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HYDERABAD INSTITUTE OF EXCELLENCE

CHEMISTRY PRACTICE PAPERS

AIPMT-1

1. Volumes of 10M HCl and 5M HCl to be mixed to prepare 10L of 6M HCl solution are
respectively,
1) 3L and 7L 2) 2L and 8L 3) 1.5L and 8.5L 4) 2.5L and 7.5L

2. Which of the following liquid pair solutions shows a positive deviation from Raoult’s law ?
1) Water – nitric acid 2) acetone – chloroform
3) Benzene – methanol 4) water – hydrochloric acid

3. Match the following
List I (oxide) List II (Magnetic property)
i) CrO2 A) Ferrimagnetic
ii) Fe3O4 B) Antiferromagnetic
iii) ZnO2 C) Diamagnetic
iv) MnO2 D) Ferro magnetic
E) Paramagnetic

1) i – D ii – A iii – C iv – B 2) i – D ii – E iii – B iv – C
3) i – B ii – A iii – C iv – D 4) i – A ii – D iii – C iv – B
4. Atoms ‘A’ are arranged in ccp array. Atoms of ‘B’ occupy all the octahedral voids and half of
the tetrahedral voids. The formula of the compound of A and B is
1) AB2 2) A2B 3) A2B3 4) AB

5. The reduction potential of hydrogen electrode is – 0.24 volt. The pH of the acid solution in
which the hydrogen electrode is immersed at a pressure of 1 atm is
1) 1 2) 3 3) 5 4) 4

6. In a cell that utilises the reaction, Zn( s )  2H  ( aq )  Zn2 ( aq )  H 2 ( g ) , addition of H2SO4 to the
cathode compartment, will
1) increase the Ecell and shift the equilibrium to the left
2) increase the Ecell and shift the equilibrium to the right
3) lower the Ecell and shift the equilibrium to the left
4) lower the Ecell and shift the equilibrium to the right

7. Given equilibrium constants for the following equilibria in gas phase :
2CO O2 2CO2 ; k1
2H 2 O2 2H2O; k2
CO H2O CO2 H2 ; k
The equilibrium constants are related as

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HYDERABAD INSTITUTE OF EXCELLENCE
CHEMISTRY PRACTICE PAPERS

3) k   k1  k2  4) k   k1 k2 
1
1) k  k1 k2 2) k  k1  k2
2 2

8. Assertion (A) : The synthesis of NH3 in Haber’s process needs 500oC inspite of the fact that the
reaction is favoured at low temperature according to Lechatelier’s principle.
Reason (R) : The reaction proceeds faster at high temperature.
1) Both (A) and (R) are true and (R) is the correct explanation of (A).
2) Both (A) and (R) are true but (R) is not the correct explanation of (A).
3) (A) is true but (R) is false. 4) (A) is false but (R) is true.

9. A reaction occurs spontaneously if
1) TΔS<ΔH and both ΔH and ΔS are +ve 2) TΔS>ΔH and both ΔH and ΔS are +ve
3) TΔS=ΔH and both ΔH and ΔS are +ve 4) TΔS<ΔH and ΔH is +ve and ΔS is – ve

10. Heat liberated in the neutralization of 500mL of 1N HCl and 500mL of 1N NH 4OH is 5.69KJ.
The heat of ionization of NH4OH is about
1) 10.98 KJ 2) 45.92 KJ 3) 51.61 KJ 4) 22.98 KJ
1
11. A gaseous reaction, A2 B C shows increase in pressure from 100 mm to 120 mm in 5
2
minutes. The rate of disappearance of A2 is
1) 8mm min–1 2) 4 mm min–1 3) 16 mm min–1 4) 2 mm min–1
12. Rate of decomposition of nitrous oxide is 0.1M s–1. What is the rate constant of the reaction if
the concentration of N2O is 0.1M
1) 10 M–2 s–1 2) 1 x 10–2 M–1 s–1 3) 6.9 x 10–2 s–1 4) 10 M–1 s–1
13. If the solubility of Mg(OH)2 is 2 , its solubility product will be
1) 8 2) 4 2 3) 9 2 4) 8 2
14. The pH of a solution of HCl is 1. The amount of acid present in one litre of the solution will be

1) 3.65g 2) 0.365g 3) 36.5g 4) 1.0g
15. Aqueous solution of potash alum is
1) slightly alkaline 2) acidic 3) neutral 4) strongly alkaline
16. Which one of the following is correctly matched ?
1) milk – solid in liquid sol 2) starch – liquid in liquid sol
3) Blood – emulsion 4) smoke – aerosol
17. An example of autocatalysis is
1) decomposition of KClO3 to KCl and O2
2) oxidation of oxalic acid by acidified KMnO4
3) oxidation of SO2 to SO3 4) oxidation of NO to NO2

