----------------- CHNH THC

( thi c 04 trang)

THI TH K THI QUC GIA NM 2017

MN THI HA HC LN 23
Thi gian lm bi 50 pht (khng k thi gian pht )
------------------------M thi: 759

Cho bit nguyn t khi ca cc nguyn t: H=1; C=12; O=16; N=14; Cl=35,5; Na=23; K=39; Mg=24;
Ca=40; Ba=137; Al=27; Fe=56; Ni=59; Cu=64; Ag=108.
Cu 1. Cht no sau y thuc loi isaccarit?
A. glucoz
B. amiloz
C. saccaroz
D. xenluloz
Cu 2. Dung dch no sau y lm qu tm ha xanh?
A. anilin
B. alanin
C. metanamin
D. glyxin
Cu 3. iu kin thng, kim loi c cng ln nht l.
A. Cr
B. Fe
C. Cu
D. Al
Cu 4. S oxi ha ca crom trong hp cht K2Cr2O7 l?
A. +3
B. +6
D. +2
D. +4
Cu 5. Thy phn hon ton tristearin trong mi trng axit thu c?
A. C3H5(OH)3 v C17H33COOH
B. C3H5(OH)3 v C17H35COOH
C. C3H5(OH)3 v C17H35COONa
D. C3H5(OH)3 v C17H33COONa
Cu 6. t chy hon ton este X thu c CO2 v H2O c t l mol 1 : 1. Cng thc tng qut ca X l.
A. CnH2n+1COOCmH2m+1 (n 1 ; m 1)
B. CnH2nO2 (n 1)
C. CnH2n+2O2 ( n 2)
D. CnH2n+1COOCmH2m+1 (n 0; m 1)
Cu 7. Cht no sau y khng to kt ta khi tc dng vi dung dch Na3PO4?
A. CaCl2
B. Mg(HCO3)2
C. AgNO3
D. HCl
Cu 8. Nhn nh no sau y l sai?
A. Nc cng l nc cha nhiu ion Mg2+ v Ca2+.
B. Nc t nhin thng c c tnh cng tm thi v tnh cng vnh cu.
C. Phng php lm mm tnh cng ca nc cng vnh cu n gin nht bng cch un nng.
D. Dng dung dch Na3PO4 lm mm tnh cng ca nc cng tm thi.
Cu 9. X phng ha hon ton m gam tristearin bng dung dch KOH d, thu c 115,92 gam mui. Gi
tr ca m l.
A. 106,80 gam
B. 128,88 gam
C. 106,08 gam
D. 112,46 gam
Cu 10. Cho 26,46 gam axit glutamic tc dng va vi V ml dung dch NaOH 1M. Gi tr ca V l.
A. 180 ml
B. 240 ml
C. 360 ml
D. 480 ml
Cu 11. Nhng thanh Zn tip xc vi thanh Cu vo dung dch H2SO4 long, khi xy ra qu trnh n mn
in ha, ng thi to thnh dng in. Ti anot xy ra qu trnh:
A. Zn Zn2+ + 2e
B. 2H2O 2OH- + H2 + 2e.
C. 2H+ + 2e H2
D. Cu2+ + 2e Cu
Cu 12. Cho dy cc kim loi: Na, Ca, Mg, Al Cu. S kim loi tc dng vi lng d dung dch FeCl3, sau
khi kt thc phn ng, thu c kt ta l.
A. 3
B. 2
C. 5
D. 4
Cu 13. Cho 13,7 gam Ba vo 200 ml dung dch Al2(SO4)3 0,2M, kt thc thu c m gam kt ta. Gi tr
ca m l.
A. 33,16 gam
B. 29,54 gam
C. 34,20 gam
D. 28,50 gam
Cu 14. Thi lung kh CO n d qua ng s cha m gam Fe3O4 nung nng, kt thc phn ng, ly phn
rn trong ng s cho vo dung dch HCl long d, thu c 4,032 lt kh H2 (ktc). Gi tr m l.
A. 13,92 gam
B. 20,88 gam
C. 6,96 gam
D. 10,44 gam
Cu 15. Nhn nh no sau y l sai?
A. Cc este c kh nng ha tan tt cc hp cht hu c, k c cc hp cht cao phn t.
B. Cc este thng l cht lng, nh hn nc, rt t tan trong nc.
C. Cht bo rn thnh phn ch yu cha cc axit bo khng no.
D. Cht bo lng lu ngy ngoi khng kh s b i.
Cu 16. T visco thuc loi?
A. t nhn to
B. t tng hp
C. t thin nhin
D. t poliamit
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Cu 17. Phn ng no sau y khng to ra mui Fe (III)?

