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SUBJECT : CHEMISTRY

PART TEST-1(PT-1)

Code

(JEE ADVANCED PATTERN)


TARGET : JEE (MAIN+ADVANCED) 2018

COURSE : VIKAAS (JA**2+)

P05-15

Date : 03-01-2016

Time: 2 Hours

Maximum Marks : 160

1.

The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.

2.

The question paper CODE is printed on the right hand top corner of this sheet.

3.

Use the Optical Response Sheet (ORS) provided separately for answering the question.

4.

Blank spaces are provided within this booklet for rough work.

5.

Write your Name and Roll Number in the space provided on the below cover.

6.

After the open booklet, verify that the booklet contains all the 40 questions along with the options are legible.

QUESTION PAPER FORMAT AND MARKING SCHEME :


7.

This questions paper consists of Two sections.

8.

Carefully read the instructions given at the beginning of each section.

9.

Section 1 contains 22 multiple Choice questions with one or more than one correct option.
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.

10.

Section 2 contains 18 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both
inclusive).
Marking scheme: +4 for correct answer, 0 if not attempted and 1 in all other cases.

OPTICAL RESPONSE SHEET :


11.

Darken the appropriate bubbles on the original by applying sufficient pressure.

12.

The original is machine-gradable and will be collected by the invigilator at the end of the examination.

13.

Do not tamper with or mutilate the ORS.

14.

Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :


15.

Use a BLACK BALL POINT to darken the bubbles in the upper sheet.

16.

Darken the bubble COMPLETELY.

17.

Darken the bubble ONLY if you are sure of the answer.

18.

The correct way of darkening a bubble is as shown here :

19.

There is NO way to erase or "un-darkened bubble.

20.

The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.
NAME OF THE CANDIDATE : ..
ROLL NO. : ..
I have read all the instructions
and shall abide by them

------------------------Signature of the Candidate

I have verified the identity, name and roll number


of the candidate.

------------------------Signature of the Invigilator

Resonance Eduventures Ltd.


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P5

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %

CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION 1 : (Maximum Marks : 88)

This section contains TWENTY TWO questions

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

1.

The weight of 350 ml of a diatomic gas at 0 C and 2 atm pressure is 1 gm. The weight of one
atom in gram is : (N = Avogadro's number)
(A)

2.

16
N

(B)

32
N

(C) 16 N

(D) 32 N

Analysis of chlorophyll shows that it contains 2.64 percent magnesium. How many atoms of
magnesium does 1.00 gm of chlorophyll contains ?
23

(A) 6.62 10

21

(B) 6.62 10

24

(C) 6.62 10

20

(D) 6.62 10

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CHEMISTRY

CHEMISTRY

CHEMISTRY

Select the correct statements for (NH4)3PO4 :

CHEMISTRY

3.

(A) Ratio of number of oxygen atom to number of hydrogen atom is 1 : 3


(B) Ratio of number of cation to number of anion is 3 : 1
(C) Ratio of number of nitrogen atom to number of oxygen atom is 3 : 4
(D) Total number of atoms in one mole of (NH4)3PO4 is 20

4.

The number of neutrons present in 7 gm of phosphonium (PH4 ) ion is


(A) 8 NA

5.

(C) 4 NA

(D) 5 NA

16 g of S2 ion has amount of charge equal to : (NA = 6.02 1023, e = 1.6 1019 C)
(A) 5 NAe

6.

(B) 3.2 NA

31 1
15 P,1 H

(B) 2 NAe

(C) NAe

(D)

1
Ne
2 A

A gas XH2 has molar mass 34 g/mol. What is the molar mass of XO3 (nearly) ?
(A) 64 g/mol

(B) 82 g/mol

(C) 80 g/mol

(D) cannot be found

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CHEMISTRY

An element has two isotopes of atomic mass number 16 and 18. Then which of the following is
false.
(A) The average atomic mass of the element can not be less than 16 amu.
(B) If the natural abundance of the heavier isotope is negligible, then the average atomic mass will
be close to 16 amu.
(C) If both isotopes are equally abundant, then mass of 3 atoms of the element will be 51 amu
(D) If the natural abundance of the lighter isotope is 75%, then the average atomic mass will be
closer to 16 amu.

8.

Tom measured the pressure of gas sample A as 1 bar, while Jerry measured the pressure of
another gas sample B as 1 Pascal. Which of two gas samples exerts greater pressure :

9.

(A) Sample A

(B) Sample B

(C) Both gas samples have same pressure.

(D) Cannot be predicted.

Which the following order represents correct increasing order of mass for given samples.
(i) 1 g-atom of C

(ii) 0.5 mole of CH4

(iii) 10 mL of water (d= 1g/ml)

(iv) 3.011 1022 atoms of oxygen

(A) ii < i < iii < iv

(B) ii < iv < iii < i

(C) iv < ii < iii < i

(D) ii < i < iv < iii


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CHEMISTRY

7.

CHEMISTRY

Which of the following statement/s is (are) INCORRECT ? (At mass of

= 4.00260244)

CHEMISTRY

10.

4He

(A) Mass of one sodium atom in gram is 23 g.


(B) 4 g of 4He contain exactly avogadro number of atoms.
(C) The gram atomic mass of chlorine is nearly 35.5 g.
(D) The relative atomic mass of sulphur is exactly 32.

11.