18. Which of the following gases is adsorbed most on one gram of activated charcoal ?
1) CH4 2) SO2 3) N2 4) HCl

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PH3 3). the products formed contain 1) NaClO2 2) NaClO3 3) NaClO4 4) all of these 25. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 19.6 2) Terylene 3) teflon 4) bakelite 28. Cerium (Z=58) is a member of lanthanides.87 26. UDAY . Which of the following statements about Cerium is incorrect ? 1) the common oxidation states of Ce are +3 and +4 2) the +3 oxidation state of Ce is more stable than +4 oxidation state 3) Ce (IV) acts as an oxidising agent 4) the +4 oxidation state of Ce is not known in solution.73 2) 2. cryolite and NaOH 4)aqueous solution of Al2(SO4)3 and dilute H2SO4 22. SbH3 4). cryolite and fluorspar 3) molten mixture of Al(OH)3. NH3 2). Reason (R) : With dilute solution of NaOH. 1) Both (A) and (R) are true and (R) is the correct explanation of (A). When chlorine gas is passed through hot and concentrated caustic soda solution. Assertion (A) : Fructose with ketone group could reduce Fehling’s solution. Heating an ore in the absence of air below its melting point is called 1) Leaching 2) smelting 3) roasting 4) calcination 21.83 3) 2. The spin-only magnetic moment (in units of Bohr magneton) of Ni2+ in aqueous solution would be 1) 1. Which of the following is not oxidised by ozone ? 1) moist KI 2) SO2 3) FeSO4 4) acidified KMnO4 24. BiH3 23.45 4) 3. Which of the following monomers gives the polymer neoprene on polymerization ? 1) CH2 CH CH2Cl 2) CH2 CH C6 H5 3) CH 2 C| COOCH3 4) CH 2 C| CH CH 2 CH3 Cl 29. D-mannose and L-fructose. 27. In the commercial electrochemical process for aluminium extraction. The metal not obtained by reduction of its oxide with carbon is 1) Fe 2) Zn 3) Pb 4) Cu 20. fructose gives a mixture of D-glucose. The strongest reductant among the following? 1). 2) Both (A) and (R) are true but (R) is not the correct explanation of (A). the electrolyte used is 1) Al2O3 in NaOH solution 2) molten mixture of alumina. A polymer which has amide linkage is 1) Nylon-6.

HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 3) (A) is true but (R) is false. b.CHO 4) CH3 -CHO 41. d 4) a. In DNA. c. 2) An S N1 reaction proceeds with complete inversion of configuration 3) An SN 2 reaction follows second order kinetics. a. Which of the following statements is incorrect ? 1) The reaction of t-butyl chloride with OH follows first order kinetics. d 2) b. d 3) a. Which of the following in the body causes allergic reactions like skin rashes ? 1) Histadine 2) Histamine 3) ranitidine 4) chloropheniramine 33. Sodium tertiary butoxide gives ether when reacts with 1) isopropyl bromide 2) tertiary butyl bromide 3) methyl bromide 4) all of the above 39. The compound B is 1) Bromobenzene 2) Diphenyl 3) Benzyl bromide 4) Benzophenone 37. a. Which of the following is more acidic ? 1) o – cresol 2) phenol 3) p – chlorophenol 4) m . 30. phosphodiester bond is present between 1) Base and sugar 2) base and base 3) sugar and sugar 4) any of these 31. c. Benzene A B . c 34. 4) (A) is false but (R) is true. Aldehydes can be prepared by the oxidation of primary alcohols using 1) Pyridinium chlorochromate 2) hot chromic acid 3) hot acidified KMnO4 4) hot conc. d. Iodoform test is not given by 1) CH3 CH2OH 2) CH3 CO CH2 CH3 3) CH3 CH2 CHOH CH2 CH3 4) CH3 CHO 35. b.nitrophenol 38. Br2 FeBr3 2 Na . dry ether 36. The following steps are involved in the conversion of isobutylbenzene to ibuprofen a) addition of HCN b) acetylation c) reduction d) hydrolysis Correct sequence is 1) b. A biological catalyst is essentially 1) a carbohydrate 2) an amino acid 3) an enzyme 4) a lipid 32. Which of the following does not undergo Cannizzaro reaction ? 1) H-CHO 2) C6 H5 -CHO 3) CH3 3 C. 4) An SN 2 reaction proceeds with stereochemical inversion. c. Identify A and B in the following conversions: A B CH3 CH3 CH3 COOH CH3 CH 2OH A B 1) LiAlH4 Zn+HCl 2) HI + red P LiAlH4 3) Zn + HCl Pd + BaSO4 UDAY . HNO3 40.

line of Lyman series and H  . In hydrogen atom the ratio of the wave numbers of H . Acetamide with Br2 and NaOH gives 1) Ethyl amine 2) methyl amine 3) ethyl bromide 4) methyl bromide OH 45. C6 H 5 N 2Cl C6 H 5OH X.line of Balmer series is a) 1 : 2 b) 2 : 3 c) 4 : 1 d) 3 : 4 47. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 4) LiAlH4 HI + red P 42. Benzene diazonium chloride can be reduced to benzene with 1) H3PO3 or H2O 2) C2H5OH or H3PO3 3) H3PO2 or C2H5OH 4) LiAlH4 or Zn/HCl 43. Assertion (A): Number of waves made by a revolving electron in an orbit is equal to Azimuthal quantum number Reason (R): Circumference of the orbit is an integral multiple of wave length of the electron a) A and R are true and R is the correct explanation of A b) A and R are true and R is not the correct explanation of A UDAY . Correct increasing order of base strength of amines is 1) C6 H5 NH2 NH3 C6 H5CH2 NH 2 C2 H5 NH 2 2) C6 H5 NH2 NH3 C2 H5 NH2 C6 H5CH2 NH 2 3) NH3 C6 H5 NH2 C6 H5CH2 NH2 C2 H5 NH2 4) C2 H5 NH2 C6 H5CH2 NH2 C6 H5 NH2 NH3 44. 1) 2 2) 3 3) 1 4) 1 5) 4 6) 2 7) 4 8) 1 9) 2 10) 2 11) 1 12) 4 13) 4 14) 1 15) 2 16) 4 17) 2 18) 2 19) 4 20) 4 21) 2 22) 4 23) 4 24) 2 25) 2 26) 4 27) 1 28) 4 29) 3 30) 3 31) 3 32) 2 33) 2 34) 3 35) 2 36) 2 37) 4 38) 3 39) 1 40) 4 41) 2 42) 3 43) 1 44) 2 45) 3 AIPMT-2 46. Correct statement among the following : 1) X is an yellow dye 2) The reaction is electrophilic substitution in phenol 3) The reaction is nucleophilic substitution in phenol 4) The reaction is electrophilic substitution in C6H5N2Cl.