A. Fe2O3 tc dng vi dung dch HCl long d.
B. Cho bt Fe n d vo dung dch AgNO3.
C. Fe tc dng vi dung dch HNO3 c, nng, d.
D. Fe(OH)2 tc dng vi dung dch HNO3 long, d.
Cu 18. Pht biu no sau y l sai?
A. Cc kim loi kim u mm v c nhit nng chy thp hn so vi cc kim loi khc.
B. Cc kim loi kim th c tnh kh mnh, kh c nc ngay iu kin thng.
C. Nhm l kim loi c mu trng bc, c tnh dn in, dn nhit tt.
D. Trong v tri t, st ng hng th t trong cc nguyn t, hng th hai trong cc kim loi.
Cu 19. Cho dy cc cht: metyl fomat, glucoz, saccaroz, alanin, triolein, metyl acrylat, tripanmitin,
glyxin. S cht trong dy lm mt mu dung dch Br2 l.
A. 4
B. 3
C. 5
D. 2
Cu 20. Phn ng no sau y l sai?
0

HCl, t
A. H2N-CH2-COOH + CH3OH
H2N-CH2-COOCH3 + H2O
0

HCl, t
B. C12H22O11 (saccaroz) + H2O
2C6H12O6 (glucoz)
0

t
NaCl + CH3-NH2 + H2O
C. CH3-NH3Cl + NaOH
0

t
CH3COONa + CH3CHO
D. CH3COOCH=CH2 + NaOH
Cu 21. Ha tan ht 56,72 gam hn hp gm Ba, BaO, Al v Al2O3 trong lng nc d, thu c V lt kh
H2 (ktc) v dung dch X ch cha mt cht tan duy nht. Sc kh CO2 n d vo X, thu c 37,44 gam
kt ta. Gi tr ca V l.
A. 6,272 lt
B. 6,720 lt
C. 7,168 lt
D. 4,928 lt
Cu 22. Nung nng hn hp gm Al v Fe3O4 (t l mol 1 : 1) trong iu kin khng c khng kh, sau khi
cc phn ng xy ra hon ton, thu c hn hp rn X. Rn X cha?
A. Al2O3 v Fe
B. Al2O3, Fe3O4, Fe C. Al2O3, Al, Fe
D. Al2O3, Fe3O4, Al, Fe
Cu 23. Glucoz th hin tnh oxi ha trong phn ng no sau y?
0

