirements.
sodium
may experience
sodium
controls.l.The
greater
energy
scrubbers.
choosing
impacts
to use
than
if
one
scrubber.
IMPACTS
Comment:
Four commenters
the
(IV-D-3,
appropriateness
of using
SO, concentrations.
SO, emissions
would
only
impact
that
bring
13 kg S0,/1,000kg
cooling
of the
ing
small
the
air
in ground-level
level
would
if
all.
at
the
include
exit
that
sulfuric
quality
the
acid
temperature
commenter
further
reported
air
for
that
controlling
or
control
to
benefits
to
reduce
sodium
gas
cost
temperature
(2000C).
suggested
cause
gas
exit
stack
in the
of Regulatory
reheating
and
This
modeling
velocity
heights
increase
NSPS little,
concentrations
analysis.
used
diminish-
a net
proposed
of
and
Alternative
below
the
a stack
15.3
exit
to
commenter
is
that
the modeling
thereby
EPA require
ground-level
scrubber
and a flue
that
the
kg coke burn-off
of the
suggested
an
below
by scrubbing,
in some cases,
level
impact,
a level
A 13 kg S0x/1,000
quality
FCCU
kg coke burn-off
is accomplished
(IV-D-I~)
dew point
of 260"C
wrote
questioned
ground-level
in a ground-level
If
benefit,
gases
flue
increase
in the
the
(IV-D-3)
small.
concentration.
reheat
stated
quite
commenter
scrubber
if they
decrease
coke burn-off
reduce
Another
a small
exhaust
and IV-D-16)
below a 13 kg 50,/1,000
about
already
IV-D-8,
scrubbers
One commenter
to a level
is
IV-0-6,
m/s.
The
velocities
I aredistorted.
Response:
Scrubbing
a gas
the
stream
Unless
emitted
gas
from
the
stream
is
scrubber
plume
reduces
lowers
reheated
stack
not using
the
effective
the
temperature
downstream
will
of the
be cooler
a scrubber.
height
wi 11 ri se.
4-11
of the
above
than
gas
scrubber,
the
the
emitted
plume
Lowering the
the
stream.
ground
plume
temperature
to
which
the
In all
the national
cases,
ambient
air
ground level
quality
SO, concentrations
standards.
plantscenarios
except the one processing
ground level SOx concentrations
predicted
For all
the
in
are
model
concentrations.;-~
In these cases,the
decrease in SO, emissions afforded by implementation
of scrubbers offsets the lower plume rise.
This analysis showed that
applying
a scrubber
to a model plant
processing
a low sulfur
feedstock
burn-off
Alternatives
levels
(Regulatory
would increase
of emission
not compensate
exhaust
occur
reduction
for the
in actuality
and,
above the
content
achieved
However,
because
SO, concentration
(uncontrolled)
by the
control
resulting
this~model
would
not
case.
The small
did
would not
0.3 weight
percent
low-sulfur
cutoff
a scrubber
downwind
alternatives
plant
feedstocks
therefore,
baseline
gas temperature.
sulfur
be installed
on the
source.
Also the model assumes that a scrubber would reduce model plane SO,
emissions
to the level
of the regulatory
reductions
required
to achieve
considered
are
than
less
alternative.
the 90 percent,
regulatory
requi.red.by
alternatives
the
standard.
used
to
achieve,
achieve
the
resulting
than
if a scrubber
tion
catalysts
less
The additional
result
same
the
the
standard
emission
plume
than
scrubber
of SO, reduc-
without
add-on
the application
by scrubbers
the
use
would
may be less
application
so that
concentrations
the
concentrations
FCCU's
provided
rise,
as
controls
of scrubbers.
would
of
likely
scrubbers
would
cata`lv-~:--.
The stack
modeling
for
reduction
reduction
lower
level
However, the
reduction
reduction
maximum ground
emission
for
emission
were used.
to meet
would provide
compensate
the
analysis
temperatures,
were
selected
heights,
and exit
as average
4-12
velocities
values
from data
used
for
in
the
actual
FCCU scrubbers.
tions
existing
before
proposal
is
Reheat
during
certain
for
the
weather
model
reason,
and the
assumption
equipped
to
are
based
with
reduce
conditions.
plants
For this
EPA believes
that
of no reheat
the
are
stack
the visible
The stack
on actual
scrubber
EPA selected
scrubber
modeling
reheat.
steam plume
parameters
sodium
installa-
installations.
input
parameters
selected
appropriate.
Comment:
One commenter
(IV-D-9)
inflating
stated
that
the
percent
the
use
overstates
reduction
of the
correlation
uncontrolled
attributed
to
SOx emis-
catalysts.
proposal
same time,
The correlation
data
reason,
it
used
for
of
a useful
SO, emissions
SO, emissions
on p.
by industry
the
reasonable
and
is
emissions.
on
For this
in the-proposal
estimating
catalyst
based
types.
shown
for
the
feedstocks.
correlation
means
of
However,
from other
3-18
SO, emissions
uncontrolled
and
presented
a large
representative
correlation,
understates
EPA concludes
lation
the
BID, overstates
at the
test
that
BID is
the
corre-
uncontrolled
FCCU
performance.
Comment:
One commenter
adequately
sions.
address
(IV-D-16)
the
effect
catalysts
(Sections
C.3.1.1
that
SO, reduction
stated
the preamble
of SO, reduction
that
the
and Docket
raised
does not
catalysts
preamble
NO, emissions.
and C.3.1.2)
catalysts
that
states
on NO, emisthat
SOx reduction
However, the
A-79-09,
item
proposal
II-B-20
BID
show
NO, emissions.
Response:
Most
from the
tion.
refiners
use
FCCU regenerators:
regenerators
show an increase
using
control
HTR or catalytically
of NO, emissions
to
promoters
4-13
promoted
CO combus-
from regenerators
in NO, emissions.
CO combustion
CO emissions
Separate
without
using
catalysts
data
for
SOx reduct.ion
in
catalysts suggest that the use of these catalysts may increase NO,
emissions. Thus, at this time, it is unclear whether the NO,~increases
observed
for
SO, reduction
catalyst
tests
catalyst
of SO,
catalysts
in FCCU's utilizing
to the
CO promoters
standards
catalyst
were available.
are expected
formulations
to use HTR
N4, emissions, EPA believes that the use of the SO, reduction catal'yst
regulations
Regulatory
that
the
unit.
(IV-D-16)
into
account
Alternative
selection
Then,
which~the
I.
unit
the
in estimating
plants
emissions
is
that
To remedy this,
of model
baseline
model
stated
BID fails
to take
baseline
emissions
for
the
include
can
proposal
commenter recommended
site
selection
be estimated
based
for
each
on the
State
in
located.
Response:
feedstock
processed,
FCCU operation,
significantly
depending on
and capacity
utilization.
Many refiners
have been able to achieve existing State SO, regulations
with little
or no control.
It is difficult
to determine FCCUSO, emission
the
rates
taking
various
individual
formats
simplifying
of
assumptions
State
State
regulations
regulations
regarding
into
do not
account
~end
because
themselves
to
FCCUSO, emissions.
factor
as there
provides
emi s s io ns .
This
is no basis
a reasonable
factor
for
site
estimate
selection.
Using an emission
of baseline
is based on emission
test
nationwide
results
that
baseline
SO, regulations
have
changed
have changed
do not
affect
FCCUSO, emissions.
4-14
little
since
EPA's
estimate
FCCUSO,
for typical
achieved by
to 1979. State
1979; those
of nationwide
regula-
Comment:
One commenter
shows a "-4" air
Response:
A "-4",
(IV-D-16)
impact
denoting
in Table
1-1 because
emissions.
This
in three
short-term
FCCUls represent
that
BID
cases.
significant
means
air
impact,
a significant
FCCUls emit
was entered
source
of SO,
than
100 tons
much greater
per
if:
(1) standards
more stringent
than
the
current
and (3)
no standards
were developed.
Comment:
One commenter
determine current
correct,
EPA should
emissions
is
levels
factor
factor
will
Model plants
test
current
generated
FCCU operations
FCCU's that
will
FCCU's that
based
not
are
but instead
to these
sulfur
based on the
of older
use of
reflect
represent
SO, standards
to this
predict
and recon-
be subject
on a composite
FCCU SO,
will
nationwide
and does
is
emissions.
based on feed
emissions
or emissions
be subject
data
were developed
model plant
is used to
model plant
factor
If the factor
to estimate
emission
SO, emissions
and throughputs;
an emission
on actual
FCCU's.
that
FCCUSO,.emissions.
use this
based
what potential
stated
nationwide
Response:
The emission
structed
(IV-D-16)
over
estimate
standard
than
those
the
next
of emissions
an emission
newer
5 years.
from
factor
FCCU's.
Comment:
One commenter
uncontrolled
(IV-K-2)
emissions
400 and
1,200
questioned
from a typical
controlled
the
FCCU are
emissions
Mg/yr.
4-15
source
of EPAls claim
between
from a typical
2,000
and
FCC~ are
that
Response:
The uncontrolled
represent
Regulatory
emissions
estimates
Alternative
referred
I (Baseline)
to in the comment
with
standard,
Emissions were calculated on the basis of 1,400 vppm for
feed sulfur content of 1.5 weight percent.
This vppm estimate is consistent with actual data from pilot and commercial FCCU's, shown in
Figure
BID.
The controlled
emission
estimates
of
400 Mg/yr and 1,200 Mg/yr represent control in the 2,500 m3/day and
8,000m3/day
regenerator,
respectively,
to 9.8 kg50,/1000
kgcokeL~_S
burn-off.
This level
catalysts
being
are
used,
lower
controlled
emissions
FCCU.
would
occur
at
this
-4
4-16
5.0
5.1
SCRUBBER
COSTS
Comment:
Five
stated
commenters
the
opinion
BID are
unrealistic
claimed
that
higher.
(IV-D-5,
that
IV-D-6,
the
scrubber
and are
the
scrubber
The reasons
1V-D-9,
costs
significantly
cost
cited
presented
and
IV-D-20)
in the
proposal
underestimated.
estimates
by the
IV-D-1O,
should
be
commentersfor
The commenters
2.2
the
to
7 times
low cost
estimates
are:
(1)
(2)
There
FCCU's
at
discharge
not
factors
different
cost
can cause
refineries.
dual
alkali
considerable
FGD systems
at
any
in
of the
systems might be
or wastewater
restricted.
of retrofit
installations.
(6)
is
variation
(5)
for
model units,
although
use of dual alkali
required
in areas where water availability
(4)
assumptions
costs,
and
costs.
estimates.
cost
of
(3)
on erroneous
waste disposal
It
interruption
shutting
down
FCCU.
is not appropriate
costs
from the
FCCU with
for
scrubber
an ESP if
modification
or
EPA to subtract
costs
scrubbers
in the
are
case
required
a credit
for
ESP
of an existing
as a result
of
reconstruction.
Response:
To respond
detailed
to perform
proposal
commenters
specific
cost
to these
data
a general
BID.
single
addressed
EPA decided
alkali
reevaluation
Concurrently,
and then
cost
for
comments,
scrubbers
of the
EPA solicited
the
individual
items.
5-1
cost
first
to solicit
from vendors
data
presented
supplementa~
cost
comments-pertaining
more
and then
in
data
the
from
to
A.
General
vendors
other
BID cost
Cost
than
Review.
EPA solicited
estimates
were
First,
based.
scrubber
The
vendors,
the costs
EPA received
scrubber
Elements
in
has
Corporation
insta~lation
with
actually
has,
of
tion
refinery
scrubbers
to
The analysis
that
the
industrial
of these
costs
provided
estimates
and are
conservative
serve
to
other
provide
the
companies
believe
the
Exxon
system
the
American
pumps,
not
is
designed
tory
linings
to
catalyst
fines
requires
sparing
by the
multiple
venturi
as specified
to maintain
of
the
FCCU's
B.
specific
safe
the
by the
scrubbers
the
for
flue
scrubber
from
gas.
than
operation
for
cases,
and
operation
In particular,
design
coded
American
provided
vessels
the
a single
Fluid
about
cost
data
larger
refrac-
abrasive
effects
the
Exxon design
cracking
nonstop,
their
periods
and
throat
catalytic
Exxon designs
of
analyzers,
3 years
for time
Petroleum
are
variable
by
of
special
and critical
vendors.
that
petroleum
and use
Further,
equipment
other
that
companies,
shell
equipment
vessel
by the
cost
specifica-
coded
Exxon
rather
design
that
LI
alkali
vendor
industry.
two vendors
steel
and reliable
comments
reliability
call
other'two
in.some
Review of Specific
cost
and applica-
of single
of all
refining
design.
venturis,
lo~ger
familiar
FCCU's.
vendor
Engineers
other
rotating
may be in continuous
significantly
in the
refinery
of all
the
equipment
the
in the
specifies
units
coded
protect
to
use of redundant
the
of Mechanical
such
not
highest
.specifications
one of the
specify
those
with
and electrical
(API);
than
necessary
design
but
Exxon
specifications.
scrubber
Society
piping,
Institute
did
vendors
is
by Exxon,
applied
then
to
scrubbers
tions
Environmental
therefore,
and equipment
boilers,
data
Corporation
a subcontractor
and,
experience
proposal
cost
Elements
as
scrubbers,
codes,
of
showed
Exxon
on which the
on an FCCU.
served
scrubber'
installed
however,
several
FCCU operation,
Andersen
been
from
detailed
Environmental
data
or
scrubbers
equal
to that
control.
Cost Comments.
provided
by companies.
5-2
the
of erroneous
information
the
concluded
FCCU's using
(see
the exhaust
HTR appear
coke
composition,
typical
levels
compared
were
found
model plant
amount
air.
exhaust
regenerator
for
not
During these
for
cost
FCCUls operating
flue
gas
the
capital
Docket A-79-09,
boilers
with jet
costs
item
must install
the
that
venturis
Fluid
the rlEV-type
would
in the
enter
a 3EV scrubber
CO boiler.
impact
the
scrubber
would be about
10 percent
an FCCU to a high-energy
IV-B-16).
This
in the
cost
Tables
A-5 through
revised
increased
of the
JEV
the
catalytic
that
the
that
Appendix
to
commenters
transport
This
solid
also
revised
units
(see
using
CO
presented
gas.volume
required
to aJEV
than
(see
Docket
A-79-09,
in about
a 3 percent
previously
calculated.
this
(IV-D-5,
assumptions
reviewed
the
IV-D-6,
volume
for
waste
IV-D-9,
contain
and disposal
waste
disposal
waste
disposal
disposal
costs
used
of collected
cost
is
IV-D-IO)
scrubber
the
the
on FCCU's
combustion
flue
volume resulted
A-7 in
gas volume
to include
cracking
of the
higher
over
and
gas
exhaust
scrubber
JEV scrubber
the
item
increase
the
costs.
Several
BID.
venturi
were
analyses,
exhaust
installed
scrubber.
and
and
for
As a result.,.,EPA
because
coke,
to industry
the
used
(JEV's)
3EV scrubbers
IV-B-16).
between
conditions.
CO boiler.
for
FCCU exhaust
gas volumes
values
EPA revised
ejector
from the
and annual
the
of actual
for
by SPA indicating
evaluations,
contribution
exhaust
to beginning
representative
analysis
to burn
prior
The EPA
relationships
necessary
Furthermor,
review
and EPA
the cost
Model plant
volumes reported
exhaust
used for
of air
Additional
item IV-B-4).
The calculated
be reasonable.
representatives
volumes
Docket A-79-09,
in part,
volumes.
commenter,
based on stoichiometric
of excess
to
gas
from the
to be appropriate.
the
to actual
were low,
of FCCU exhaust
gas volumes
EPAlscosts
and received
information
that
that
assumptions
was requested
reviewed
stated
catalyst
t~ased only
5-3
BID represent
fines
on the
in
stated
that
costs.
the
The
proposal
additional
mass
of
solid
wastes
collection
to
be disposed
device instead
In the proposal
treated
liquid
the
use
of a wet
BID, no costs
were credited
it is appropriate
disposal
to surface
water.
by assuming
that
as the
4.3 of this
document).
