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ANJAY KUMAR, PGT CHEMISTRY

K V KHANAPARA
INSERVICE COURSE CHEMISTRY 2014
CLASS: XII
SUBJECT: CHEMISTRY
BLUE PRINT

S.
No

Chapter

VSA

SA I

SA II

VBQ

LA

1
Mark
1

2
Marks

3
Marks
1

4
Marks

5
Marks

M (Q)

Solid State

Solution

5(2)

Electrochemistry

5(2)

Chemical Kinetics

5(2)

Surface Chemistry

General Principles &


Processes of isolation of
elements

P block elements

d- & f- block elements

Coordination Compounds

10

Haloalkanes & Haloarenes

11

Alcohols, phenol & ethers

12

Aldehyde, ketones &


carboxylic acid

13

Organic compounds
containing Nitrogen.

4(2)

14

Biomolecules

4(2)

15

Polymers

3(1)

16

Chemistry in everyday life

3(1)

M(Q)

4(2)

4(2)
3(1)

8(2)

5(1)

3(1)

5(5)

4(1)

4(2)

10(5)

36(12)

4(1)

15(3)

6(2)

70(26)

CLASS:XII
SUBJECT: CHEMISTRY
TIME: 3 HRS
MAX.MARKS: 70
----------------------------------------------------------------------------------------------1. All questions are compulsory.
2. Questions number 1 to 5 are very short answer questions and carry 1 mark each.
3. Questions number 6 to 10 are short answer questions and carry 2 mark each.
4. Questions number11 to 22 are also short answer questions and carry 3 marks each.
5. Questions number 23 is values based and carry 4 marks.
6. Question number 24 to 26 are of long answer questions and carry 5 marks each.
7. Use Log tables, if necessary. Use of calculator is not allowed.
8. There is no overall choice in the paper; however there is an internal choice in one question of 2 marks weightage, one question

of 3 mark weightage and all questions of 5 marks weightage.

(1).What is meant by 'doping' in a semiconductor?

(2).Give IUPAC name of the compound :- CH2=CH(OH)-CH2OH

(3)Arrange the following compounds in an increasing order of their reactivity in nucleophilic

Addition reactions: ethanal, propanal, propanone, butanone.

(4) Arrange the following in the decreasing order of their basic strength in aqueous solutions:

CH3NH2, (CH3)2 NH, (CH3)3 N and NH3

(5) Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are
insoluble in water. Explain.
(6) A 1.00 molal aqueous solution of trichloroacetic acid (CClCOOH) is heated to its boiling point.

The solution has the boiling point of 100.18 C. Determine the van't Hoff factor for trichloroacetic acid.
(Kb for water = 0.512 K kg mol)
(7) Explain the following
(i) Henry's law about dissolution of a gas in a liquid (ii) Boiling point elevation constant for a solvent

2
2

(8) What do you understand by the 'order of a reaction' ? Identify the reaction order from each of the

following units of reaction rate constant: (i) L1 Mol S-1 (ii) L Mol-1 S1
2
(9)(i) What is meant by coagulation of a colloidal solution? Describe briefly any three methods by which
coagulation of lyophobic sols can be carried out.
2
(10) Name the two groups into which phenomenon of catalysis can be divided. Give an example of each
group with the chemical equation involved.
3
(11) Tungsten crystallizes in body centred cubic unit cell. If the edge of the unit cell is 316.5 pm, what is the
radius of tungsten atom?
3
OR
Iron has a body centred cubic unit cell with a cell dimension of 286.65 pm. The density of iron is
7.874 g cm. Use this information to calculate Avogadro's number. (At. mass of Fe = 55.845 u)
(12) Calculate the amount of KCl which must be added to 1 kg of water so that the freezing point is depressed
by 2K. (Kf for water 1.86 K kg mol-1 )
3
(13)(a) The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500 . What is the
cell constant if the conductivity of 0.001 M KCl solution at 298 K is 0.146 x 103 S cm-1
3
Q14. For the reaction
2NO(g) + Cl2(g) 2 NOCl(g) the following data were collected. All the measurements were taken at 263 K :

(a) Write the expression for rate law.


(b) Calculate the value of rate constant and specify its units.
(c) What is the initial rate of disappearance of Cl2in exp. 4 ?

