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IIT/ELITE 2011
PET I/PET IV/CMP/P(II)/SOLNS
BRILLIANTS
NATIONAL SIT-DOWN
PROGRESSIVE EVALUATION TEST
FOR STUDENTS OF
OUR ONE/TWO-YEAR POSTAL COURSE
TOWARDS
IIT-JOINT ENTRANCE EXAMINATION, 2011
PAPER II SOLUTIONS
CHEMISTRY MATHEMATICS PHYSICS
PART A: CHEMISTRY
SECTION I
1. (A) When ionic product exceeds the solubility product, precipitation occurs.
4 + 4
Concentration of ions after mixing are 0.5 10 M [Ag ] and 0.5 10 M [Cl ]
4 ) (0.5 10 4) = 0.25 10 8
ions. Hence ionic product of AgCl is (0.5 10
= 2.5 10
9
which is greater than 1 10
10
(K ). Hence AgCl will
sp
precipitate from solution. In other cases ionic product of AgCl is less than K
sp
of AgCl.
2. (C) For acetic acid dissociation,
+
CH3 COOH
CH3COO + H
C(1 ) C C
[CH COOH] = [1 ] C
3
+
[H ] = [ C + 0.01]
Brilliant Tutorials Pvt. Ltd. IIT/ELITE/PET/CMP/P(II)/Solns
35
[CH COO ] = C
3
[C] [ C + 0.01]
K=
[(1 ) C]
Assuming (1 ) = 1 and
2
C + 0.01 = K
5
1.69 10 = 0.01 (approximately)
1.69 10 5
= = 1.69 10 3 = 0.169 102
0.01
3
(The assumption is accepted since the value of is 1.69 10 a very small
value).
3. (A) Since basic strengths of the hydroxides of alkali metals increases from LiOH
to CsOH, CsOH forms the most stable carbonate salt. Hence the stability
order of their carbonates is
Cs CO > K CO > Na CO > Li CO
2 3 2 3 2 3 2 3
4. (C) As the size of cation increases, the heat of hydration decreases while the
lattice energy remains almost the same. Hence solubility order is
BeSO > MgSO > CaSO > BaSO
4 4 4 4
H
5. (A) CH3 CH2 C CH3
CH3
CH3
CH3
CH3
CH3
CH Cl NO2
3
II III I IV
SECTION II
Cl
CH3 CH3
Cl
H
CH2 = CH CH2 CH3 CH3 C = C CH3 CH3 C = C CH3
H H H
CH3 H
10. (9) In C=C , number of hydrogen atoms involved in
CH3 CH3
hyperconjugation is nine.
11. (3) Hydrogen atom present in COOH group, C C H group and phenolic
OH group are acidic and can be replaced by reaction with sodium metal.
SECTION III
13. (C) is the most stable carbanion as it has stability due to aromaticity.
A + 2B 2C
15. (B) 2 3 2
Initial conc. mol / litre
2 2 2
2.5 3 + 1 1
At Equilibrium conc. 2
2 2
mol L 1
[C]2 1 1 2 2 2
K= 2
=
[A][B] 2 2 2.5 4 4
2 1
= = = 0.05
10 4 20
D 1 = d(1 + )
D d 104.16 62 42.16
= = =
d 62 62
421.6 1 6.8
= = = 0.68
62 10 10
SECTION IV
18. (A) (p), (r); (B) (p), (t); (C) (q); (D) (p), (s)
19. (A) (q), (r), (s); (B) (q), (t); (C) (p), (q), (r), (s); (D) (p)
In isothermal process, G 0, H = 0, E = 0, T = 0
In adiabatic process, G 0, H = 0, E 0, T 0
In cyclic process, G = 0, H = 0, E = 0, T = 0
PART B: MATHEMATICS
SECTION I
5
20. (C) tan (tan 1) < 0 0 < tan < 1 0, , =A (1)
4 4
1 1 1
|sin | < 0 < sin < when sin is positive and sin > when sin is
2 2 2
negative
5 7 11
0, , , , 2 = B (2)
6 6 6 6
7
A B = 0, ,
6 6
(
21. (D) cos 1 x 3 + cos 1 x =) 2
x must be positive.
cos 1 x 3 =( ) 2
cos 1 x = sin 1 x = cos 1 1 x 2
1
x 3 = 1 x2 4x2 = 1 x = only.
