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Roll No.

xE

SS41Chem. (Supp.)

No. of Questions 30
No. of Printed Pages 15

=SS vE {E {I,

2013

SENIOR SECONDARY SUPPLEMENTARY EXAMINATION, 2013

x Yx
CHEMISTRY

1
4

Ph]

{hE : 56
x] : Eh E +E i i ii { JB*
{Il E B x xn :
GENERAL INSTRUCTIONS TO THE EXAMINEES :
1.

{Il |l +{x |x {j { xE +xi: J*


Candidate must write first his / her Roll No. on the question paper
compulsorily.

2.

|x Ex +x *
All the questions are compulsory.

3.

|iE |x E =k n M< =k-{iE J*


Write the answer to each question in the given answer-book only.

4.

Vx |x +xiE Jhb , =x E =k BE l J*
For questions having more than one part the answers to those parts
are to be written together in continuity.

5.

|x {j E xn +OV {xi E |E E j] / +xi / v x


{ xn E |x E x*
If there is any error / difference / contradiction in Hindi & English
versions of the question paper, the question of Hindi version should
be treated valid.

SS41Chem. (Supp.)

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6.

7.

|x J

+E |iE |x

1-13

14-24

25-27

28-30

Q. Nos.

Marks per question

1-13

14-24

25-27

28-30

|x GE 21, 27, 28, 29 30 +xiE E{ *


Question Nos. 21, 27, 28, 29 and 30 have internal choices.

1.

EU xE {nl +xSEi Mh i * <E C Eh ?


Some chemical substances show paramagnetic property. What is the

reason ?

2.

n-

il p-|E E +rSE xx i Ex G: Ex- ii i ?

What elements are added respectively to make silicon n-type and

p-type semiconductors ?

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3.

E j] AgCl G] E Pxi E {ii C x Ei ?


Why does Frenkel defect not change the density of AgCl crystals ?

4.

BE x E 500 ml 4 g NaOH * <E i Yi EVB*


500 ml of a solution contains 4 g NaOH. Calculate its molarity.

5.

+G

A B

+G n nMx Vi V

E pi E S Mx

g Vi * < +G E E] i<B*
In reaction, A B rate of reaction is doubled when concentration of A
is increased four times. Give the order of reaction.

6.

+G

C12H22O11 + H2O

H+

C6H12O6 + C6H12O6

ME

<I-E

C]V

E M VE JB*
Write the rate expression for the reaction

C12H22O11 + H2O
Cane sugar

SS41Chem. (Supp.)

H+

C6H12O6 + C6H12O6
Fructose
Glucose

. SS441.

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7.

VE ( Z = 30 ) E Gh ii x x M * Eh nVB*
Zinc ( Z = 30 ) is not regarded as a transition element. Give reason.

8.

[ Co ( en ) 3 ] 3 +

Yi EVB

a)

Co

E +CEh +l

b)

Co

E x J*

Determine in [ Co ( en ) 3 ] 3 +

9.

a)

oxidation state of Co

b)

coordination number of Co.

il Mb E ti {x Ex i <xE Ex- E +x E ={M


Ei ?
For electroplating of silver and gold which of their complex ions are

used ?
10.

|{x |{xx n E EM ? {Ih J*


How will you distinguish between propanal and propanone ? Write the
test.

SS41Chem. (Supp.)

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5
11.

b<BVEh +G E Eh nVB*
Give the equation of diazotisation reaction.

12.

+E il +xE Bx + C +i ?
What is the difference between essential and non-essential amino

acids ?

13.

ME E +h CHO E ={li xSi Ex i +G JB*


Give reaction to confirm the presence of
molecule.

14.

a)

CHO

group in glucose
1

r E il BE x E { n B i{ E v +J JSx {
G: |{i G E Sj x<B*

b)

xEx V xi Jx { v EEB Ec Vi * Eh
nVB*

a)

Draw the diagram of the curves obtained by plotting a graph


between vapour pressure and temperature of pure solvent and a
solution, respectively.

b)

Blood cells collapse when suspended in saline water. Give


reason.

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15.

H2

il O2 E ={M Ex <vx E SU B xEi Sj x<B* <

<C]b +G+ E Eh JB* <vx E BE ={M nVB*


Draw labelled diagram of fuel cell using H2 and O2. Write the equations
of electrode reactions. Also give one use of the fuel cell.

