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    Lexzyrie Sybelle S. Tolarba
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    Hazardous Waste Management

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    Hazardous Waste Management

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    5 views18 pages

    Hazardous Waste Notes

    Uploaded by

    Lexzyrie Sybelle S. Tolarba
    Hazardous Waste Management

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 18
    CEC C € A g « os LLL 3493 140 BY + b »& \ .__ DATE ses COURSE DESCRIPTION 2st ’ ae rs@_will cover the regulations and guidelin RA 646 —lovic Gnd Hazardous Waste Law with emphasis on the requirements ; He: | generation and saurits of the waste, deir life cycle analysis, minimization, control and management strategy. The course will also cover life tye GNd Fisk assessment analysis, brownfields and site remediation; QOUASE pByECTIVES Affer completing this wourse, tne student must beable +o: a) understand tne diff, environmental regulations for_manaaing hazardous waste ) design appropriate methods tv minimize the aeneration of waste, wHliving Concepts OF Sourle reduction, reuse and Toad, ©) determing and design appropriate treatment fechnologies + manage haardous waste 4) calanate thé risk ata site based on selected exposure pathways of the pollutants 2) design appropriate eatment management for site _reme diction COURSE OUTUNE L_Introducton and Course overview 4. Waste ytneration and characterization 3. Uhemistty of hazardous wastes 4. Legislative framework and laws addressing hazardous waste 5. Fate OF contaminants sorption /partitioning voldtilization 6. Hazardous waste ident fication T_ isk assessment 8. Rey'ts for hav. waste generators 4. Regs for M42. waste transporter and_treaters 2 i BrowoFields’ and envirinmental site assessment fasrlNsitue 8 sys and OFF: site remediation)» 18.: Treat ment. processes t 1 EDTA Physica = Gemical bibremediation Natural attenuation /phyto'eme dation dolidification (Stabilization oeew G&G & o@ » » RA 6969 acfinitiyes: sj HAS Substances that are without any safe commercial, industrial, agricultural, Of eoonumic usage and are shipped, transported or brought from the ewuniry of origin for dumping or disposal into or in transit through any part oF +he Philippines. BA 6969 ¢ o Shall also refer 0 by: Products , sidé-products, process residues, spent reagian media, contaminated plant or equipment or other substances from _manutacuring operations and as consumer discards of manufactured produds whidn present unreasonable risk and/or injury to health and safety oF the public Gnd te He environment: *IGNITABILATY /-FLAMMABILIYS 1 1 Bog he_waste js j «fA tiduid, other than an aqueous solution containing wi flash point of eg -Acnon-liguid which under normal conditions can cause fire through fricrion, absorption Of moisture, or spontaneous dnemical changes, and burns st vigorously when ignited that weates a havard ORIQNS: ere AD a a The_waste = a -I6 an cqueous liquid and has o pH laid or Baa nes “1S q:liquid and corrodes steel at @ rate. Greater than @.3¢ mm/car ray REACTIVITY The waste ‘Is normally unstable and readily undergoes violent change, without detonation ‘Violently reacts with water + Forms potentially explosive mixtures with water ~ Generates foxio_gases or fumes in..quantity sufficient to presenta. danger +0 public health or the environment when mixed with water ‘ «A Gand or SiFide “pearing Wine thar: ‘whenexposeacte. > ‘ H between faPand RG con generate toxic gases iy "Clpable oF detonation or explosive deomposition of reach =~ at standard temperature and pressure Wy iy t “IS capable of d¢tonation or explosive: reaction if it i¢ Subjected +p é sifong initiating Source: prvit is heated under confinement = 8 s € “TOXICITY & The waste is pH adjusted 10 landfill conditions, and a toxig & characteristic leaching procedure is performed. 