-2 Second Thermodynamics

Exergy balance in the general equation for transient expressed [22, 23]

where in

Exergy transfer is indicated by heat at Ti

Exergy transfer is indicated by the input and output of the system.

By rewriting the equation (11) according to entropy production, Exergy destruction is calculated

The last equation in various stages of adsorption refrigeration cycle and it is applicable for all the
components and processes. It should be noted that in this study, the condenser and evaporator
independent of exergy destruction and computing focused on the adsorbent bed and its components.
Also, due to the very small difference between the temperature of the thermal fluid inlet and outlet
pipes, the fluid in the heat source is constant.


-2-2-2-1. Exergy balance in various stages of refrigeration cycle adsorption bed
- Heating step constant mass (1-2)
At this stage, due to the closure of valves and inlet to the condenser and evaporator Exergy input
and output of the substrate is zero and also due to changes small amount of fluid absorbed (w wmax)
the calculated heat absorption and entropy production corresponding to it be taken. the relationship
(14) simplify to

where in
It is noteworthy that in the heating step followed by a revival of constant mass and constant
pressure high-temperature heat source in contact with the substrate, and thus TH = Tin-heating; The
ambient temperature of the thermal fluid temperature in the cooling condenser (T0 = Tin-
cooling) [24].
Constant pressure recovery step (2-3)

At this stage inlet valve to condenser open and fluid absorption in the


At this stage, the inlet valve to condenser open and the liquid is adsorbed into the adsorbent
material was extensively restored and the heat adsorbed from the adsorbent vapor exits into
the condenser
Equation (14) in the recovery step constant pressure to be written as:

where in

Constant pressure adsorption step (4-1)

At this stage evaporator inlet valve to open and release steam into the evaporator with a
specific heat (heat absorption) is absorbed in the absorbent material. But because of the
pressure gradient along the substrate uptake rate of the working fluid vapor from the
evaporator is not identical with the arrival rate. Eq. (14) According to the description of the
relationship (24) in the absorption constant pressure to be written as:
S4 1 U4 1 i
23) ( 21) (22) (

hg sg .
h0 s 0