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DPT-1:

1. The general valence shell electronic configuration of f-block elements is
a) (n – 1)f1 –14 (n – 1) d1 or 0 ns2 b) (n – 2)f1 –14 (n – 1) d0 or 1 ns2
c) (n – 3)f1 –14 (n – 1) d1 or 2 ns2 d) (n – 1)d1 to 10 (n – 1)s2

2. The position of element with atomic number 44 in the periodic table is
a) 8 th group, 4th period b) 6th group, 5th period
c) 8th group, 5 th period d) 6th group, 4th period

3. If the ionic radii of K+ and F– are nearly same i.e. 1.34 A0 , then the atomic radii of K and
F respectively are
a) 1.34 A0 , 1.34A0 b)0.72 A0 , 1.96A0 c) 1.96 A0 , 0.72 A0 d) 1.96 A0 , 1.34A0

4. The first ionisation potentials of four consecutive elements present in the third period of
the periodic table are 5.98 eV, 8.15 eV, 11.0 eV and 10.4 eV respectively. Which one of the
following is the first ionisation potential of phosphorus (in eV) ?
a) 5.98 b) 8.15 c) 10.4 d) 11.0

5. For four elements the IP2 curve is shown. In the graph the elements represented by A, B, C
and D are

D
IP2 B

A C

Atomic no

1) Na, Mg, Al, Si b) Mg, Al, Si, P c) Al, Si, P, S d) Si, P, S, Cl

6. Which of the following is exothermic process ?
N( g) +e - ® N(-g ) O(-g) +e- ® O 2- ( g) F( g) +e - ® F - ( g ) Na( g) ® Na +( g) +e -
a) b) c) d)

7. I.P. and E.A of Cl are 13.0ev and 4.0 ev respectively E.N of Cl will be
a) 4.03 b) 2.5 c) 3.5 d) 3.03

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HYDERABAD INSTITUTE OF
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8. The bond energies of H – H, X – X and H – X are 104 K.Cal, 38 K.Cal and 138 K.Cal
é 67 = 8.18ù
ê
ë ú
û
respectiely the electronegativity of ‘X’ is
a) 3.0 b) 3.5 c) 3.8 d) 1.7

9. Assertion (A) : Electronegativity of phosphorous is greater than that of sulphur
Reason (R) : Phosphorous has stable half - filled configuration in 3p – orbitals
a) A and R are true and R is the correct explanation of A
b) A and R are true but R is not correct explanation of A
c) A is true R is false d) A is false R is true

10. The order of acidic nature of oxides
C l 2O7 >SiO2 >P4O10 >SO3 C l 2O7 >SO3 >P4O10 >SiO2
a) b)
SiO2 >P4O10 >SO3 >C l 2O7 SO3 >C l 2O7 >P4O10 >SiO2
c) d)
11. Three elements X, Y and Z belong to the same period. Their oxides are acidic, amphoteric
and basic respectively. The order of these elements in the periodic table is
a) X, Y, Z b) Y, Z, X c)X, Z, Y d) Z, Y, X

12. The strongest oxiding agent and the strongest reducing agent (in aqueous solution) are
a) Cs, F b) F, Cs c) F, Li d) F, O

13. Covalency of ‘P’ in P4 is
a) 1 b) 2 c) 3 d) 4

14. An atom of an element which exhibits pseudo inert gas configuration is
a) Pd b) Zn2+ c) Ag+ d) Pd (or) Zn2+ (or) Ag+
15.

X Where ‘X’ is
% ionic character

1 2 3
EN difference
a) 25 b) 35 c) 50 d)
75

16. Which of the following is least ionic
a) CaF2 b) CaCl2 c) CaBr2 d) CaI2

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17. The total energy holding the ion pair in the crystal can be calculated by using the formula
(N = Avagadro Number)
AZ +Z - e2 Be2 AZ +Z - e 2 Be 2
-N +N n -N + n
r r r r
a) b)
+ - 2
AZ Z e B AZ +Z - e 2 NBe 2
- +n - + n
r r r r
c) d)

18. Set – I (Position of ion in the unit cell) Set – II (No. unit cells sharing the ion)
1) Body centre A) 8
2) Face centre B) 4
3) Edge of a face C) 2
4) Corner D) 1
Correct match is
1 2 3 4 1 2 3 4
a) D C B A b) D B C A
c) D A B C d) D C A B
19. Statement – I : Glucose is a polar covalent substance hence soluble in water.
Statement – II : Iodine is a non – polar covalent substance hence soluble in C6H6.
Statement – III : Camphor is soluble in CCl4.
Statement – IV : Fructose is Insoluble in C2H5OH.
Correct statement is / are
a) Only I, II & III b) Only I, III & IV c) I, IV only d) All

20. According to VBT, the expected bond angles in NH3 and H2O respectively are
a) 1070, 900 b) 900, 1040.30| c) 1070, 1040.30| d) 900, 900

21. The formal charge of second nitrogen in the following resonance structure is

N(1) N(2) O

a) –2 b) 0 c) –1 d) +1

22. In the following pair of species the central atom undergoes dsp 2 hybridisation and the
shape of the species is square planar

