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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

LD7 Liquid Developer Aerosol
Version 2.0

Revision Date 02.08.2011

Print Date 04.08.2011

1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name

: LD7 Liquid Developer Aerosol

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture
Recommended restrictions
on use

: Developer.
: None known.

1.3 Details of the supplier of the safety data sheet
Company

Telephone
Telefax

: Chemetall Ltd
Denbigh Road
Bletchley Milton Keynes MK1 1PB
: 01908 649333
: 01908 373939

Contact person product safety
Telephone
E-mail address

: +49(0)6971652832
: msds.de@chemetall.com

1.4 Emergency telephone number
Emergency telephone
number

:

01908 649333

2. Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Flammable aerosols, Category 1
Eye irritation, Category 2
Specific target organ toxicity - single exposure, Category 3

H222: Extremely flammable aerosol.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.

Classification (67/548/EEC, 1999/45/EC)
Extremely flammable
Irritant

R12: Extremely flammable.
R36: Irritating to eyes.
R67: Vapours may cause drowsiness and dizziness.

2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
1 / 14
- EN

or on clothing. on skin.No smoking. Remove contact lenses.EN . 1907/2006 LD7 Liquid Developer Aerosol Version 2. 2 / 14 . May cause drowsiness or dizziness. Vapours may cause drowsiness and dizziness. Hazardous components which must be listed on the label: Propan-2-ol  67-63-0 Labelling according to EC Directives (1999/45/EC) Hazard pictograms : Extremely flammable R-phrase(s) Irritant : R12 R36 R67 Extremely flammable. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Do not get in eyes. Causes serious eye irritation.2011 Extremely flammable aerosol. Keep away from heat/sparks/open flames/hot surfaces. Do not spray on an open flame or other ignition source.0 Revision Date 02. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P211 P260 P262 P280 Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Irritating to eyes.08. Wear protective gloves/ eye protection/ face protection.SAFETY DATA SHEET according to Regulation (EC) No. . if present and easy to do.08.2011 Hazard pictograms : Signal word : Danger Hazard statements : H222 H319 H336 Precautionary statements : Prevention: P210 Print Date 04.

Composition/information on ingredients 3. In case of contact with eyes. Keep away from sources of ignition . H220 >= 10 .SAFETY DATA SHEET according to Regulation (EC) No. 2.No smoking. 1907/2006 LD7 Liquid Developer Aerosol Version 2. 3.1 Substances Identification: LD7 Liquid Developer Aerosol 3.08. H319 STOT SE 3.EN . >= 25 . 2. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Keep out of the reach of children.2011 : Pressurized container. R12 Flam. H336 Propane 74-98-6 200-827-9 F+.0 Revision Date 02.08. R11 Classification Concentration (REGULATION [%] (EC) No 1272/2008) Flam. This material and its container must be disposed of as hazardous waste.2 Mixtures Chemical nature : Mixture of organic solvents containing surfactants. Wear suitable gloves and eye/face protection.3 Other hazards The information required is contained in this Material Safety Data Sheet. Registration number 67-63-0 200-661-7 01-211945755825- Classification (67/548/EEC) F. 2. Liq. R36 R67 Eye Irrit. Do not spray on a naked flame or any incandescent material.< 50 H225 Xi. Hazardous components Chemical Name Propan-2-ol CAS-No. Do not pierce or burn. rinse immediately with plenty of water and seek medical advice. Gas 1.< 25 3 / 14 . Use only in well-ventilated areas. S37/39 S51 S60 Special labelling of certain mixtures Print Date 04. Avoid contact with skin and eyes. even after use. EC-No.2011 S-phrase(s) : S23 S24/25 S26 Do not breathe spray.