Upon review,
all
of the
the treated
costs
scrubber
to the disposal
due to
liquid
EPA decided
that
estimate of liquid
affected
facilities
would
discharge to sewers.
Some refiners,
especially
in coastal locations,
will likely be able to discharge the treated scrubber liquid wastes to
surface
waters
without
incurring
a sewer discharge
cost.
site
soil conditions,
turnaround
and startup
in the
water,
protection,
fire
The scrubber
refer
within
to that
process
unit
available
limits,
cost
costs
costs
estimates.
steam,
and its
equipment
will
in this
of the
refinery
include
air,
climate,
electricity,
utilities.
impacts
include
associated
the
a 20-percent
contingency
turnaround
startup,
and
a particular
not
the FCCUbattery
than that
assumed in the
is
that
provided
the
site
expense
therefore,
in
site-specific
schedules,
and the
have,
are
within
contingency
are
limits
Where utilities
climate,
with
isavai-lable
space
and
of off sites
been
considered
by EPA.
In support
space
and equipment
requirements,
retrofit
of
their
comments
availability,
one commenter
installation
on costs
provided
of a sodium scrubber
from an FCCU at
of construction
(IV-D-10)
an existing
5-4
' I:i
for offsites,
and other
cost
equipment.
conditions,
availability,
included
limits
estimate.
to soil
costs
equipment availability,
Off sites
capacity
However,
cost
related
specific
compressed
supporting
the refiner
soil
of the
or insufficient
each capital
are
portion
variability,
up costs, or construction
the battery
estimates.
costs
or equipment
including
schedule,
space
cli mate .
EPA's assumptions
conditions,
., j
capital
to control
refinery.
climate,
system
costs
for the
both particulate
The single
'~
alkali
scrubber
is
sized
for
a flue
gas
volumetric.flow
rate
similar
to
A compar-
ison
estimate
of
shows
the
that
commenter's
the
total
The commenter
compared
to
adjustment,
construction
climate.
and believes
that
in this
these
response).
cost
estimate
is
cost
estimate
for
on an existing
project
estimate
for
tions
tive
the
the commenter's
EPA's
revised
scrubber
by a vendor.
stages
are
typically
installed
to the
This
a constru~F;tion
project
well
A factor-
cost
specifications
the
final
these
scrubber
the
with
costs
design
allowances
and construc-
cost
cost.of
experience
that
defined.
generous
actual
on a vendor's
of this
of cost
several
more defined,
and closer
cost
very
from a preliminary
type
of
in equipment
not
contain
becomes
are based
of the
factors
of cost-factors
than
were developed
early
uncertainties
lower,
EPA's costs
costs
specifications
will
is
and
for by EPA's
dollars,
alkali
cost
cost
accounted
higher
single
provided
in
As a project
normally
commenter's
costs
also
allowance,
the discussion
50 percent
scrubber
estimate
when the
tion.
design
same.
indirect
The cor~menter
to equivalent
a comparably-sized
for
the
27-percent
the
(see
about
FCCU.
cost
account
factor
approximately
is developed
to
by EPA.
cost
is
account
are adequately
When adjusted
estimate
type
to
EPA evaluated
cost
The commenter's
factor-type
estimates
productivity,
factors
contingency
revised
an additional
labor
The
both
used
estimate
included
EPA's
factor
factor
cost
with
for
a 60-percent
base
which
20 percent
cost
40-percent
this
estimate
direct
applied
to the
applied
cost
estimate
project.
scrubber
The
app~ica-
than
the
cost
estimate
estimate
and EPA's
of
commenter's
nature
the
revised
cost
single
than
parts,
alkali
cost
data
single
alkali
indicated
the
"front
systems
to show that
half"
largely
due
that
to the
EPA's cost
use of dual
alkali
or wastewater
systems.
is
preliminary
estimate.
be based on the
availability
provided
costs
discharge
dual
A dual
and the
alkali
alkali
"back half."
5-5
estimates
FGD systems,
in areas
is restricted.
systems
scrubber
should
where
The con~snenter
The front
half
of two
of a dual
alkali
scrubber
resembles
a single
alkali
scrubber
without
a wastewater
treatment unit and performs the same function--removing SOx from a gas
stream by contacting it with a caustic or soda ash scrubbing liquor.
In the back half of a dual alkali scrubber, however, the purge is
treated
to regenerate
scrubber
the
simply treats
to single
calcium
water,
that,
alkali
sludge
but disagrees
discharge
scrubbers
would be a viable
alkali
alkali
produce a
disposed
scrubbing
wastewater
alternative
scrubbers
a single
of scrubber
that
that
for reuse;
where direct
scrubbers
sulfate
liquor
and discharges
dual
alkali
scrubbing
systems
than
waste-.
would be more
EPA's proposed
estimates
compared
single
by the
scrubber
commenter's
in the proposal
commenter
to estimate
for
actual
alkali
scrubbers
The comrmenter's
cost
tion
these
of
dual
alkali
(see
Docket A-79-09,
systems
single
half
alkali
of
differences
costs
cost
costs
alkali
assuming
scrubber
and sulfur
scrubber
both
sizes
Corporation
of
provided
scrubber.
Also,
them
independent
by an
existed,
based
90 percent.
costs
loading.
are a func-
The commenters
costs
a dual
EPA performed
on.data
item
from.vendors
IV-B-15).
back-half
Exxon provided
vendor
for
EPA with
of dual
costs
Exxon's
for the
Environmental
both
sizes
a cost
alkali
estimate
front
Elements
of dual
scrubbers
evalua-
dualalkali..
Speci fically,
scrubber.
costs
higher than
a further
of
cost
information
to
scrubber
dual
alkali
scrubber
BID, a computer
dual
dual
costs.
contractors.
Thecommenter'-s
tion of volumetric
costs
on proprietary
presented
SO, reduction.
capital
alkali
were based
provided
L~
alkali
provided
for
the
to
back
capital
cost
based on a scrubber
are
than
those
estimates
capital
that
cost
estimates
in the proposal
for Exxon's
design
single
5-6
for dual
alkali
alkali
scrubbers
than Exxon's
scrubber.
This is
:I;
because
scrubbing
less
liquor
costly
purged
than
costs
dewatering
the
disposal
A comparison
remained significantly
on proprietary
scrubbers
actual
costs
commenter
plants,
total
alkali
believes.
applied
to
Therefore,
plants
it
model
systems.
for
the
scrubber
model plants,
the
alkali
are 93 percent
inappropriate
are
a function
capital
costs
cost
by vendors
scrubber
of nationwide
costs;
dual
only
use of dual
(IV-D-20)
also
alkali
cost
estimates
because,
of both
for single
whereas
gas
alkali
flow
systems
5-7
data
are
model
cost
estimates
costs.
of model
for single
single..alkali
for
cost
data
BID (see
single
EPA's revised
alkali
costs
for
The commenter's
alkali
for dual
and feed
alkali
the
represent
control
costs
single
costs
for
national
model plants.
capital
as
scrubbing,
costs
higher.than
costs.
sys-
more costly
in the proposal
to EPAls revised
alkali
waste
of this
assume that
was
alkali
are
alkali
cost
estimates
sulfur
alkali
of EPA's indivi-
estimates
ofS02
The commenter's
percent
cost
some facilities.
provided
of dual
at
an analysis
of dual
of dual
the
costs
alkali
costs
less,~costly
decrease
not to revise
alkali
provided
information
costs
alkali
would
those
single
are similar
cost
sludge
is based
single
waste-
information
cost
item IV-B-24).
systems
cost
current
to single
Docket A-79-09,
for
total
EPA's
comparison
the
dual alkali
ratherthan
plants
with
dual
costs
was decided
This commenter
alkali
costs
total
by the
alkali
Therefore,
to reflect
dual
be
system.
by Exxon
detailed
supplied
single
estimate
the
treat
alkali
and a comparison'
provided
scrubber
which reflect
a conservative
to
by contractors
commenter,
of data
that
dual
developed
commenter,
to those
The EPA's'analysis
total
data
to the
dual
than
alkali
the commenter's
cost
to EPA by the
indicates
dual
t~he commenter's
because
notprovided
tems
of the
and provided
capital
needed
to
facilities.
of EPA's revised
However,
was found
specified
cost
the purged
reuse,
from a single
ponds
the
for
system
discharge
than
estimate.
it
treatment
in-ground
greater
scrubber,..whe~e
regenerate
before
for
are
and
to
alkali
wastewater
liquor
treatment
by the
treated
the
scrubbing
Construction
water
is
of the.dual
capital
this
approach
alkali
systems
sulfur
a function
costs
only
content,
of waste
is
reagent
Dual alkali
solution,
the
of which depends,
in part,
on the
.i:13
s'ulfur
single
alkali
by applying
sulfur
believes,
costs,
Therefore,
a constant
content
control
single
percentage
that
reevaluate
cost
alkali
these
The EPA
Costs
that
alkali
associated
-..3
EPA needed
FCCU's with
to another-based
of land.
single
content, is doubtful.
existing
costs.
ii
for different
of retrofitting
derived
estimates.
the cost
only of
estimates
costs
in erroneous
are a function
alkali
of dual
therefore,
costs
with
to
scrubbers.
retrofit
will
on the refinery
In some cases,
,4
space
configu-
limitations
that
retrofit.
model plants.
capital
cost
(less
added
anticipated
to
three
shutting
interruption
down the
reliability
states
emissions
device
still
cost
be able
would
interruption
or unavoidable
be incurred.
One commenter
credit
to operate
impact
inappropriately
are
the FCCU.
For
this
when revising
(IV-D-20)
operated
reason,
the
stated
during
3.2),
a period
a violation
the
not
i~:T
of
provided
During
refiner
would
interruption
include
a business
BID costs.
EPA subtracted
Llj
to 40 CFR 60
no business
of an existing
5-8
malfunction
and maintained.
EPA did
proposal
that
in the easer
limit
failure,
Therefore,
a cost
in Section
Provisions
not considered
scrubber
5 years.
have demonstrated
(discussed
of an emission
This
FCCU's
a scrubber
sodium scrubbers
in excess
the control
of a sudden
result.from
some
scrubber
of 95 percent
device
of the
The General
of a control
for
by one commenter.
.can occur.
malfunction
period
would
in excess
mal functions
that
that
FCCU. Although
factors
estimates
modified/reconstructed
standard
stated
that
cost
of 20 percent
seven
to~this
(IV-D-20)
dn the
was estimated
of the
to be subject
business
scrubber
costfactor
contingency)
One commenter
for
be included
A re.trofit
cost
was
should
an ESP cost
place
if
scrubbers
reconstruction.
priate
the
ESP cost
cases.
credit
retrofit
C.
as a result
in these
which
are required
the
were
three
of costs
credit
BID costs
modified
or
is not appro-
were revised
or
to eliminate
reconstructed
FCCUls
in
included.
reevaluation
an ESP cost
The proposal
for
costs
that
of modification
and of the
As a result
review
of specific
cost
comnents,
changes
were adjusted
revised
to
account
as a result
increased
for
to include
were
installed
costs
were
ESP cost
waste
for
of the
on modified
i ncl uded.
gas
air;
Costs
volume
discharges;
modified
or
then
further
the
are
of
the
document.
costs
BID costs
new cost
Changes
to increase
1984 dollars,
estimates
in cost
(fron
costs
to increase
adjusted
to
from proposal
Thus,
total
nationwide
after
the
annual
therefore,
are
not
cost
to
content
is
show that
of the
above
0.3
$45 million.
would
applicable,
need to
dual
alkali
all
dollars.
EPA concluded
2.2
to
7.
A of this
million);
capital
adjusted
from
nationwide
of
would
to
proposal
annual
per.year);
of 29 percent
8117 million,
facilities
a scrubber.
scrubbers
result
The fifth
feedstocks
could
assuming
feedstocks
year
nationwide
with
sulfur
feed sulfur
Where sodium
be used
in
5 years
processing
5-9
1984
retrofit
nationwide
a total
standards
processing
scrubbers.
to
B36.6.million
percent.
install
which
63 percent
caused
that
per year).
the
weight
Units
percent
not
of
increased
standards
are used at
of 0.3-weight
sodium
costs
for
Appendix
caused
date
scrubbers
cost
contents
capital
effective
sulfur
in cost
(from %35.to
annual
estimates
in
a total
Changes
scrubbers
and
these
sodium-based
above
by 5 percent
1984 dollars,
FCCU's;
by a.factorof
as described
were
reconstructed
understated
increased
costs
cost analyses,
presented
costs
scrubber
for retrofit
adjusted
are
by 30 percent
capital
not
the
were
(4) a cost
FCCU's
proposal
entering
reconstructed
were
costs
was deleted
or
components
with
flue
combustion
credit
of individual
received;
liquid
was added
(1) costs
increased
of CO boiler
installation
that
were made:
at
cutoff
and
scrubbers
a similar
5.2
SO, REDUCTIONCATALYSTSCOSTS
Comment:
catalyst
technology
requires
a capital
outlay.
units
subject
Two commenters
to the modification
or reconstruc-
that
little
outlay
for capital
equipment,
two exceptions
-~
would be:
(1) a smal~~,cefinery that does not have a sulfur recovery unit, and
-7
,I
the increased sulfur load due to the SO, reduction catalyst technology.
In either case, a capital expenditure would be necessary.
Two of the
commenters(IV-D-6 and IV-D-9) also stated that annual costs for SO,
reduction
catalysts
will
likely
be at
least
2 times
higher
than
EPA's
estimate.
Response:
Many refiners
regeneration
tion (e.g.,
throughput).
standards
advantages
temperature
these
offers
older
over conventional
cannot
to select
capital
utilize
SO, reduction
another
control
reyenera-
to
provisions
is more likely.to
use SO,.
techniquethan
the refiner
incur
is more
a 810-20 million
expenditure.
fuel
gas,
catalysts
will
increase
fuel
gas in a sulfur
recovery unit.
The increase in the amount of H2S to a sulfur recovery
unit is only about 5 to 10 percent.
Sulfur recovery units generally
are
overdesigned
in H2S production
this
process
5-10
to account
units.
is doubtful
It
that
the
unit
capacity
not
catalysts
the
standards
are
tion
would
reasonableness
of
to obtain
catalysts.
a sulfur
in certain
need
to
cases
be added.
standards,
These
demonstrated
developers
reported
recovery
factors
since
do
the
technology.
or licensing
for commercially
recovery
sulfur
however,
developing
costs
Catalyst
that
as best
companies
current
would overload
the
based on scrubbers
catalysts
however,
or a new unit
affect
alone
SO, reduction
available
costs
for
SO, reduc-
the
technology
ranging from $0.60 to g1.60/m3 of fresh feed processed; The fifth year
cost
cost
factors
annual
catalysts
.provided
throughput
containing
by the
for
greater
all
than
is
under
a newer catalyst
the
cost
to
catalyst
affected
0.30
as the
by,multiplying
by the
total
processing
percent
sulfur.
are presented
the
fifth
year
year
to 850 million.
as a range because
The upper
end
developer
of this
catalyst
the
feedstocks
development.
decrease
developers
weight
catalyst
formulation;
calculated
facilities
catalysts
technology
was then
of the
formulation
is
range
the
represents
catalyst
expects
produced
in
greater
quantities.
