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SAASTHA EDUCARE

TEST-1 MAX MARKS: 40

CHAPTERS: AMINES, SOLID STATE TIME: 90 MIN
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ANSWER THE FOLLOWING 4 X5 = 20M

1) A)Give equations for the preparation of methylamine (methanamine) by Gabriel-phthalimide
synthesis
B) Give an example for a coupling reaction with an equation. (3 +2)
2) A) Explain Carbylamine reaction
B) Write a short note on Hoffmann bromamide degradation (3 +2)
3) A) Calculate the Packing efficiency of HCP lattice
B) Write any three differences between Schottky and Frenkel defects ( 3+2)
4) A) Calculate the packing efficiency of BCC lattice
B) Explain the classification of solids ( 3+ 2)

ANSWER THE FOLLOWING 10 X 2 =20M
1) What is sandmayer reaction? Explain
2) What is diazotisation? Explain
3) How is nitro benzene converted to aniline?
4) Arrange 1o, 2o, 3o amines in the decreasing order of their basic strength i) gas phase
ii) liquid phase
5) How is diazonium salt converted into Iodobenzene
6) Write any three differences between crystalline and amorphous solids
7) A compound is formed by two elements X and Y. The element X forms ccp and
atoms of Y occupy 1/3 rd of tetrahedral voids. What is the formula of the compound?
8) Silver forms ccp lattice and X- ray studies of its crystals show that the edge
lengthof its unit cell is 408.6pm. Calculate the density of silver (atomic mass = 107.9 u)
9) How many tetrahedral and octahedral voids is present, if the number
of sphere is N?
10) What is meant by anisotropy? What type of solids show this nature?

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