1272/2008. 2. see Section 16. For the full text of the Notas mentioned in this Section. R36 R66 WEL substance : Butane Talc 106-97-8 203-448-7 Eye Irrit. If symptoms persist. H225 >= 2.EN . see Section 16. For the full text of the H-Statements mentioned in this Section. also under the eyelids. Gas 1. If inhaled : Move to fresh air.< 25 ous substance or mixture according to Regulation (EC) No. Move out of dangerous area. 2.2011 Press. Gas 14807-96-6 238-877-9 >= 25 . R11 Flam. 1907/2006 LD7 Liquid Developer Aerosol Version 2. 4. If symptoms persist. H319 R67 STOT SE 3.< 50 Not a hazard>= 10 .SAFETY DATA SHEET according to Regulation (EC) No. First aid measures 4. H220 Nota C Press.1 Description of first aid measures General advice : First-aid crew: Ensure self-protection.08. Liq. see Section 16. call a physician. For the full text of the R-phrases mentioned in this Section.5 .08. In case of skin contact : Wash off with soap and plenty of water. If swallowed : Rinse mouth with water.< 10 Xi. Consult a physician. call a physician.0 Revision Date 02. H336 F+. In case of eye contact : Rinse immediately with plenty of water. Gas Acetone 67-64-1 200-662-2 F. R12 Flam. 4 / 14 . Take off contaminated clothing and shoes immediately.2011 Print Date 04.

2 Special hazards arising from the substance or mixture Specific hazards during fire fighting : May form toxic gases on heating or in case of fire. 1907/2006 LD7 Liquid Developer Aerosol Version 2.08.2011 Print Date 04.2 Most important symptoms and effects.SAFETY DATA SHEET according to Regulation (EC) No. 6.3 Methods and materials for containment and cleaning up 5 / 14 . Accidental release measures 6. Avoid subsoil penetration.2 Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system. 4. Carbon monoxide Carbon dioxide (CO2) 5. 6. Consult a physician. both acute and delayed Symptoms : May cause drowsiness or dizziness.3 Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically.0 Revision Date 02.3 Advice for firefighters Special protective equipment for fire-fighters Further information : In the event of fire. 6.1 Extinguishing media Suitable extinguishing media : Carbon dioxide (CO2) Dry powder Alcohol-resistant foam Water spray Unsuitable extinguishing : High volume water jet media 5.1 Personal precautions. protective equipment and emergency procedures Personal precautions : Wear personal protective equipment. 5. wear self-contained breathing apparatus.2011 Do NOT induce vomiting. : Use water spray to cool unopened containers. Risks : irritant effects 4.EN . For specialist advice physicians should contact the Poisons Information Service. Fire-fighting measures 5.08.

3-diene 6 / 14 . (e.0 Revision Date 02. 7. sand. The identified substances include those which: . 6. vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). cool and wellventilated place.EN .are assigned the risk phrases 'R45: May cause cancer'.08. soak up with non-combustible absorbent material. Advice on protection against fire and explosion : Keep away from sources of ignition . 1907/2006 LD7 Liquid Developer Aerosol Version 2. Handling and storage 7. 'R49: May cause cancer by inhalation' or . Carcinogenic only applies if butane contains more than 0. Exposure controls/personal protection 8.2011 : Ensure adequate ventilation.3 Specific end uses Specific use(s) : Developer.450 mg/m3 Update Basis 2007-08-01 GB EH40 Carc: Capable of causing cancer and/or heritable genetic damage.4 Reference to other sections See chapter 8 and 13 7.No smoking. earth. diatomaceous earth. Storage temperature : 5 . Vapours may form explosive mixtures with air. Floor level ventilation required. Value Butane 106-97-8 TWA Further information : Control parameters 600 ppm 1.2011 Methods for cleaning up Print Date 04.2 Conditions for safe storage. 'R46: may cause heritable genetic damage'.08.1 Control parameters Components CAS-No. Have eye wash bottle or eye rinse ready at the work place.1 Precautions for safe handling Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. Normal measures for preventive fire protection. 8.a substance or process listed in Schedule 1 of COSHH. Contain spillage. including any incompatibilities Requirements for storage areas and containers : Keep containers tightly closed in a dry. Take precautionary measures against static discharges.40 °C 7.SAFETY DATA SHEET according to Regulation (EC) No.1% of buta-1.g.