5.3
ECONOMIC
IMPACT
ANALYSIS
Comment:
Several
IV-D-20)
stated
on the
control
some cases,
economic
new
point
device
ZV-D-1O)
Executive
prices
to the
(IV-D-3,
will
and the
wrote
postpone
impact
not
that
nation's
the
the
economy.
wrote
that
attractiveness
additional
costs
have
cost
Three
of
new investments
the
5-11
(IV-0-15)
Impac~
wrote
of FCCU modifica-
commenters
or other
(TV-D-3,
standards
of FCCU operation
FCCU's.
affect
costs
of a Regulatory
of a scrubber
proposed
and
an adverse
the compliance
on the profitability
IV-D-15,
Four commenters
One conunenter
be feasible.
the
IV-D-10,
would
preparation
Order 12291.
reduce
IV-D-9,
standards
and IV-D-20)
where the
would
IV-D-6,
proposed
high to require
under
current
tions
of
IV-0-15,
sufficiently
that
the
industry
IV-D-9,
Analysis
and
that
refining
(IV-D-6,
are
commenters
would,
SO,
IV-D-9,
in
a significant
and construction
Response:
The cost.analysis
Executive
Since
Order
that
upward.
these
presented
in the proposal
time,
in response
This latest
revisions,
to comments,
cost revision
the
fifthyear
is presented
nationwide
Order 12291.
less
than
The price
0.4 percent.
(OMB).
costs
in Appendix A.
With
costs
a regulatory
are still
impact analysis
increasesublished
Using the
under
these
annualized
revised
~9
in the proposal
control
costs
and
0.8 percent for.the worst case considered (3.5 weight percent sulfur
feedstock).
The EPAstill
The capital
"
i4
required
for
the
control
devices
will
increase
the
investmentfor a newFCCU
by 9 percent for the 8,000m3/sdunit and by
15 percentfor
percentages
that
is otherwise
high
to
economically
deter
a decision
to
install
an FCCU
justified.
Comment:
One commenter
classified
as small
('IV-D-16)
percentage
the discontinuance
the
level
is anticipated
of
small
refining
of concern.
to mean insignificant
should
be exempt
an exemption
businessesbecause
construction
the
suggested
for
that
refineries
in the
of the entitlements
at small
businesses
The commenter
emissions
for
program, very
refineries.
affected
Therefore,
will
be well
seemed to.interpret
and suggested
that
proposal
this
small
below
statement
refineries
reason.
Response:
The EPA does
refineries
to
not consider
the potential
be insignificant,
Scaling
emissions
from small
down emissions
from
EPA's
greater
refineries
that,
than
currently
with
100 Mg SO,/yr.
because
A recent
that
even
of
feedstock,
Therefore,
insignificant
investigation
operate
a low sulfur
has
emissions
would
be
emissions.
revealed
that
14 of the
as small
116 refineries
refiners,
i.e.,
less than 1500 employees and less than 8000 m3/sd crude oil refinery
5-12
-3
throughput.
Analysis
should
be performed
business
sector
will
require
believe
20 per'cent
asignificant
adverse
that,
due
entitlements
program,
very
refineries.
However,
EPA examined
would
have
on
small
impact,
Annual Refining
percentile
little
to the
of the small
economic
discontinuance
construction
the
Flexibility
is
impact
impact.
of the
anticipated
that'the
at
small
regulations
business.
To examinethat
Journal
a Regulatory
if more than
experience
to
that
throughput
EPA selected
Survey,the:
of
the
from
the
1984 Oil
FCCU representing.the
population
of currently
and Gas
low 20th
operating
small
refineries,
~nich was an 950 m3/sd FCCUin a 1,350 m3/sd refinery.
To approximate`the impact on revenue and production costs, EPAused the
control
costs'
in Appendix
BID scaled
down to
19 percent
drop in product
sales
revenue
the
A and the
refinery
amounted
to
revenues
size
with
prices.
less
on page
revenues
one
and
of the
reduced
The compliance
than
9-34
cost
one-half
to
proposal.
reflect
as a percent
of
percent.
The
an FCCU of
15 percent
expect
Therefore,
any
on
unit
to
size
provide
small
EPA does
and smallrefiners.
this
under
scrubber
refineries
not
is
feel
these
to
that
standards
controls.
close
the
as
to
size.
5-i 3
cost
Furthermore,
a result
differential
significantenough
would
justify
an ad'diEPA does
of this
impact
To
action.
between
an exemption
large
based
6.0
6.1
COMPLIANCE
TESTING
AND MONITORING
COMMENTS
GENERAL
Comment:
One commenter
proposed standards
CO incinerator
(JV-D-11)
states
while
pointed
that
SO, testing
velocity
and
for
metric
SO, concentration
flow
correct
rate."
the preamble
flow
rates
The regulation
"shall
be the
The commenter
believed
to the
volumetric
out that
are
determined
indicates
that samp-
regulation
volu-
statement
is
Response:
The EPA agrees
at
the
with
same location
specified
in
the
the
as the
commenter;
SO, testing
volumetric
flow
rate
pointed
out that
should
be performed
measurement,
as is
regulation.
Comment:
One commenter
states
that
sampling
The commenter
manual
(650-7690C).
due
sample
should
stated
sampling
tical
(IV-D-20)
due
that
be conducted
it
to the
frequent
probe
unsafe
high
Additionally,
to
is
flue
upstream
to
gas
train
of the
require
operating
regulation
CO boiler.
personnel
temperatures
sainpl i ng at extreme
sampling
the proposed
at
to
this
temperatures
problems
conduct
location
is
and
imprac-
rapid
failures.
Response:
The EPA recognizes
Sampling
for
the
operator
the
either
upstream
standard
without
add-on
to test
downstream
chooses
calculation
procedures
SO, contribution
or
commenter's
downstream
to and approved
by the
addition,
the
location
downstream
of
th~
CO boiler
safety.
from the
CO boiler
is
for
However,
of the
submitted
to
regarding
controls.
for determining
recommended
concern
the
CO boiler,
the
owner
rate
and the
for
the
inlet
the
standard
prior
must be
to sampling.
GEMS has
with
or
alternative
coke burn-off
Administrator
6-1
if
acceptable
add-on
been
In
changed
controls.
Comment:
Seven
commenters
(IV-D-2,
and IV-D-20)
requested
standards
be
to
menters
to
(IV-D-P)
of
catalyst
(IV-D-3)
also
feed sulfur
lishment
IV-D-6,
performance
establishment
the spent
inclusion
determine
IV-D-3,
periodic
One cormnenter
the
used
(IV-D-2,
conducting
the
IV-D-S,
also
the
during
3-hour
the
compliance
value
test
IV-D-7,
IV-D-9,
to
(S):
feed
monitoring
or sulfur
Another
commenter
by theratio
suggested
sulfur
on
estab-
from the
of actual
feed
or
between
would be derived
(A) to the
suggested
sulfur
(IV-D-16)
com-
emissions.
of a relationship
One commenter
(C) multiplied
report
(weekly)
SO, emissions.
of
and IV-D-20)
excess
IV-D-16,
in the
A number
periodic
between
IV-D-9,
methods
determine
determination
of a trigger-level
test
emissions.
suggested
compliance
excess
tests
and emitted
IV-D-7,
of alternative
a relationship
suggested
IV-D-6,
feed
during
i_g
sulfur
the
T = CA/S.
Response:
The standards
basis.
not
now require
The methods
reasonable
because
(vs.
excess
6.2
WITH
proposed
methods
they
do not
by the
to use
generate
emissions)
ADD-ON
compliance
to
be determined
commenters
for
on a daily
excess
for
determining
compliance
data
sufficiently
accurate
emissions
are
on a daily
for
basis
compliance
determinations.
CONTRO1
DEVICES
Comment:
One commenter
device
should
proposal,
the
used.
be given
which
operation
(JV-K-1)
would
of continuous
inlet
over
recent
highly
most
variable.
content
with
test
the
required
supported
compliance
The commenter
both
to be highly
an inlet
an operator
flexibility
monitoring
is expected
from using
have
that
to choose
using
The commenter
the
the
stated
this
an outlet
monitor
and outlet
by suggesting
that
not
test
if
stated
justify
the
feed
that,
variable,
the
to
where
the
monitor~to
control
an inlet
would
and outlet
of an add-on
only,
and
monitor
are
the
advantages
additional
the
the
operator
cost
FCCU is
feed
not
sulfur
may benefit
demonstrate
compliance
standard.
Another
commenter
for
standard
the
(IV-K-2)
for
add-on
stated
controls,
6-2
that,
during
the
a measurement
compliance
at
both
the
inlet
and the
the
outlet
proposed
provided
is
standards
needed.
However,
after
the
by an outlet
monitor
compliance
service,"
test,
which could
be
alone.
Response:
The standard
reduction
for
or 50 vppm, whichever
monitoring
for
compliance
on a daily
meet
this
status
intent,
tial
problems,
the
90 percent
the
the
of the
inlet
outlet
standard
the
source,
however, that
an inlet
the
compliance
determinations
on controls.
Thus,
or
standard
operators
for
to
determine
basis
controls
tion
change
their
"90 percent
a CEFtS is
as
well
as
choice
compliance
the
intent
to
determinations
would
be subject
to the
or 50 vppm, wt~ichever
is less
add-
the
control
that,
device
for
such
for
so they
for
S02 emissions
out
will
regard
the
recognites,
to meet
point
device.
at
compliance
so that
of the
control
maintained
Therefore,
regulation
by the
and
source
50 vppm standard
outlet
without
or the
outlet
wishes
variable,
The Agency
their
the
scrubber
an incorrect
the
declare
with
for maki~pgcontinuous
the
modified
only
S02 emissions
reduction
installed
to
The Agency
have both
constant.
to
by limitingtheir
a GEMS at
compliance.
being achieved
to
of compliance
standard.
in relation
To
compliance
is not "highly"
may stay
may lead
has
actual
to FCCU-operation
reduction
Agency
proposal.
must
monitor is unnecessary
install
of the outlet
Agency
due
emissions
percent
the
owners or operators,
alert
of
determine
revised
determination
performance
may choose
add-on
to 50 vppm and
simply
to
show the
outlet
for
owners
that
the
may vary
determination
is
in the
data
standard,
is 90 percent
The intent
controls
needs
scrubber
the
add-on
Agency
data.
controls
stringent.
make an accurate
while
only
for
less
as described
concentration
measuring
is
basis,
reduction
feed,
add-on
andto
and outlet
of the
FCCU's using
the
percent
reduc-
inlet
of
whole
standard
stringent,"
the
control
may
on
provided
device
outlet.
Comment:
Several
recommended
the
standard
to indicate
commenters
that
for
the
outlet
add-on
compliance
(IV-D-3,
IV-D-6,
IV-D-9,
CEM requirements
controls
(determine
because
excess
6-3
IV-D-11,
should
GEMS are
emissions).
and LV-D-16)
be eliminated
an
unsuitable
for
means
Three conanenters
inlet
SOx concentrations.
S02 concentration
established
expected to indicate
Therefore,
the
scrubber
ii
outlet
cannot be
standard
over
1V-D-16) cited that the outlet S02 concentration measured during the
performance test of the scrubber and used to define excess emissions is
relatively
meaningless since it would be very difficult
to determine a
" rep r es e nt a t i ve "~fe ed . Two commenters (IV-0-6 and IV-D-9) also stated
that
the outlet
SO2 concentration
as there
exists
a strong
possibility
that
the
because
to indicate
scrubber
of the relationship
feedstocks
level
into
performance
accountthe
pq
--Y
is
variation
between S03 and SO2 over time and over the range of
to be used.
the outlet-monitor
Finally,
that
is necessary
to indicate
scrubber
performance.
Response:
At proposal,
affected
facilities
for
scrubber
trigger
outlet,
outlet
concentration
performance
test.
standard
ance
control
of the
'device.
controls.
or operators
established
based on a
reduction.being
ThereforP,
the
regulation
daily
achieved
compli-
by the
to
who elect
to comply~with
vppm standard,
were determined
emissions
level
determinations
add-on
and excess
as discussed
the
standard
in the
previous
6-4.
comment,
for
add-on
with the 50
is required
to
install
only an outlet
commenters
is
GEM.) Thus,
the
situation
described
stated
that
since
method
of determining
by the
eliminated.
Comment:
One commenter
only
triggers
(IV-D-16)
awareness,
the
specified
adjusting
to
an oxygen-free
basis
an excess
emission
excess
emissions
is
report
and thus,
unnecessary.
Response:
The standards
basis,
rather
than
now requi`re
determination
determination
of excess
determinations
have
determinations
because
a source
is
in
a greater
need
the
former
compliance
for
are
while
the
of compliance,
emissions.
precision
used
latter
has
been
excess
determine
are
Compliance
than
to
on a daily
used
emission
whether
to
or
trigger
Therefore,
not
aware-
the oxygen-free
retained.
Comment:
One commenter
achieves
the
greater
standard
fluid
are
leaks.
dual
commenter
by an initial
as
"less
seal
systems
for
that
test,
this
quarterly
meeting
monitoring
referred
approach~in
include
system
to detect
be determined
monitoring
to
which
a barrier
requirements
compliance
device
compliance
The commenter
~OC monitoring
that
control
technologies
drastic"
an example
proposed
performance
an add-on
than
are reasonable.
This
because
controls,
60,
mechanical
that
in S02 emissions
add-on
for scrubbers
pumps with
felt
reductions
without
requirements
Subpart
(IV-K-9)
instead
of inlet
and out-
let SOx'concentration
monitoring
scrubber
gas
of wet gas
ratios,
ongoing
and
pressure
process
drop,
to
variables,
evaluate
such
scrubber
as
pH, liquid-to-
performance
in an
basis.
Response:
Monitoring
and testing
technique
moni to ri ng a nd t es t i ng .
techniques
has no bearing
monitoring
or testing
example
in Subpart
requirements
are
GGG referred
intent
stringency
selection
requirement
chosen
by the
6-5
be appropriate
or goal
of the
of different
of the
to
commenter
control
most appropriate
technique.
is
not
The
appropriate.
technique;
how well
seals
dual
the
seals,
that
control
the
exemption
usetwo
is doing,
and repair
monitoring
but rather
it
control
control
techniques.
is the control.
technique.
and repair
based on its
The purpose
on each control
of the
baris.
technique
suggested
status
In summary, the
requirements
for
commenter
are
for dual
seals
not give
was
technique.
is determining
data..
can be determined.
information
information
The
on the
opera-
be determined.
scrubbers
standards
Therefore,
but it does
can
these
the
is not a monitoring
to the control
by the
scrubber,
compliance
for
The dual
Therefore,
requirement
appropriateness
of monitoring
compliance on a daily
procedure
The testing
is the
is not to monitor
determined
tion
leak detection
monthly
"exemption"
the
is,
monthly
are
that
appropriate
the monitoring
for determining
continuous
to
support
a change.
by
Comment:
Several
commenters
(IV-D-2,
IV-0-3,
due to monitor
generation
of imprecise
intensive
operator
unreasonable
that
operational
maintenance
data,
excessive
This
of the
commenter
GEMS, stating
inlet
to maintain
commenter
and
ability
his
plugging
knowledge,
run 24 hrs/day
commenter
referred
to
analyzer
IV-K-2
of the
included
the
also
and
full
month
gaps
GEMS data
6-6
of
give
accurate
monitoring
it
about
difficulties
showing
an outlet
is very
gas stream.
concerns
Commenter
in the
be eliminated.
operability
expressed
and
for continuous
potential
have
controls
in a saturated
analyzer.
not
to the
add-on
about
GEMS, stating
one
zero
noted
the requirement
FGD experience
the
EPA does
for
outlet
concerns
Commenter
of an inlet
particulate
and
utility
difficult
Problems
are
requirements.
expressed
that
IV-D-16,
S02 monitors
sample system
IV-D-7,
continuous
problems.
and inaccurate
attention,
IV-D-6,
This
the
oper-
due to
LV-K-2 stated
that
the
results.
that,
device
to
can
Th i s
by a GEMS in each
of
--7i
the
first
10 days
in Figure
C-l
asked
collecting
of the
BlD for
theproposed
how GEMSreliability
and
conditioning
standards.
was proven,
systems
were
used
and what
to
prove
GEMS
reliability.