Q15. (a) How is copper extracted from a low grade ore of it ?


(a)Describe the principle involved in each of the following processes.

(i) Mond process for refining of Nickel.


(ii) Column chromatography for purification of rare elements.
Q16. Define the following terms: (i) Mole fraction(ii) Ideal solution (ii) Isotonic Solution
Q17. Give the formula of each of the following coordination entities:

3
3
1x3=3

(i) Co3+ ion is bound to one Cl , one NH3 molecule and two bi dentate ethylene diamine (en) molecules.
(ii) Ni2+ ion is bound to two water molecules and two oxalate ions.
Write the name and magnetic behaviour of each of the above coordination entities.
(At. nos. Co = 27, Ni = 28)
Q18. Answer the following questions:
(i) What is meant by chirality of a compound? Give an example.
(ii) Which one of the following compounds is more easily hydrolyzed by KOH and why?
CH3CHClCH2CH3 or CH3CH2Cl
Q19. Describe the following giving the relevant chemical equation in each case:
(i) Carbylamine reaction (ii) Hofmann's bromamide reaction (iii)Gabrel Phthalamide
Q20. Write any three properties of glucose which cannot be explained by the open chain structure of
glucose molecule.
Q21.(a) Define the term, 'homopolymerisation' giving an example.
(b) Draw the structure of the monomer for each of the following polymers: (i) Nylon 6 (ii) Polypropene

3
3

Q22 What are the following substances? Give one example of each one of them.

3
3
3

(i)Tranquilizers (ii) Food preservatives (iii) Synthetic detergents


Q23. A farmer cultivating his land near the village pond was also drawing water from it for irrigation. He used insecticide
excessively to protect his crops and improve the harvest, over a period of time his agricultural growth improved vastly.
But the pond lost its aquatic life.
(i) Give IUPAC name of the compound used as an insecticide but not a pesticide
(ii)Contrast the activity in plants and aquatic life with insecticide.
(iii)What value got expressed in students suggestions?
1x3= 3
Q24. (a) Complete the following chemical reaction equations:

(i) P4 + SO2Cl2
(ii) XeF6 + H2O
(b) Predict the shape and the asked angle (900 or more or less) in each of the following cases:
(i) SO32- and angle O-S-O
(ii) ClF3and the angle F Cl F
(iii) XeF2 and the angle F Xe F
OR
(a) An organic compound A with molecular formula C5H8O2 is reduced to n-pentane on
treatment with Zn-Hg/HCl.
A forms a dioxime with hydroxylamine and gives a positive iodoform test and Tollens
test. Identify
the compound A and deduce its structure.
(b) Write the chemical equations for the following conversion:
(i) Ethyl benzene to benzoic acid
(ii) Acetaldehyde to 3-hydroxy butanal
(iii)
Acetone
to
propan-2-ol
2+3=5
Q25. (a) Complete the following chemical equations:

(i) NaOH + Cl2 (hot and conc.)


(ii) XeF4 + O2F2
(b) Draw the structures of the following molecules: (i) H3PO2 (ii) H2S2O7 (iii) XeOF4
OR

Give reason for the following :(i)


Bond angle in PH4+ is higher than that in PH3.
(ii)
PCl3 fume in moisture.
(iii)
O3 act as a powerful oxidising agent.
(iv)In vapour state sulphur shows paramagnetic behavior.
(v) nitrogen is less reactive at room temperature.

Q26. (a) Illustrate the following name reactions giving suitable example in each case:

(i) Clemmensen reduction (ii) Hell-Volhard-Zelinsky reaction


(b) How are the following conversions carried out?
(i) Ethylcyanide to ethanoic acid (ii) Butan-l-ol to butanoic acid (ii) Benzoic acid to m-bromobenzoic acid
OR

(a) Illustrate the following reactions giving a suitable example for each.
(i) Cross aldol condensation (ii) Decarboxylation

(b) Give simple tests to distinguish between the following pairs of compounds
(i) Pentan-2-one and Pentan-3-one (ii) Benzaldehyde and Acetophenone (iii) Phenol and Benzoic acid

CLASS:XII
SUBJECT: CHEMISTRY

Marking Scheme
CLASS:XII
SUBJECT: CHEMISTRY

Marking Scheme
SNo.
1

Expeted answer/Value Point

Addition of a suitable impurity to the semi-conductor to increase its conductivity is


called Doping.