2
2
22. (D) x 2x (a + b) + 3ab = 0
Sum of the roots = 0 a + b = 0
1 1 1
23. (A) log 3 (x + 1) log 3 (1 x) = log3 (2x + 3)
2 2 2
x +1 5 1 1 5
= 2x + 3 x2 + x 1 = 0 x = or (1)
1x 2 2
200 2 40
k= =
30 29 87
SECTION II
a 2 + b2 + c 2 ab ab 1 0 0
26. (1) AA = I ab a 2 ab = 0 1 0
ab ab a 2 0 0 1
2 2 2
a + b + c = 1 and ab + bc + ca = 0
2
(a + b + c) = 1 + 2 0 = 1 |a + b + c| = 1
27. (9) Equation of the common chord is 6x 6y (C + 15) = 0
If this is the longest common chord, this should be diameter of the smaller
circle.
If it is a diameter of C , then (0, 4) should satisfy its equation.
1
k
Since m1 m 2 = a, m3 = . Now (2 h) = a + m 3 (m1 + m 2 )
a
kk
This 2 h = a +
a a
2 3 2 2
Hence locus of (h, k) = y = a 2a + a x
2 2
Since this is part of y = 4x, a = 4 or a = 2
a a a
29. (6) QX = ; OX = tan 30 =
2 2 2 3
a
OX = OA =
2 3
2
Area of square ABCD = AB
2 a2 a2
= OA 2 + OB2 = =
12 6
a2 a2
Given = ,k=6
6 k
a
2
SECTION III
2
31. (A) y = x + 4
V = ( 4, 0)
This meets the line y = 1 at
2
C( 3, 1) and this satisfies x = ky
2
3 = k (1)
k=3
Hence for parabola P , k = 3 and its
2
2
equation is x = 3y
1 1
Slope of the tangent at ( 3, 1) to P is =
2 6(1) 6
1
32. (B) Equation of tangent line L is y 1 = (x + 3)
1 6
(i.e.,) x + 6y 3 = 0
2
This meets parabola I, x = y 4 at Q
2 2
y 4 = 3 6y or y + 6y 7 = 0
y = + 1 or 7
y-coordinate of Q = 7
x-coordinate of Q = 45.
m1 m 2 10
tan = where m1 = =1
1 + m1 m 2 3+4
70 1
m2 = =
45 + 4 7
1
1+
= 7 =4
1 3
1
7
2 n 2 n n+1 2n
34. (B) (1 + x + x ) a + a x + a x + . + a x + a x ++a x I
0 1 2 n n+1 2n
1 2n
Replace x by and multiply x
x
n
1 1
x2n 1 + + = a 0 x2n + a1 x2n 1 + ... + a n x n + ... + a 2n II
x 2
x
Comparison gives a = a , a = a ,
0 2n 1 2n 1
Putting x = 1, in I
n
3 = a + a + . + a +a +a +a + . + a
0 1 n1 n n+1 n+2 2n
= 2 (a + a + . + a )+a
0 1 n 1 n
3n a n
a 0 + a1 + a 2 + .... + a n 1 =
2
2
35. (B) Put x = 1, , in I and add (where is a complex cube root of 1)
n
3 = 3 [a + a + a + a + ..]