16.

Na2SO4

E B

E Mhx EVB n

SO 24 = 160 0 S cm2 mol 1

Calculate

for

Na + = 50 1 S cm2 mol 1

il

* < |H x E { JB*

Na2SO4

if

Na + = 50 1 S cm2 mol 1

SO 24 = 160 0 S cm2 mol 1 . Define the law used for it.

17.

1++

and
1+1

>V +G xnE E v +J E Sj xE Gh >V { =i|E


E | E Z<B*
Draw diagram of curve between energy and reaction coordinate and
explain the effect of catalyst on activation energy.

18.

1+1

VE +C<b VE E xEh E v JB* < x +G E


Eh JB*
Write the method of extraction of zinc from zinc oxide. Give equation of
reaction that takes place in it.

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19.

20.

a)

Ti 3 + +x

b)

xlxb ESx C ?

a)

Ti 3 + ion is coloured while Ti 4 + ion is colourless. Give reason.

b)

What is lanthanoid contraction ?

Mx i VE

Ti 4 + +x

Mx* Eh nVB*

1+1

xxJi E ME E I.U.P.A.C. x nVB :


a)

K 2 [ Zn ( OH )4 ]

b)

[ Co ( NH3 ) 4 ( H2O ) Cl ] Cl2 .

Give I.U.P.A.C. names of the following complex compounds :

21.

a)

K 2 [ Zn ( OH )4 ]

b)

[ Co ( NH3 ) 4 ( H2O ) Cl ] Cl2 .

2-]x

E V

NaOH

il BEE

NaOH

1+1

E l xE

+G+ E Eh nVB* |iE +G E |E i<B*


+l
Bl BE E xVx E +G E Eh JB* <E G v E
{n Z<B*
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Give the equations of chemical reactions of 2-Bromobutane with
4

aq. NaOH and alc. NaOH. Write the type of each reaction.
OR

Give the equation of dehydration of ethyl alcohol. Explain the steps of


its mechanism.
22.

wh PhE BE <b

+ 1
SN2

+G x E |ix E l {z

i * BE =nh u Z<B*
In optically active alkyl halides, SN2 reaction is completed with
inversion. Explain by an example.
23.

C4H10O

+hj S BE E +h+ E Sx j

1+1
I.U.P.A.C.

nVB*
Write structural formulae and I.U.P.A.C. names of four alcohol
molecules having molecular formula C4H10O.
24.

a)

x E + |Ei nx n +GB nVB*

b)

x <l h +G E Eh nVB*

a)

Give two reactions that show the acidic nature of phenol.

b)

Write the equation of Williamson ether synthesis.

SS41Chem. (Supp.)

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1+1

9
25.

a)

( CH3 ) 3 N

b)

CH3CONH2 E LiAlH4 il

E IEi

CH3NH2

CHCl 3 il alc. KOH E

E * Z<B*

V G Ex { ME

l M Ex { nMxv ME

xi V
Y

xi *

il Y E j I.U.P.A.C. x nVB*

a)

Basicity of ( CH3 ) 3 N is less than CH3NH2 . Explain.

b)

CH3CONH 2 gives a compound X on reaction with LiAlH4 and

water, which gives a foul smelling compound Y on heating with


CHCl 3 and alc. KOH. Give formulae and I.U.P.A.C. names of

X and Y.

26.

a)

1++++

i{ P] il i{og E C +xi ? E<], {lx,


{]<x, b<b Vx E <x M MEi EVB*

b)

x<x-6, 6 xx E +G E Eh nVB*

a)

What is the difference between thermoplastic and thermosetting


polymers ? Classify bakelite, polythene, polystyrene, urea
formaldehyde resins in these groups.

b)

Give equation of reaction for preparation of Nylon-6, 6.

SS41Chem. (Supp.)

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27.

a)

{iv il G C +i ? |iE E BE =nh nVB*

b)

Ej vE E Ei ? <xE ={M v M u C E
Vi ?
+l

i A n +v E x i B nB MB =xE M EVB :
i A

a)

i B

B{x

|i]x

{xx

|iVxx Ii +v

Bm<x

|iE

xBlxbx

Vhx

Vhv

]xbx

{c*

What is the difference between antiseptics and disinfectants ?