Res ponse:
The EPA extensively
GEMS during
the
development
of 40 CFR 60.
systems
Current
provide
maintenance
obtain
in
the
rator
the
proposed
are
similar
dioxide
of
some of these
to
Appendix
assurance
F,
GEMS but
Procedure
procedures
The Agency
scrubber
reheat
has,
using inlet
II-A-18A).
flue
gas prior
to the
12 days.
Over
data.
occurred
time
testing
with
regard
60,
which
conducted
tests
rather
just
does
that
not
was on a saturated
monitor.
The duration
no difficulty
of the
saturated
nature
that
with careful
outlet
removal
quality
of the
outlet
flue
gas.
maintenance
monitors
on a saturated
difficulty
is difficult.)
6-7
without
in
was about
obtaining
analyzer
This
system
limited
of the monitors,
can be avoided.
the
item
in the flue
of the testing
problems
that
stream
was experienced
backflushing
directly
gas
state
it
contains
to compare
at
time,
to
insufficient
history
example,
on the ope.cational
for
monitor
suggests
regenerators.
determinations.
inlet
the
acceptable
gas.
this
proven
40 CFR Part
and outlet
regene-
generators;
for
Some regular
due to
to
were
as discussed
to FCCU catalyst
installed
data
steam
technology
information
the
i,
The outlet
of the
valid
been
is necessary
D, FCCU catalyst
of coal-fired
be applicable
and
Experience
Further,
Appendix
S02 monitoring
have
basis.
availability.
to those
operation
of manual attention
standards,
should
monitors
regenerators;
greater
monitoring
when proper
on a continuous
2 hrslday
continuous
state-of-the-art
data
employed
or
the
steam generators
Sulfur
accurate
D, Subpart
show that
approximately
exhausts
therefore,
for
are
an 85 percent
reliability
of Subpart
and
techniques
BID for
the
studies
precise
studied
The difficulty
gas
stream
can be
cannot
be overcome,
but
problem.
In-stack
shields
and improved
filters
outside-stack
with better
conditioning
have been
systems
when necessary.
designed
prevent
systems usually
particulate
plugging
have back-purge
of the
sampling
capabilities
probe
to
in the stack.
Studies have also shown that high pressure (greater than 70 psi) air in
backflushing sample lines and~probes improves removal of particulate
and moisture from the in-stack probes and filters
both upstream and
downstream
of scrubbers.
Manufacturers
of the
systems
and installation
Proper
design
along
will
with consistent
particulate
be able
and proper
maintenance
to obtain
that
an
requirements.
tained
are reliable
and accurate
when properly
promulgated
S02 moni to rs .
24 hrslday
retain
and main-
determining
standards
operated
~%
compliance
the
with these
requirement
sta nda rd s.
for continuous
The EPA does not expect the GEMSto run nonstop for
for an entire
month.
collection
of 18 valid hours of data per day for 22 days out of every
30) provide for downtime. This provides the owner or operator time to
maintain
and
calibrate
the
GEMS and
correct
minor
malfunctions.
Comment:
One commenter
"undeveloped"
(IV-K-2)
continuous
asked
emission
60.106(e)(2)
control
and outlet
device inlet
the
NSPS on an
which requires
to determine
to
kg of SD2/hr values,
while
The "similar
is confusing
GEMS" referred
the proposed
the
reliability
to by the
commenter
standards,
p. 0-13,
6-8
Response:
The commenter
of two different
that
CEMSls.
is in Appendix
is a GEMSthat
is to
obtain
an estimate
latter
estimate
of both
requires
clearly
states
that
serious
questions
measurement
measurement
as to the
this
GEMS, ~hich
that
i s cons i dered
tries
require
standard
1981)
the
the
add-on
demonstrated
as specified
commenter
are
needs
that
control
and
of these
(see Docket
monitors
measurement
of
tries
the
to make is
standard
a format
for
the
add-on
in parts
to the
requires
the
02 or
02 or CO2 CEMS's
for
in this
evaluating
format
In summary, the
Continuous
reliability
and
the
are deemed
inappropriate.
have
is
the
and diluent
specifications
item II-J-2).
that
Rather,
and outlet
Such
60.13
It
add-on
be measured
inlet
systems
in 40 CFR Part
available
burn-off.
monitoring
A-79-09,
for
S02 emissions
performance
BID
kg of coke burn-off,
S02 emissions
device.
and the
estimate;
standards
of coke
The
introduces
resulting
the
burn-off.
12~ parameters
kg S02/1,000
However,
The reliability
acceptability
adequate
of the
C02emissions.
been
accuracy
kg of.coke
many variables
measurement
has
10 to
of this
un rel i ab le .
do not
scrubber
of
to estimate
controls
per million
26,
comparison
emission
accuracy
to
meet
controls.
Comment:
One commenter
downtime
instead
that
(IV-K-3)
and maintenance,
of 22,
such
and 12 hrslday
they
1 year).
According
believe
commenter,
service
added
that
more complex,
and the
of 18.
is reasonably
a GEMSplaced
because
of its
for
15 days
The commenter
performed
GEMSwould be expected
per
GEMS
month
stated
(installed
of a CO boi~e~
exposure
for
upstream
than thatseen
sampling
allowance
successful
is downstream
data
commerci'al- experience
The installation
to the
an increased
as requiring
instead
GEMS installation
than
recommended
a
less
and an ESP.
would be subject
to hot catalyst
to
fines
by a downstream analyzer.
by an upstream
GEMS would
be
factor.
Response:
In requiring
based
data
its
selection
18 hours
of data
compliance,
EPA
in a 24-hour
requirements
for compliance
of
sufficient
information
to characterize
emis-
to the
flue
gas scrubber.
Comnent:
permitted
shut
down for
to be lost
requirements
correction
provide
various
reasons
but limit
beforesupplemental
time
amount of data
sampling is required.
for GEMSmaintenance
of minor malfunctions.
the
and calibration
Malfunctions
These
and
to occur
will
be rarel.y
necessary
sampling;each
owner
samplingscheme,
representing
for supplemental
in the-quality
acceptable
to meet them.
at least
Any
18 hours of operation
daily.
data
Method 8 is unlikely
to be used, however, because it measures SO, when only S02 data need to
be obtained.
to be used.
If Method 6
sample representing
Method 6B, if
used,
would also
a minimum of 18 hours.
6-10
sampling requires
have to collect
If a back-up monitor is
used
instead,
still
then
a minimum of
18 valid
hours
to
obtain
a valid
Method
6 nor
day is
required.
Comment:
One commenter
be usd
(ZV-K-2)
to supply
back-up
for
Method
pointed
data
the
neither
GEMSfails
because:
forbidden
when using
6A and 49 FR 9686
out that
that
when the
problems
9684
believes
for
that
method
6B).
at
(1) Methods
either
Method
68 can
(see
49 FR
The commenter
least
1600C is needed
when
testing.
Response:
The commenter
may be used
data
to
8,
gather
requirements
temperature
which
without
is concerned
supplemental
for the
referred
is
used
to
by the
to
methods
these
possible
missing
poor
that
reliability
operator.
and are
Details
not
with
the commenter's
of the
operator
would be provided
Appendix
F,
Procedure
only
actual
minimum
The 160"0
when using
the
commenter's
standard
concern
been
concerns
addressed
in 49 FR 9684.
the
the
controls.
required
Method
for
about
FCCU's
Methods
tothe
procedure(s)
two methods
to
chosen
Control
sampling
changes
can supplement
means~~availabl~e
in the Quality
about
by the
These
to meet
for Method 8.
have
as reported
is
to 1200C is irrel~vant
identified
add-on
compliance
temperature
methods
in order
for
Thus, the
probe
test
cor~Tienter
in dete~mining
6A and 6B limiting
and
data
standard
add-on controls.
problems
with the
the
made
are
occasional
owner
or
by the owner or
Planirequired
by
1.
Conanent:
One commenter
of the
control
of
GEMS data,
the
(IV-K-2)
device
The commenter
operator
from "bunching
taking
minimum
be calculated
rather
period.
suggested
than
felt
all
this
up" valid
measurements
that
using
the
of the
should
6-11
hours
daily
within
be done in order
GEMSdata
on "bad"
individual
days.
points
performance
the
averages
7-day
to prevent
an
Response:
The deliberate
de'scribed
by the
actions
be seen as an attempt
to
60.
Further,
collect
18 valid
requirements
(i.e.,
requirement
limit
to
the potential
.s
determining
has retained
it
necessary
daily
the
to change
compliance
averaging
when using
of all
valid
the
add-on
-;I
data
controls
and
hours.
Ijij
Comment:
One commenter
averaging
rolling
daily
that
percent
average
separately.
(IV-K-2)
suggested
reduction
rather
inlet
and outlet
in making this
was analyzed
values
than averaging
The commenter,
reduction
that
that
provides
a more stringent
both averaging
the
data
suggestion,
pointed
in terms
of percent
averaging
percent
emission
7-day
out
values
r~
emission
standard.
Response:
valuesand
the
averaging
7-day
rolling
inlet
and outlet
average.
daily
data
Calculating
percent
separately
a daily
reduction
when calculating
average
of hourly
for
inlet
time
or
a minimum of 18 hrs/day
and outlet
that
either
monitors
are
data
separately
monitor
to obtain
allows
rolling
methodsdescribed
(see
calculation
is insufficient
the
opposite
day.
Averaging
more leeway
before
back-up
in the
measurements
ir3
needed.
calculated
analysis
a little
is not functioning
a valid
r9
by the
7-day percent
commenter
Docket A-79-09,
provided
by the
as the
for
the
item IV-B-13).
commenter
to
result.
6-12
data
value
used
using
in the
In addition,
show a I'more
construct
the
time
the
stringent"
two
series
example
standard
an example showing
_:5
In summary,
data
separately
does
so with
operators
the
Agency
believes
adequately
the
the
and accurately
potential
of cost
by decreasing
averaging
the
need
inlet
determines
savings
for
of
to
using
and outlet
compliance,
affected
back-up
owners
and
and
measurement
methods.
Comment:
Two commenters
reported
by EPA.
collecting
and
were
included
cost
of 840,000
D-l gives
asked
One commenter
conditioning
in the
in
a cost
whether
the
of the
preamble
the
Agency
updated
(IV-K-9)
mated
GEMS.
costs
(analyzer,
of
sampling
per
8175,000
per analyzer
816,000
stack
the
system.
the
This
for
for
monitoring
minated
commenter
additional
monitor
appears
the
because
inlet
of
the
sampling
the
proposed
of
the
proposal.
the
82,000
coot
8150,000
to
This commenter
to
be about
for an across-the-
that
the
to reflect
and
total
would be about
costs
stated
and
underesti-
that
system,
system
estimate
only
the
installation
requirement
and outlet~to~
cost
questioned
GEMS
original
costs)
that
the
estimated
also
felt
a reliable
maintenance
the
sample
(1981 dollars),
from
for an across-the-stack
and not
at
costs
the
of CEMS's
to 880,000
an extractive
annual
costs
commenter
additional
commenter
analyzer
ensure
This
The second
the
commenter
felt
to
and installation
for an extractive
840,000
of
analyzer
estimated
the
the
This
system,
8100,000
also
GEMS.
for
the
asked whether
needed
of a GEMSas $59,000
(IV-K-2)
systems
price
questioned
for
add;on~control
of
cost
costs.
continuous
~devices
be eli-
revised
proposal
CEMS's.
Response:
The cost
notice
reflected
tin
February
for
the
additional
the
cost
of an extractive
analyzer
system
of 869,300
data
by contacting
(see
Docket
also
A-79-09,
for
item
IV-A-1).
an S02/diluent
installation
original
a revised
installation
1981 costs
fourth
and data
quarter
acquisi-
DAS).
attempted
and source
and
the
and obtained
the
the
analyzer
(including
without
recently
vendors
in
(DAS); 846,200
The Agency
costs
GEMS reported
1981 dollars).
estimate
system
vendor
the
extractive
1984 cost
tion
of
to
obtain
ownersor
The study
extractive
updated
operators
found
system
GEMS cost
using
GEMS
"worst-case"
from 943,000
to
8100,000
costs
(1984 dollars).
for
longer
backflush
are
sample
systems,
generating
lines,
worst-case
costs
for
%180,000 (including
an extractive
815,400
data
reports.)
an S02/N0,/diluent
costs
i.ncluded
corrosion-resistant
and computer
emissions
far
(The worst-case
GEMS) ranged
an extractive
probes,
acquisition
Worst-case
systems
from 82,000
analyzer
to 886,000.
system,
costs
of
(which
to 980,000.
Total
including
The commenter
probe
capable
installation
analyzer
additional
installation,
provides
costs
ranged
an estimate
to
for
from
of about
8100,000
falls
in the middle-to-upper
that
its
when updated
costs
range
original
estimate
to 1984 dollars,
reported
in the
still
updated
costs.
I~
for an extractive
falls
within
the worst-
study.
outlet
added a cost
for
of 820,000
cost,including
(February
dollars
a cost
a nd i ns tal la t i o n .
of about
costs
Best-case
without
condition
analyzer
(834,000
815,000
installation).
for the
Commenters
in the upper
The annual
proposal
the-stack
maintenance
BID Appendix
GEMS.
thecommenter's
range
estimate
896,000,
analyzer
plus
(analyzer,
GEMS
installation
estimated
cost
of 816,000
for
results
for
to 8153,000.
to 860,000
a DAS, plus
costs
sampling,
of the worst-case
costs
the
DAS,
more
with
to be 834,400
IV-K-9 estimated
D were 811,000
Updating
1984
880,400
quarter
for an S02/diluent
were estimated
to 945,000
Total
costs
a DAS.
GEMSgathered
fromB44,000-to
892,900
Agency
was, thus,
cost to fourth
vendor estimates
a DAS) to range
for
monitor
Data on across-the-stack
show worst-case
(including
outlet
Updating this
estimate
to which the
and 820,000
for the
1981 dollars).
system
installation
installation,
yields
recently
monitoring
either
is
of about
estimates.
Agency
in the
an extractive
an estimate
an extractive
8400 to
and installation),
vendor
by the
per
or across-
similar
to
system and is
more
conservative
than
the
commenter's
estimate
for
an across-the-stack
system.
6.3
Comment:
Several
that
commenters
commenter
(IV-Kd)
and analyze
daily
traversing
system
3-person
would
is
used,
estimated
for
checks,
crew
operation
would
in part,
that
analyzed
at 15 minutes
rates
to
that
daily
Method
for
the
8 sampling,
and analysis
management.
annual
would
that
cost
3 technicians
the
have
cost
commenter
8 to
did
"reasonable"
not yet
of effort
be
not
would
think
developed.
and implemented.
it
costs
an automatic
This
preparing
FCCU.
an automatic traversing
and
asked
the
are
to
claim
based,
also
in part,
based
traversing
noted
Commenter
system
that
reports
the
the
total
believes
cost
on
'(at 858,800/yr).
yearly
unknown?
the
costs
costs
The
to
on a traversing
asked the
cost
the
commenter
estimates
to be 8 hours
that
This
la~or
be about
for
and 1 professional
system.
commenter
would
12 hours
1V-K-6
hours
reasonable
are
labor
per
when
was
This commenter
daily
be required
The commenter
of revised
that
(IV-K-2)
"reasonable"
when the
an automatic
assumption
8184,000
the
used~'vendor
estimated
trains,
that
estimated
Commenter
IV-K-12
teach at B41,600/yr)
Another
commenter
Commenter
stated
would be required
estimated
which
of the
$250,000jyr.
a contractor,
and
a full-time
also
This commenter
using
manually.
crew,
1V-K-3
This
no automatic
require
commenter
charges.
apiece
be about
4 man-years
Method
labor
assumes
testing
to be about
samples
to collect
and maintenance
This
per sample.
estimate
and project
stack
One
9300,000/yr.
would
Commenter
sixteen
labor
is accomplished
repair,
cost
for
cost
sampling
etc.