UDAY

and SiCl4 c) PdBr4 and [Ni(CN)4] 23. d) PdBr42. B. In which of the following reactions.2D c) 0. there is change in hybridization ® ® A) BF3 + F– BF4– B) H2O + H+ H3O+ ® ® + H + NH + D) C H + Cl C2H4Cl2 C) NH3 4 2 4 2 a) A.74D d) 0.1D 6. The percentage of ionic character is 12. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ a) XeF and PdBr 2. the dipole moment is a) 1D b) 2. The bond length of HCl is a) 2. The inter atomic distances of H2 and Cl2 molecule are 0.36A0 d) 1.72A0 b) 2. is a) 900 b) 1200 c) 1500 d) 1800 5.98A0 respectively . Which of the following species does not have resonating structure ? CO2 C6 H 6 SiO2 NO3- a) b) c) d) UDAY . D b) A.2: I 3- 1. D 1) B 2) C 3) C 4) D 5) B 6) C 7) D 8) C 9) D 10) B 11) D 12) C 13) C 14) A 15) D 16) D 17) C 18) A 19) A 20) D 21) D 22) C 23) D DPT. C. Average bond energy of C – H bond is 416 kJ/mole which of the following is correct CH 4 + 416 Kj ® C + 2 H 2 CH 4 ® C + 4 H + 416 KJ a) b) CH 4 +1664 KJ ® C + 4 H CH 4 ® C + 4 H +1664 KJ c) d) 4. C c) B. B.25A0 . The shape of ion is a) linear b) planar tringle c) tetrahedral d) angular 2. b) XeF4 and [Ni(CN)4]2- 4 4 2. 2. The bond angle that would result maximum dipolement for the triatomic molecule XY2.74A0 and 1. D d) A.33 % Bond length is 1.48A0 c) 1.24 A0 3.

7 The data illustrates the law of a) constant proportions b) conservation of mass c) multiple proportions d) Reciprocal proportions 10. 1atm b) 273K. 1atm d) 546K.7 92. The molecular orbital shown in the diagram is p* p s 2 Pz s * 2 Pz a) b) c) d) 8. 15 cc of gaseous hydrocarbon required 45 cc of oxygen for complete combustion. 0. In acidic medium.5 gm of an organic compound on combustion produced some gaseous products. The % composition of four hydrocarbons is as follows.3 %H 25 20 14.5 gms. The species having highest bond order is O2 O2. O2+ O22- a) b) c) d) 9.+ zH 2O ® aPH 3 + bH 2 PO2- 12.mole of CO2 occupies maximum volume at a) 273K. The relation between x and y is a) x = y b) x < y c) x > y d) x + y = 1 UDAY . i) ii) iii) iv) %C 75 80 85. If 30 cc of CO2 is formed. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 7. One gram . The increase in weight of potash solution was found to be 1. a) 82 % b) 40 % c) 60 % d) 75 % xP4 + yOH . the formula of the gaseous compound is a) C3 H6 b) C2H2 c) C4 H10 d) C2H4 11. the number of moles of ferrous oxalate (FeC2O4) oxidised by one mole of each KMnO4 and K2Cr2O7 are respectively x and y. 2atm 14. The percentage of carbon in the compound is nearly. which were passed into caustic potash solution. 2atm c) 546K.3 8. then (x + y + z) -(a + b) is a) 3 b) 4 c) 7 d) 12 13.

12% c) 88. R properly explain A b) Both A and R are true. Reason (R): Bond angle in H2S molecule is less than that of H2O.5 mole of AO2– to An+. 4 gms of CO2 gas is evolved.2 mole of KMnO4 in acid solution oxidises 0. a) Intense blue . Assertion(A): Bond energy of F2 is less than that of Cl2 Reason( R ) : Bond length of F2 is less than that of Cl2 a) Both A and R are true. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 15.P. starch solution b) Pale pink . 0. Assertion (A) : Dipolemoment of H2S is greater than that of H2O.T. Assertion (A) : Boiling point of water is greater than that of hydrogen fluoride Reason (R) : Molecular weight of water is 18 and that of hydrogen fluoride is 20 a) Both A and R are true. R does not explains A c) A is true.09% b) 92. The percentage purity of CaCO3 is a) 9.4% d) 90. and R is not the correct explanation of A c) A is true but R is falsed) A is false but R is true 22. In the dichromate titrations the end point is recognised by the formation of --------- colouration in the presence of indicator -------------. and R is correct explanation of A b) Both A and R are true. A mixture of Mg metal and Magnesia weighing 20 gm when treated with HCl produced 4. What is the empirical formula of the hydrocarbon ? a) CH3 b) C4H9 c) CH d) C3H8 19. On complete calcination of 10 grams of Ca CO3. diphenyl amine 21. but R is false d) A is false. Here ‘n’ is a) 1 b) 3 c) 5 d) 7 18. 10g of Calcium carbonate contains a) 10 moles of CaCO3 b) 1 gram atom of Calcium c) 6x1022 atoms of Calcium d) 0. but R is true 23. UDAY . methyl orange d) Intense blue. Four grams of hydrocarbon (CxHy) on complete combustion gave 12 grams of CO2. then what is weight percent of Mg in the mixture? a) 50% b) 64% c) 36% d) 24% 20.48 litre of H2 at S.9% 16. self indicator c) pale pink .1g of Calcium 17.

