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NARAYANA IIT ACADEMY

INDIA
Sec: Sr.IIT ALL STREAMS & LT-IIT

PHASE -II

Date: 01/04/14

GRAND TEST-4

Max Marks:360

KEY SHEET
PHYSICS :1) 4

2) 3

3) 3

4) 3

5) 2

6) 3

7) 4

8) 4

9) 2

10)4

11) 4

12)2

13)1

14) 1

15)1

16)1

17)3

18) 2

19)3

20)4

21) 3

22)2

23)4

24) 3

25)3

26)4

27)2

28) 1

29)1

30)2

CHEMISTRY :31) 2

32)2

33)2

34) 3

35)1

36)1

37)2

38) 3

39)2

40)3

41) 1

42)1

43)2

44) 3

45)1

46)3

47)4

48) 3

49)2

50)1

51) 3

52)3

53)3

54) 2

55)3

56)4

57)3

58) 4

59)3

60)3

MATHEMATICS:61) 2

62)2

63)2

64) 4

65)2

66)3

67)2

68) 1

69)1

70)2

71) 2

72)4

73)1

74) 2

75)1

76)1

77)3

78) 3

79)1

80)3

81) 1

82)1

83)4

84) 1

85)2

86)1

87)2

88) 4

89)3

90)4

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01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4

PHYSICS
1.

Vm 3i

Let VR ai bj
VRM VR Vm

= 3iai bj
VRM3 ai bj
VRM. Vertical
i.e 3 a 0
a3

If Vm 6i

VR1M 6iai bj
VR1M6 aibj

It is 450 with vertical


i.e , 6 a b
63 b
b3
VR 3i 3 j
VR 3 2 kmph

2.

Given vR 36
V 2 369 ; V18V
Equivalent of 6

&9

69 18
3.6
15
5
3.6 and
2

Are in series
So vR

3.

1 8 3 .6
V2
2
V2 10V
x 3t2t3

V1
R1
V2

R2

When x is maximum dxt 0 d


d
x

t3t 2 0
dt
6t 3t2
3t 6 t2
x 0. 3t 2 t3
t 3 s ec
When t 4sec

maximum x

x 348
4m
x 316 6416m

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So distance travel . 4 416 24m


4.

P1000kw103103 J / sec
Energy in one hour 1063600J
36108 J
mass decay E2 36106 8
C
9101
410 kg 40g 8

5.

PE at the top of the inclined plane


= work done against friction
mgh mg L cosmg L
cos

hL
cos1
13 2
h cos
3
L
2
3

s
i
n

cos 2 tan
2

6
.

E l El 1
l 5 3l / 2
l 2 l1
53
l1 3l
10
F ks1/3

7.

m d ks1/3
dt
m d ds ks1/3

s dt
m d ks1/3ds
ds
m ks 2
2
2/3
1/3
s

2/3

P FV
P s1/3s1/3
P s0

8.

9.

8q 2q
x 2 x L2
2 1
x xl
2 x 2L x
x 2L
F f Ma translational motion

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FR fR I I a Rotational motion
R
F

I 2 MR 2
5

F f Ia2 (1)
R
F f Ma (2)

Solving
a 10 F
7
M

10.

Mean square value2

v dt
dt

For T

4
v at ( up to T/4increases with time)

At t T / 4, V v0
v0 aT
4
4v0
a

T
T /4

v2dt

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01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4

t 2 dt
T /4

dt

dT

16v2t /
30
0

T /4

T /4

T
V0 2
3
v
v0

r
m
s

11.

Equation of the particles are


x1 Asinwt

x2 Asinwt

When they meet AsinwtAsinwt

2Asinwt / 6 0
wt 5
6
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t 5 5T
5T

t
6

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6w 6.2 12

Altier

A to A T

01/04/14_ Sr.IIT ALL STREAMS &

LT-IIT _Phase-II_JEE-Main_GTM-4

They meet at the mean position


-AA 0 T so T T 5T
4

12.

4 6 12

No.of beats 220 10


If tuning fork frequency is n.
n10 10.2 n

1
0
9
.
2

n
194Hz

dF

Gm.dx

x2
Gma bx2dx
dF
x2

la

F= Gm xa2 dx Gmb dx

dx

=
Gmax 1
Gmbl


Gma 1 1bl

1
4
.

l
I4

x
I0 cos2 / 2 3 I0
4
cos
/ 2 3
2

/
2

3
0

60

x 6

As it is formed between 5th maxima and 6th minima


x

5 31
6
6
31t
6

31

t 3
2
1

15.

substituting t=9.3m

When separation occurs


2

mg m r
g w2 r
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01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4

r g2
w
T1sec , w 2
r g 2 1 0.25m
4
4

16.

surface tensional force wt.of the liquid column


2 d1 d2T d2 d1hg

2
2

4T
h
d2d1g

17.

4R2x
4R3w
3
R
x

w1

x R
3

18.
19.

2 2
h r w 25104222 m 0.02m

2g
210

T
2m1m2g
m1 m2

S T2

2.m.2mg
3
m
r 4mg
3
s

20.