This commenter
sampling
this
stated
Method 8 testing.
expense
testing
be necessary.
assumed,
hour
that
daily
analyses,
and IV-K-12)
would be about
testing,
and maintenance
$400,000/yr.
annual
but all
that
IV-K-6,
of daily
and 2 assistants)
be responsible
back-up
that
indicates
(supervisor
calibration
costs
Method 8 samples
specifically
The commenter
IV-K-4,
the
believes
commenter
of
(IV-K-3,
be
system
Agency to identify
adding
questioned
be readily
equipment
EPA's
developed
such
as
and
Another
testing
degrade
on-stream
commenter
requirement
mance of this
test
exists,
connmenter,
future
is
of the
stack
stated
that
the daily
out that
speculative
because
development
protocols
determination
no means of automated
it must be performed
and unfounded
testing
may be
manual stack
pointing
system
factor.
(IV-K-4)
is premature,
to this
traversing
manually.
of an automatic
given
perfor-
Accordi ng
traversing
the technical
complexity
involved.
Response:
The standard
year.
requires
one 3-hour
sample
per day,
explicitly
assumption.
After
commenters
that
further
the
assumption
evaluating
the
the
other
consideration,
commenters
the
contends that
it
the
made the
of an automatic
and recommending
that
traversing
daily
with
system
the
should
Method 8 testing,
is technologically
cost
same
estimate
feasible.
assuming
that
monorail
systemwill be instal;edat eachof the twosampling
pens
and that
the
a single
sampling
item
IV-B-12).
that
it
area
to protect
tions,
sampling
train
for
will
traversing
Although
be used,
and changing
not addressed
was appropriate
the
train
to also
sampler
by the
include
from
and enclosure
is estimated
estimated
cost
the
two sampling
using
trains,
is used,
(see
for
of
Docket A-79-09,
EPA decided
an enclosed
various
weather
sampling
condi-
With the
system,
we assumed
revised
assumptions,
only
one sampling
this
would be devoted
sample
is
average
sampling,
required
of 8labor
each
to this
day.
hours
and perform
full-time
per
periodic
claim
stack
testing.
The Agency
believes
day to
prepare
maintenance
6-16
i4
traversing
ports
movement
to be 820,000.
an automated
manual
commenters,
a cost
and equipment
with
the
that
to the
next;
i.l
3 or more people
it
equipment,
on spare
would
take
conduct
equipment,
with
an
the
an
-
added
labor
for
analysis
of
for
the
each
This
strongly
Commenter
the
that
to prepare.
The Agency
of
sample
quarterly
is
equivalent
per
sample.
This
by Commenter
reports
estimate
to
less
than
the
12 hour
of
the
above
per
affected
1V-K-3.
would take
with
basis
cost
hours
points,
the
On the
annualized
1.3
disagrees
IV-K-6.
revised
to that
number
Agency estimated
about
about 50 hours
one
per
hour
day
is
per
day.
estimate
assumptions
facility
The
used
by
and revisions,
estimated
to
be
8120,000.
Comment:
Many commenters
and IV-K-8)
standard
tha't
stated
for
daily
that
FCCU's
testing
according
(IV-K-1,
daily
without
for
1V-K-3,
testing
should
add-on
to one commenter
monitoring
IV-K-2,
scrubber
or
One commenter
(IV-K-3)
stated
which this
basis
type
to satisfy
stated
that,
in general,
be required
burden
compliance
if,
occurs.
in
the
FCCU's, as the
Commenter
costs
impose
are
IV-K-1
that
feed
states
the
hydrotreat
information
it,
of
option.
instance`
in
on a daily
not
an unreasonable
that
a disproportionate
that
especially,
performed
This
of obtaining
also
the
is being
independent-of:
stated
felt
he knew of no other
compliance
course
will
under
requirements.
direct
commenters
sampling
CorrPTienter IV-K-3
Method 8 testing
The
IV-K-6,
from the
testing
of non-routine
IV-K-5,
be deleted
controls.
(1V-K-4),
the
IV-K-4,
the
cost
hardship
cost
of'daily
on small
unitsize.
cost
of daily
Method
8 testing
that
burden
the
estimated
cost
on FCCU operators
cat al ysts
of 8130,000/yr
who choose
would
to develop
put
an onerous
A third
significant
commenter
(lV-K-6)
This commenter
noted
that
the
stated
that
profitability
the corporation
the
economic
impact
is
of FCCU operation.
operates
9 FCCU's and
daily
Method
8 testing.
6-17
to
Response:
The Agency
recognizes
inexpensive,
but that
has examined
various
the
standards.
to meet
the
testing
is
Agency
daily
is
be sure
the
just
that
Agency
the
control
8 is
cost.
determined
alternative
or
operator
not
The Agency
compliance
owner
cost
costs
of
relative
options
costs
are
reasonable
requiring
with
catalysts
that
daily
Method
that
enables
the
i~s in compliance
or
eliminating
on a
will
economic
impact
reported
and
standards
large)
refiner
should
petroleum
of the
the
controls.
of
on small
facility
of other
a valid
is
needed
situations
basis
for
for
this
being
standard
FCCU's
the
without
that
are
with
the
economic
add-on
impacts
to affect
6-18
notice
of the
costs
be
These
affected
which
FCCU's
of complying
will
of the
refined
controls,
for
to
land
reasonable.
projected
standard
the monitoring
unlikely
is
add-on
controls
and
if not all,
prices
impact
FCCU's with
potential
to the small
most,
by all
the
proposal
impact
price
compliance
of FOOD
refineries
original
in the
compliance
for
large
because
included
or "onerous,"
profitability
and
in the
resulting
standard
is "unreasonable"
The economic
assuming
than
Method B testing
not
What
etc.)
an affected
The Agencystudied
to be small
Therefore,
for
is
or the
findings
and the
the
various
monitoring,
lack
burden
affected.
standards
be capable
expensive
standard
the
(49 FR 2072).
with
more
add-on
be adversely
obtained
for
testing
is "significant,"
products
facilities
that
is expected
were
Daily
of the
standards
to
annual,
sampling
subject
compliance.
discussed
these
facilities
Similarly,the
requirement.
excluding
the
determining
investment
(capital,
unreasonable.
impact
affected
capital
total
for
for rejecting
for
meeting
basis
"non-routine"
this
methods
to all
of the
the
for
similar
results
various
not a basis
is whether
of compliance
cost
the
is not a valid
is relevant
daily
Method
to show daily
viable
compliance available
as the
the
available
only
with
not an unreasonable
that
the
testing
basis.
the standards
is
also
methods
currently
continuous
the
daily
For facilities
The relative
is
it
standards,
to
that
without
with
smaller
associated
SO, reduction
with
catalyst
I:i
development.
catalysts
are still
likely to be the least expensive route to meeting
the standard.
Thus, development on SO, reduction catalysts
will still
continue
these
as owners or operators
costs
in meeting
standards.
Method 8 testing
are highly
unlikely
is 8400,000
to occur
because:
both
all
FCCU's
(e.g., such as those with very high sulfur feed contents) to use SO,
reduction
catalysts
overestimates
the
cost
of
is reasonable
methods that
compliance
approval
Comment
allow
the
determinations
of the
that
compliance.
are encouraged
Less expen-
accurate
daily
to the
Administrator.
basis
stack testing.
using
to justify
such.an
According to this
either
Method
8 or
of frequency
and is
inequitable
options.
In
addition,
the
presented
to support
necessitate
Another
testing
using
The commenter
Method
to refiners
commenter
that
(1V-K-5)
Method 8 for
provided
the
opposed
reasons
runs counter
to the
tivity
of the
American
various
that
no
in terms
control.
data
have
been
basis.
the
as the
effort
workforce.
6-19
daily
reduction
basis
for
his
manual
catalysts.
remarks:
requirement;
national
proposed
sulfur
as daily
unreasonable
using
emissions
FCCU's using
three
6 is
remarked
on a daily
commenter
requirement
commenter, daily
a modified
a thesis
monitoring
extraordinary
requirement
to increase
the produc-
as to
Response:
These standards
require
an owner or operator
to determine
compli-
is the
goal.
the
accomplish
one 3-hour
test
reduce
the
labor
strongly
disagrees
that
the
frequency
but still
of the testing
is either
unreasonable or inequitable,
standard
or
for
add-on
controls
alsd required
to make daily
industry
example,
(for
for
low-sulfur
determinations.
content
feeds
are
item
-"
sampling to
burden,
this
IV-K-8)
that
by
show wide
variation
in SO, emissions from FCCU's using SO, reduction catalysts.
Even if this variation does not vary "so widely," an FCCUoperating
right
at
the
emission
limit
may go above
small variation.
Thus, daily
out that
tion
catalysts
determination
testing
and
approval,
to change.
can
effort
see
labor
no merit
to
increase
perform
the
for ensuring
to
the
determined
the
the
a cleaner
comment
testing
productivity
of
that
cost
That the
to
runs
counter
the
American
the
cost
be reasonable.
Thus,
testing
the
Agency
and employment
to the
work
approach
environment.
such
may
to
are appropriate.
to Method 8 testing
is unlikely
has
due
alternatives
is irrelevant.
limit
determinations
as additional
of compliance
daily
emission
is labor-intensive
of the
compliance
are generated,
become available
the
national
effort
of
to
force.
Comment:
One commenter(IV-Kd)
contractor
believed
manpower exists
that
to conduct
the
insufficient
qualified
Method 8 compliance
sampling.
Response:
The EPA assumed
the
Method
8 compliance
that
in-house
sampling.
personnel
would
6-20
be used
there
to
is
conduct
sufficient
lead
on
time
to train
contractor
such
personnel
without
requiring
or solely
relying
manpower.
Comment:
One commenter
(1V-D-16)
stated
that
the
proposed
regulation
does
Section
60.106,
"Test
to determine
total
SO,
emissions.
Response:
The EPA agrees
been revised
specified
with
the commenter.
to indicate
in Reference
SO, emissions
that
Therefore,
modification
Method 8 will
the
to the
be required
regulation
calculation
has
procedures
to calculate
total
as SOE.
Comment:
One commenter
Table C-14 of the
proposal
(IV-0-16)
proposal
BID states,
for the
values
in reference
in Table
C-14,
to the
0.1.3.2
field
"S03 could
could
be presented
in
tests
providing
not be determined
the
in the
data
field
Response:
The remaining
of the
proposal
were later
BID states
analyzed
The emission
"Sulfur
portion
that
statement
made
in Section
sulfate
in a laboratory
summaries
Trioxide"
of the
in Table
included
all
0.1.3.2
samples
by ion chromatographic
C-14 of
the
proposal
sulfates~'collected
analysis.
BJD labeled
in the
isopropanol
next
water
comment).
soluble
The emissions
probe
and
h~~~ed
all
and
the
in the
included
as
of
collected
"Sulfates"
filter,
analysis
sulfates
labeled
leachate.
Comment:
One commenter
acid
mist
and
(IV-D-16)
sulfur
trioxide
asked
can
if
be
separate
values
for
sulfuric
determined.
Response:
for
these
technique
two species.
6-21
to determine
separate
Comment:
alternatives
continuous
to daily
compliance.
Method 8 testing
The commenters
for
suggested
three
testing,
Method 8
and (3) the use of continuous S02 monitors with periodic testing for
-"
SO3. One commenter (1V-K-8) stated, in general, that the daily application of Method 8 is cumbersome, and thus, the proposed rule should
contain
provisions
to allow
compli~ance based
on a broader
Qermitteeto
spectrum
demonstrate
of options.
for flexibility
or operating
encourage better
with
strategy;
process
regard
to future
understanding
within
continuous
This commenter
the
improvements
language
the regulated
in
would
community;
II
and (3) exclusion of such a provision would require that future changes
be made through
formal
rulemaking.
testing
for~continuous
as frequently
if
emission
tests
compliance
as proposed.
a week of daily
limit,
Method
then
on consecutive
commenter pointed
more frequently
Thi~s commenter
8 testing
the testing
shows
suggested,
that
frequency
out that
the tests
than necessary
no test
should
for
is
over
be relaxed
or semi-annually,
and that
example,
a history
the
to seven
The
to be performed
of testing
by Method 8 is notnecessary
that
data may
if there are no
upsets.
testing
asdetermined
on a case-by-case
recommendation
SO, monitc:
dnd develop
commenter provided
to annual
Conenter
testing)
performance
literature
(1V-K-4)
1V-K-5 suggested
that
standards
on an S02 monitor
basis
EPA specify
for
until
las a second
a continuous
such a monitor.
that
This
they thought
less
frequent
experience
compliance
with
was sufficient
FCCU catalysts
from an FCCUthat
gradual
testing
indicates
can achieve
to allow
the
less
should
that
the proposed
frequent
be used until
because
changes
that
general
in emission
standards
compliance
their
rates
are sufficiently
testing.
Another
some alternative
to the SO,
to be practical
in
service.
compli ance,
of periodic
with
(e.g.,
feedstock
the multipl
biannual)
that
i er determined
measurements
the periodic
and operating
tests
using
could
conditions
be run at repre-
to ensure
a fair
estimate
commenter
determinations
periodic
are
comparisons
(IV-K-12)
required,
the
recommended,
compliance
of performance
if daily
between the
suggestion
on the
basis
with
GEMSand Method 8.
of:
(1) their
belief
describe
the variability
and scattered;
the
in the
requirement
insignificant;
ratio
for daily
FCCU regenerator
is operated
testing
is based,
in a complete
are
limited
to occur when
combustion
mode without
to maximum concentrations
at one of their
mode without
between
tion
sulfur;
sulfur
if SO, reduction
(4) a summary provided
FCCU's operating
reduction
additive
per million
their
conclusion
that
additive
is not
by them of emission
in the complete
shows
method,
reasonably
good
regenerator
agreement
FCCUtest
combustion
results
flue'gases
of total
provided by them
on units
not
of S03,
6-23
on the
SO.2 monitor
modified Method 6.
be determined
periodically
occurs
by a Method 8 or
continuous basis.
This commenter pointed out that
them indicates that approximately 10 to 20 percent
sulfur
I'
data provided by
of the flue gas
as SO3.
Response:
The Agency has considered
the alternatives
suggested
by the
comme
nte rs i The Agency agrees that any test should not be performed
more frequently than necessary and that a history of test data may
show that
daily testing
is unnecessary.
:~~
i;i!
of
monitoring
or testing
schemessuggestedcan be implemented
at this time and ensure that
accurate
continuous
commenters
did
compliance
not provide
determinations
much data
are made.
to support
their
Further,
arguments,
the
and
above,
one of the
commenters
provided
:II~
literature
on an
monitors
for their
examined
ability
to monitor SO,.
has proven
that
suitable.
many of these
alternatives
Therefore,
the standard
alternatives
supported
case basis.
ratio,
product
temperature),
catalyst
The development
explicitly
may be shown
thdt
such
feed variability,
operationdl variability
alternative,
by sufficient
To date,
frequency
of product
slate
changes,
of a successful
upon approval
schedules,
SO, monitor
by the
Administrator,
conditions.
be an accepta~,~
to Method 8 testing.
In the meantime, however, ~the Agency has retained daily Method 8 testing
for determining compliance on a continuous basis for the FCCUwithout
add-on
control
standard.
6-24
?[.~
Comment:
will
without
provide
add-on
controls
Response:
As discussed
continues
tant
a means of determining
at
a more
in Section
to believe
that
2.2,
reasonable
cost
"Regulated
Pollutant,"
SO, is the
without
do not measure
SO3, they
cannot
detenninations
compliance
than
Method
controls.
regulated
po~lu-
As SOE monitors
be used to provide
catalysts
8.
the Agency
most appropriate
add-on
for FCCU's
continuous
compliance
Comment:
monitoring
requirement
FCCU's without
tions
add-on
commenters
argued
considerably
should
controls
indication
that
unsuitable
that
for the
FCCU outlet
SO, emission
in subsequent
the
the continuous
be eliminated
of the
during
stated
because
variables
from those
concentrations
and IV-D-9)
S02 concentra-
rate.