R is true 28. Assertion (A) : Para hydroxy benzaldehyde has a lower boiling point than ortho hydroxy benzaldehyde. c) A is true. Assertion (A):Balancing of gaseous phase equations always requires conservation of volumes Reason (R):When gases combine they do so by simple ratio of their volumes a) Both A and R are true. but R is false d) A is false. (R) false d) (A) false. R is false. b) (A) and (R) are true but (R) is not the correct explanation of (A). but R is true 26. a) A & R are correct. Reason (R) : Compound of an element. and R is correct explanation of A b) Both A and R are true. HNO 3 27. R is the not correct explanation of A. a) (A) and (R) are true and (R) is the correct explanation of (A). b) A and R are true and R is not the correct explanation of A. c) (A) true. Assertion (A) : In a redox reaction. R is false. c) A is true. R is the correct explanation of A b) A & R are correct. b) Both A and R are correct. Assertion (A) : acts as an oxidising agent. where the element is in its maximum oxidation state undergo reduction. but can not undergo oxidation. Assertion (A) : The equivalent weights of nitric acid and crystalline oxalic acid are same Reason (R) : The basicity of nitric acid and oxalic acid are same The correct answer is a) A and R are true and R is the correct explanation of A. R is the correct explanation of A. R is true. 24. R is not the correct explanation of A c) A is true. c) A is true. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ a) A and R are true and R is the correct explanation of A. but not as reducing agent. Reason (R): Ortho hydroxybenzaldehyde has intramolecular hydrogen bonding. b) A and R are true and R is not the correct explanation of A. (R) true 25. R is false d) A is false. and R is not the correct explanation of A c) A is true but R is false d) A is false but R is true UDAY . d) A is false. d) A is false. the oxidation number of oxidant decreases while that of reductant in creases Reason ( R) : Oxidant gains electron (s) and reductant loses electron (s) a) Both A and R are correct. R is true.

4 lit Reason (R) : One mole of water contains 12. R is not the correct explanation of A c) A is true but R is false d) A is false but R is true 1) A 2) C 3) C 4) A 5) C 6) C 7) D 8) C 9) C 10) D 11) A 12) A 13) C 14) B 15) D 16) C 17) C 18) D 19) D 20) D 21) B 22) B 23) D 24) D 25) A 26) C 27) A 28) D 29) D 30) C DPT-3: 1.5 mole of Sodium Carbonate the number of mole of Carbondioxide formed is 1) 0.T.5 3) 1.25 2) 0.165gm. The volume of the mixture will be 1) 10 litres of Cl2 2) 30 litres of HCl 3) 10 litres of Cl2 & 20 litres of HCl 4)10 litres of Cl2 & 30 litres of HCl 3.5 mole of HCl is allowed to react with 0. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 29.P. The volume of ozonized Oxygen is 1) 200ml 2) 230ml 3) 190ml 4) 220ml 4.P weights 1. occupies 22. Then the gas may be 1) Acetylene 2) CO 3) Oxygen 4)Methane UDAY .25 2. 10 litres of H2 and 20 litres of Cl2 are mixed and exploded. and R is correct explanation of A b) Both A and R are true.046 x 1023 atoms of hydrogen a) Both A and R are true.0 4) 1. Assertion (A) : One mole of water at S. If one litre of a gas at S. R is the correct explanation of A b) A and R are correct.T. 200ml of dry Oxygen is subjected to electric discharge. Assertion (A) : Oxidation state of carbon in C6H12O6 is zero Reason (R) : Oxidation state of carbon in all organic compounds is zero a) Both A and R are correct. 0. and R is not the correct explanation of A c) A is true but R is false d) A is false but R is true 30. Only 15% of O2 is converted to O3.

2 lit 4) 5. Y = 5.Z respectively are 1) X = 3.6 lit 6. A gas mixture containing 7g of CO & 11 g of CO2 was passed over and hot coke. then the compound Q will have 14 parts by weight of 'X' and UDAY . volume of H2 gas liberated is 2. Q. Then the S. Then the percentage of 'Mg' metal in the given sample is 1) 90% 2) 80% 3) 70% 4) 60% 10.Y. The orbital angular momentum for a 2p – electron is 3h 6h 2h 1) 2) 3) Zero 4) 11. 4g of a sample containing Mg + MgO is treated with excess of dil HCl acid. S and T. They form a series of compounds P. Then the volume of gas mixture at STP is 1) 22.P.24 lit. R is false 4) A is false.8 lit 3) 11. Two elements X and Y have atomic weights of 14 and 16. The values of X. Z = 2 2) X = 8. The ratio of weight of 'Y' which combined with 14g of 'X' in these compounds is 1 : 2 : 3 : 4 : 5. Y = 3. Z = 4 3) X = 4. If the compound P has 28 parts by weight of X and 16 parts by weight of Y. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 5. In which of the following compounds Fe exhibits lowest oxidation state 1) K4[Fe(CN)6] 2) K3[Fe(CN)6] 3) Fe(CO)5 4) FeSO4  8. Y = 8. Z = 4 9.T. Y = 4. R is correct 7.4 lit 2) 16. In the balanced equation H2SO4 + XHI H2S + YI2 + ZH2O. Assertion (1): The basicity of Ortho Phosphorus acid is 2 Reason (R) : In Phosphorus acid molecule three hydrogen atoms are attached to phosphorus through oxygen atoms 1) Both A and R are correct and R is the correct explanation of A 2) Both A and R are correct and R is not the correct explanation of A 3) A is correct. R. Z = 5 4) X = 5.