A. CH2OH-[CH2OH]4-CHO + 2AgNO3 + 3NH3 + H2O

HOCH2-[CH2OH]4-COONH4 + 2NH4NO3 + 2Ag
0

t
CH2OH-[CH2OH]4-CH2OH
B. CH2OH-[CH2OH]4-CHO + H2
C. CH2OH-[CH2OH]4-CHO + Br2 + H2O CH2OH-[CH2OH]4-COOH + 2HBr
D. 2C6H12O6 + Cu(OH)2 (C6H11O6)2 + 2H2O
Cu 24. Ln men m gam glucoz thu c ancol etylic v kh CO2 (hiu sut phn ng t 80%). Hp thu
ton b kh CO2 sinh ra vo dung dch Ca(OH)2, thu c 16,0 gam kt ta; ng thi thu c dung dch
c khi lng gim 5,44 gam so vi dung dch ban u. Gi tr ca m l.
A. 21,6 gam
B. 54,0 gam
C. 43,2 gam
D. 27,0 gam
Cu 25. Hp cht hu c X c cng thc phn t C5H11O2N. un nng 17,55 gam X vi dung dch KOH
va , c cn dung dch sau phn ng, thu c 19,05 gam mui ca -amino axit. Cng thc cu to ca
X l.
A. H2N-CH2-CH2-COOC2H5.
B. (CH3)2-CH-CH(NH2)-COOH.
C. CH3-CH-CH(NH2)-COOCH3.
D. CH3-CH(NH2)-COOC2H5
Cu 26. Cho s phn ng sau:
(1) 2X + 2Y + 2H2O 2Z + 3H2
(2) Z + CO2 + H2O T + KHCO3
(3) 2X + 3Cl2 2XCl3
(4) 2X + 6HCl 2XCl3 + 3H2
Cc cht X, Y, Z, T ln lt l.
A. Cr2O3, NaOH, NaCrO2, Cr(OH)3
B. Al, KOH, KAlO2, Al(OH)3.
C. Al, NaOH, NaAlO2, Al(OH)3
D. Cr2O3, KOH, KCrO2, Cr(OH)3
Cu 27. Este X mch h, khng tn ti ng phn hnh hc v c cng thc phn t C 6H8O4. un nng 1
mol X vi dung dch NaOH d, thu c mui Y v 2 mol ancol Z. Bit Z khng tc dng vi Cu(OH)2
iu kin thng, khi un Y vi H2SO4 c 1700C khng to ra anken. Nhn nh no sau y l ng?
A. X c mch cacbon khng phn nhnh.
B. Cht Y c cng thc phn t l C4H4O4Na2.
C. Trong X cha hai nhm -CH3.
D. Cht X phn ng vi H2 (xc tc Ni, t0) theo t l mol 1 : 3.

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Cu 28. Ha hi hon ton 10,64 gam hn hp X cha hai este u n chc, mch h th th tch hi ng
bng th tch ca 4,48 gam N2 (o cng iu kin nhit v p sut). Nu un nng 10,64 gam X vi 300
ml dung dch NaOH 1M, c cn dung dch sau phn ng, thu c mt ancol duy nht v m gam rn khan.
Gi tr ca m l.
A. 14,48 gam
B. 17,52 gam
C. 17,04 gam
D. 11,92 gam
Cu 29. Cho dung dch Ba(OH)2 n d ln lt vo cc dung dch: Al2(SO4)3, (NH4)2CO3, FeCl3, CaCl2,
NaHCO3, KHSO4, s dung dch to ra kt ta l.
A. 5
B. 4
C. 6
D. 3
Cu 30. Hc sinh Nguyn Cng Bo c cc hp cht amin di y nh sau:
(1) CH3-NH2:
metanamin.
(2) CH3-NH-CH3:
metylmetanamin.
(3) CH3-CH(NH2)-CH3:
metyletan-2-amin.
(4) CH3-NH-CH(CH3)2:
N-metylpropan-1-amin.
(5) C6H5-NH-CH3:
N-metylphenylamin.
S amin m hc sinh Nguyn Cng Bo c sai l.
A. 3
B. 2
C. 1
D. 4
Cu 31. Thy phn 0,15 mol peptit X, thu c hn hp gm 0,04 mol Gly-Gly-Ala; 0,06 mol Gly-AlaAla; 0,02 mol Ala-Ala; 0,04 mol Gly-Gly; 0,08 mol Gly v 0,10 mol Ala. Phn t khi ca X l.
A. 331
B. 274
C. 260
D. 288
Cu 32. Cho t t dung dch Ba(OH)2 n d vo dung dch cha AlCl3 x (mol/l) v Al2(SO4)3 y (mol/l).
Phn ng c biu din theo th sau:
S mol kt ta

