LAMPIRAN

Data Profil Temperatur, Pressure Drop, dan CO leak

KATALIS LTSC
Pressure
T
Waktu

drop

Bed 1

Bed 2

CO

CO

inlet

top

bot

top2

bot 2

outlet

inlet

leak

(kg/cm2
31 Agustus 2012

0,725

199,95

207,2

215,8

216,7

218,8

221,9

3,24

0,29

30 April 2013

0,7405

200,2

203,5

213,6

215,5

222,7

223,2

3,34

0,35

31 Agustus 2013

0,752

201

202,9

213

215,2

223,4

224,5

3,41

0,33

30 April 2014

0,733

203,9

204,6

213,7

216,4

226,11

228

3,55

0,36

31 Agustus 2014

0,712

204,3

204,2

213,3

215,7

226,3

228,2

3,62

0,37

14 April 2015

0,698

204,3

204

208,8

212,2

224,7

229,2

3,68

0,41

12 Agustus 2015

0,679

204

203,3

206,8

209,9

223,3

229,6

3,67

0,49

Keterangan :
Pressure drop dalam kg/cm2
Temperature dalam Celsius
CO dalam %vol

LEMBAR PERHITUNGAN
Perhitungan Neraca Massa
Contoh perhitungan neraca massa untuk data aktual tanggal 12 Agustus 2015
Gas Alam Process
Neraca atom gas alam process :
KOMP.GAS HARIAN

CO2

5,338

%m

5,338

10,676

N2

0,078

ol
%m

0,156

CH4

85,818

ol
%m

85,818

343,27

C2H6

3,873

ol
%m

7,746

C3H8

2,73

ol
%m

8,19

23,238

iC4H10

0,589

ol
%m

2,356

21,84

nC4H10

0,691

ol
%m

2,764

5,89

iC5H12

0,284

ol
%m

1,42

6,91

nC5H12

0,185

ol
%m

0,925

3,408

C6H14

0,414

ol
%m

2,484

2,22

ol

117,04

5,796
412,57

10,676

0,156

1
1,1704

4
4,1257

0,1067

0,0015

Jumlah

Formula gas alam : C1,17041H4,12754O0,10676N0,00156

3

Laju alir gas alam proses = 25127 Nm /hr

= 25127/22.4
= 1121,74 kmol/hr

Hidrogen Recovery Unit (HRU)

H2 HRU 12 Agustus 2015
Komposisi
Senyawa

(%vol)

H2

88,65

CH4

0,72

N2

9,68

Ar

0,95

Total

100.00

Laju alir HRU

= 1531 Nm3/hr
= 1531/22.4
= 68,34821 kmol/hr

Steam
Laju alir steam

= 71,5 ton/hr
= 71500/18
= 3972,22 kmol/hr

A. PRIMARY REFORMER
Data inlet Gas masuk Primary Reformer
Sistem
Gas Proses

1121,741

Mol atom
C
1312,896967

Steam Proses

3972,222

7944,444444

3972,222222

H2 Recycle

68,34821

0,492107143

123,1498125

5162,312

1313,389075

12695,60626

4091,979299

Total

Flowrate

Mol Atom H

Mol atom O

4628,012008

119,7570768

Data Analisis Gas Outlet Primary Reformer

Komponen Komposisi (y)
CO2

11,82

CO

9,81

H2

64,94

CH4

13,27

Ar

0,01

N2

0,15

Neraca Massa tiap atom/unsur mengikuti persamaan :