and ... Eka silicon belongs to . Which one of the following is correct 1) EN of Chlorine > EN of Fluorine 2) EA1 of oxygen > EA1 of sulphur 3) EA1 of silicon > EA1 of sulphur 4) EA1 of Chlorine > EA1 of Fluorine 19. VI B group 2) 6th period . gives how many grams of alumina ? 1) 2. Identify the correctly matched set among the following 1) Zinc-d-block-Representative element 2) Lanthanum -d-block-Inner transition element 3) Cerium-f-block-Transition element 4) Actinium-d-block-Transition element 15. VI B group 4) 4th period . The electronic configuration of element (x) in its ground state is [Ar]3d 54s1 . R is correct 17. The period having elements of all blocks and the longest group in periodic table respectively are 1) 1st . O and O2. IV B group 18. The position of element just below it in modern periodic table is 1) 4th period . The radii of F-1.1 g 3) 2. IIIB 3) 7th & IIB 4) 6th .F.. R is false 4) A is false..42 g 4) 10. When 2. Assertion (A) : Fluorine atom has less electron affinity than Chlorine atom Reason (R) : Additional electrons are repelled more strongly by 3p electrons in Chlorine atom than by 2p electrons in Fluorine atom 1) Both A and R are correct and R is the correct explanation of A 2) Both A and R are correct and R is not the correct explanation of A 3) A is correct.7g..3 g 13. IA 14.are in the order UDAY . VI B group 3) 5th period .86 g 2) 5. of Aluminium metal on heating with excess of oxygen. zero 2) 6th . HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 1) 16 parts by weight of Y 2) 32 parts by weight of Y 3) 48 parts by weight of Y 4) 8 parts by weight of Y 12. in long form of periodic table 1) Group 14 and fourth period 2) Group 14 and third period 3) Group 4 and third period 4) Group 16 and fourth period 16..

l l the possible values of ‘m’ are .A I.E.116A° 2) 2.464A° 24.+E.>F1. possible values of are 0 to (n-1).J.55x10 .>F>O F>O 2.E.0…….>F 1) 2) 3) 4) 20. R is correct 23./mole. the kinetic energy of electron is 82KJ / mole.>O O 2.6 125 544 1) 2) 3) 4) l 22. Assertion (1) : For n = 3. In an atom.+E. Some statements related to IP2 are given among them the incorrect statements is 1) IP2 of Na > IP2 of Mg 2) IP2 of oxygen > IP2 of nitrogen 3) IP2 of Be > IP2 of B 4) IP2 of Ne > IP2 of Fluorine 21.+E. 2 and ‘m’ may be 0. R is false 4) A is false.>O>F O 2. (+2. (+ 1and 0 ).For each value of .…….E. the kinetic energy of the electron is 4. 1. When Ionisation energy and Electron affinity of an element are expressed in K. The distance of that electron from the nucleus is 1) 2.+E.116nm 3) 8.E.+ 1) Both A and R are correct and R is the correct explanation of A 2) Both A and R are correct and R is not the correct explanation of A 3) A is correct.A 2 5.. In hydrogen atom. The wave number of the 4th line in the Lyman series of hydrogen spectum is 24 25 25R 24R cm -1 cm -1 cm -1 cm -1 25R 24R 24 25 1) 2) 3) 4) 25 Velocity of electron in 3rd orbit of Li+2 ion is 1) 3 times the velocity of electron in first orbit H-atom 2) 1/3 times the velocity of electron in first orbit H-atom 3) Equal to velocity of electron in first orbit of He+ ion 4) Equal to velocity of electron in second orbit of He+ ion 26.>O>F1. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ O 2.>F1. the electronegativity in the Pauling scale is given by I. may be 0.>F1.464nm 4) 8. Then its de Broglie wavelength is UDAY .A I. + 1 and 0) l l Reason (R) : For each value of ‘n’.A I.25 J.

1.6 A0 2) 0.1A0 29. 2 4) 2.6 A0 3) 2. 2s 4. z axis 5.53 A0 4) 0.53 A0 . Assertion (A) : CuCl is more covalent than KCl Reason (R) : Cu+ ion has pseudo inert gas configuration 1) Both A and R are correct and R is the correct explanation of A 2) Both A and R are correct and R is not the correct explanation of A 3) A is correct. 1 30. The electron configuration of which of the following is not correct 1) 2.1A0 & 2. yz-plane 3d x 2 -y2 C. 1 3) 2. Two planes at 90° each other and which make 45° to X and Y axis The correct match is A B C D A B C D 1) 2 3 4 5 2) 2 3 5 4 3) 2 3 5 1 4) 3 4 2 5 28.1. 1 2) 2. 3. 18. In the radial probability distribution curve for the 2s orbital of the hydrogen atom. Zero B. 2Px 1. 2. the second maximum and the node respectively occur at the following distances from the nucleus 1) 1. yz & xz-planes D.1A0 & 0.1A0. R is correct 32. 18.6 A0 &1. R is false 4) A is false. 8. The difference in angular momentum associated with the electron in two successive orbits of hydrogen is h h 3h 3h  2π 2π π 1) 2) 3) 4) 31. 3dxy 2. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 1) 1000A0 2) 6500A0 3) 7250A0 4) 8650A0 27. 8.53 A0 .6 A0 . 0. List-A (orbital) List-B (Nodal Planes) A. 8.53 A0 & 2. 14. 8. the first maximum. 13. The number of unpaired electrons present in the first excited state of chlorine atom is 1) 3 2) 5 3) 7 4) 1 UDAY .