Give one example of each.

b)

What are artificial sweetening agents ? Why are these used by


diabetic persons ?

1 + 1
OR

SS41Chem. (Supp.)

. SS441.

11
Match the drugs given in Column A with their class given in
6

Column B :
Column A

28.

a)

Column B

Aspirin

Antihistamine

Penicillin

Anti-fertility drug

Erythromycin

Tranquilizers

Norethindrone

Bactericidal

Valium

Bacteriostatic

Terfenadine

Analgesic.

iE +vh il xE +vh n +i JB* |iE


+vh E BE =nh nVB*

b)

+G

N2 ( g ) + 3H2 ( g )

Fe ( s )
Mo ( s )

2NH3 ( g )

Mo ( s )

={M Fe ( s ) E l C E M ? B {nl E C Ei ?
c)

E] v +I{E E xEi Sj x<B*


+l

SS41Chem. (Supp.)

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a)

pM B p M E<b n +i JB* |iE E<b E BE


=nh nVB*

b)

ti +{x E xEi Sj u |ni EVB*

c)

x E vx G E Z<B*

a)

Write

two

differences

between

physiosorption

and

chemisorption. Give one example of each type.

b)

In

reaction,

N2 ( g ) + 3H2 ( g )

Fe ( s )
Mo ( s )

2NH3 ( g ) , why

Mo ( s ) is used with catalyst Fe ( s ) ? What name is given to


such compounds ?
c)

Draw a labelled diagram of Cottrell smoke precipitator.


OR

a)

Write two differences between lyophilic and lyophobic colloids.


Give one example of each colloid.

b)

Draw labelled diagram to exhibit electrodialysis.

c)

Explain cleansing action of soaps.

SS41Chem. (Supp.)

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13
29.

a)

15

E ii E VEi E <C]x x +iH li

C i ? Z<B*
b)

BE i +vi ` X, V +v n{i i , E

CS2

x M ] {j Jx { i: V =`i i v
Y

c)

ni * X Y E +hj nVB il +G E Eh nVB*

H2SO3

il H2SO4 E SxB nVB*


+l

a)

M 18 E ii E =iE] M C Ei ?

b)

H2SO4 E

=i{nx E { |G E ix Sh x +G+ E

Eh nVB*
c)

XeF2

il XeF4 E SxB x<B*

a)

Why the valency shell electronic configuration of 15th group


elements has additional stability ? Explain.

b)

A poisonous white waxy non-metallic solid X, glows in dark.


When dissolved in CS2, a filter paper dipped in it, catches fire in
air on drying and forms dense white fumes of Y. Give the
molecular formulae of X and Y and equation of the reaction.

c)

Give structures of H2SO3 and H2SO4.


OR

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a)

Why are the elements of group 18 known as noble gases ?

b)

Give the equations of the reactions that take place in three


steps of H2SO4 production by contact process.

30.

c)

Draw structures of XeF2 and XeF4.

a)

xxJi +G+ A, B, C D E {SxB :


H

i)

ii)

2CH3

O+

CHO

1+2+1

p KOH

A+B

ix NaOH
C

H 2O

b)

Vxhb +{Sx E Eh u Z<B*

c)

Ex- n x E ={M M x xx i E Vi ?
+l

a)

xxJi +G+ A, B, C D E {SxB :


H+

OH

i)

CH3

ii)

C6H5COOCOCH3

CN

H2 O

H2O

H+

OH

C+D

b)

-b-VE +G Eh nE Z<B*

c)

R-COOH

E ClxE i +h BE =SS i *

Eh nVB*
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15
a)

Identify A, B, C and D in the following reactions :


H

i)

ii)

2CH3

O + Conc. KOH

CHO

A+B

dil. NaOH

H2 O

b)

Explain Rosenmund reaction giving equation.

c)

Which two chemicals are used for preparing Fehling solution ?


OR

a)

b)
c)

Identify A, B, C and D in the following reactions :

H+ or OH

i)

CH3

ii)

C6H5COOCOCH3

CN

H2 O

H+ or OH

H2O

C+D

Explain Hell-Volhard-Zelinsky reaction giving equations.


R-COOH has higher boiling point than that of alcohols having
same molecular mass. Give reason.

SS41Chem. (Supp.)

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