5H2O are a) Electrovalent.covalent. RMS velocity of SO2 at 27º C is 0.3 – dimethyl but – 2 – ene c) 2 – methyl but – 1 – ene d) 3 – methyl but – 1.3 m/sec b) 0. The fraction of the original gas remaining in the flask is 3 1 1 2 a) b) c) d) 4 2 4 5 53. Hydraulic mortar is prepared by heating a) Lime stone and clay b) Lime stone only c) Magnesite and clay d) Magnesite and sand 57.2 m/sec d) 0. Comproportionation b) Cr(OH)3   CrO4-2 .31A0 c) 2. 0. If the ozonolysis of an olefin gives only propanone. Which of the following is M a) Mg b) F c) N d) Be 54. In which of the following all species have same geometry a) NH3. CO2 c) SF6. Oxidation c) 2S2Cl2 + 2H2O   SO2 + 4HCl + S. The flask is heated to 5270C at the same pressure.5g of an organic compound in Kjeldahl method liberated NH3 which was exactly neutralised by 20ml of 1N H2SO4 percentage of nitrogen in the compound is a) 28 b) 56 c) 84 d) 40 51. BF3 b) SO2. then the olefin is a) But – 1 – ene b) 2.ene UDAY . OF2. covalent b) Covalent .5A0 d) 5A0 50.31A0. Its covalent radius is a) 2. XeF2.9 m/sec c) 1. CCl4 49.03A0 b) 2. An open flask has helium gas at 2 atm and 3270C. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS c) A is true. Disproportionation d) MnO4-1   MnO4-2 . M(g) + e-1   M-1(g) is exothermic. The types of bonds present in CuSO4. IUPAC name of NH3 is a) Azane b) Ammonia c) Amine d) Oxidane 52. Reduction 56. BF4-1 d) CH4. H3O+. R is true 48.3 m/sec then RMS velocity of the same gas at 927º C is a) 0. The atomic radius of Potassium is 2. co – ordinate covalent c) Electrovalent. dative and hydrogen bond d) Electrovalent 58. NH4+.6 m/sec 55. Pick up the wrong match a) Cr2O7-2   CrO5 . R is false d) A is false.

HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 59.6 cc d) 22. 2.7 d) 60 60. Wrong match is a) NaClO3  Herbicide b) CCl2 F2  Ozone depletion c) PO43  Eutrophication d) NO2  Contaminant 62. Hybridisation of silicon in silica a) sp b) sp3 c) dsp2 d) sp3d2 63. In the second period elements the IP1 values of some elements are shown below Element Li Be B C N O F IP KJ/mole 520 899 1086 1314 1681 Then the IP1 values of B and N are respectively a) 900. Which is known as 1. 1290 c) 801.4 cc 64. 1289 69.24lt of H 2 liberated at STP. when treated with dil HCl. The weight percentage of magnesia [MgO] in the mixture is a) 20 b) 33.E. Their K.2 – Benzopyrene UDAY . The relation ship between PC. Si2O7-6 unit is present in a) Orthosilicates b) Pyrosilicates c) Cyclic silicates d) Chain silicates 65. What Volume of perhydrol is required for the complete combustion of 2 liters of Ethene ? a) 60 cc b) 10 cc c) 5. The reaction that does not take place in Fischer-Ringe’s method is a) CuO + CO   CO2 + Cu b) CO2 + 2KOH   K2CO3 + H2O c) CaC2 + N2  1073K  CaCN2 + C d) 3Mg + N2   Mg3N2 67.3 c) 66. 1403 d) 995. ratio is a) 4 : 1 b) 1 : 2 c) 1 : 4 d) 1 : 1 61. VC and TC is 3 3 a) PCVC  RT b) PCVC  RTC c) PCVC  3RTC d) PCVC  RTC 8 5 66. 1200 b) 1000. Which among the following is more stable H3C  C   CH3  a) CH 3  H 2 C  b) H3C  HC   CH 3 c) | d) CH 3 CH3 68. Debroglie wavelength ratio of two particles having same mass is 2 : 1. 3g of mixture of Mg and MgO.

The gas ’X’ is a) SO2 b) C4H10 c) Cl2 d) C5H8 77. (CH3)2CH – CH (CH3)2 d) CH3 – CHBr – CH3. CH3 – CH = CH2 + HBr   A  Dry ether Na  B. Then the products in this are CH 3 a) Acetone & Acetaldehyde b) Acetaldehyde only c) Acetone & Acetic acid d) Acetic acid only 76. wt of As = 75] a) 156.6 b) 99 c) 49. Hybridisation of all carbon atoms in C60 a) sp b) sp2 c) sp3 d) dsp2 UDAY .ol 78. One mole of Na2CO3 on hydrolysis produces a) 2 moles of H  b) 1 mole of H  c) 1 mole of OH  d) 2 moles of OH  71. (CH3)2CH – CH (CH3)2 74. Ammonia gas diffuses twice as fast as another gas ‘X’. The equivalent weight of As2O3 in the equation As2O3 + 2I2 + 2H2O   As2O5 + 4HI [At.5 d) 127 73. while that of another orbital B are 5 and 0. |   Products. Which of the following is not an isomer of butanal a) Butanone b) 2 – methyl propanal c) 2 – butanol d) but – 2 – en . CH3 – (CH2)4 – CH3 b) CH3 – CHBr – CH3. O2 molecule contain a) Two unpaired electrons in pi antibonding MO b) One unpaired electron in pi antibonding MO c) Two unpaired electrons in pi bonding MO d) One unpaired electron in pi bonding MO CH 3  C  CH  CH 3 KMnO4 / H  75. n and values of an orbital A are 3 and 2.1. CH3 – (CH2)4 – CH3 c) CH3 – CH2 – CH2Br. The energy of a) B is more than that of A b) A is more than that of B c) A and B are equal d) None of these 72. ion in water causes methemoglobinemia (Blue baby syndrome) a) SO42 b) NO3 c) CN  d) F  79. In the above reaction A and B are a) CH3 – CH2 – CH2 – Br. The presence of ……. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS CH 3 a) b) c) d) CH 3 70.