The
operations
performance
test,
standard
can differ
making outlet
as a gauge of compliance.
Response:
As originally
reasonable
catalysts,
however,
that
determination
sions
(i.e.,
such an excess
of compliance
daily testing
Comment:
emission
relevant
using
as the most
is no longer
daily
S02 monitoring
emissions
S02 concentration
of SO, emissions
concern,
excess
recognizing
on FCCU outlet
cation
EPA considered
means of determining
reduction
based
proposed,
SO,
level
a precise
indi-
This particular
as the
standard
now requires
direct
measurements
of SO, emis-
in the
flue
Method 8 requires
gas to the
"the
absence
outlet
(IV-K-2)
gases.
of other
this
the
whether
also
particu!ate
matter?"
asked in a later
revised
from particulates
commenter questioned
This commenter
to interference
scrubber,
propo2ed
as is Method 8.
testing
of revised
6-25
comment letter
In addition,
proposed
the
Method 8 has
interference,
repeatability
by
testers,
precision, and accuracy.
EPA has failed to recognize
possible
ulate
interfering
control
believes
refiners
of either
adjust
are likely
standard.
injection
associated
that
particulate
effects
particle
ammonia
that,
amine
interfering
effects
and quantify
methodology
the presence
the
in the
_i
more developmental
interfering
EPA adopts
effects
a specific
test
purposes.
of "other
results.
regulation
particulate
Therefore,
to permit
matter"
appropriate
the
insertion
of a
heated filter
and probe in the sampling train, prior to the impingers.
The heated probe and filter will prevent the particulate
matter from
getting
at least
99.95
Method 5.
percent
There
efficient,
the
analysis
of particulates
would be required
as required
is no indication
Filters
still
in Section
or reason
to suspect
problem.
exist,
then
these
alternative
by the
standards
of
filters
analytical
tech-
Administrator.
are
interference
that
3.1.1
If analytical
to specifically
testing
address
of Method 8 as modified
the
commenter's
under
concerns.
reason,
however,
fications
subpart
would adversely
reproducibility,
precision,
oraccuracy
of Method 8.
In
procedures
for minimizing
the
repeatability,
addition,
sulfate
tive
EPA is currently
interference
of measuring
same equipment
developing
in particulate
both
particulate
and analytical
test
mattermeasurements.
matter
techniques
6-26
and
will
sulfur
the
The alternaoxides
be addressed
-4
ESP to
in SO, determinations
these
before
into
to EPA, the
according
test
The commenter
or an "enhanced"
resistivity
SO, emission
measurement.
on the
test
for pa~tic-
with
at
that
the
time.
the
ference
problems
and/or
that
interference
and are
with respect
are
a~ternative-'
currently
techniques
studying
to ammonia.
Thus,
on
to
potential
in cases
effects
inter-
where ammonia
problems,
the
owner
methods.
Comment:
One commenter
using
Reference
(IV-K-6)
Method 8 is
analyzer,
even though
S02 ratio
in the stack
could
the
gas.
SOx emissions
the collection
than
of a grab sample
a continuous
to obtaining
standardsspecified
in the
operator
the
that
the
course
ratio
that
in the
stack
that
the
evidence
operators
will
for the
commenter's
valid
operating
actions
on the
results
clearly
part
tosampling.
of an owner or operator
constitute
a circumvention
S02 to SO3
samples
will
prior
SOx through
in the
each day.
variation
obtain
of
would be
in total
representative
not alter
sample.
the measurement
catalysts
the variation
than
SOg to
could
daily
on-line
where an unscrupulous
conditions
proposed
that
reliable
could
results
operating
Response:
The revised
less
there
give unrealistic
adjust
stated
remarks.
that
are
and, therefore,
Such deliberate
to obtain
unrealistic
of the standard
and is
illegal
under Subpart A, the General Provisions (40 CFR Section 60.12).
Inspection of plant operating data by EPA and State personnel would
lead
to
detection
of
such
alteration
of
plant
operation.
Comment:
One commenter
the
appropriate
revised
(IV-K-2)
temperature
Method tl.
questioned
for the
The commenter
whether
heated
based his
1600C (320"F)
on the
is
in the
following
as se rt io ns :
(a)
The commenter
believed
be above this
value,
that
especially
6-27
more than
sulfur
in the feed,
acid
filter
will
in the
to yield
(b)
heated
correct
and collecting
revised
sulfuric
:j
Method 8
results.
seems to be recreating
an earlier
problem.
(c)
that
this
modification
is reached
if
the
stack
temperature
is hotter,
or if
it
I:i
is
of the temperature
i::ii
that
up only a small
this
part
problem
of the
provided
1600C
The commenter's
The materials
filter
Further,
holders
the
3-hour test)
required
that,
to underestimate
the
is
mist,
the
filter
and the
would
rest
--3
in the impingers.
in such situations,
emissions,
third
assertion
but believes
and filter
foy cleaning.
periodic
is
and stainless
to conduct
acid
because
a potential
that
it
is small
maintained.
used (glass
probes
sulfuric
and be collected
is small
neither
steel)
to corrosion
holder
checks.
6-28
nor
correct,
from sulfuric
acid.
In addition,
leak
relevant
FCCUoperators
If
leaks
are
the
would be
detected
in
the
system,
need
to
regard
the
will
system
fails,
stack
temperature
if
then
standpoint
pass
- and thus
the
system would
is
hotter,
the
filter
from the
there
is
no temperature
adjustment
and a temperature
is common practice
desired
di~fferent
through
It
the
being
temperature
impingers
made.
the
stack
at the probe.
the
to
temperature,
problem
in
sampling
be repaired.
With
probe
OP if the
be trapped
has
to
be made
is colder,
less
adjustment
to electrically
heat
no
has
the probe
SOx
to
be
to attain
temperature.
Finally,
operating
with
regard
procedures,
requires
that
collected
the
sample
eliminates
to plugging
sampling
probe
conducted
be cleaned
be discarded
the potential
of the
from
problem
probe,
using
out
after
the
analysis.
brought
as part
revised
each
Method
run
This
up by the
of normal
8
and that
the
procedure
commenter.
Comment:
One commenter
deleted
from
(IV-K-2)
Method
asked
why the
isopropanol
impinger
was
8.
Response:
Method 8 was designed
measurement of sulfuric
is used to collect
peroxide
the
hydrogen
peroxide
emissions.
capture
the
In the
will
standards
hydrogen
absence
collect
all
of the
catalysts
EPA eliminated
the
IPA impinger
is to simplify
the
test
analysis,
calculations.
IPA
the SO,
Therefore,
of which
and
(IPA) impinger
is no need to separate
effect
6.4
separate
SO,; there
Method 8, the
and
the
The isopropanol
impinger
The current
based on total
sulfur
acid
is used to collect
compounds together.
are
for
sulfuric
impinger
impinger,
primarily
procedure,
Comment:
One commenter
sulfur
too
that
at
expensive
to
such testing
previously
for
FCCU's
(IV-K-1O)
using
the
that
the cost
alternative
be performed
should
felt
more
feed
often
be required
found to contain
than
of testing
sulfur
is
cut-off
necessary
a week.
6-29
sulfur
the
feed
standard
is
and suggested
feed is
in every
sample
Response :
For these
standards,
are required
FCCU fresh
on adail_y basis).
most refiners
Fresh
feed
Requiring
sulfur
samples
to
manually sample
content,
to
however,
be collected
once
This
sulfur
frequency
would measure
practices.
The sampling
major
fluctuations
considering
current
program suggested
by the
refinery
on a daily
not
of
a good
indicator
future
basis.
use;
Furthermore,
many refiners
feed
sampling
in fresh
use
is in fact
past feed usage is
different
feeds
this
alternative
standard.
6-30
r"
7.0
7.1
SOURCE OPERATION
COMPLIANCE
COMMENTS
DURING MALFUNCTIONS
Comment:
that
allow
a certain
requiring
a FCCU shutdown.
that
amount
of
EPA consider
scrubber
establishing
downtime
without
Response:
The General
Provisions
control
equipment.
failure
of air
process
to operate
caused
any
other
scrubbers
this
levels
standards
Thus,
for
of
it
scrubber
usual
sudden
and
process
manner.
are
emissions
equipment,
of the
are
operation,
considered
of
or of a
that
careless
in excess
(discussed
is unnecessary
a standard
due
standard.
to
In addi-
re~i-
in Section
to provide
or
malfunctions.
95 percent
of
unavoidable
Failures
not
a violation
applied
in excess
document).
or
represent
currently
equipment,
condition,
60.8(c),
do not
only
for malfunction
by poor maintenance,
upset
Section
a malfunction
ability
in a normal
or in part
in
means
control
preventable
As stated
tion,
"Malfunction"
pollution
entirely
in 40 CFR 60 provide
3.1
aprovision
of
in the
downtime.
Comment:
One commenter
to continue
(IV-D-16)
operating
asked
duriny
if
the
continuous
affected
facility
emissionmonitor
is
allowed
malfunctions.
Response:
An affected
emission
monitor
60.7(b)
shall
facility
malfunctions.
and (c)(3)
maintain
toring
However,
of any
or monitoring
(or semiannual,
periods
device
is
if no exceedances
report
shall
tifying
each period
during
which the
system
properly
except
repairs
operate
or
for
zero
adjustments.
or maintain
which
inoperative,
include
and span
It
continuous
should
a continuous
7-1
under 40 CFR
a continuous
and the
moni-
quarterly
during a particular
the date
checks,
continuous
have occurred
compliance
during
as prescribed
during
quarter)
inoperative,
to operate
records
system
may continue
and time
monitoring
and the
be noted
monitoring
idensystem was
nature
that
failure
of the
to
system would be
considered
as a violation
rather
than
a malfunction
and 60.13).
7.2
Comment:
One commenter
requirement
that
(1V-D-3)
stated
that
EPA should
delete
the
to reduce
and rejoin
with
the
scrubbed
exhaust
portion
a smaller
gas could
further
scrubber
bypass
downstream.
the
scrubber
A refiner
capacity
to
meet the 9.8 kg 50,/1,000 kg coke burn-off level of the standard for
FCCU's without
add-on
controls.
A smaller
scrubber
-7
capital and annual operating costs, energy savings, eliminate the need
'"
for
reheat,
and
improve
nonair
environmental
benefits.
Response:
The 90 percent
scrubbers,
which
stream.
can
A relaxation
would cause
7.3
standard
it
is
achieve
intended
90 percent
of the standard
no longer
to reflect
to reflect
control
the capability
of the
ent'ire
to 9.8 kg S0,/1,000
the
capability
of
exhaust
kg coke burn-off
of scrubbers.
Comment:
Rather,
the
commenter stated
one compliance
time selected
test
to another.
for each
is sufficient.
Response:
This comment is no longer
daily determinations
test (by definition)
applicable
operator
standards
now require
of compliance.
Under the standards,
a compliance
is required every day regardless of the standard
as the
has been
previously
Four commenters
(IV-D-2,
seeks
subject.
Comment:
the
90-day
to another
notification
should
prior
be modified
IV-D-6,
IV-D-16,
to changing
to allow
7-2
for
that
change
in
emergency
ca ses .
as an emergency
to
the
commenters,
different
add-on
in
standard
controls
of a hydrotreater
such
(e.g.,
to
the
cases
a refiner
would
change
from the
standard
feed
sulfur
such
want
Acco rd i ng
to comply
with
for FCCU's.without
cutoff)inediately,
rather
than
;urrail FCCU
processing
until the shut-down
controlunit is repaired.
Two of these
notification
commenters
compliance
of thechange
all
removed
records
appropriate
only
a refiner
annual)
for
to demonstrate
required
when an owner-or
to90
is alsd
requiredin
is sub~ect'may
compliance
EPA agrees
prior
no prior
to
inwriting
in writing
whenever
reduction
with
determinations
with
notification
compliance
operator
percent
The notification
notified
compliance
Thus,
requirements
is
EPA~is
that'daily
standards.
comply.
that
method.
compliance
Notification
the
the
notification
GEMS (e.g.,
maintained,-and
now requires
of the
and has
prior
are
in compliance
Response:
The regulation
maintained,
stated
demonstrate
be made for
the
provided
elects
be-submitted
report.
7-3
However,
to go from.the
any
50 vppm
or 50 vppm compliance).
a quarterly
any other
are-
or operator.adds
report
of any change
that
the regulation
of the change.
an owner
commenters
changes
along
in the
with
elects
standard
a quarterly
in
to
towhich
(or
semi-
8.0
MODIFICATION/RECONSTRUCTION
COMMENTS
Comment:
One commenter
tion,as
written
(IV-D-2)
in 60.108(a),
which is replaced
The corranenter
or
suggested
should
by equipment
cited
that
alike
an example
the definition
be modified
to exclude
in design,
of an existing
of reconstruc-
shape,
unit
equipment
and metallurgy.
damaged
by disas.ter
misfortune.
Response:
Section
tion
60.15
occurs
the
upon
of
be required
if
is
technologically
the
replacements,
performance.
are
not
50 percent
to construct
specifies
if
of the
and
economically
to comply
the
entirely
the
reconstruc-
capital
capital
feasible
with
that
fixed
fixed
a comparable,
The circumstances
pertinent
Provisions
of components
exceeds
would
after
General
replacement
new components
it
the
cost
if
for
applicable
an existing
of
that
new facilityand
the
facility,
standards
when determining
cost
of
activities
facility
has
undergone
reconstruction.
Each
basis.
reconstruction
Section
will
use
facility
ically
60.15(f)
in maki.ng
can
determination
his
provide
feasible
to
sets
is.decided
forth
the
comply
that
with
the
If
it
it
is
which
the
the
Administrator
ownerloperator
not
of the
technologically
applicable
criteria
determination.
evidence
on a case-by-case
standards,
or
the
econom-
facility
NSPS.
Comment:
One commenter
included
in these
definition
catalysts.
the
standards
to
that
supercede
a special
Section
Specifically,
the
FCCU regenerator
that
pre-project
X), reduction
will
case,
catalysts
result,
the
operators
emission
level
provision
60.14
will
is using
increase
the
to
SO, emis-
SO, reduction
be allowed
whether
an
to
for
use,
A modification
be
referred
in determining
should
should
regarding
commenter
from an existing
emission
stated
of modification.
the determination
sions
(IV-D-3)
had
unless
the post-project
level.
Operators.who
advantage
exceeded
the
adjusted
and'thereby
avoid
an emission
a net
pre-project
catalysts
project
affected
this
emissi'ons
would have an
increase
catalysts
emission
in a
concurrently
increase
at
the
facility.
Response:
The inclusion
with
Section
of the
111(a)(4)
suggested
of the
special
Clean
Air
provision
Act,
is
which
inconsistent
defines
"modifica-
of" a source
to the
intent
that
"modification"
Air
Act.
new pollution
this
is
the
current
definition
Clean
emissions.
provision
best
serves
problems.
compliance
increases
from,
intent
of the
modified
of
statute
NSPS at,
contrary
NSPS program.
The
of the
Section
NSPS program
the
with
is also
application
the
It
and the
straightforward
by requiring
emissions
increases
of the modification
EPA believes
the
that
seeks
111
of
is
to
to
achieve
and thereby
prevent
minimizing
facilities.
