8 views

Uploaded by jamy862004

CRE Tutorials questions

- Digiovanni Castlegate
- Predicting the Permeability of Pervious Concrete From Non-Destructive Electrical Measurements
- Pore Pressure.docx
- Tight Gas Sandstone Reservoirs in China, Characteristics and Recognition Criteria - Zou Et Al. 2012
- Scale of Experiment and Rock Physics Trends
- 35 4 WASHINGTON DC 08-90-1418-Lime Injection
- L16 Formation Pressure w10c
- SPE-56417-MS
- 95510-9393 IJET-IJENS
- Chapter 7
- Final Presentation Arias Et Al
- RX126[1]
- 01-Introduction to Well Testing
- Form Damage
- Dr. Hilmi S. Salem Determination of Porosity Formation Resistivity Factor Archie Cementation Factor and Pore Geometry Factor Energy So-libre
- SPECIFICATION AMORPHOUS SILICA
- ch10_1.pdf
- garca2016
- Diffusion_Experiment_2009
- 1-s2.0-S1359835X99000639-main

You are on page 1of 2

1. The reaction is first order. Find the role played by internal diffusion in the

following cases. The experiments are conducted in a CSTR. Classify as diffusionfree, strong diffusional resistance, and intermediate case. Units are all consistent

with each other.

(a)

dp

W

CA0

Vol flow rate

XA

3

1

100

9

0.4

12

4

300

8

0.6

(b)

dp

4

8

W

1

3

CA0

300

100

60

160

XA

0.8

0.6

W

4

6

CA0

50

100

10

5

XA

0.2

0.6

(c)

dp

2

1

k e 1.6kJ / m / hr / K

De 5 x10 5 m 2 / hr

L 4 x10 4 m

hT 160 kJ / hr / m 2 / K

C Ab 20 mol / m

k m 300 m / hr

5

H 160 kJ / molA

3

robs 10 mol / m / hr

(a) Is external mass transfer important to consider?

(b) Are there significant limitations due to pore diffusion?

(c) Do we expect significant temperature gradients within the pellet & outside? (not

covered in the class. Pl refer Fogler)

3. Consider the liquid phase reaction CH 3 COOH 2O2 2CO2 2 H 2 O . The catalyst

consists of Mn, Co, La oxides on a zinc aluminate carrier. Three sizes of the

catalysts (in terms of equivalent spherical diameter) are used 0.038; 0.054; 0.18

3

3

cm. At 260 0C, the robs 2mol / m / hr (0.054 cm) & robs 1.4mol / m / hr (0.18

cm).

(a) For the 0.054 cm, it is to be assumed that the effectiveness factor is 1. Find

the effectiveness factor for the 0.18 cm pellets

(b) Based on the following data, calculate the true & apparent activation

energies

1000/T (K-1)

rco2x107 (gmol/gcat/s)

0.054 cm

0.18 cm

1.807

3.55

2.10

1.842

1.876

1.912

2.60

2.00

1.42

1.70

1.40

1.13

i)

ii)

iii)

Cracking of gas oil at 500oC: Catalyst particle diameter 1/8th inch. Mean pore

radius 30A. Pore volume is 0.37 cc/gm. The molecular weight oil is 150. At

atmospheric pressure with 30 oA radius the diffusion is of Knudsen type.

The rate constant interpreted from the experiments is 0.25 cc/s.g catalyst.

Assume that tortuosity factor of 3.0 is applicable.

Dehydrogenation of n-butane takes place on spherical chriomia-alumna

catalyst at 530oC. The catalyst size is 0.32 cm and the experimental data in

laboratory suggest a first order rate constant of about 0.94cc/s.g catalyst. The

pore radius is given as 110 oA. Assuming Knudsen diffusivity at this low

pressure and estimating the pore volume as 0.35 cc/g, predict an effectiveness

factor of the catalyst. Tortuosity factor of 3.0 is applicable.

Pyrolysis of n-octane gives an apparent rate constant of 0.25 cc/sec. g catalyst.

The data was obtained at atmospheric pressure with a monodispersed catalyst

whose average pore size of 30 oA. Other properties are: Particle size: 1/8 inch,

porosity: 0.35 cc/gm, tortuosity factor 2.0 and surface area 230 m2/gm cat.

Given: Knudsen diffusivity is related to temperature as

1/ 2

Dk 9.7 x 10 a

MA

Where a is pore radius in cm, D in cm2/sec and T is in K

3

5. Derive the equation for the effectiveness factor for the porous slab (thickness L)

of the catalyst in which diffusion takes place only in one direction i.e

perpendicular to the face of the slab. Reaction is first order reversible and external

mass transfer is negligible. .