5 d) 1.kcal/mole a) 12. It exhibits resemblances with another element ‘B’ of the valency configuration a) 2s2 b) 3s2 c) 1s2 d) 3s23p1 81. Which of the following is false a) Maximum covalency of Al is 6 b) Boron exists as a cation c) Al can react with NaOH d) Boron can react with conc. b c) a. Energy difference between eclipsed and staggered form of ethane is……. d 82. c d) a. Correct statements regarding diborane are a) Diborane is electron deficient b) The heat of combustion of diborane is more than that of ethane c) Diborane is called inorganic benzene d) Diborane has two centered three electron bonds a) c. H-bonding is strongest in a) NH3 b) C2 H5OH c) H2O d) HF 86. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 80. The attacking electrophile in aromatic Sulphonation is: a) SO3 b) SO2 c) SO4-2 d) HSO3-1 CH3 90.9 c) 4. The electronic configuration of an element ‘A’ is 1s22s1. Sublimation method can be used for the purification of a) Naphthalene b) Benzoic acid c) Camphor d) All 83.0 88.5 c) 0. Here x is a) 3 b) 1. b. C + H2O  1000 C  CO + H2 CO + H2O  Catalyst 4500 C  CO2 + H2. HNO3 87.5 d) 340 89. IUPAC name of is a) 3 – Methyl cyclo hex-1-ene b) 1 – Methyl cyclo Hex-2-ene c) 6 – Methyl cyclo hexane d) 1 – Methyl cyclo Hex-5-ene UDAY . b.55 b) 2. The density of electron cloud is zero for dxy – orbital in the plane of a) yz b) xy c) xz d) both 1 & 3 0 84.The catalyst used in the reaction is a) V2O5 b) Asbestos ‘Pt’ c) Fe2O3 / Cr d) Fe 85. d b) a. x moles of potassium dichromate oxidises 1 mole of ferrous oxalate in acidic medium. c..

Third period element of the following group forms most acidic oxide 1) IA 2) IVA 3) VII A 4) IIA 50.08 x 107 m-1. 578. s = + ½ 4) n = 3. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS CHEMISTRY 46) c 47) d 48) d 49) a 50) b 51) a 52) a 53) b 54) d 55) a 56) a 57) c 58) b 59) a 60) c 61) d 62) b 63) a 64) b 65) b 66) d 67) c 68) c 69) a 70) d 71) a 72) c 73) d 74) a 75) c 76) d 77) c 78) b 79) b 80) b 81) b 82) d 83) d 84) c 85) d 86) b 87) c 88) b 89) a 90) a AIPMT-3 46. First four ionisation energy values of an element are 191. If R = 1. s = +½ 3) n = 2. m = -3. s = +½ 48.Cals. Which of the following quantum number are not possible? 1) n = 2. In a H-atom. l =1. The ratio of kinetic energies of 2gm of H2 and 4g of CH4 at a given temperature is 1) 4 : 1 2) 2 : 32 3) 1 : 4 4) 16 : 2 53. the transition takes place from L to K shell. m = -1. s = . The number of valance electrons in the element is 1) 4 2) 3 3) 1 4) 2 49. Which of the following has a planar structure 1) NH4+ 2) SCl4 3) XeF4 4) BF4- 52. 872 and 5972 K. Tb and Tc is increasing order 1) Ti < Tc < Tb 2) Tb < Tc <Ti 3) Tc < Tb < Ti 4) Ti < Tb < Tc UDAY . l = 0. Number of bonding electrons in N2 molecule according to MOT 1) 4 2) 5 3) 6 4) 10 51. l = 2. m = 0. l = 2.½ 2) n = 3. the wave length of the light emitted is nearly 1) 4400 Aº 2) 1250 Aº 3) 1650 Aº 4) 7700 Aº 47. Arrange Ti. m = -2.

and conc.4 4) 0. -H O Δ 2 1) Carborundum 2) Quartz 3) Silica 4) Carbon 66. The resulting volume of the mixture is 1) 40 ml 2) 20 ml 3) 30 ml 4) 10 ml 56.2 59. Exhausted cation exchange resin is regenerated by using solution of moderately concentrated 1) NaOH 2) Na2CO3 3) H2SO4 4) NaCl 58. The principle involved in Ammonia – Solvay process is 1) Low solubility of Na2CO3 2) High solubility of NaHCO3 3) Low solubility of NaHCO3 4) High hydration energy and lattice energy of NaHCO3 61. a KMnO4 + b H2SO4 + c FeSO4  K2SO4 + MnSO4 + Fe2(SO4)3 + H2O. In Fischer-Ringe’s method of separation of noble gas mixture from air. Basicity of H3BO3 is 1) 1 2) 2 3) 3 4) 0 64.6 3) 79 4) 158 55.786 2) 4 3) 0. 2H2O 62. 10. 10 3) 2. 8. 8 4) 2. In the hardening stage of plaster of parts. The equivalent weight of Bayer’s reagent is 1) 31. When 20 ml of methane and 20 ml of oxygen are exploded together and the reaction mixture is cooled to laboratory temperature. The hybridisation of boron in borax 1) Two borons in sp2 and two borons in sp3 2) One boron in sp3 and three borons in sp3 3) Three borons in sp2 and one boron in sp3 4) All are in sp3 hybridisation 63. 2H2O 3) CaSO4 . HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 54. 10 2) 1. the compound formed is 1) CaSO4 2) Orthorhombic CaSO4 . NaOH is 1)1 : 2 2) 2 : 1 3) 2 : 3 4) 1 : 1 60. In this unbalanced stoichiometric equation the values of a. 4. H2O 4) Monoclinic CaSO4 . ____ is used 1) 90 % CaC2 + 10 % CaCl2 2) Coconut charcoal 3) Soda lime + Potash solution 4) 90 % CaCO3 + 10% urea UDAY . b and c respectively are 1) 2. The normality of 2. 8.6 2) 52. The ratio of volumes of H2 liberated when equal amounts of aluminium reacts with dil.24 vol H2O2 is 1) 1. 16 57. SiO2 does not react with 1) HF 2) H2SO4 3) Na2CO3(fused) 4) NaOH Identify B in the following reaction H2SiO4  A   B + CO 1000ºC Carbon 65.