Which of the following statements is not correct from the view point of molecular orbital theory. Identify incorrect statement among the following 1) Ionic nature is in the order of NaCl < KCl < RbCl < CsCl 2) Melting temperature are in the order of NaCl < KCl < RbCl < CsCl 3) Crystal lattice energy is in the order of NaCl > KCl > RbCl > CsCl 4) The co-ordination numbers of metal ions in NaCl = KCl = RbCl < CsCl 37.5 kg ms. R is false 4) A is false. 1) Be2 is not a stable molecule 2) He2 is not stable but He+ is expected to exist 3) Bond strength of N2 is maximum amongest the homonuclear diatomic molecules 4) The order of energies of molecular orbitals in F2 molecule is UDAY . HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 33. The geometrical arrangement of hybrid orbitals in and shape of are respectively 1) Trigonal bipyramidal and linear 2) Octahedral and linear 3) Planar triangular and Planar triangular 4) Tetrahedral. then lattice energy associated with the crystal AB is 1) X 2) 2X 3) 4X 4) 8X 35. If positive ion is present at the body center of the unit cell in FCC lattice.. The uncertainty in the momentum of an electron is 1x10 .05x10-28m 2) 1. Pyramidal 39. Assertion (A): BF3 molecule is planar and NF3 molecule is pyramidal in shape Reason (R): Nitrogen atom is smaller than boron atom 1) Both A and R are correct and R is the correct explanation of A 2) Both A and R are correct and R is not the correct explanation of A 3) A is correct. R is correct I-3 I-3 38. The uncertainty in the position will be 1) 1. the negative ions are present .1.05x10-26m 3) 5. 1) Only at face centers 2) Only at corners 3) Only at the center of edges 4) At corners and also at face centers 36. If the ionic size of A+2 is equal to that of Na+ and B-2 is equal to that of Cl.25x10-28m 34.27x10-30m 4) 5. Lattice energy of NaCl is ‘X’.

H3O  ]&[NO3 . the Ionic charge is 4.]&[BF3 .48 3) 5.8 2) 0.NO3. sp2 – s and p – p 3) PCl5 C) sp2 – sp2.4 44.8 x 10 –10 esu.hydroxybenzaldehyde is more soluble than O-hydroxybenzaldehyde in water C) The B. In a polar molecule. sp2 – s and sp – p 4) CO2 D) sp3d – p 1) 1 – B 2 – C 3–D 4–A 2) 1–B 2–C 3–A 4–D 3) 1 – B 2 – B 3–D 4–A 4) 1 – B 2–A 3–C 4–D 42.BF3 ] [NF3 . the correct statements are A) O . Among them.BF3 ] 1) 2) [NF3 . Identify the iso structural pairs in the following ? [NF3 .4 4) 2.BF3 ] 3) 4) UDAY . Following molecules of atoms of A and X have SP 3 hybridisation of the central atom A. If E is the lone pair. of O-hydroxybenzaldehyde is greater than that of P-hydroxybenzaldehyde 1) All are correct 2) Only A and B are correct 3) Only B and C are correct 4) Only A and C are correct 43. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________  σ2S   2S *   2PX    2PY    2PZ    2P  * X   2P  * Y Ekk* < E <E <E =E <E <E =E < E  * 2PZ  40. Some statements are given below.hydroxybenzaldehyde is steam volatile B) P .P.H3O + ] [NF3 . The Dipolemoment is _____ Debyes 1) 4. The Inter Ionic distance is 1A 0. bond angle is minimum for 1) AX2E2 2) AX3E 3) AX4 4) Equal in all 41 List-I (Molecules) List-II (overlappings) The correct match is 1) C2H4 A) p – p and sp-p 2) C6H6 B) sp2 – sp2.HN 3 ]&[NO3 .H 3O  ]&[HN 3 .

O +2 <O 2 <O 22. A group which deactivates the benzene ring towards electrophilic substitution but directs the incoming group towards o .<O-2 1) 2) 3) 4) 1 1 2 3 3 3 4 1 5 2 6 3 7 3 8 2 9 4 10 4 11 1 12 2 13 2 14 4 15 1 16 3 17 3 18 4 19 1 20 3 21 4 22 1 23 4 24 4 25 4 26 3 27 3 28 4 29 4 30 2 31 1 32 1 33 3 34 3 35 4 36 2 37 2 38 1 39 4 40 1 41 3 42 2 43 1 44 4 45 3 DPT.and p . The correct increasing order of bond lengths O +2 <O-2 <O2-2 <O 2 O 2 <O-2 <O 2-2 <O +2 O +2 <O 2 <O-2 <O 22. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 45. Geometrical isomerism is not exhibited by Ph Ph N N N N OH OH OH OH a) b) c) d) 2. Which of the following statements is wrong a) Benzene does not decolourise alkaline potassium permanganate solution UDAY . Westron ‘C’ on reduction with sodium in liquid ammonia gives a) Cis – 2 – butene b) Trans – 2 – butane c) 1 – butyne d) 2 – butyne 4.positions is a) –NH2 b) –Cl c) –NO2 d) –C2H5 Zn + Alcohol Na 2CH3I     excess A excess B C + 2Nal 3.4: 1.

HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ b) Benzene is aromatic hydrocarbon  c) Benzene has delocalised – electron cloud d) Benzene does not undergo substitution reactions 5. Carcinogenic polynuclear hydrocarbon. (R) is the correct explanation of (A). Assertion (A) : Acetylene is used in oxyacetylene flame Reason (R) : At a temperature of 200 . 1. b) Both (A) and (R) are correct.2–benzanthracene is a) b) CH3 CH3 c) d) 7.p–directing nature of –CH3 group on benzene ring is due to a) Hyper conjugation b) –Mesomeric effect UDAY . c) (A) is true. (R) is not the correct explanation of (A). o. but (R) is true 6.400°C in presence of silver and air ethylene forms epoxide a) Both (A) and (R) are correct. but (R) is false d) (A) is false.

