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of
alcohols.
air
and
plethora
of
solvents.
catalysts
allow for
formation
Applications
of
tetrasubstituted
of
Materias
olefins
via
cross
Ruthenium
Cross-Metathesis (CM)
Enyne Metathesis
metathesis.
Catalysts:
Tris(triphenylphosphine)ruthenium(II) dichloride
97%
Synonym: Dichlorotris(triphenylphosphine)ruthenium(II),
Ruthenium(II)-tris(triphenylphosphine)
dichloride,
Tris(triphenylphosphine)dichlororuthenium
Dihydridotetrakis(triphenylphosphine)ruthenium(II)
Synonym: Tetrakis(triphenylphosphine)ruthenium
dihydride
Z, Z' (electron withdrawing groups) = CO2R, COR, CHO, CN, NO2, etc.
Knoevenagels use of primary and secondary amines, and their salts as
catalysts
provided
an
early
foundation
for
the
study
of
with
novel
new
catalysts
and reaction
and
ultrasound
Solvent
reactions36
irradiated
conditions7,8
free
synthesis9
Solid-phase
Photochemical condensation with fruit extracts as catalysts
Aplication
Catalyst
alkynes,Knoevenagel
transferhydrogenation
for
hydration
reactions
and
of
nitriles,
conjugate
isomerization
additions,
of
and
Cis-Bis(2,2-bipyridine)dichlororuthenium(II) hydrate
C20H16Cl2N4Ru xH2O
Application
cis-Bis(2,2-bipyridine)dichlororuthenium(II)
hydrate
was
used
in
the
of
Precursors
3,8-Bisphenyl-1,10-phenanthroline
of
Derivatives:
3,8-Bis(4-mercaptophenyl)-1,10-
Application
Reactant
Dithiolate-bridged
for
ruthenium-rhodium
synthesis
heterobimetallic
complex
Amido / phosphine pincer hydrides of ruthenium
of:
dihydride
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
Synonym: Dicarbonylchloro[(1,2,3,4,5,-)-1,2,3,4,5pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium
C37H25ClO2Ru
Application
Reactant
Synthesis
for:
of
cyclopentadienyl
ruthenium
dicarbonyl
catalyst []
exchange[]
Ligand
bonds[]
C:C
Catalyst
(S)-Selective
for:
dynamic
Stereoselective
kinetic
synthesis
of
resolution
of
neonicorinoide
secondary
pesticide
alcohols []
derivatives []
Citation
Metal catalyst used in conjunction with enzymes for enantioselective
transformations via dynamic kinetic resolution
Referensi
Highly efficient synthesis of enantiopure diacetylated C(2)-symmetric diols
by
ruthenium-
and
enzyme-catalyzed
dynamic
kinetic
asymmetric
transformation (DYKAT).
Beln Martn-Matute, Michaela Edin, Jan-E Bckvall
Highly efficient synthesis of enantiopure diacetates of 2,4-pentanediol and
2,5-hexanediol starting from commercially available mixtures of the diols
(dl/meso approximately 1:1) has been realized by combining a fast
ruthenium-catalyzed epimerization with an enzymatic transesterification.
The in situ coupling of these two processes produces the diacetates in
high yield in >99 % enantiomeric excess.