Comment:
One commenter
as standpipes,
should
not
slide
be
fined
include
in a single
of the
work
on an affected
cost
of
an
fractionator
the
entire
items
that
of
cost
other
maintenance
regenerator
if
internal
a facility
require
the
routine
affected
and
an affected
of a new unit.
facility
FCCU,
routine
gas
plant
facility
Also,
entire
and
cost
redework
exceed
of rebuilding
of the
FCCU includes
usually
are
Another
rebuilding
can commonly
the
or
shouldbe
20 percent
an
modified
because
such
components
increase.
facility
can represent
To a refiner,
is
items,
maintenance
a resultantemissions
fractionator
turnaround
50 percent
significant
without
(1V-D-16) stated
to
and
that
in determining
Many of the
repaired
commenter
stated
valves,
included
reconstructed.
frequently
(IV-D-7)
new unit
th~
do not require
any
rebuilding.
Response:
The reconstruction
until
facility
50 percent
of the
provision
"fixed
with a comparable,
new facility
8-2
cost"
cannot
to replace
be invoked
the
existing
by the
owner
.,-
or
operator.
and
repair
erator
The period
is
called
refractory
inspected
from
and
the
ranging
repaired
10 years
II-D-40,
II-D-41,
determine
incurred
1I-D-42,
the
total
to replace
and repair
fixed
of the existing
Thus,
maintenance
items
from the
can exceed
literature
articles,
refineries
(see
erator
routine
If
to
the
to
tion
are
not,
for the
or
however,
choice
the
a typical
of equipment
such
rebuilding
nition
of the
tion
is
a new unit
affected
provision).
discussed
earlier
or
facility
(i.e.,
operational
in
this
provision
change
led
regen-
replaced
during
the
oil,
Justifica-
affected
Section
restrict
to
facility,
2.2
of
this
50 percent
broaden
invoking
of the
FCCU
Such ma3or
occurrence.
reason
the
reconstruction
the
defi-
reconstrucprovision
section.
an existing
8-3
is invoked
facility
turnaround,
point.
in
of
or converting
a single
the
cost
because
increasing
crude
to
EPA to
of the
an inadequate
The modification
physical
is
as
comprises
The possibility
is
than
50 percent
document.
of
this
reports,
services
data
50 percent
discussed
facility.
turnaround
during
is
cost
routine
trip
These
sour
in 40 CFR 60.101(n),
of the
fixed
work typically
responses,
rather
as defined
that
components
of a new affected
turnaround
that
during maintenance
rebuilding
above,
occur
surpass
costs
exempt
than
or more
regeneration,
may approach
less
changes,
a heavier
surmnation
specifically
that
repaired
major
those
(assuming
IV-8-18).
As discussed
several
high-temperature
changes
is
in the
of expended
who provide
rebuilding
used
items
sunmation
114 letter
item
are
provisions.
cost
Section
are typically
changing
cost
capital
A-79-09,
facility.
turnaround.
to
comment
and companies
components
capacity,
from
Docket
a new affected
the
of the
data
no need
are
life
when they
are
components
in the
a useful
Docket A-79-09,
incurred
reconstruction
with
50 percent
that
facility's
is
of time
incurred
The costs
regen-
on information
have
The costs
cost
maintenance
components
Based
(see
II-D-43).
capital
there
internal
period
costs.
conclude
and
for
turnaround,
components
turnarounds
components.
regenerator
during
a typical
as required.
to an indefinite
and maintained
shut.down
and other
replaced
industry,
FCCU is
During
cyclones,
or
repaired
to
the
a turnaround.
linings,
refining
from
in which
when any
results
in an
increase
in the emission
a standard
applies.
As the
increase
emissions,the
addition,
paragraph
nance,
repair,
and
actions
described
modification
(e)
provision
of Section
replacement
by the commenter
60.14
to which
do not
specifies
by themselves,
that
shall
routine
not
:'ij
In
mainte-
be considered
~?
modifications.
Comment:
period"
with
struction
provisions
during
a normal 2-year
of the
A refiner
a routine
a i-calendar
for reconstruction
A refiner
pr ematu r el y.
that
is more logical
turnaround
standards
could
period
by the
recon-
began 1 or 2 months
a sizeable
due to the
be affected
if a shutdown
shutdown
year or a 12-month
process modification
excessive
downtime
incurred.
Response:
The EPA considered
i-calendar
year
or a 12-month
than
(i.e.,
period
and
and therefore,
this
schedule
period
for
for
A process
repair
items
unit
that
is
of.the
NSPS.
Therefore,
period
whether
regenerator
provides
extensive
component
6U.15.
The Agency
of
the
of
that
the
to
with
during
2-year
the
includes
capital
costs
period
will
alter
to unduly
the
intent
equipment.
:1
prolong
that
determining
if
an emissions
questioned
increase
is
original
actually
intent
period
again
the methods
has
8-4
the
method of determining
"proposing"
of
at
Section
the
4-year
Comment:
(IV-D-13)
the
of avoiding
NSPS.
One commenter
each 2-year
objective
the
from
be a "reconstruction."
likely
the
is
that
on when to replace
particular
is every
as fixed
2-year
is not
within
consider
indicates
typically
an FCCU regenerator
replacement,
will
Information
qualify
likely
that
reconstruction
FCCU regenerators
turnaround
a reasonable,
an owner/operator
FCCU's.
components
for this
for
would occur
do not
not
and concluded
BID, p. 5-3)
revamping
review
period"
is,
2-year
"inclusion
proposal
a turnaround
useful
period
maintenance
That
(see
of operation).
decisions
the P-year
a 2-year
and literature
normal turnaround
years
again
occurred
to be used in
when determining
the
applicability
that
of the modification
EPA should
emission
asked
outline
factor
intends
to use.
consideration
material
Another
balance
tonnage
suggested
a coke
for an
factor
(IV-D-15)
of
a~ceptable
approach.
emission
commenter
the
information
AP-42 or other
whether
substantial
the specific
and/or
what specific
provisions.
burnoff
taking
is
into
increased
by
amounts.
Response:
Specific
guidelines
whether
an
increase
ability
of possible
be considered
would
cannot
in
emissions
has
is whether
is
to
to
the
that
an emission
facility
be used
due
One factor
whether
the
to
occurred
circumstances.
in assessing
occur
be presented
wide
vari-
undoubtedly
increase
or will
determine
would
had occurred
be capable
of
or
utilizing
than
bility
those
that
the
was designed
to
previously
used,
SO, emissions
accommodate
will
the
in emissions
resulting
considered
a modification
[see
that
be considered
of
increased
increase
sions
coke
related
to
the
Pollutant
factors
generally
reflect
the
ators.
The range
determined
complete
Catalyst
boiler.
determining
amount
rates
can
range
regeneration
is
coke
composition
required
to
in the
for
emission
factor
be capable
an
SO, emis-
is directly
FCCU regenerators
from
these
thus
individual
FCCU regener-
emission
ranges
in feed
the
rates
sulfur,
stoichiometric
do not
may be
coke
relation-
FCCU catalysts.
similar
to
solid
8-5
the
coke.
fuel
combustion
may be calculated
rate
by
emission
levelsand
pollutant
typical
not
feedstock,
cause
however,
and by evaluating
in regenerating
or will
then
off.
in AP-42;
of emissions
is
Another
undoubtedly
burned
however,
alone
is
be estimated
average
the
change
no change
is
of FCCU regenerator
by considering
involved
that
represent
that
possi-
facility
raw material,
facility
will
a strong
existing
coke
described
ships
the
of
factors
the
rate
the
If the
is
40 CFR 960.14(e)(4)~.
Assuming
because
emission
emission
yield,
burn-off.
amount
from
whether
to increase
using
is
ther'e
change.
alternative
an increase
would
and thus,
in a
by
and by calculating
Coke formation
rates
is operated.
Coke yield,
11-1-53).
hydrogen,
sulfur,
and small
amounts of
Assuming
carbon
3-15
and 3-16.
Comment:
to dllow a better
Section 60.100(b)
understanding
and (c)
of reconstruction.
Response:
Sections
nition
or clarification
of the definition
of reconstruction,
as it
clarifications
as applicable
for
Subpart
or additions
J,
are
to the definition
provided
8-6
under
Section
of reconstruction,
60.108,
9.0
Comr~nt:-
The Office
reporting
the
of Management
was too
Agency
to
trequent,
obtain
and Budget
andthat
the
commented
semiannual
necessary
that
quarterly
reporting
would
all~ow
information.
Response:
quarter)
is t'he appropriate
reasons.
ance
information
rather
testing
isneeded
icant
emission
emissions
near
true
there
littl'e
regulated.
long
periods
occur,
~ facilities
addition,
to ensure
of time during
quarterly
have.had
the
Sources'complying
supply
only
pliant
sources
this
reporting
a period
amount of data
with
a semiannual
the
that
is
proposed
negative
are
toprovide
reports.
9-1
of
located
areas.
signifexcess
This
the control
category
to
is
in clusters
Because
be recovered
standard
declaration
of several
on the environment.
for
the
tech-
resale,
be self-
appropriate
revised
no further
so periods
sources
to be provided
compli-
performance.
one
which significant
when the
would be required
the quarterlycompliance
source
direct
because
for
particular
source's
nonattainment
cannot
(or semi-
the following
contain
quickly
generally
pollutants
i.ncentive
Therefore,
impact
popu'lated,
and the
for
refineries,
refineries
does not
correctly
is
could
urban,
generally
niques
petroleum
because
during.a
The FCCU is
have a significant
industrial,
refinery
in
of the
betaken
documentation.
sources
particularly
the reports
can
reporting
occurred
fre~uency
indicators
action
for
could
is that
than
enforcement
have
reporting
Therefore,
for
no exceedances
quarterly
environmental
for quarters
has
been
impacts
when
exceeded.
in these
cases
s.tandard
would need to
statement.
additional
In
is reasonable.
Only noncom-
information
in
10.0
MISCELLANEOUS
COMMENTS
Comment:
One commenter
states
that
SO, rules
,
(IV-D-16)
FCCU flue
that
gas
wrote
is
that
similar
apply to stationary
FCCU's.
If these
releases
less
rules
than
to
the proposal
stationary
sources
were applied
250 million
since
preamble
source
flue
gas,
should be prescribed
to FCCU's, regenerators
the
for
with
heat
Response:
The EPA assumes
referring
to
utility
from
a coal-fired
erator
exhaust
cable,
it
boilers
is
that
boilers.
utility
gases,
not
two source
and
economic
for
which
boiler
and
is
simply
categories.
are
the
to
that
copy
the
being
the
developed
devices
are
standards
differences
characterize
of the
should
for
could
exist
the
process
source
is
flue
gas
of FCCU regen-
same control
to
commenter
composition
Whenever practical,
that
standards
the
similar
some of the
when significant
aspects
sources,
Although
appropriate
to FCCU's
the
by stationary
appliutility
between
operation
category
or
be considered.
industry
In
available
to FCCU's that
are
boilers.
The utility
boiler
refiner's
flexibility
the
treating.
Thus,
it
fo r ut ii i ty boile
standard
catalysts,
not available
applied
feedstocks
low sulfur
is not reasonable
to utility
to simply
and would~not
allow
feedstocks,
or hydro-
copy the
S02 standards
rs .
Comment:
Two commenters
package
should
undergo
NAPCTACreview
NAPCSAC
meeting the regulation
proposed
standards
Response:
The purpose
are
for
from an independent
regulatory
facto rs .
alternatives,
Althouyh
because
the proposal
at the original
of SO,.
a NAPCTACmeeting
committee
control
the standard
again
that
in terms
advisory
suggested
is
for
EPA to receive
regarding
techniques,
control
is stilf~achievable
10-1
the
comments
need for
costs,
add-on
standards,
and other
controls
by the identified
is
controltechniquesandthe environmental,
energy,andeconomic
impacts
are still
reasonable.
Therefore,
it
is not necessary
to conduct
another NAPCTAC
review due to the change of this standard from S02 to
SO,.
Comment:
monitoring
data
have
been
18 valid
hours
dates
and
of continuous
emissions
obtained.
Response:
Facilities
more valid
using
hours
add-on
controls
of GEMSdata
for
at
are required
least
to obtain
18 or
As
the "bad"
actions
illegal
days in trying
are attempts
to circumvent
wo~ds,
valid
60, Subpart
invalidate
to meet the
the
standard.
standard,
A, Section
may turn
off
which is
60.12.
the
In other
GEMSor otherwise
Such delib-
explanation,
less than 18
the Agency can
One commenter
"monitored
parameter
(IV-K-2)
data,"
suggested
that
EPA'should
not use
to target
inspections.
Response:
The discussion
of
"Monitored
Parameter
Data"
and "Excess
inspections
parameter
emis'si o n data.
equipment rather
operating
being proposed.
data
to collect
that
emission
parameters
would likely
ta rget i ng i ns pect i o ns .
be the
best
in some cases,
require
data
limit,
excess
particular
monitoring
to collect
continue
than
for
to judge,
on a
case-by-case
or
basis,
is appropriate
for-each
NSPS
NESHAP.
Comment:
One commenter
"redundant"
EPA states
later
(IV-K-2)
GEMSand a "spare"
that
redundant
discusses
the
use
between
out that
because
of cost,
but
100 percent
of the
time,
GEMS.
Response:
If
then
EPA required
a second
GEMS would
ability.ilt
is
100 percent
availability
ddwntime.
requirements
at least
68 testing,
refers
to the
is
there
GEMS as
not
no meaningful
high
to
cost
be met`by
the
percent
secbnd
availmonitor
for ensuring
close
EPA proposed
a single
may be.times
to
minimum
GEMS, taking
when minimum
into
data
the~needed
GEMS.
It
a "spare"
required.
that
Thus,
(first)
and the
to
the
warranted.
there
a second
requirements
but
that
likely
still,
to
EPA refers
in obtaining
or
who chooses
is
not
could
Even
second
optional,
operator
is
options
Method
data
that
three
minimum
context
that
close
to ensure
GEMSand believes
requirements
account
operate
be required
in this
as a "redundant"
data
a GEMS to
is
data
in this
monitor.
manual
a second
difference
between
contextthat
that
GEMS for
the
a second
for
GEMS
an owner
back-up
"redundant"
EPA
with
options,
purchase
- Method 6 testing,
Therefore,
testing
has
or
purposes
and
"spare."
Comment:
Onecommenter
(IV-K-2)
as
pointed
88 percent
reduction
being
exceedance
out that
an exceedance
than
the
preamble
may not,
in
example
fact,
of
be an
50 vppm.
Response:
The pgency
i nc omp1ete .
50 vppm or
the
add-on
that
the
would
less
control
outlet
primarily
occur
that
the
An add-on control
are
was
agrees
is
not
percent
example
point
when the
out
control
in
in exceedance
reduction.
provided
that
for
device
10-3
of the
50.
percent
efficiency
preamble
is
S02 emissions
standard
The example
than
the
regardless
implicitly
The object
reduction
was less
of
assumed
of the
example
an exceedance
than
90 percent.
Comment:
One commenter'(IV-K-2)
to
achieve
a standard"
describe
emissions
suggested
rather
greater
than
that
"exceedance
of a standard"
to
The
would be a reduction
better
than
reduction
required.
Response:
of not
reduction
achieved
reduction
standard
an emission
means that
level
a facility
tin this
case,
"exceedance"
consistency
has
been
with other
90 percent
specified
or process
unit has
emission
of performance.
standards,
the
Therefore,
retained.
Comment:
One commenter
(IV-K-2)
asked whether
standards
should
owner" on
be "source
owner or operator."
This
commenter
also asked whether the word "provide" on page 46465, column 1, paragraph
i, of the preamble to the revised
In addition,
in the preamble.
proposed standards
means "i~epore" or
commentletter
of editorial
(IV-D-16),
this
and typographical
notice.
clarify
referred
that
to by the
the requirement
Therefore,
to provide
or an appropriate
person
o pe, ra to r .