The reactivity order of the following towards dehydrohalogination is A) (CH3)3C-Br B) CH3–CH2–CH2–Br C) (CH3)2CH-Br a) A > B > C b) C > B > A c) A > C > B d) A = B = C 10. d) Both (A) and (R) are correct. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ c) –Inductive effect d) +Electromeric effect anhyd. Assertion (A) : Peroxide effect is observed in the addition of HBr to unsymmetrical alk– enes. but (R) is false b) (A) is false. but not observed in the addition of HCl Reason (R) :H–Br bond is cleaved by free radical whereas H–Cl bond is not cleaved byfree radical because of more bond energy a) (A) is true. + Excess of chlorine X The correct statements of the following I) 'X' is aromatic compound II) 'X' is benzene hexachloride III) 'X' is used as insecticide IV) 'X' is hexa chloro benzene a) I and II b) II and III c) III and IV d) I and IV 9. 2–butanol is converted to acetaldehyde by which of the following sequence of reactions? a) Dehydration followed by oxidation with Baeyer's reagent b) Dehydration followed by ozonolysis in the presence of zinc c) Dehydration followed by oxidation with acidified KMnO4 d) Dehydration followed by addition of H2 in the presence of Lindler's catalyst UDAY . AlCl ¾¾ ¾ ¾¾ 3® dark. but (R) is true c) Both (A) and (R) are correct. (R) is not the correct explanation of (A) 11. (R) is the correct explanation of (A).cold 8.

C-1. B-4. C-1. When 'x' is reacted with alcoholic KOH 'y' is formed 'x' and 'y' are respectively a) Br-CH2-CH2-Br and C2H2 b) C2H5Br and C2H4 c) C2H5Br and C6H6 d) C2H3Br3 and C2H4 15. C-1. The formation of product in the following reactions follows Markovnikov's rule ® a) CH3–CH=CH2 + HBr CH3–CHBr–CH3 + CH3–CH2–CH2Br Major Minor ® b) CH3–CH=CH2 + HBr CH3–CHBr–CH3 + CH3–CH2–CH2Br UDAY . D-3 14. B-4. D-5 b) A-2. Correct matching to get benzene is a) A-3. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 12. Ethylene is reacted with Br2 in CCl4 to form 'x'. Which of the following is non-aromatic? O a) b) c) d) 13. HCl C) Acetylene 3) anhydrous AlCl3  D) Benzene sulphonic acid 4) Zinc dust. D-2 d) A-2. Set-I Set-II A) Sodium benzoate 1) Red hot iron tube B) Phenol 2) dil. D-3 c) A-5. B-5.  5) Soda lime. B-4. C-1.

HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ Minor Major (C H CO) O 2 2 6 ¾ ¾¾ 5 ¾ ¾® c) CH3–CH=CH2 + HBr CH3–CHBr–CH3 + CH3–CH2–CH2Br Major Minor (C H CO) O 6 ¾ 2 ¾ 5 ¾ 2® ¾¾ d) CH3–CH=CH2 + HBr CH3–CHBr–CH3 + CH3–CH2–CH2Br Minor Major 16. II c) IV. I. The correct sequence of steps in electrophilic substitution reaction of benzene is I) Formation of sigma complex II) Removal of proton III) Generation of electrophile IV) Formation of arenium ion a) I. II d) II. III. Polyethene can be produced from calcium carbide by the following reactions ® CaC2 + 2H2O Ca(OH)2 + C2H2 ® C2H2 + H2 C2H4 ® n(C2H4) (C2H4)n The mass of polyethene obtained from 20 kgs of CaC2 is a) 5. Which of the following gas decolourises alkaline KMnO 4 but does not give white precipitate with ammonical silver nitrate ? a) C2H2 b) C2H4 c) CH4 d) C2H6 17.65 Kgs b) 8. II.75 Kgs c) 12 Kgs d) 20 Kgs 18. IV b) III. III. IV i)Iodoform + Ag ¾¾  ®X redhot iron ii) X ¾¾ ¾¾ ®Y (powder) tube 19. I. The correct statement about 'X' and 'Y' are UDAY .

The type of overlappings involved in the formation of ethyne molecule are sp 2  s sp 2  sp 2 p  p a) Four . two and two sp 2  s sp 2  sp 2 p  p d) Four . HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ a) Both 'X' and 'Y' form same ozonide b) Both 'X' and 'Y' form white precipitate with Tollen's reagent c) 'X' is a cyclic trimer of 'Y' d) The ozonolysis products of 'X' and 'Y' are same 20. one and two sp  s sp  sp p  p c) Two . Which of the following has more acidic behavior? a) 1–Butyne b) 2–Butyne c) Acetylene d) Propyne 21. two and one UDAY .KOH Alcolic Zn ¬¾ ¾ ¾ ¾¾ ¾¾ ¾¾ ®B 44. one and one sp  s sp  sp p  p b) Two . A Br–CH2–CH2–Br 'A' and 'B' can be distinguished using a) Baeyer's reagent b) Bromine in CCl4 c) Tollen's reagent d) Fehling's solution 45. Wrong statement of the following is a) The straight chain alkenes have higher boiling point than branched chain alkenes b) Trans-But-2-ene has zero dipolemoment  c) Dehydrohalogination of alkyl halides is an example of –elimination reaction d) (CH3)2C=CH–C2H5 will show geometrical isomerism Excess  alc.

HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 1) 2) 3) 4) 5) 6) 7) 8) 9) 10) 11) 12) 13) 14) 15) 16) 17) 18) 19) 20) 21) 22) 23) D 24) B 25) B 26) D 27) B 28) B 29) A 30) D 31) C 32) C 33) B 34) C 35) C 36) A 37) A 38) B 39) B 40) B 41) D 42) C 43) D 44) C 45) B DPT-5: 46. IUPAC name of the compound is a)2. The ratio of & bonds in benzene is a)4:1 b)2:3 c)3:2 d)1:4 C2 H 5 CH 3  CH  CH 2  CH  CH 3 C2 H 5 48.Diethyl pentane b)2-Ethyl-4-methyl hexane UDAY .4 . sp2 and sp3 hybrid orbitals in the compound CH3-CH=CH-C≡C-CH3 a)1:1:1 b)2:3:2 c)1:2:2 d)2:3:4 s p 47. The ratio of the sp.

AgBr The correct matching is A B C D A B C D a) 3 4 1 5 b) 4 1 3 2 c) 3 1 5 2 d) 4 5 1 3 51.5 – Di methyl heptane d)4-Ethyl-2-methyl-hexane 49.The percentage of nitrogen in the compound is a)28 b)56 c)42 d)84 52. Which of the following is a pair of functional Isomers? UDAY . Prussian blue 1.5gm of an organic compound neutralized 10ml of 1M H2SO4. Blood red 3. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ c)3. Pick out the incorrect statement a) Alkyl group on Benzene ring is ortho and para directing because of hyperconjugation b) In Duma’s method Nitrogen is estimated c) P-Nitrophenol and O-nitrophenol are separated by steam distillation d) In paper chromatography. Pale yellow 4. Violet 2. In kJehldahl’s estimation of nitrogen. Match the following List – I List – II A. Na4[Fe(CN)5NOS] 5. [Fe(SCN)]+2 B. Fe4[Fe(CN)6]3 D. mobile phase is liquid and stationary phase is solid 50. the ammonia evolved from 0. AgCl C.

HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ a) Maleic acid and Fumeric acid b) 2-Butene and 1-Butene c) Propionaldehyde and Acetone d)2-pentanone and 3-pentanone 53. Energy barrier between staggered and eclipsed conformations of ethane is a)0.< (CH3)3C- d) Ethene > Propene > 1-Butene > 2-Butene 54.cal/mole c)12 K.6 K.cal/mole 57.cal/mole d)16 K.< CH3CH2.cal/mole b)2. Which of the following orders about stability is correct? a) CH3+ > CH3CH2+ > (CH3)2CH+ > (CH3)3C+  CH3  CH 2   CH3  2  CH 3  3 C  CH 3  CH  b) c) CH3. b) HSO3. Both methane and ethane may be obtained separately in one step from a)CH3I b)CH3COONa c)C2H5Cl d)both a and b 56. Which of the following has maximum boiling point a) b) UDAY .< (CH3)2CH. Which of the following is not a nucleophile a) OH.9 K. c) NH3 d) BF3 55.

which one of the following is also formed in minute quantity? a)CH4 b)C6H6 c)C4H10 d)C2H6 60. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ c) d) d)  HCl  S2Cl2  Zn C2 H 5Cl       A B C.Heptane. Here C is a) Westron b) Ethylene glycol c)Mustard gas d)Westrol 59. In the chlorination of ethane in the presence of sunlight. the compound ‘B’ is UDAY . 5000 C 58. In the following sequence of reactions. when passed through Cr 2O3 supported over alumina at 6000C respectively give a) Benzene and heptane b) Heptane and toluene c) Benzene and Benzene d)Benzene and toluene 61.Hexane and n. n.

UDAY .3-Dimethyl Butane on Wurtz reaction.KMnO 4 to respectively give a)Acetic acid and Ethylene oxide b) Oxalic acid and epoxy ethane c) Oxalic acid and ethylene glycol d) Ethyl alcohol and Acetaldehyde HBr X (Major) CH3CH=CH2 HBr/Peroxide Y (Major) 63. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________   O3   H 2O / Zn CH3CH=CHCH3 A B a)CH3CH2CH2CHO b)CH3CHO c) CH3COCH3 d) CH3CH2CHO 62.KOH. d) Y gives 2. Acetylene and Ethylene react with cold and dilute alk. Incorrect statement among the following is a) Formation of ‘X’ is electrophilic addition and ‘Y’ is free radical addition. b) X and Y are positional Isomers. c)’X’ gives propene with alc.

Which of the following reacts with an aqueous solution of [Ag(NH 3)2]+OH-  a) CH3 CH= CH2 b) CH3 C CH  c) CH3 CH = CH CH3 d) CH3 C C CH3 67. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ KMnO4 64. the same percentage composition by weight. Match the following List-I (Reagent used with Ethyne) List-II(Product) A) H2 in the presence of Ni I) Benzene B) 40% H2SO4+1% /HgSO4 II) Ethene C) Red hot copper tube III) Ethane D) H2 in the presence of Lindlar’s catalyst IV) Ethanal A B C D A B C D UDAY . The compound which decolourises dilute alkaline and does not give precipitate to ammonical cuprous chloride is a)Ethane b)Benzene c)Ethene d)Ethyne 65. Which among the following will be the correct formulae of A and B a) A = C2H2 B= C6H6 b) A = C6H6 B= C2H2 c) A = C2H4 B= C2H6 d) A = C2H2 B= C3H8 68. Two organic compounds A and B both containing C and H yield on analysis. Which of these will not react with acetylene Cl a)NaOH b)Na c)Tollen’s reagent d)H 66. A decolourises bromine water but B does not.