Stoping potential 1.1V


i.e. KEma 1.1eV
h

w0 KEma

4000A0

12400 w1.1eV w 2eV


4000

T
s

21.

0 12400 6200A0 620nm


2
at at 2
d e a 2at
dt
2

dt e dt R

H P

H
0

1a

2at2 dt
R
1a22 4a t 4a . t
2 3

2 0

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1a23 4 a23
2a23
3
R

a3 43 23
3
R

a 413
R 3
a3 2
3R

22.

In FM Band width is less

23.

Boi0 e
2
2r T
T r
3/ 2
r
Br13/2 15/2
.r
r
rn 2

24.

B 15
n

Voltage gain = Av V0IIc


Roi v
5mA
6k50
A 600

in

bR

=1000
25.

After two hours


F
o
u
r
h

x : y No : No 1 : 1
22

ours

o : 3 No 1 : 3
4
4

Six hours 8 8
No : 7No1: 7

26.

Here it is 1 : 4
So t > 4 hrs
If u x

< 6 hrs

10 x
f12cm
11 1
u
f
1 1 1 solving
x 10 x 12
u x 20cm
30
M 1 5
M v / u 1.5

2
7
.

Y A BA
B
A B A

B
AA AB AB BB
O AB AB O

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2
8
.

AB ABOR gate
dQ mSdT

dQ
mA T

dt

20

= mA T4

2
9
.

01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4

mA204 mA16104 4mA104


4
4

h R 1 2 12

n
1

R n2n 2n21 if n >>1


nn1

R42n 13
n
n

3
0
.

Initial int ernal energy 4CvdiaT 4 5R T


2
final int ernal energy 2Cvdia T 4Cvmono T

2 5 R T 4 3R T

1
R

Then Q11RT10RT RT

CHEMISTRY

31. Volume strength 5.6 Normality


32.
M gBr

COOM gB r

C OOH

Mg

CO2

33.

H2O

5 f 14, 6d 3 Total 17e


5 f 14 (n l) 5 3
8

34.
35.

6d 3 ( n l ) 6 2
8

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01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4

CH 3

CH 3

CH 3

Br

Br

r2

Sn/

HCl

HB

NO2

NO2

NH 2

(B)

(A)

C
O
O
H

CH 3

CH 3

Br

B
r

MO
K n 4

(E)

O
H2
OH

Br

(D)

H3 2
PO

2-bromobenzic acid

2Cl

(C)

36.

V H 2 V He 1 1
H2He
R 12 12 Rz2 12 12

n1

4
n2

n1 1 &
n2 2

39.

Vender wall's equation for 1 mole gas is p a2 (v b) RT

AT low p,

volume is
High. so (Vb)=V
p a2 v RT

(or) PV + a RT
V

PV RT a
V

40. Work done 1 (4P1 P1)(3V1 2V1)


2

4
4
.

= 3 P1V1
It is a basic buffer
pH = 8.65

pOH 14 8.65 5.35

POH=

pkb

log [NH4 ]
[NH4OH ]

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5.35 = 4.75 log [NH4 ]

[NH4OH ]

[NH4 ] anti log(5.35 4.75)


[NH4OH ]

[NH4 ] 0.2 30 4
[NH4OH ] 0.3V1
V= 5 ml

45. 1-alkyl halides follows SN2 path and walden Inversion takes place
46. B2H6+6H2O 2H3BO3+6H2
3B2H6+6NH3a0b0o
2B3N3H6+12H22vCe
4
7
.

A2B3 2A3+ + 3B2-

Ksp 108x5
4 58.5g - No. of unit cells 61023

1 gram = ?
48.
1 61023 2.561021
458.5

Al2(SO4)3 2Al3 3SO42

0
.
Initially let
After

1
1

i 1 2 3 4.2
1
1 4 4.2
4 3.2 3.2 0.8 80%
4
TfA 2
52. Given
1 e
TfB 1 1 / 2
B should associate to show lower inT

54. Cell reaction : 2Fe3++Fe 3Fe2+


E0ell 0.77 (0.44)1.21 spon tan eous c
Fe3 & Fe will reduce

55.

Al3++3e- Al
1 mol Al = 27g = 3F
13.5 gr of Al = ? F= 1.5F

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57.

01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4

Order with respect to A 0.03x 45


5

0
.
0
1

3 3 x 2
x

Order with respect to B 0.02x 5


0.01

2.5

2 2 y = 1
y

Rate = K

A2B1

59.

I order 100%t1/2 50%H2 25%

Given 2t1/2 1hr


t1/2 1 hr
2
28VN2 at STP100
60. %N
22400WoC
28 22.4100 11.2%
22400 0.25

6
1
.

6
2
.

MATHEMATICS

Tr 100cr (51/6)100 (21/8 )r As 5 and 2 are relatively prime, Tr+1will be rational if 100 r
r

r are both integers 100-r is a multiple of 6 and r is a multiple of 8, 100-r is

and 8
multiple of 6 if r = 4, 12, 20 100 of which 12, 36, 60, 84 are divisible by 6. Hence,
there are just four rational terms. no. of irrational terms is 101 - 4 = 97.
2

Z = rei Then
2

12

r cos 3 r
=r=3
3
3

(ei ei )2 1 r3 r2

3 r2

3 max value of |z|

1 cos2

63.