10-4
from the
EPA wishes
to
designated
by the owner or
monitors
explained
or an approved
46467 under
"Recordkeeping
jectto
standard
to
manual emission
the
~ecord!the
data
from
in
the
A listing
provided
context
of each
here
since
the
the
Requirements,'!
add-on
controls
continuous
emission
Therefore,
the'worb
of this
on page~
refiners
sub-
would be required
monitor
at
"provide"
the
inlet,
means to
requirement.
typographical
errors
As
proposed standards
and Reporting
test),.
error
and suggested
and suggestion
changes
is not
do not
affect
the
typographical
errors
impairs
the
meaning
orexplanation
of
the
changes
1U-5
APPENDIX
CONTROL EQUIPMENT
AND FIFTH
COSTS
YEAR IMPACTS
TABLE A-i.
-
BASIS
FOR DETERMINING
-~--
Direct
Operating
SCRUBBER
-1-~--~-
ANNUAL COSTSa
--~-`---
---I
Costs
Laborb
817.51/hour
Maintenance
(includes
labor,
and overhead)
materials,
1.5 percent
of total
capital
cost
Uti lities
Electricity
B0.0795/kWh
Water
80.0763/m3
Compressed Air
90.861/1,000 m3
CausticSodac(ZodaRshd)
f268/Mg
(8122/M9)
Steam
813.53/1,000
kg
Polyelectrolytee
B10.07/kg
BZ0.13/Mg
Operating
Insurance,
Capital
Fourth
80.16/m3
Costs
and Administration
Recovery
quarter
(to sewer)
4 percent
Factor
1984
13.15
of~total
percent
of total
Bureau
Liquid~caustic
soda,
100 percent;
F.O.B.
Gulf
light,
99 percent;
F.O.B.
Wyoming; Docket
F,O.B.
3300,
Dallas,
From industrial
cost
capital
dollars.
blnciudes
40percentoverhead;
V.S.Department
of Labor,
Polymer
capital
an anionic
polyacrilomide
Coast;
settling
Docket
of
Labor
A-79-09,
A-79-09,
ayent;'~0-pound
Statistics,
item
item
II-E-6
II-E-6.
bags,
Texas.
boilers
- EPA-450/3-82-021
August
1982.
and Nitrogen
A-i
Oxide
Control
onfossil
cost
TABLEA-2.
CAPITALCOSTFORSODIUM-BASED
HIGHENERGY
VENTURI
SCRUBBING
SYSTEM AND PURGE TREATMENT FOR MODEL UNITSa
Capital
Costs
Direct
Costsb
Indirect
Costs
Contingency
2,500 m3/sd
8,000 m3/sd
Model
Model
CostsC
dollars,
Materials
to
2.9
5.0
1.3
2.2
0.8
1.4
5.0
8.6
-1.0
-1.8
of dollars,
a Gulf
Unit
Coast
adjusted
to fourth
quarter
location.
and labor.
Twenty percent
From Table
in millions
delivered
Unit
of total
A-9 in this
direct
appendix;
and indirect
cost
A-2
costs.
provided
for
comparison
purposes.
TABLE A-3.
2,500m3/sdMODEL
UNITS
Annual
Annual
test,
in
Thousands
of
i)ollarsa
Costs
0.3
wt.
Sulfur
Oirect operating
Feed
1.5
wt.
Sulfur
3.5
Few
wt.
Sulfur
Feed
Costs
Labor
53.7
53.7
53.7
Maintenance
75.0
75.0
75.0
Electricity
22.4
22.4
22.4
water
10.2
10.2
10.2
Utilities
Compressed
Caustic
Air
0.4
Soda
155
579
(95)
(355)
(Soda Asn)
0.4
1,089
(668)
Steam
1.1
1.1
1.1
Polyelectrolyte
4.9
4.9
4.9
7.1
7.1
15.6
15.6
Solid
waste
Oispasal
Insurance,
Capital
TOfAL
ANNUAL
and Administration
Cost
(5004 Ash)
(Soaa
EMISSION
15.6
200
200
200
658
658
658
1,200
1.630
(1,140)
(1.400)
-272
-272
ESP Credite
Caustic
7.1
COST
Soda
ANNUAL
Costs
Recovery
Caustic
HET
0.4
2,140
(1,720)
-272
COST
Soda
Asn)
930
1,360
1,870
(870)
(1,130)
(1,440)
450
1.570
3,130
2.070
810
600
REDUCTION
bAssumes liquid
add to totals
waste disposal
on net
annual
cost
due to rounding.
to sewer, 50 gal/minute,
appendix.
with
Fourth
caustic
soda.
A-3
quarter
1984 dollars.
TABLE A-4.
8,000 mSLsdMODEL
UNITS
Annual
Ai~nual
Cost,
in
Thousanas
of
Dollarsa
Costs
0.3
wt.
Sulfur
Feed
1.5
wt.
Sulfur
3.5
Feed
Suifur
wt.
Feed
53.7
Maintenance
129
53.7
53.7
129
129
Utilities
Electricity
water
Compressed Air
71.6
71.6
71.6
30.6
30.6
30.6
0.4
0.4
Caustic Sooa
(5044 ASh)
506
(313)
Steam
1,1)60
0.4
3,480
(2,150)
3.2
3.2
3.2
14.6
14.6
14.6
22.7
22.7
' 22.7
31.2 ~
31.2
31.2
Insurance,
Capital
and AQalnistrafion
Recovery Cost
344
304
304
1,131
1,131
1.131
Caustic
Soda
(soda Asn)
ESP Credit'
2,340
3.690
5.310
(2.150)
(2,980)
(3,980)
429
-429
-424
Caust~e Soda
(Sop4 Psh)
EnISS~ON
1,910
3,260
4.1380
(1,720)
(2,550)
(3.550)
1,440
5.350
9,990
1.330
610
490
REDUtTIDN
E~ngSD, removed/yrl
COST EFFECtIVENESSd
on net
annual
cost
appenair.
*~th
caustic
soda.
A-4
TABLE A-5.
2,500 m3/sd
Capital
Costs
Direct
Costsb
Indirect
Costs
Contingency
Model
Costsc
TOTAL CAPITAL
COST
delivered
bMaterials
cTwenty
in millions
to
a Gulf
of dollars,
Coast
8,000 m3/sd
Unit
Model
Unit
4.2
7.2
1.6
3.2
1.2
2.1
7.0
12.5
-1.0
-1.8
adjuste'd
to fourth
quarter
location.
and labor.
percent
of total
direct
and indirect
costs.
A-5
1984
TABLE A-6.
2,500
m'/sd
JET
VENTURI
SCRUBBING
FOR
MODEL UNITS
Annual
Annual
EJECTOR
Cost,
in
Thousands
of
3ollarsa
Costs
1.5
vs.
Sulfur
Dfrecs Ogcradng
O
reed
3;5
vs.
Sulfur
X
Feed
Costs
Labor
53.7
~a~nrenance
53.7
205
105
364
304
Utilities
Electricity
Ylter
10.2
Compressed
Air
10.2
3.3
Caustic
Soda
(5064 Ash)
0.3
568
(341)
1,083
(650)
Steam
1.1
1.1
Polyelectroyte
5.2
5.2
7.1
7.1
31.1
31.1
Solid
Uaste
DlsDosal
insurance,
Capital
TOfAL
and
Recovery
ANNUAL
Administration
Cast
ESP Crealt
ANNUAL
2,290
(2.060)
2.800
(2.370)
-272
-272
2,020
(1,790]
2, 530
(2.100)
1.610
3,070
EffECTIYENESSc
1,250
due to rounding.
bAssuunas liquid
to sever.
caasea
921
REOUCTIOH
921
CDSf
Caustic
Soda
(5064 Ash)
WISSION
280
COSf
Caustic
Soda
(5964 Asn)
NET
280
on net
vaste
annual
dlsDosal
cost
rith
caustic
Fourth
50 gal/minute.
soda.
A-6
820
guarter
1984 dollars.
i`?
TABLE A-7.
8,000 m3/,dE~ODEL
UNITS
Annual
Annual
Cost,
of 0011arsa
Costs
l.S
Sulfur
Direct
in Thousands
Operating
wt.
t
Few
3.5
Sulfur
wt.:
Few
Costs
Labor
53.7
naintenance
53.7
188
188
Utitities
Electricity
976
Yater
30.7
Compressed
Caustic
Air
976
30.7
0.4
Soda
(Soaa Asn)
3.4
1,818
3,606
(1,101)
(2.183)
Steam
3.4
Polyelectrolyte
15.6
15.6
22.7
22.7
62.3
62.3
Indirect
Tax,
Operaring
Insurance,
Capital
TOTAL
Costs
and
Recovery
ANNUAL
Caustic
(Soaa
~ninisrrazion
Cost
500
1.644
1,644
COST
Soaa
'
Asn)
ESp
Credit
NET
AN~QIAL COST
Caustic Soda
(Soda Asn)
EnISSION
500
5.310
7,100
(4,600)
(5,680)
-429
-029
1,BSD
(4,170)
6,670
(5,250)
5,160
9.840
940
630
REDUCTION
due to rounding.
bAssumes
to sewer,
'aaseo
liquid
on net
waste
annual
disposal
cost
with
caustic
Fourtn cluarter
100 gal/minute.
sooa.
A-7
19134dollars.
TABLE A-8.
SULFUR
Model
CAPITAL
Direct
Costs
Contingency
Unit
Model
Unit
2,500
4,400
1,100
2,000
Costs
TOTALCAPITALCOST
ESP Capital
8,000 rn3/sd
COSTS
Costs
Indirect
WEIGHT
FEEDa
Cost Credit
700
1,300
4,300
7,700
(1,000)
(1,800)
ANNUAL COSTS
Labor
38
65
116
33
Maintenance
75
Utilities
Soda
Ash
Lime
101
Electricity
Water
Was te
Indirect
Di s pos a~
Operating
Tax,
61
191
125
393
172
308
565
1,013
Costs
Insurance,
and
Capital
Administration
Recovery
Cost
ESP Credit
NET ANNUALCOST
EMISSION
316
(272)
(429)
870
2,020
REDUCTION
1,670
5,350
COST-EFFECTIVENESS
520
dollars.
A-8
380
TABLE A-9.
ELECTROSTATIC PRECIPITATOR COSfSa
(Fourth
Quarter
1984 Dollars)
2,500 m3/sd
Costs
Model
CAPITAL
Unit
8,000 m3/sd
Model
Unit
COSTS
Equipment Costs
Control Deviceb
324,000
542,000
Auxiliariesc
43,400
81,100
36,700
62,300
fares
29,400
49,800
and Freighte
Installation Costsf
611,000
fOTAL CAPITALCOSTS
1,045,000
ANNUAL
Direct
1.037,000
1,772,000
COSTS
Costs
Operating
Laborg
General Maintenanceh
Replacement Parts'
UtilitiesJ
Waste Disposalk
Indirect
Tax,
Insurance,
28,100
28,100
820
1,380
11,000
35,200
7,840
25,100
32,800
32,800
41,800
70,900
and
Administrationm
Capital
27,000
Costs
Overheadl
Property
27,000
Recovery
Cost"
TOTAL ANNUALCOSTS
A-9
122,800
208,200
272,000
429,000
TABLE A-9.
afourth
quarter
FOOTNOTES
1984 dollars.
for the 2,500 m3/sd unit = 1,000 m2, for the 8,000 m3/sd unit = 3,200 m2
air flow for the 2,500 m3/sd unit
27 m3/sec, for the 8,000 m3/sd unit =
87 m~/sec. Docket A-79-09; item II-I-1I.
tAuxiliaries
include bypassducting:
6.4 mm carbon
steel,
insulated;
2 expansion
joints;
4.5
conveyor.
m screw
2 round
19.7 m length,
2 elbows
dampers
Docket
with
A-79-09,
equipment
cost.
127 cm diameter,
6.4 mm carbon
automatic
items
steel,
controls;
II-A-5,
insulated;
and
II-E-5,
a 23 cm x
and II-E-95.
Docket
A-79-09,
item
1I-A-5.
as 141 percent
include
costs
work, piping,
of purchased
equipment cost.
Indirect
installafor foundations
and supports,
erection
and handling,
insulation,
and piping.
Docket A-79-09, item
II-A15.
9lncludes
operator
and supervisor
costs.
Operating
labor
costs
are based on
1.25 operator
man-hours
per shift,
3 shifts
per day, 365 days per year and
817.51 per man-hour.
Supervisor
labor costs are included
by adding 15 percent
to
the
hInciudes
operator
labor
costs.
and material
Docket
costs.
0.75 man-hours
per man-hour.
per shift,
3 shifts
Material
costs are
costs,
A-79-09,
Docket
A-79-09,
item
item
Maintenance
II-A-5.
labor costs
are based on
II-A-5.
A124.
and 1,000mZplate area for the smallESPand 3,200m2plate area for the
large
ESP.
Docket
A-79-09,
item
II-A-5.
and
II-A-5.
Docket
mCalculated
item
as 4 percent
item
II-A-5.
of total
installed
capital
cost,
Docket A-79-09,
II-A-5.
"Capital
interest
item
A-79-09,
recovery
rate.
cost
Capital
basedon
recovery
20 years
operating
factor
= 0.1175.
II-A-5.
A-10
life,
and 20 percent
Docket
A-79-09,
annual
TABLE A-3O.
FIFTH
YEAR CAPITAL
COST IMPACTSa
Fresh Feed
Feed Sulfur
Capacity
Content
(m~/sd)
(wt. %)
Number of
Capital
Units:
Per
Cost
Unit:
Capital
Cost:
A x B
(8 Millions)
(B Millions)
2,500b,C
0.3
5.0
5.0
8,000b,e
0.3
8.6
8.6
2,500b
1.5
5.0
15.0
8,000b
1.5
8.6
25.8
2,500b
3.5
5.0
5.0
8,000b
3. 5
8.6
8.6
TOTAL CAPITAL
COST
IMPACT
68.0
Fresh Feed
FeedSulfur
Capacity
(m~/sd)
Content
(wt. 1)
Number
of
Capital Cost
Units:
Per Unit:
B
Adjustmente: C
(8 Millions)
(~ Millions/Unit)
Retr.ofit Cost
Capital test:
A x (B + C)
(B Millions)
2,500d
1.5
7.0
--
7.0
2,500b
1.5
5.0
0.8
5.8
8,000b
1.5
8.6
--
8.6
8,000d
1.5
12. 5
--
12.5
8,000b
1.5
8.6
1.4
20.0
8,000b
3. 5
8.6
--
TOTAL CAPITAL
aqth
quarter
COST
8.6
IMPACT
62.5
1984 dollars.
of 0.3
this
sulfur
would
percent
cost
dJet-ejector
e20 percent
would
content
need
to
or less,
not
be
of higher
be met,
the
and
than
0.3
percent,
this
cost
would
regenerator
the
90 percent
be incurred.
to meet the
incurred.
venturi scrubber.
of direct
and indirect
capital
cost;
A-ii
excludes
emission
At feed
ESP credit.
sulfur
reduction
contents
standard,
and
TABLE A-ii.
Fresh
Feed
Feed
Caeaci
ty
(m3/sd)
FIFTH
Sulfur~
Number
Content
(wt. X)
of
Annual
IMPACTS"
Cost
Annual
Units: A
Per
Uniti B
(B i,ooo s)
Cost
AxB
(8 1,O0O's)
2,50Ob,C
0.3
930
930
2,500b
1.5
1,360
4,080
2,500d
1.5
2,020
2,020
2,500ble
1.5
1,780
1.780
2,SOOb
3.5
1,870
1,870
8,00Ob,C
0.3
1,910
1,910
8,000b
1.5
3,260
13.040
8,000d
1.5
4,880
4,880
8,000b,e
1.5
3,950
7,900
8,000b
J. 5
4,880
9,760
aqth quarter
48,170
1984 dollars.
standard
feed sulfur
contents
be
to meet
required
dJet-ejector
eAnnualized
of 0.3 percent
the
standard,
and this
or less,
and
this
cost
would
the regenerator
cost
would
not
be incurred.
would not
be incurred.
venturi scrubber.
capital
cost
includes
retrofit
A-12
cost;
excludes
ESP credit.
At