Which of the following contain maximum number of molecules?


(A) gas mixture of O2 and H2 having pressure 2 atm at 300 K and 4 L volume.
(B) gas mixture of CO2 and H2 having pressure 1 atm at 240 K and 8 L.
(C) 1.8 g water
(D) 3.2 g CH4.

12.

Which of the following compounds are aromatic (homocyclic) ?


NH2

(A)

(B)

(C)

(D)

OH

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CHEMISTRY

Which of the following groups are attached to the cyclohexane ring in the following compound:
H3CHCH2C

CHCH3

CH3

CH3
CH2CH3

(A) Methyl

14.

(D) Neo-pentyl

(B)10

(C) 15

(D) 20

Which of the following has/have all 1, 2 and 3 carbon atoms only.

(A)

16.

(C) Iso-propyl

How many 1 hydrogens are present in iso-octane.


(A) 5

15.

(B) n-propyl

(B)

(C)

(D)

Which of the following are possible strcutures for the molecular formula C4H6 ?

(A)

(B)

(C)

(D)

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CHEMISTRY

13.

CHEMISTRY

Which of the following is not alicyclic hydrocarbon

(A)

18.

(B)

(C)

CHEMISTRY

17.

(D)

For the following statements, incorrect option/s is/are :


S1 : Empirical formula of cyclopropane and butene are same.
S2 : General formula of cycloalkene is CnH2n.

S3 :

is an unsaturated Heterocyclic compound.

S4 : Pyridine
(A) TTTT

19.

is a homocyclic aromatic compound.


(B) TTFF

(C) FTFT

(D) TFTF

What is the empirical formula of following structure :

(A) C2H5

(B) C3H4

(C) CH4

(D) C2H3

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CHEMISTRY

What is the hybridisation of underlined atom of Ketene CH2=C=O ?


2

(A) sp

21.

(B) sp

(D) dsp

Which of the following has/have similar general formula?

(A)

22.

(C) sp

(B)

(C)

(D)

What is the IUPAC name of the following compound?

(A) Oct-2, 4-diene-6-yne

(B) Oct-4, 6-diene-2-yne

(C) Oct-6-yne-2, 4-diene

(D) Hept-2,4-diene-6-yne

Space for Rough Work

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CHEMISTRY

20.

CHEMISTRY

This section contains EIGHTEEN questions.

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

For each question, darken the bubble corresponding to the correct integer in the ORS

Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
1 In all other cases

23.

What is the ratio of weights of O2 and He, the mixture of which contains equal number of
molecules of each gas ?

24.

16 gm of an ideal gas SOx occupies 5.6 lt. at STP. The value of x is

25.

How many statements are incorrect ?


(a) Mass number can not be fractional
(b) Gram atomic mass of Cl35 is 35.5 g
(c) Both heavy water and normal water have same molar mass.
(d) The numerical value of R is independent of units, as it is universal gas constant.

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CHEMISTRY

SECTION 2 : (Maximum Marks : 72)

CHEMISTRY

An element exist in three isotopic form :


40

X and

42

X. Relative abundance of

X = 30% by mole. If average atomic mass of X' is 41.25 u, find out the ratio of %

abundance (by mole) of

27.

X,

41

40

X to % abundance (by m ole) of

41

X.

If the mass of 0.25 mole of an element X is 4.5 g, then the mass of one atom of X is about
p 1023 g. Find the value of p.

28.

Two sealed containers of the same capacity are filled with 88 gram N2O (container-I) and 44 gram
CO2 (container-II) at the same temperature. If the pressure of CO2 in second container is 1 atm,
the pressure of N2O gas in the first container (in atm)would be:

29.

Find the weight of a sample (in g) which contains 0.2 mole Ne gas and about 1.08 1024
molecules of an unknown gas X, if the sample has average molar mass 38 g/mol. Report your
answer after dividing the weight of sample by 9.5.

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CHEMISTRY

26.

40

CHEMISTRY

How many of the following is/are correctly related ?

CHEMISTRY

30.

(i) 1 torr > 1 bar


(ii) 10 L > 1 dm3
(iii) 0.4 atm > 100 torr
(iv) 1 m = 106 m
(v) 1 = 1010 m
(vi) 1 fm = 1012 m.

31.

From 196 g H2SO4, 6.023 1023 H2SO4 molecules are removed, x moles of H2SO4 are left.
From 1.96 g H3PO4, 12.046 1021 H3PO4 molecules are removed, y moles of H3PO4 are left.
Give value of 'x + y'.

32.

Calculate the 3 hydrogens in the following compound :

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CHEMISTRY

How many total number of -bonds present in following compound.


CH2=C=CH-CCH

34.

Calculate the sum of numbers appearing in IUPAC naming of following compound :

35.

How many carbon atoms are sp hybridised in following compound.

CH2 = C = CH CH2 C C CH2 NH2

36.

Calculate the total number of -bonds in following structure.


CN
NC

37.

In buta-1,3-diene ; if X is number of hydrogen atoms and Y is number of -bonds present.


Calculate (X + Y).

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CHEMISTRY

33.

CHEMISTRY
2

How many sp -sp bonds are present in the given compounds:

39.

Calculate the degree of unsaturation in the following structure :

40.

In the given structure; if number of sp C-atoms are M and number of sp -sp C-C -bonds are N.

CHEMISTRY

38.

Find the value of (MN).

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