methyl – 4 – pentane 1 .ene 4) 4 –ethyl -3. 1] octane 2) Bicyclo [2. Zn-Cu. The IUPAC name of 1) 2-ethyl – 3 –methyl – 1-pentene 4–yne 2) 2 – ethyl – 3. The chemical and the reaction conditions required for the preparation of ethane are 1) C2H5I.diol UDAY . 3] octane 4) Bicyclo [1.yne 71. H2O 3) KOOC-CH = CH – COOK. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 67. The compound is known by which of the following names 1) Bicyclo [2.methyl – 4 – pentyn 1 – ene 3) 4–ethyl–3–methyl–1– pentane–4 . C2H5OH 2) CH3Cl. What is the atomic number of noble gas that reacts with F2 1) 10 2) 2 3) 18 4) 54 68. Na. NaOH. Among the following which has Z. Deactivated filters in activated carbon method for deflouridation can be activated by 1) Defluoran – 1 & defluoran – 2 2) Lime. Bayer’s reagent oxidises ethylene to 1) Ethylene chlorohydrin 2) Ethyl alcohol 3) CO2 and H2O 4) Ethane – 1.NaCl & 5 % H2SO4 solution 70. 2. CaO. electrolysis 4) CH3CO2Na. 2 .  75. Smog is mainly due to 1) Oxides of sulphur & Carbon particles 2) Oxides of Pb 3) Oxides of carbon 4) Oxides of Chlorine 69. bleaching powder & alum 3) 4 % NaOH & 1 % H3PO4 4) 4 % . 1. 2.configuration 1) 2) 3) 4) 73. 2] octane 3) Bicyclo [1. 2. Which of the following is the least stable carbonium ion ?   +  CF3 CCl3 CH(NO2)3 CH3 1) 2) 3) 4) 74. 1] octane 72.

tetrahedral UDAY . C2H6 3) C2H6. II 2) I. C2H2Cl4 2) C6H6. then that alkene is 1) CH3 – C  C – CH3 2) CH3 – CH = CH – CH3 3) CH3 – CH = CH2 4) CH3 –C  CH 77. C6H6Cl6 3) C6H6.6.KOH B  H2 /Ni 200ºC C. F II. CH4 79. III. a) Chlorobenzene b) Nitrobenzene c) Benzene d) Phenol e) Toluene 1) d > e > c> a > b 2) b > a > c > e > d 3) d > e > c > b > a 4) e > d > c> a > b CaC2 + 2H2O  X. C H OH 2 5 1) CH4. HCl 84. Which method is regarded as internal wurtz reaction 1) Freunds method 2) Wislicenus method 3) Dieckmann method 4) Ziegler method 80.63 x 10-29 85.63 x 10-21 4) 6. C2H4 4) C2H6. II. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 76. III 86. sp3. square planar 4) CH4. Identify the correct order in which the ionic radius of the following ions increases - I. dsp2. CH3 – CH2Cl   Y. C6H6Cl2 82. linear 3) HN4+. respectively are 1) CH3 – CH(CN)2 & CH3 – CH(OCOCH3)2 2) CH3-CH(CN)2 & CH2 = CH(OCOCH3) 3) CH2 = CHCN & CH3-CH(OCOCH3)2 4) CH2 = CHCN & CH2 = CH(OCCOH3) Cl 81. The product of ozonolysis of an alkene are ethanal and methanol. C6H5Cl 4) C6H6. angular 2) H2O. x 10-7 2) 6. C2H4 2) C2H4. N3- 1) III. The final products formed when acetylene reacts with HCN & CH3COOH separately. Here A and B are Alc. Na + III. The de Broglie wavelength associated with a particle of mass 10-6 kg moving with a velocity of 10 ms-1 is (in meters) 1) 6.KOH Zn-Cu 78.63 x 10-6 3) 6. sp2. III 3) II. X   Y In this reaction the reagent ‘z’ is alcKOH Z 83. Here ‘C’ is 1) C2H6 2) C2H5Cl 3) C2H4 4) C4H10 B  C2H5Cl   A . CH  CH  Redhot tube  A  2/light  B A and B are 1) C6H6. I. Which one of the following is a correct set ? 1) H2O. 1) Ni / H2 2) LiAlH4 3) Pd + BaSO4 4) (Zn – Hg) + conc. C2H6  1MoleCl2 sunlight  A  Alc. I . dsp2. Arrange the following compounds in the descending order of their reactivity towards electrophilic substitution. I 4) II.