1% of buta-1. Where dusts contain components that have their own assigned workplace exposure limits.810 mg/m3 2007-08-01 Print Date 04. as amended by the ISO/CEN convention.250 mg/m3 2006-09-01 GB EH40 Talc 14807-966 TWA 1 mg/m3 Respirable 2005-04-06 GB EH40 Further information : Acetone 67-64-1 Further information : 1: For the purposes of these limits. deposition and fate of any particular particle after entry into the human respiratory system and the body response that it elicits. Most of industrial dusts contain particles of a wide range of sizes. Where no specific short-term exposure limit is listed. Talc is defined as the mineral tals together with other hydrous phyllosilicates including chlorite and carbonate materials which occur with it.2011 GB EH40 Further information : Carc: Capable of causing cancer and/or heritable genetic damage. Carcinogenic only applies if butane contains more than 0. but excluding amphibole asbestos and crystalline silica.08.EN . respirable dust and inhalable dust are those fractions of the airborne dust which will be collected when sampling is undertaken in accordance with the methods described in MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust. depend on the nature and size of the particle. The COSHH definition of a substance hazardous to health includes dust of any kind when present at a concentration in air equal to or greater than 10 mg/m3 8-hour TWA of inhalable dust or 4 mg/m3 8-hour TWA of respirable dust. The behaviour.are assigned the risk phrases 'R45: May cause cancer'. Advice on control is given in EH44 and in the great majority of workplaces reasonable control measures will normally keep exposure below these levels. Inhalable dust approximates to the fraction of airborne material that enters the nose and mouth during breathing and is therefore available for deposition in the respiratory tract. However some dusts have been assigned specific WELs and exposure to these must comply with the appropriate limit.210 mg/m3 2000-06-16 2000/39/EC TWA 500 ppm 2005-04-06 GB EH40 Indicative 67-64-1 7 / 14 .3-diene Propan-2-ol 67-63-0 TWA 400 ppm 999 mg/m3 2006-09-01 GB EH40 67-63-0 STEL 500 ppm 1. The identified substances include those which: .a substance or process listed in Schedule 1 of COSHH. This means that any dust will be subject to COSHH if people are exposed above these levels.08.2011 106-97-8 STEL 750 ppm 1. 1907/2006 LD7 Liquid Developer Aerosol Version 2.0 Revision Date 02. Respirable dust approximates to the fraction that penetrates to the gas exchange region of the lung. all the relevant limits should be complied with. a figure three times the long-term exposure should be used TWA 500 ppm 1. HSE distinguishes two size fractions for limit-setting purposes termed 'inhalable' and 'respirable'. 'R49: May cause cancer by inhalation' or .SAFETY DATA SHEET according to Regulation (EC) No. 'R46: may cause heritable genetic damage'. Fuller definitions and explanatory material are given in MDHS 14/3.

Recommended Filter type: AX-P2 Hand protection : Neoprene gloves butyl-rubber Protective gloves complying with EN 374. Wash hands before breaks and immediately after handling the product.08. Avoid subsoil penetration.210 mg/m3 67-64-1 STEL 1. Personal protective equipment Respiratory protection : In case of insufficient ventilation. Avoid contact with skin and eyes.EN .500 ppm 3. Eye protection : Tightly fitting safety goggles Eye protection (EN 166) Skin and body protection : Chemical resistant protective clothing according to DIN EN 13034 (Type 6) Hygiene measures : Take off contaminated clothing and shoes immediately. drink and animal feedingstuffs. Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. Do not breathe spray.2 Exposure controls Engineering measures Provide sufficient air exchange and/or exhaust in work rooms.SAFETY DATA SHEET according to Regulation (EC) No. Also take into consideration the specific local conditions under which the product is used. wear suitable respiratory equipment.0 Revision Date 02. such as the danger of cuts.08.620 mg/m3 2005-04-06 GB EH40 8. and the contact time. Do not breathe vapour.2011 Print Date 04.2011 1. Keep away from food. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. abrasion. 8 / 14 . 1907/2006 LD7 Liquid Developer Aerosol Version 2.