1F woste leachate ii L ry ee ve ee ee eG HS ¥ vy wv ¥ \ Concentration is greater than TcLP list, waste is nara MOST COMMON HAZ WASTES PETROLEJM i Hoh AS d precaution against fire naaard, they have bean stored ih h UST “Gasoline Contains benzeng ; toluene, ethylbenzene and. sky _xulleng, which have toxic effects Tanks NON~ HALOGENATED SOLVENTS “Used as carriers for paints ondzinss etc. -02 iy cas 3 * volatile HALD6ENATED SOLVENTS sed far leaning machine parts to computer chips . iF “Volatile dense dnd migrate through tne substance PESTIGIDES ¥ “chemical, physical, or bidlogical Agent that destroys or controls fi organisms including insects, Plants. fungi, rodents and Fear «Most Common types are 2 3 mn INSEGTIGIDE (insects) siadl bait “Dicnloroipheny!Tricaloroethane , endosulfan HoRBICIOES (plants) Funeicipes (fungi) EXPLDSIVES 0) Classified based on veloctty. Of ow EXPLOSIVES “React slowly and burn rapidly instead Of detonating “Eq black powder , common Fireworks solid rocket fuels HIGH EXPLOSIVES “Produce, extreme pressure by rapid detonation ; requires high activation energy + bg. nitroglycerine , trinitroroluent fl POLYCHLORINATED BIPHENYLS (AUR0ATS Heat-stable oils used as transformer or hydraulic. fluias ecPOCHLOBINATED DIBENZUIOXINS AND DIBENZOFUKANS S Not manufactured but trace impurities formed during manufacture, ‘ es combustion of other organic Compounds 9 8 aio ltny HEAVY METALS AND INORGANIG NON METALS Ll + Arsenio "Nickel cs «Cadmium “Mercury i 33 | “| + chromium *Cyanides x | “lead ~ Astoestos pa vere jptitettent g 3 bitth defects i} carcinogenio 2 = NUCLEAR WASTES | “Poses hazard by emitting ionizing radiation S00 a HIGH: LEVEL WASTES ‘High level of radigactivity “_Spent_fuel_from nuclear reactors Classifications HOMORU = vv &s w ve —Ta Sy YY Ww YW vvxveeee edd & LoW- LeveL WASTES eMinimal radioactivity “Generated by hospitals, universities and industry ie ] ——OLASSIFIGATION OF BAZARDIUS WASTE etsy bea GLASS WASTE NUMBER A.WOste with Cyanide AIO! 8. Acid_Wastes Sulfuric add 8201 Hydrochloric odd 202 Nitric Odd 6203 Phosphoric acid Bad¢ Hydrofluorio aud 8205 mixture OF sulfurig and B206 hydrodnloric aud other inordanic add 8207 organic add B20g other add wastes B04 C. AIKli Wasits caustio soda Potash Alkaline cleaners Ammonium hydroxide C30ly 6302 Lime slurries” 2306" - ofher alkali wastes = D.Wastes with inorganic Chemicals : | Seleniurn and its dompdunds Dao! : : Arsenio and its compounds 0402 Barium and its wmpounds 9403 Cadmium and its compounds 0404 chromiur Compounds 40s Lead compounds na = 0406 «7 7 Mercury and mercury. Conipournds 0407 flupridé and its compounds 0408 £. Reautive chemical wastes oxidizing agents ESO! Reducing agents ES02 Explosive and unstable chemicals E03 Highly readive chemicals 5699 Finks / oyes / Pigments / Paints/ Resins /Latex / Adhesives Solvent based F602 Inorganic pigments F603 Ink formulation FGlO 6. Waste Ofganio Solvent Halogendted_organiy lvents 6103 Non- halogenated organic @104 H. Puttesdible /organio wastes : orease trap wastes from iNdustrial 1802 rer ‘ or commerdal premises Dun caWIQn ene e¥Ee eve vb ob bb bb dOdod te oP Pod SE CLASS WASTE NUMBER a ee ; |. Oils waste oils 104 ¢ uly J. Containers Containers previously containing toxic J20t chemical substances k. stobilived waste wlidified wastes polymerized waste K30 Chemically Fixed wastes 430311 tncapsulatea wastes £303 L. Organic chemicals Wastes With specific non- halogenated ual Joxio_organio chemicals Ovone’ depleting substances L402, Polychlorinated. Biphenyls (Po8s) wastes L406 M. Miscellaneous wastes Pathological or infectious wastes Ms0l Asbestos wastes soz Pharmaceutvals and Drugs Msg posticiaes MSo4 Persistent Oryanio Pollutants (POPs) sos pesticides j waste from electrical and electronio i M06 equipment (WEEE) Special Wastes «_NS07 0 T20N ~__Stugy of poisons and ter eects on living ogamsms y. USE IN AWM. : ” ~ 10 assess potential biological ef fects of panards chemicals = 0S G bAsis for_per forming risk assessments es me MANIMALIAN PRYSIOLOGY +The SKIN primary line Of ‘defense + Respiratory system : inhale and exhale dir Glweoli~ transfer area Of Cds and blodd GK + Digestive system 4 chewing Large intestine: undigested food are aritd ’ 3 Gnd ampacted : ee Liver: remove certain toxins poe oo ”_:..-' “Ciraul tem ins: bldod vessels towards heart arteries: away from heart 5 a +The liver 3 1 Mpg - Regulates cart metabolism and release of sugars when» t tevels become low! in thé bloodstream i é ugulates glucose, meta boism ae i OO 3 10. m DATE other detoxitivation-reactions of toxio compounds in: the body~ “Cytochrome _p- 450 “The Kidney Excretion of end products of metabolism “Conttdl of concentrations gf electrolytes and grher constituents in tne body fluids MEGHANISMS: OF TOXICITY. Routes Of exposure OEKMAL «Skin is protective harrier for the body «Non-polar Compounds readily peneivate the epidermis ORAL

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