3 nm 4) 454.8 nm 2) 91. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 87 An open vessel at 27ºC is heated until three-fourths mass of the air in it has been expelled. 2 3) 12. 4 47. then ‘X’ is Br CH 2 CH 2 CH3 CH3  CH  CH 3 CH 2  CH 3 1) 2) 3) 4) 49. X on oxidation followed by hydrolysis gives phenol and acetone . 2 4) 8. Shortest wavelength in Lyman series of hydrogen spectrum is 1) 364. 2 2) 14. H3PO4  on gentle heating   strong heating  Y . Where ‘X’ would be 1) Na2CO3 2) Ca(OH)2 3) NaHCO3 4) NaOH 50. 250 C 51.2 nm 3) 656. Neglecting the expansion of the vessel. Number of electron with +1/2 spin in n = 3 is 1) 18 2) 9 3) 3 4) 1 90. An oxide precipitate is formed when NaOH reacts with the aqueous solution of 1) FeCl3 2) Zn(OH) 3) FeSO4 4) AgNO3 89. A mixture of Na2CO3 and NaHCO3 having a total weight of 100 gm on having produced 11. Diborane does not liberate H2 gas with 1) KOH 2) H2O 3) HC / A C 3 4) C 2 .8 % 2) 44. Which of the following exhibits colour due to d-d transition? 1) K2Cr2O7 2) MnSO4 3) KMnO4 4) Na 2CrO4 UDAY . . The number of sigma and  -bonds in ‘X’ respectively 1) 8. The percentage of Na2CO3 in the mixture is 1) 55.2 % 3) 84 % 4) 16 % AIPMT-4 46.2 lit of CO2 under STP conditions.8 nm  CH 3 CH 2 CH 2 Br  anhydrous   A Br3  X (major) 48. the temperature to which the vessel has been heated is 1) 927ºC 2) 108ºC 3) 1000ºC 4) 477ºC 88. When excess CO2 gas is passed through an aqueous solution of ‘X’ a clear solution is formed.

1MA C 3 4) 0. 2 3) 5. 6 55. 2 1) -960 2) +852 3) -852 4) 960 62. Purest form of iron is 1) steel 2) pig iron 3) wrought iron 4) cast iron -5 59. IUPAC name of positional isomer of ‘X’ is  major 1) Isopropyl bromide 2) n. Which of the following is not directly subjected to nitration.1M NaC 3) 0. The ionisation constant of 0. CH3  CH  CH2  HBr  R 2O2  X .propyl bromide 3) 1-Bromo propane 4) 2 – Bromopropane 53. 3 2) 3. 1) 2. In a reaction H 2g  O2g  H 2O   H 0  286KJ . NH 2 C OCH3 1) 2) 3) 4) UDAY . HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 52.1MK4 Fe  CN 6  54. The formula of an ionic compound is AB. The best coagulant for As2S3 sol is 1) K 4 Fe  CN 6  2) FeC 3 3) ZnSO4 4) PtC 4 58. 6 4) 2. Biodegrable polyester co-polymer among the following is 1) PHBV 2) polyglycolic acid 3) polylactic acid 4) Nylon -6 0 56. The disaccharide which can’t reduce Tollen’s reagent is 1) Sucrose 2) Maltose 3) Lactose 4) Starch 63. The main green house gas among the following is 1) NO2 2) CO2 3) SO2 4) O3 1 61. Ssurr 0 of the process is ------. The number of valence electrons in A and B respectively. Among the following which solution has lowest freezing point? 1) 0.1 M CH3COOH at 250 C is 10 . Existence of benzene in liquid state at 25 can be explained by 1) Ion-dipole forces 2) dipole-dipole forces 3) dipole-induced dipole forces 4) Dispersion forces 57. Paramagnetic species among the following is 1) S8 2) S6 3) O2 4) O3 64.J/K. [ H  ] of the solution is 1) 10-1M 2) 10-2M 3) 10-3M 4) 10-4M 60.1 M urea 2) 0.

Among the following which is more reactive towards nucleophilic substitution by unimolecular mechanism ? Br Br Br 1) 2) Br 3) 4) 76. Fluorine is the strongest oxidant among halogens because. The time required for it’s concentration to be reduced from 1M to 0.75 69. SiF4  H2O  X  Y . XeF4 2) XeO2F2 .1 M HCl 4) 0. In the decomposition reaction of ammonia on gold surface the concentration of NH3 decrease from 1M to 0. the molecular formula of the compound is 1) C6H12O6 2) C3H6O3 3) C12H22O11 4)  C6 H10O5 n 74. III 3) II. H2O2 atcs as an acid in it’s reaction with 1) PbS 2) NaOH 3) KMnO4/H+ 4) Ag2O 73.5 3) 1. The covalency and oxidation state of silicon in ‘Y’ respectively.XeO4 4) XeO2 F2 . Among the following which has highest specific conductance at a given temperature ? 1) 0. XeF4 70. 6 4) 6. The compounds of xenon formed in third excited state of xenon are 1) XeO3 . 1) 6. Among the following which alcohols can respond to Haloform test ? OH O CH3  CH  CH3 CH 3  C  CH 3 I) CH3CH2OH II) CH3CHO III) IV) 1) I. Hight ‘T’ 2) High ‘P’. The P-O bond order in orthophosphate ion is 1) 4 2) 1.minutes. +4 2) 4. UDAY . low ‘P’ 4) Low ‘P’ low ‘T’ 71.5 M in 20minutes. If it’s vapour density is 90. +2 67. II 2) I. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 65. +4 3) +4.25 4) 1. SiC 4  H2O  X  Z . III 4) III.1 M CH3COOH 2) 0.1M NH4OH 3) 0. low ‘T’ 3) Hihgt ‘T’. When proton and   particles have same velocity their de-Broglie wavelength ratio is 1) 1 : 2 2) 1 : 4 3) 4 : 1 4) 2: 1 75. 1) 20 2) 40 3) 200 4) 35 68. XeOF4 3) XeO3 .1 M H2SO4 72.125 M in ----------. The empirical formula of a compound is CH2O. IV 66. For the formation of gaseous hydrogen molecule from gaseous H-atoms (assuming the reaction is reversible) the favourable conditions are 1)High ‘P’.