10.2 Chemical stability Stable under normal conditions.1 Reactivity No dangerous reaction known under conditions of normal use.5 Incompatible materials Materials to avoid : Strong acids and oxidizing agents 9 / 14 .1 Information on basic physical and chemical properties Appearance : aerosol Colour : white Odour : alcohol-like Flash point : Boiling point/boiling range 12 °C Method: ASTM D 93 Active substance -60 °C Butane/Propane : not applicable Density : 0.EN . 10. 1907/2006 LD7 Liquid Developer Aerosol Version 2.2011 Print Date 04.08. Stability and reactivity 10.96 g/cm3 at 20 °C Water solubility : completely miscible 9.SAFETY DATA SHEET according to Regulation (EC) No.3 Possibility of hazardous reactions Hazardous reactions : Vapours may form explosive mixture with air. Protect from frost.2 Other information Explosivity : no data available 10.0 Revision Date 02. 10. hot surfaces and sources of ignition.2011 9. Physical and chemical properties 9. heat and sunlight. 10.4 Conditions to avoid Conditions to avoid : Keep away from open flames.08.

76 mg/l Exposure time: 4 h Species: rat : LD50: 13.211.08.0 Revision Date 02.6 Hazardous decomposition products Risk of decomposition. 1907/2006 LD7 Liquid Developer Aerosol Version 2. Serious eye damage/eye irritation Eye irritation : Causes serious eye irritation.570 mg/kg Species: rat Acetone : LD50: 5.EN .08. 11.800 mg/kg Species: rat Acute inhalation toxicity : Acute toxicity estimate: 2. : No decomposition if stored and applied as directed.2011 Print Date 04.38 mg/l Method: Calculation method Acute inhalation toxicity Propan-2-ol Acetone Acute dermal toxicity Propan-2-ol Acetone : LC50: 30 mg/l Exposure time: 4 h Species: rat : LC50: ca. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity Propan-2-ol : LD50: 4.2011 10. 10 / 14 .000 mg/kg Species: rabbit Skin corrosion/irritation Skin irritation : May cause skin irritation in susceptible persons.400 mg/kg Species: rabbit : LD50: 20.SAFETY DATA SHEET according to Regulation (EC) No.

000 mg/l Exposure time: 24 h Species: Daphnia Acetone Toxicity to algae Propan-2-ol Acetone Toxicity to bacteria Propan-2-ol : EC50: 12.000 mg/l Exposure time: 72 h Species: Desmodesmus subspicatus (green algae) : 3.2011 Print Date 04.EN .540 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) Toxicity to daphnia and other aquatic invertebrates.970 mg/l Exposure time: 48 h Species: Leuciscus idus (Golden orfe) : LC50: 5. Propan-2-ol : EC50: > 1. Ecological information 12.2 Persistence and degradability 11 / 14 . Toxicity to fish Propan-2-ol Acetone : LC50: 8.08.0 Revision Date 02.08.400 mg/l Exposure time: 48 h : IC50: > 100 mg/l Species: Bacteria 12. 12.1 Toxicity Ecotoxicology studies for the product are not available.600 mg/l Exposure time: 48 h Species: Daphnia : IC50: > 1. 1907/2006 LD7 Liquid Developer Aerosol Version 2.2011 Respiratory or skin sensitization Sensitisation : no data available Further information : Vapours may cause drowsiness and dizziness.SAFETY DATA SHEET according to Regulation (EC) No.