cal/mole d)36K. The heat of hydrogenation of Benzene is 51K.cal/mole. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ a) III IV II I b) III IV I II c) IV III I II C) IV I II III  X   Zn 69. .cal/mole b) 22K.cal/mole. In this sequence B is a)Benzene b)Benzene Sulphonic acid c)Phenol d) C2H2 Cl2 / h A C6H6 Cl2 / FeCl3 B UDAY .cal/mole c)29K. while its resonance energy is 36K. Sodium benzoate C6H6. The function of anhydrous AlCl3 in Friedel craft’s reaction is a) To absorb water b) To absorb HCl c) To produce attacking electrophile d) To produce nucleophile 71. Here X and Y are respectively a) NaOH + CaO and C6H5CHO b) Zn and C6H6 c) NaOH + CaO and C6H6 d) Zn and C2H6 70.cal/mole C2 H 2   Re   d not Fe tube A Fu min g H 2 SO4 B 72. C6H5OH Y. Then the heat of hydrogenation of cyclohexene is a) 14K.

Dinitro benzene 75. A and B respectively are. the possible products are/is a) C2H6 b) CO2 c) NaOH d) All the above 77. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 73. The correct order of reactivity of the following compounds towards electrophilic substitution is A)Nitrobenzene B)Benzene C) Phenol a) A>C>B b) A>B>C c) B>C>A d) C>B>A 76. a) Hexa chloro cyclohexane & Hexa chloro benzene b) Chloro benzene & Hexa chloro cyclohexane c) Hexa chloro cyclohexane & Chloro benzene d) Hexa chloro benzene & Hexa chloro cyclohexane 74.98% b) Tritium is radioactive and emits low energy β radiations only UDAY . When an aqueous solution of sodium acetate is electrolysed.3. Nitration of Benzene with Nitration mixture at 1000C gives a) 1. The correct order of acidic nature of   A) C2H2 B) CH3 C CH and C) CH3C C CH3 is a) C>A>B b) B>A>C c) C>B>A d) A>B>C 78. Incorrect statement among the following is ( H2 ) a) The isotopic abundance of normal hydrogen is 99.5 –Trinitro benzene b)m-Dinitro benzene c)O-Dinitro benzene d)P.

Which of the following has greater degree of hardness UDAY .Purest form of hydrogen is obtained by a) Electrolysis of aq. Incorrect statement among the following H 2O 40 C a)The density of is maximum at H 2O D2O b)The dielectric constant of is higher than that of D2O H 2O c)Ionic product of is higher than that of NaCl H 2O D2O d) is more soluble in than in 83. the substance which is used to remove temporary hardness of water is a) Na2Al2Si2O8. Ba(OH)2 solution b) Reduction of steam with coke c) Watergas shift reaction d)Reaction of Zinc with aq. Electron precise compound among the following is a) NaH b) NH3 c) CH4 d) ZrH2 81. Exhausted anion exchange resin is revived by using a solution of a) NaOH b) Na2CO3 c) H2SO4 d) Both a & b 85.xH2O b)Na2[Na4(PO3)6] c) RNH3OH d)Ca(OH)2 84. In Clark’s method. alkalies 80. Which of the following has highest boiling point a) CH4 b) NH3 c) H2O d) HF 82. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ c) H2 and D2 bondlengths are same d) Tritium is more reactive than deuterium due to high activation energy 79.

8V b) 5. solution is electrolysed a) H2O2 2) H2 c) H2S2O8 d) H2SO3 88. HOCl and PbS are oxidised 89.2V d) 22. Study the following reactions carefully HOCl + H 2O 2  H 3O + + Cl . when 50% H2SO4 aq. HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ a) Water with 1mg CaCl2 per litre b) Water with 1mg CaSO4 per litre c) Water with 1mg MgSO4 per litre d) all have equal value 86.4V 90. H2O2 reduces MnO4 a) FeSO4 / H+ b) KI / H2O c) / H+ d) All the above UDAY . The product obtained at anode. Mark the correct statement a) In ‘A’ HOCl is reduced and in ‘B’ PbS is oxidised b) In ‘A’ HOCl is oxidised and in ‘B’ PbS is reduced c) In both A and B. In the following reactions which is deuterolysis   I) Al4C3+12D2O 3CD4+4 Al(OD)3 II) SO3+D2O D2SO4   III) SiCl4+2H2O SiO2+4 HCl IV) NaOH+D2O NaOD+ HOD a) Only I and II b) Only I. B.+ O 2 PbS + 4H 2O 2  PbSO 4 + 4H 2O A. HOCl and PbS are reduced d) In both A and B. II and IV c) Only I d) Only III 87. The volume strength of 1N H2O2 is a) 2.6V c) 11.

HYDERABAD INSTITUTE OF EXCELLENCE SR NEET : HIGH DEPENDENCY QUESTIONS ___________________________________________________________________________ 1) d 2) a 3) c 4) d 5) a 6) b 7) c 8) b 9) d 10) d 11) b 12) a 13) c 14) c 15) d 16) b 17) c 18) d 19) c 20) a 21) b 22) a 23) b 24) c 25) c 26) c 27) b 28) c 29) b 30) d 31) d 32) d 33) d 34) a 35) c 36) c 37) c 38) d 39) d 40) a 41) c 42) c 43) a 44) b 45) c UDAY .