The dipolemoment of chlorobenzene is same as that of C C C C C C 1) 2) C 3) C 4) 85. The drug used in the prevention of Heart-attacks is 1) Ibuprofen 2) Aspirin 3) Paracetmol 4)Phenacetin 78. -894. Number of optically active isomers possible for 2. The best fuel among the following is 1) C(Graphite) 2) CH4 3) H2 4) C2H4 80. The number of H+ ions required to balance the half reaction MnO4  Mn 2 are UDAY . In which of the following process more energy is emitted ?     1) C  g C  g 2) F g   F(g) 3) Br(g)  Br(g) 4) I(g)  I(g) 79 The enthalpy of combustions of C(graphite) . Dalton’s law of partial pressures is not applicable for a mixture of 1) NH3  HCl 2) H2  N2 3) CO2  O2 4) N2  O2 86. CoC 3 . xNH3 exhibits cis – trans isomerism. H2 and C2H4 are -394. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 1) It is highest electronegative element 2) It has highest electron affinity - 3) F has low hydration energy and F2 has more bond dissociation energy. CH4.dihydroxy butanedioic acid are 1) 4 2) 3 3) 2 4) 6 ka 83. -286 and -1430 KJ/mol respectively. The alcohol which is more readily dehydrated is CH3  CH  CH 2  OH 1)  CH3 2 CH  OH 4)  CH3 3 C  OH CH3 2) CH3CH2OH 3) 81. 77. The fraction of chloride ions satisfying both primary and secondary valencies of cobalt in the complex is 1 2 1 3 1) 2) 3) 4) 3 3 2 4 82. Which of the following has highest p ? OH COOH CH2-COOH 1) 2) CH3COOH 3) 4) 84. 4) F2 has low bond dissociation energy and F– has more hydration energy. 3.

HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 1) 5 2) 8 3) 6 4) 4 87. The liquid can be purified by 1) Steam distillation 2) Vaccume distillation 3) Fractional distillation 4) Simple distillation 88. The hormone which is responsible for maintaining constant sugar levels in blood is 1) Insulin 2) Thyroxine 3) Testosterone 4) Estradiol 90. Which of the following is an example of primary cell? 1) Lead accumulator 2) Leclanche cell 3) Edison battery 4) Acid-storage battery 89. CH3 3 C  Br  NaOC2H5  X  Major The product ‘X’ is CH3  C  CH 2 1) | 2)  CH3 3 C  O  C2H5 3)  CH3 3 C  OH 4)  CH3 3 C  ONa CH3 CHEMISTRY 1) 2 2) 2 3) 2 4) 3 5) 4 6) 3 7) 1 8) 3 9) 2 10) 3 11) 1 12) 3 13) 3 14) 4 15) 3 16) 4 17) 1 18) 1 19) 2 20) 1 21) 1 22) 4 23) 1 24) 3 25) 1 26) 2 27) 2 28) 3 29) 1 30) 4 31) 3 32) 1 33) 3 34) 1 35) 3 36) 2 37) 1 38) 3 39) 4 40) 4 41) 1 42) 1 43) 4 44) 2 45) 4 AIPMT-5 UDAY . An organic liquid on heating decomposes before reaching it’s boiling point.

The equilibrium constant for the decomposition of N2O4( g ) 2 NO2( g ) given by [   degree of dissociations.But it is spontaneous process Reason (R): S  ve and H  T S 1) A & R true. P = Equilibrium pressure]  2P 4 2 P P 1 1) 2) 3) 4) P 1 2 1 2 1  1  124. For this system rate of reaction with passage of time  450 1 log t 2 log a 1) Increases 2) Decreases 3) Remains constant 4) First increase and then decreases 127. The enthalpy of neutralisation of strongacid with strong base is 57.The enthalpy of formation of water is 285. Graph between log and log P is straight line at an angle of 450 with intercept of 0. Assertion (A): Dissolutions of salt ‘X’ in water is Endothermic .Then formula of oxide will be 1) X 2YO4 2) X 5Y4O10 3) X 4Y5O10 4) XY2O4 x x 122.8 1010  1) 104 M Ag   104 M Cl  2) 106 MAg   105 M Cl  3) 106 M Ag   106 M Cl  4) 1010 M Ag   1010 M Cl  126. When equal volumes of the following solutions are mixed. ‘ H ’ is 1) + Ve 2) –Ve 3) Zero 4) May be the +Ve (or) –Ve 125.32KJ / mole . Equilibrium constant Kp increases with increase in temperature. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 121. Consider the following statements.26KJ / mole 4) 114. ppt of AgCl will occur only with  Ksp  1. m m value at a pressure of 1 atm is 1) 2 2) 6 3) 4 4) 8 123. and R is not the correct explanation to A UDAY .2KJ / mole 129. and identify the correct statements 1) Order of reaction can never be zero 2) Rate of reaction always decreases with time for non zero order reactions 3) Activation energy of a reaction depends on temperature 4) Rate of reaction always increases with rise of temperature whether reaction is exothermic or endothermic 1) Only 2 and 4 2) Only 3 and 4 3) Only 1 and 3 4) All are correct 128. While one half of the octahedral voids are occupied by ‘Y’ ions.6020.84KJ . In a cubic packed structure of mixed oxides the lattice is made up of oxide ions one fifth of tetrahedral voids are occupied by ‘X’ ions.52KJ / mole 2) 228.Then enthalpy of formation of hydroxyl ion is 1) 228.52KJ / mole 3) 114.