- Digiovanni CastlegateUploaded byMehdi Alizadeh
- Predicting the Permeability of Pervious Concrete From Non-Destructive Electrical MeasurementsUploaded byMarcelo Henrique
- Pore Pressure.docxUploaded bynoor
- Tight Gas Sandstone Reservoirs in China, Characteristics and Recognition Criteria - Zou Et Al. 2012Uploaded byDavid Cova
- Scale of Experiment and Rock Physics TrendsUploaded bySando Crisiasa
- 35 4 WASHINGTON DC 08-90-1418-Lime InjectionUploaded byblaireauxx
- L16 Formation Pressure w10cUploaded byMohammad Iqbal Mahamad Amir
- SPE-56417-MSUploaded byDaniel Camilo Bustos
- 95510-9393 IJET-IJENSUploaded byReza Febyanto
- Chapter 7Uploaded byIvan Boscho Naibaho
- Final Presentation Arias Et AlUploaded byPresa Gio
- RX126[1]Uploaded byElZeroMJ
- 01-Introduction to Well TestingUploaded byDuong Duong
- Form DamageUploaded byMahmoud Ahmed Ali Abdelrazik
- Dr. Hilmi S. Salem Determination of Porosity Formation Resistivity Factor Archie Cementation Factor and Pore Geometry Factor Energy So-libreUploaded byanouari2014
- SPECIFICATION AMORPHOUS SILICAUploaded bydivyesh_parihar
- ch10_1.pdfUploaded byBinu Kaani
- garca2016Uploaded byAnonymous u7Z8KWX
- Diffusion_Experiment_2009Uploaded bytaj232
- 1-s2.0-S1359835X99000639-mainUploaded byFernando Volpatto Ramos
- chuah2016Uploaded byAndrew Pi
- Chen 2008Uploaded byBrian Antonio Perez Balarezo
- Lecture_3_-_Final_for_Posting.pdfUploaded byAsahel Nuñez
- Bits Pilani-shivam SrivastavaUploaded byShivam Srivastava
- PorosityPermeability.pdfUploaded byVennela Vasupilli
- PET524-2a-permeability.pdfUploaded bymhdstat
- definisi katalisUploaded bysophiaallamin
- Utilization of Scoria as Aggregate in Lightweight ConcreteUploaded byInnovative Research Publications
- Effect of Water to Cement Ratio and Age on Portland Composite Cement Mortar Porosity, Strength and Evaporation RateUploaded byAJER JOURNAL
- 06 InfiltrationUploaded bykardra

- NileshUploaded byjamy862004
- 1001463.pdfUploaded byjamy862004
- 1001497.pdfUploaded byjamy862004
- 1001497.pdfUploaded byjamy862004
- ashish.pdfUploaded byashish
- topics-mathematical_physics.pdfUploaded byjamy862004
- Indian-Economy-For-Civil-Services-Examinations-7edition.pdfUploaded byjamy862004
- CTT PaperUploaded byjamy862004
- CT paperUploaded byjamy862004
- SCFM vs ACFM Conversion GuideUploaded byFreddy Salvatierra Saavedra
- Notes 24.2.18.txtUploaded byjamy862004
- prac (2) (4) (1)Uploaded byjamy862004
- OverlapUploaded byjamy862004
- Practise ProblemsUploaded byjamy862004
- Additional ProblemsUploaded byjamy862004
- fuck you scribd for making us do an upload!Uploaded byjamy862004
- MBA (Oil & Gas)MBA (Oil & Gas)Uploaded byjamy862004
- MTech Sem 1 SyllabusUploaded byjamy862004
- CASE 1Uploaded byjamy862004
- CL 601_HW1_2016Uploaded byjamy862004
- Greens Function and SL operator.pdfUploaded byjamy862004
- Checklist Before Taking Possession of Your New ApartmentUploaded byjamy862004
- Checklist Before Taking Possession of Your New ApartmentUploaded byjamy862004
- Pda GraphicsUploaded byjamy862004
- Std11 Acct EM[1]Uploaded byniaz1788
- Industrial Reactors 1Uploaded byjamy862004

- Magnetic Properties 2Uploaded byAhmed Shehab Ali
- Magnetocaloric Effect in Melt-spun MnCoGe RibbonsUploaded bySumith Saleheen
- Experiment 1 MagnetismUploaded byNur Atikah Shuhada Rosli
- 4 Periodic Table of ElementsUploaded byIza MohdSabri
- Food Grade HexaneUploaded byAnonymous FwS0w7xh7c
- DPP 04 Ionic Equilibrium JH Sir-4295Uploaded byT sidharth
- Chemical World Lesson PlanUploaded byellencolusso
- 202917Uploaded byAgustynho Magimba
- MeldeExperiment 14Uploaded byCharles
- 12.Environmental Chemistry 211-221Uploaded byeamcetmaterials
- Refrigeration and Airconditioning2Uploaded byAbdelsattar
- nasa20unit20workUploaded byapi-263461177
- Pleiadian CivilizationUploaded byEskay
- 2014 chemistry cbse sample paperUploaded byVijaykumar Shukla
- MasterGlenium SKY 8522 v1Uploaded byJaga Nath
- IIT Class XI Phy Rotation MotionUploaded bysatish jadhav
- PAPER1 ft5.pdfUploaded byshreyash
- Sub Grigore ScuUploaded byVaibhav Rana
- Goldstein_18_21_13_14_20[1]Uploaded byAbdul Shakoor Butt
- Optoelectronics SyllabusUploaded byabdulbabul
- Student Unit Op Lab manual_Thin Film Evaporator.pdfUploaded byMuiz Moktar
- DETERMINATION METHOD OF THERMAL CONDUCTIVITY OF BUILDINGPARTS IN SITU THROUGH IR IMAGING BY MINIMIZING THE INFLUENCE OFENVIRONMENTAL PARAMETERSUploaded byG.-Fivos Sargentis
- Accretion Disk ArticleUploaded byNikos Lesgidis
- vertebrate and invertebrate metabolism of polycyclic aromatic hydrocarbonsUploaded byapi-308990474
- Infrared Spectroscopy Tutorial RevisedUploaded byOlivia Rae Irving
- Theoretical Explanation of the Biefield-Brown EffectUploaded byDalep
- Decl Conf XPS30Uploaded byirini
- etilenglicolUploaded byMauricio Agudelo
- Rate Based vs Equilibrium ModelUploaded byzorro21072107
- Reduction of Chemical Effects of Swelling and ShrinkageUploaded byAkshay Setlur