Marks
1

2
3
4

Prop-1-ene-2,3 diol

5
6

Due to H- bonding

1
2

(a) (i) The Partial pressure of the gas above the liquid is directly proportional
to the mole fraction of the gas dissolved in the liquid.
(ii) Boiling Point Elevation Constant. It is equal to elevation in boiling
point of 1molal solution, i.e., 1 mole of solute is dissolved in 1 kg of
solvent. (or mathematical expression)

The sum of powers of the concentration of the reactants in the rate law expression
is called the order of that chemical reaction / r= k[A] x[B]y
Order =x+y
(i) zero order
(ii) second order
The process of settling of colloidal particles is called coagulation or precipitation
of the sol.
(i) By Electrophoresis / The collidal particles move towards oppositely charged
electrodes.
(ii) By mixing two oppositely charged sols
(iii) By addition of electrolytes / When excess of an electrolyte is added the coll- , ,
oidal particles are precipitated.

Homogenous and Heterogenous catalysis


Any reaction of heterogenous and homogenous catalysis

10

Ethanol > Propanal >Propanone> Butanone.


(CH3)2 NH >(CH3)3 N >CH3NH2 > NH3

11

1
1
1

+1/2
2

r=137 pm
OR

12

13

14

15

16

17

(a) By hydrometallurgy
(i) Ability of Nickel to form volatile compound which can decompose on further
heating.
(ii) Different components of a mixture are differently adsorbed on an adsorbent
(or described in any other appropriate manner)
(i) Mole fraction is the ratio of number of moles of one component to the total
number of moles in a mixture (or mathematical expression)
(ii) Two solutions having same osmotic pressure at a given temperature are called
Isotonic Solutions.
Ideal Solution:-The solution which obeys Raoults law under all conditions is known as an
ideal solution.
(i) [Co(en)2(NH3)Cl
: amminechloridobis-(ethane-1,2-diamine) cobalt(III) ++
diamagnetic
(ii) [Ni(C2O4)2(H2O)]2: diaquadioxalatonickelate(II), ++

18

paramagnetic
The objects which are non superimposable on their mirror image are said to
be chiral and this property is known as chirality
eg. Butan-2-ol
CH3CHClCH2CH3 because it will form secondary carbocation which is more stable (SN 1mechanism)

19

(1)

20
21

Does not react with NaHSO3 ,Does not react with


Polymerisation involve same type of Monomer unit 1
Polymerisation of ethane to form polyethene
1

3
3

22

(i) Tranquilizers are chemical compounds used for the treatment of stress and
mild or even severe mental diseases. +
eg. equanil/meprobamate/veronal (or any one correct example)
(ii) Food preservatives: are the compounds which prevent spoilage of food
due to microbial growth. eg: sodium benzoate, vinegar +
(or any one correct example)
(iii) Synthetic Detergents are cleansing agents which have all the properties of
soap but which actually do not contain any soap +
eg: Sodium Lauryl sulphate. (or any one correct example)

23

Pyramidal or
o

Bent T-shaped The angle F-Xe-F is greater than 90

The angle O-S-O is greater than 90


o

24

OR
(a) A is a straight chain organic compound with carbonyl functional group.

Formation of dioxime suggests the presence of two carbonyl groups.


It is positive towards iodoform test which indicates presence of
1/2.

CH3CO-

Positive tollens reagent test indicates the presence of CHO group.


Therefore the organic compound is 4-oxo pentanal

group

1/2
1/2

(b)
(i)
1

n-propyl

benzene

to

benzoic

acid

(ii) Acetaldehyde to 3-hydroxy butanal

2523. (i)2,2-Bis(4-chlorophenyl)-1,1,1-trichloroethane

mark
(ii)Plants growth improved because it is a very effective insecticide but aquatic
life got destroyed as it is toxic to fish.
1 mark
(iii)We should not used insecticide excessively by keeping environmental
concern in mind.
1 mark
OR
Five reactions of one mark each,
26

OR

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