Neraca atom C
atom C masuk = atom C keluar
nCin

= nCH4out +(

1313,389 = (1 +

yCOout
y CH 4 out ) nCH4out+(

9,81
13,27 +

11,82
13,27

) nCH4out

nCH4out = 499,3889 kmol/hr

nCOout =(

yCOout
y CH 4 out ) nCH4out
9,81
x
499,3889 kmol/hr
13,27

= 369,178992 kmol/hr
y CO2 out
nCO2out =( y CH 4 out ) nCH4out
=

11,82
x
499,3889 kmol/hr
13,27

= 444,8211708 kmol/hr

Neraca atom O
atom O masuk = atom O keluar
nOin

= nH2Oout + nCOout + 2 nCO2out

y CO2 out
y CH 4 out ) nCH4out

4091,979

= nH2Oout + 369,178992 + (2 x 444,8211708)

nH2Oout

= 2833,157965 kmol/hr

Neraca atom H
atom H masuk = atom H keluar
nHin

= 2nH2out + 2nH2Oout + 4nCH4out

12965,6062 = 2nH2out + (2x2833,157965) + (4x499,3889)

nH2out

= 2515,867344 kmol/hr

Neraca atom N
atom N masuk = atom N keluar
nN2in = nN2out
nN2out = 14,9821306 kmol/h
Neraca atom Ar
atom Ar masuk = atom Ar keluar
nArin = nArout
nArout = 0,6493kmol/h
B. SECONDARY REFORMER
Gas outlet Primary Reformer + Udara Proses = Gas inlet Secondary Reformer
Data Inlet Gas Masuk Secondary Reformer
Sistem

Flowrate
st

Mol atom C

Mol Atom H

Mol atom O

Gas Outlet 1 ref

6678,046

1313,389075

12695,60626

4091,979299

Udara Proses

1808,17

759,43125

Total

8486,215

1313,389075

12695,60626

4851,410549

Data Analisis Gas Outlet Secondary Reformer

Komponen

Komposisi (y)

CO2

7,99

CO

13,61

H2

55,23

CH4

0,52

Ar

0,25

N2

22,4

Neraca atom C
atom C masuk = atom C keluar
nCin

= nCH4out +(

1313,38 = (1 +

yCOout
y CH 4 out ) nCH4out+(

13,61
0,52 +

7,99
0,52

y CO2 out
y CH 4 out ) nCH4out

) nCH4out

nCH4out = 30,875 kmol/hr

yCOout
y CH 4 out ) nCH4out

nCOout =(

13,61
x
30,8754 kmol/hr
0,52

= 808,102 kmol/hr
y CO2 out
nCO2out =( y CH 4 out ) nCH4out
7,99
x
0,52 30,875 kmol/hr

= 474,411 kmol/hr

Neraca atom O
atom O masuk = atom O keluar

nOin

= nH2Oout + nCOout + 2 nCO2out

4851,410

= nH2Oout + 808,102 + (2 x 474,411)

nH2Oout

= 3094,485 kmol/hr

Neraca atom H
atom H masuk = atom H keluar
nHin

= 2nH2out + 2nH2Oout + 4nCH4out

12965,6062 = 2nH2out + (2x3094,485) + (4x30,875)

nH2out

= 3191,566 kmol/hr

 Neraca atom N
atom N masuk = atom N keluar
nN2in = nN2out
nN2out = 2871,89 kmol/h
Neraca atom Ar
atom Ar masuk = atom Ar keluar
nArin = nArout
nArout = 0,6493 kmol/h

C. HIGH TEMPERATURE SHIFT CONVERTER (HTSC)

Reaksi yang terjadi :
CO + H2O CO2 + H2
Gas outlet Secondary Reformer = Gas inlet HTSC Data
Analisis Gas Outlet HTSC
Komponen

Komposisi (y)

CO2

15,46

CO

3,67

H2

59,77

CH4

0,44

Ar

0,24

N2

20,42

Neraca atom C
atom C masuk = atom C keluar
nCin

= nCH4out +(

1313,38 = (1 +

yCOou t
y CH 4 out ) nCH4out+(

3,67
0,44 +

nCH4out = 29,52 kmol/hr

15,46
0,44

) nCH4out

y CO2 out
y CH 4 out ) nCH4out

yCOout
y CH 4 out ) nCH4out

nCOout =(

3,67
x
0,44 29,52 kmol/hr

= 246,30 kmol/hr
y CO2 out
nCO2out =( y CH 4 out ) nCH4out
15,46
x
29,52 kmol/hr
0,44