Disposal considerations 13.6 Other adverse effects Additional ecological information : slightly water endangering Do not flush into surface water or sanitary sewer system.1 (D). Do not allow material to contaminate ground water system. 1907/2006 LD7 Liquid Developer Aerosol Version 2.08.FLAMMABLE Butane.2011 Print Date 04. Contaminated packaging : Dispose of as unused product.EN .1 Waste treatment methods Product : Dispose of in accordance with local regulations. ADR UN number UN proper shipping name Transport hazard class(es) Classification Code Packing instruction (LQ) Labels Tunnel restriction code Environmentally hazardous : : : : : : : : 1950 AEROSOLS Butane. 13.5 Results of PBT and vPvB assessment no data available 12.2011 : no data available 12. Transport information 12 / 14 . no IATA UN number Description of the goods Class : 1950 : AEROSOLS.4 Mobility in soil Distribution among environ: no data available mental compartments 12. preferably in discussion with the waste disposal authorities. Propane 2 5F LQ2 2.SAFETY DATA SHEET according to Regulation (EC) No.1 14.3 Bioaccumulative potential Bioaccumulation : no data available 12.0 Biodegradability Revision Date 02. Waste Code : Waste codes should be assigned by the user.08. Propane : 2.

13 / 14 .SAFETY DATA SHEET according to Regulation (EC) No.1 F-D S-U no RID UN number Description of the goods Transport hazard class(es) Classification Code Hazard identification No Labels Packing instruction (LQ) Environmentally hazardous : : : : : : : : 1950 AEROSOLS Butane .08.2 Chemical Safety Assessment A Chemical Safety Assessment is not required for this substance. health and environmental regulations/legislation specific for the substance or mixture Water contaminating class (Germany) : WGK 1 slightly water endangering VWVWS A4 Other regulations : The product is classified and labelled in accordance with EC directives or respective national laws.0 Revision Date 02. : Classification / Labeling according to Directive 2008/47/EU.EN . Propane 2. 15.1 LQ2 no 15. 1907/2006 LD7 Liquid Developer Aerosol Version 2.2011 : no IATA_P Environmentally hazardous : no IMDG UN number Description of the goods Class Labels EmS Number 1 EmS Number 2 Marine pollutant : : : : : : : 1950 AEROSOLS Butane.1 Packing instruction (cargo aircraft) IATA_C Environmentally hazardous : 203 Print Date 04. Propane 2 5F 23 2.1 Safety.1 2. Regulatory information 15. Regional or national implementations of GHS may not implement all hazard classes and categories.08.2011 Labels : 2.

2011 Print Date 04. Vapours may cause drowsiness and dizziness. May cause drowsiness or dizziness. Full text of Notas referred to under section 3 Nota C Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers. The delivery of this safety datasheet does not free the recipient of the product from his own responsibility to follow the relevant rules and regulations concerning this product. In this case the manufacturer or any other person who markets such a substance must state on the label whether the substance is a specific isomer (a) or a mixture of isomers (b). Extremely flammable. Example: (a) 2. In Annex I. Extremely flammable aerosol.08.2011 16. these are not guaranteed.08. Regarding the product properties. 14 / 14 . Full text of H-Statements referred to under sections 2 and 3. Further information The information provided is based on our current knowledge and experience and apply to the product as delivered.0 Revision Date 02.EN .4-dimethylphenol (b) xylenol (mixture of isomers). Irritating to eyes. Repeated exposure may cause skin dryness or cracking. 1907/2006 LD7 Liquid Developer Aerosol Version 2.SAFETY DATA SHEET according to Regulation (EC) No. Other information Full text of R-phrases referred to under sections 2 and 3 R11 R12 R36 R66 R67 Highly flammable. a general designation of the following type is sometimes used: "xylenol". Highly flammable liquid and vapour. H220 H222 H225 H319 H336 Extremely flammable gas. Causes serious eye irritation.