5MH2 SO4 are mixed so as to release maximum amount of energy and form 100ml solution 1) 42.ol 2) Butan 2-ol 3) propan -1-ol 4) Ethanol 134. of benzene lowered the freezing point of benzene by 0.40 131. SP3d 4) ‘T’ shape. Compound of sulphur acting as both lewisacid and lewisbase is 1) SF6 2) SCl4 3) SO2 4) both 2 and 3 139.12K. kg / mole] 1) 25. Oxy-acid of sulphur in which sulphur atom exhibits ‘+4’ oxidation state 1) Sulphurous acid 2) Sulphuric acid 3) Marshall’s acid 4) Caro’s Acid 140. The alcohol with highest boiling point 1) Butan 1.4 144. 1g. Composition of flux produced in the extraction of copper is 1) CaSiO3 2) MgSiO3 3) FeSiO3 4) MnSiO3 142. Strongest oxidizing agent is 1) HClO4 2) HClO2 3) HClO 4) HClO3 138.4K. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 2) A & R true. Number of moles of PCl3 required to react with three moles of Ethanol is 1) 1/3 2) 1 3) 0. SP3 3) Pyramidal. Vant Hoff factor (i) for tetramerisation of substance ‘A’ assuming 80% association is 1) 0. How many compounds among the following can give positive test with NaOH/I2 1) Acetophenone 2) 3-Pentanone 3) Propanal 4) 2-Butanone 5) 2-propanol 1) 5 2) 3 3) 4 4) 2 132.6 4) 1. What is molecular weight of solute? [ Kf of Benzene is 5. Insulin is a UDAY . 50 4) 60. In what proportion 1M NaOH and 0. Conversion of Benzene into chloro benzene in presence ‘Fe/dark’ is 1) Nucleophilic substitution 2) Electrophilic substitution 3) Nucleophilic Addition 4) Free-radical substitution 135. of non – electrolyte solute is dissolved in 50g.33 3) 50.6 2) 2560 3) 256 4) 128 143. Electrophile involved in Reimer – Tiemann reaction is OH ONa CHCl2 CHO   1) C Cl2 2) C HCl2 3) 4) 133. SP2 2) Pyramidal.4 2) 0. Shape and hybridization of ClF3 1) Triangular.5 3) 1. and R is the correct explanation to A 3) A is true but R is false 4) A is false but R is true 130. Element in 4d series exhibiting highest oxidation state 1) Os 2) Mn 3) Rh 4) Ru 141.5 4) 3 136. SP3d 137.58 2) 67.

and R is not the correct explanation to A 2) A & R true. Which of the following is not an antacid 1) Omeprazole 2) Lansoprazole 3) Ranitidine 4) Phenalzine 155. Which of the following on heating produces a coloured paramagnetic gas and a colourless paramagnetic gas 1) NH4 NO3 2) Pb( NO3 )2 3) NH4 NO2 4) NaNO2 157. amino acid derivative 145. Which of the following is not formed when ethanal and propanal are heated in presence of dilute alkali 1) 2-pentenal 2) 2-butenal 3) 2-hexenal 4) 2-methyl-2-butenal 152. Equivalent weight nitrobenzene is least when it undergoes reduction in……. Highest P Ka is for 1) A 2) B 3) C 4) D 151. Fe(CO) X obeys EAN rule.medium 1) Strong alkaline 2) Acidic 3) Weak alkaline 4) Neutral 153. Value of ‘X’ is 1) 5 2) 10 3) 6 4) 4 159. Conductance ratio of a 0.. Which of the following is an example of homogeneous catalysis 1) Haber’s process 2) Ostwald’s process 3) Lead chamber process 4) Contact process 149. The weight of substance obtained at cathode is ……grams 1) 1 2) 23 3) 2 4) 46 147. amino acid hormone 4) Steroid. 1F of electricity is passed through aqueous NaCl solution. Which of the following is not a branched polmer 1) Glycogen 2) Amylose 3) Amylopectin 4) All of these 158. peptide hormone 2) Non – steroid. Which of the following is water insoluble 1) C6 H 5 N2Cl  2) C6 H 5 N2 HSO4 3) C6 H 5 N 2 Br  4) C6 H 5 N 2 BF4 150. Assertion (A) : Nitrogen is chemically inert Reason (R) : Nitrogen has abnormally high ionization potential 1) A & R true. ……% of thorium orthophosphate is present in monazite sand 1) 60 2) 50 3) 10 4) 30 160. During electrochemical corrosion the metal undergoing corrosion acts like 1) Cathode 2) Anode 3) Cathode (or) Anode 4) Neither cathode nor anode 148. The reducing agent used in Belgian process is 1) Hydrogen 2) Coke 3) Water gas 4) Sodium 121) 3 122) 3 123) 2 124) 1 125) 1 126) 3 127) 1 128) 2 129) 1 130) 3 UDAY 131) 2 132) 1 133) 1 134) 2 135) 2 136) 4 137) 3 138) 4 139) 1 140) 4 141) 3 142) 3 143) 1 144) 2 145) 2 146) 1 147) 2 148) 3 149) 4 150) 1 151) 3 152) 2 153) 3 154) 4 155) 1 156) 2 157) 2 158) 1 159) 4 160) 2 . Ozonolysis product of natural rubber is 1) Pentanal 2) 2-oxobutanal 3) 4-oxopentanal 4) 3-oxopentanal 154.1 pH of the weak acid 1) 1 2) 2 3) 3 4) 4 146. HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS 1) Steroid. peptide hormone 3) Non – Steroid.1M weak monobasic acid is 0. and R is the correct explanation to A 3) A is true but R is false 4) A is false but R is true 156. CH 3COOH ( A)  Cl2 Re d P  B  Cl2 Re d P  C  Cl2 Re d P  D .

HYDERABAD INSTITUTE OF EXCELLENCE CHEMISTRY PRACTICE PAPERS UDAY .