= 1037,557 kmol/hr

Neraca atom O
atom O masuk = atom O keluar

nOin

= nH2Oout + nCOout + 2 nCO2out

4851,410

= nH2Oout + 246,30 + (2 x 1037,557)

nH2Oout

= 2529,99 kmol/hr

Neraca atom H
atom H masuk = atom H keluar
nHin

= 2nH2out + 2nH2Oout + 4nCH4out

12965,6062 = 2nH2out + (2x2529,99) + (4x29,52)

nH2out

= 3758,75 kmol/hr

Neraca atom N
atom N masuk = atom N keluar
nN2in = nN2out
nN2out = 2871,89 kmol/h
Neraca atom Ar
atom Ar masuk = atom Ar keluar
nArin = nArout
nArout = 0,6493 kmol/h
D. LOW TEMPERATURE SHIFT CONVERTER (LTSC)

Gas outlet HTSC = Gas inlet LTSC

Data Analisis Gas Outlet LTSC
Komponen

Komposisi (y)

CO2

17,97

CO

0,49

H2

61,18

CH4

0,45

Ar

0,24

N2

19,67

Neraca atom C
atom C masuk = atom C keluar
nCin

= nCH4out +(

1313,38 = (1 +

yCOout
y CH 4 out ) nCH4out+(

0,49
0,45 +

17,97
0,45

) nCH4out

nCH4out = 31,25 kmol/hr

nCOout =(

yCOout
y CH 4 out ) nCH4out
0,49
x
0,45 31,25 kmol/hr

= 34,032 kmol/hr
y CO2 out
nCO2out =( y CH 4 out ) nCH4out
=

17,97
x
31,25 kmol/hr
0,45

= 1248,101 kmol/hr

Neraca atom O
atom O masuk = atom O keluar
nOin

= nH2Oout + nCOout + 2 nCO2out

4851,410

= nH2Oout + 34,032 + (2 x 1248,101)

y CO2 out
y CH 4 out ) nCH4out

nH2Oout

= 2321,174 kmol/hr

Neraca atom H
atom H masuk = atom H keluar
nHin

= 2nH2out + 2nH2Oout + 4nCH4out

12965,6062 = 2nH2out + (2x2321,174) + (4x31,25)

nH2out

= 3964,119 kmol/hr

Neraca atom N
atom N masuk = atom N keluar
nN2in = nN2out
nN2out = 2871,89 kmol/h
Neraca atom Ar
atom Ar masuk = atom Ar keluar
nArin = nArout
nArout = 0,6493 kmol/h
E. PERHITUNGAN T APPROACH
K=

%mol CO 2 X %mol H 2
%mol CO X %mol H 2 O

K=

1248,101 X 3964,119
34,03 X 2321,174

K = 62,6312
Pada tabel kesetimbangan reaksi di shift converter didapat T equlibrum sebesar
0

269,95 C ( buku pedoman operasi ammonia kaltim-4 lampiran A1-A3)

Tapproach = Teq T out
= 269,95 229,6
0

= 40,35 C
F. PERHITUNGAN H2 DAN AMONIA YANG HILANG

H2 yang hilang

3mol CO
x BM H 2 x 22,4
1000

334,032
x 2 x 22,4
1000

=
NH3 yang hilang

4,99073 ton/hari

2mol CO
x BM N H 3 x 22,4
1000

234,032
x BM NH 3 x 22,4
1000

27,7708 ton/hari

G. PERHITUNGAN PRESSURE DROP NORMALIZED

Pressure drop normalized =
=

actual flow outlet LTSC

design flow outlet LTSC
234555,34 Nm 3 /hr
198292 Nm 3/ hr

= 0,80317 kg/cm2

x pressure drop measured

x 0,679