7a
5a
3a

S mol Ba(OH)2
T l x : y l.
A. 2 : 3
B. 2 : 1
C. 1 : 2
D. 3 : 2
Cu 33. Cho cc pht biu sau:
(1) t chy bt k mt amin, lun thu c nit n cht.
(2) iu kin thng, imetylamin l cht kh, tan tt trong nc.
(3) Nh nc Br2 vo dung dch alanin,xut hin kt ta trng.
(4) Dung dch anilin khng lm i mu phenolphtalein.
(5) Propan-2-amin l amin bc 2.
(6) Cc peptit u cho phn ng mu biur.
S pht biu ng l.
A. 5
B. 3
C. 4
D. 6
Cu 34. Tin hnh in phn 200 ml dung dch CuSO4 xM v NaCl 0,6M bng in cc tr, mng ngn
xp vi cng dng in khng i I = 5A trong thi gian 7334 giy th dng in phn, thy khi lng
dung dch gim m gam. Dung dch sau in phn ha tan ti a 2,16 gam Mg. Nhn nh no sau y l
ng?
A. Gi tr ca m l 16,02 gam.
B. Dung dch sau in phn cha Na+, Cu2+, H+ v SO42-.
C. Gi tr ca x l 1,5M.
D. Nu thi gian in phn l 7720 giy th nc bt u in phn c hai cc.
Cu 35. Thc hin cc th nghim sau:
(1) Cho a mol Mg vo dung dch cha a mol Fe2(SO4)3.
(2) Cho a mol Fe tc dng vi dung dch cha 3a mol HNO3, thu kh NO l sn phm kh duy nht.
(3) Cho a mol Fe vo dung dch cha 3a mol AgNO3.
(4) Sc a mol kh CO2 vo dung dch cha a mol Ca(OH)2.
(5) Cho dung dch cha 3a mol NaOH vo dung dch cha a mol AlCl3.
Sau khi kt thc phn ng, s trng hp thu c dung dch cha hai mui l.
A. 4
B. 5
C. 2
D. 3

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Cu 36. Cho 33,26 gam hn hp X gm Fe3O4, Fe(OH)3, Fe(OH)2 v Cu vo 500 ml dung dch HCl 1,6M
thu c dung dch Y v 7,68 gam rn khng tan. Cho dung dch AgNO3 d vo Y, thu c kh 0,045 mol
kh NO (sn phm kh duy nht ca N+5) v 126,14 gam kt ta. Cc phn ng xy ra hon ton. Phn trm
khi lng ca Fe(OH)2 trong hn hp X l.
A. 14,1%
B. 21,1%
C. 10,8%
D. 16,2%
Cu 37. Hn hp X gm glucoz, lysin v hexametyleniamin. t chy hon ton 0,2 mol X cn dng
1,46 mol O2, sn phm chy gm CO2, H2O v N2 c dn qua bnh ng H2SO4 c (dng d), kh thot
ra khi bnh c th tch l 28,672 lt (ktc). Mt khc cho 24,06 gam X trn vo dung dch HCl long d,
thu c dung dch Y c cha m gam cc hp cht hu c. Gi tr ca m l.
A. 10,05 gam
B. 28,44 gam
C. 12,24 gam
D. 16,32 gam
Cu 38. t chy 16,8 gam bt Fe trong oxi, sau mt thi gian thu c 19,84 gam rn X. Ha tan hon
ton X trong dung dch cha NaHSO4 v x mol NaNO3, thu c dung dch Y cha cc mui trung ha v
hn hp kh Z gm NO v H2 (t l mol 1 : 1). Cho dung dch NaOH d vo Y (khng c mt oxi), thu c
30,06 gam kt ta. Bit kh NO l sn phm kh duy nht ca N+5. Gi tr ca x l.
A. 0,06
B. 0,08
C. 0,09
D. 0,12
Cu 39. Hn hp X gm ba este u no, mch h, trong phn t ch cha mt loi nhm chc. t chy
hon ton 35,34 gam X cn dng 1,595 mol O2, thu c 22,14 gam nc. Mt khc un nng 35,34 gam E
vi dung dch NaOH va , thu c hn hp Y cha hai mui ca hai axit c mch khng phn nhnh v
17,88 gam hn hp Z gm mt ancol n chc v mt ancol hai chc c cng s nguyn t cacbon. Phn
trm khi lng ca este n chc trong hn hp X l.
A. 4,98%
B. 12,56%
C. 4,19%
D. 7,47%
Cu 40. Cho 0,15 mol hn hp rn X gm Mg v Fe vo dung dch cha FeCl 3 0,8M v CuCl2 0,6M thu
c dung dch Y v 7,52 gam rn gm hai kim loi. Cho dung dch AgNO3 d vo Y, thu c 29,07 gam
kt ta. Nu cho 0,15 mol X trn vo dung dch HNO3 long d, thy kh NO thot ra; ng thi thu c
dung dch Z c khi lng tng 4,98 gam so vi dung dch ban u. C cn dung dch Z thu c lng
mui khan l.
A. 33,86 gam
B. 33,06 gam
C. 30,24 gam
D. 32,26 gam
---------HT---------

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