If the lines a1 x +b1 y+c1 = 0 and a2x +b2y+c2 = 0 meets the axes is concyclic points
then a1a2 = b1b2

64.

Sol : A (x1, y1) be any point on parabola y2 = 4x and B (h,k) is its image w.r.t

x-y+13

h x1 k y113 0

= 0 then

k y1 (1)1 x h13, yk13


1

hx
1

h132 4k13

65.
66.

and

Formula application
Taking the coordinates of vertices O,P,Q,R as (0,0), (a,0), (a,a), (0,a) respectively we
get the coordinates of M as a, a and of

a ,a

N as

Area

2 h 2 ab

.
68.

Shortest distance is 0.

69.

foot of the perpendicular A (1,0,2) to the line is B 1 ,1, 3 /

2
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70.

01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4

we find dxt when x 1 and y 23 given that dyt3 units/s and x2 y2 1


d

Differentiating x2 y2 1, we have 2x dxt 2 y dyt 0


d

Putting x 1 , y 23 and dyt3 , we have 1 dxt 23 (3) 0 dxt 3 3


2
L
t

7
1
.

Clearly

x
0

1
1

x x

xe

2d

0 f0 Continuous at x = 0

1 1

x x

L
t

x
e

L
e
t

L
t
x

Lt
x0

x0

x0

x0

1 1

x x

fx f0 Lt xe
x0

01

x0

0 = Lt
x0

Not differentiable at x = 0
72.

1 , 1 are the roots of cx2 bx a 0

cx 2 b x a c x 1 x 1

e2 / x 0

73.

T : x -x = 0 is integers reflexives y - x is integer symmetric (x-y) + (y-z) = x -z is


integers transitive T is equivalence and S : y - x = 1 x - x 1 not reflexive.

cos

7
4
.

x dx cos2 x cos2x dx

1 a

1 a x

0
/2

1 ax

cos2 x dx

cos2 x

dx2

75.

[2sin

(1)dx

(2)dx

(2)dx

x]dx

11
2

(1 )dx

11
6

dy x2 xy y2 is a homogeneous differential equation, put y = vx.

6
.
dx

7
7

x2

We have ex cos xdx 1 exsin x cos x2

.
Therefore, I x. 1 exsin x cos x
2

exsin x cos xdx e


2

x exsin x cos x 1 excos x sin x dx


2

2
x exsin x cos x 1ex cos x c
2

78.

1 ex x sin x x cos x cos x c


2
from truth table pq p p p q

We have

9
.

100

c50 100!
50!50!

sin xdx

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The exponent of 7 in 50! is57050 71 8

72

And the exponent of 7 in 100!


10017020 14 2 16 ,

Thus, exponent of 7 in C50 is 16 28 0 100

80.

total no of ways of answering is 15. Out of 15 combinations only one is correct. The
probability of ticking the answer at the first .. is 115 , that of 2nd is 14 .114 115 and that
of 15
third is 14 .13.113 115 probability that the student will get marks for the question if
15 14

he is allowed into 3 chances


3115 1 .

8
1
.

Let f x x 2ax a a 3 0

Then (i)

(ii) sum of root <6

(iii) f3 0

82.

b 2ac ; c 2bd
ac
bd
c

(a c)(b d) 2ac . 2bd 4 ad ab bc cd ad 4ad


b

x
2

8
3
.
84.

i
1

400

n 16 hence, possible value of n = 18.

80
n
n
n
cot tan m sec2. m tan1
sec cos n tan2. n sec2

tan2 nnm2

1/3

from (1) & (2) similarly sec2 mn2m1/3 eliminate


85.
8

sin1sin 3 3
sin1sin 4 4

AD 2BC x 2

sin1sin 5 5 2

sum2

xy 4

CF 2BA y 2
E

87.

for no solution or infinitely many solutions


1
1
1

1 012 2 0
1

1,1, 2

but for = 1, there are infinite solutions when = -2, we have


2 x y z 3,
x 2 y z3 x 2 y 2z3 adding 0 = - 9, which is not true no
solution.

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88.

01/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-4

AA ' I
0

0 1 0

0
00

1 0 1 0

0 0 1

0 0 0 1

0
0

1
0

0 1 0

0
(-1, 2)

C (2 , 1 )

89.

01

The two shaded areas are congruent


Area = The area ACEF
1
area of circleOAD
4

9
0
.

5 1 5 2 .
42
4
2
2
Differentiating x 2 y y c, 2x 4 yy1 y1 0 2x4y1 y1

Replacing y by 1 , 2xdy 4y1


y1 dx

44ydy1
2

dxx

ln4 y1 lnx ln c1
2

4 y1 c1x2

Sr.IIT ALL STREAMS & LT-IIT_JEE-MAIN

y cx2 1 , 4c c1.
4

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