0 3 6 9
n 1
a +a +a +=3
0 3 6
2 n 2 2n
36. (D) (1 + x + x ) a + a x + a x + . + a x I
0 1 2 2n
1
Replace x by
x
n
1 1 a1 a 2 1
1 + 2 a0 +
2
..... + a 2n . II
x x x x x2n
2n
Multiply II by x
2 n 2n 2n 1 2n 2
(1 x + x ) a x a x +a x . + a III
0 1 2 2n
2n
Multiplying I and III and comparing coefficient of x ,
2n 2 2 2 2 2
Coefficient of x on RHS = a0 a1 + a 2 a 3 + ...... + a 2n
2n 2n 2 2 n
Coefficient of x on LHS = Coefficient of x in {(1 + x + x) (1 + x x)}
2n 2 4 n
= Coefficient of x in (1 + x + x ) = a by comparing it with I.
n
SECTION IV
37. (A) (s); (B) (q); (C) (p); (D) (r)
( )
(A) (z 6i) z + 6i + (z 2) z 2 = 25 ( )
2 z z + 2(z) (3i 1) + 2z ( 1 3i) + 15 = 0
15
z z + z ( 1 + 3i) + z ( 1 3i) + =0 centre (1 + 3i)
2
( )
(B) (z 1) z 1 4 z + 1 (z + 1) = 0 ( )
5 5
3 z z + 5z + 5z + 3 = 0 or z z + z + z +1=0
3 3
5 5
Centre is or + i0
3 3
(C) 1 i
(D) The line segment joining 6 8i and 10 + 4i is a diameter of the circle.
Hence the centre is 8 2i.
2
(A) (x + 4) = 25 x = 1 or 9, Both are not valid. Number of solutions is zero.
( )
(B) 2y 2 + 2 1 2 y 2 2 = 0 where y = log x
2
( y 2 ) ( y + 1) = 0 log 2 x = 2 or 1
1
Hence x = 2 2 or . Number of rational solutions is one.
2
log3 3 log 3 x
(C) + (log3 x)2 = 1
log 3 3 + log3 x
1y
= 1 y2
(1 y) 1 (1 + y)2 { }
= 0 where y = log x
1+y 1+y 3
1
(1 y) y (y + 2) = 0 y = 0, 1, 2 x = 1, 3,
9
Number of solutions = 3.
3 2 3
(D) + + =0 where y = log x
y 1+y 2+y 4
2
4y + 8y + 3 = 0
1 3
(2y + 1) (2y + 3) = 0 y = or y =
2 2
1 3
log 4 x = or
2 2
1 1
x = or
2 8
PART C: PHYSICS
SECTION I
ML2 T 2
39. (B) [P] = = ML 1 T 2
3
L
1
[C] = LT
ML2 T 2
[Q] = = MT 3
L2 T
1 2 x 3 y 1 z 0 0 0
Given: (ML T ) (MT ) (LT ) =M L T
x+y=0
x+z=0
2x 3y z = 0
Choice (A) gives x + y = 2 which is not acceptable. Choice (B) satisfies all the
three equations, hence it is the right choice.
1
40. (B) We have r =r +v t+ a rel t2
rel 0 rel 0 rel 2
In our case, r = 0, because both the bodies are at the same point.
0 rel
2 2 2
v0 rel = v0 + v0 2 v0 cos 0
2
2
v0 rel = 2 v0 (1 sin 0 )
a =gg=0
rel
rrel = v0 rel t
2
= 2 v0 (1 sin 0 ) t
= 2 82 (1 sin 30) 2
= 8 2 = 16 m
Aliter
1
At t = 2s, P1 0, v0 t gt2
2
1
P2 v0 cos 0 t, v0 sin 0 t gt2
2
1
2 2
s = v0 cos2 0 t2 + v0 t 2 (1 sin 0 )2 2
1
3 1 2
= v0 t + = 8 2 = 16 m
4 4
d
41. (C) Given that = k , where k is a constant of proportionality.
dt
d
+k= 0
dt
d t
+ k dt = 0
0 0
i.e., ln + kt = 0
0
i.e., = e kt
0
In the 1st second = 90%
0
In the 2nd second it will become 90% of what is available at the end of first
90 90
second. Therefore angular velocity at the end of 2nd second is = 81%
100
2
42. (B) y = (cos 2t 2 cos t + 2 sin t + 1) sin 500 t
1 + cos 2t
=2 cos t + sin 2 t sin 500 t
2
2 2
= 2 (cos t + sin t cos t) sin 500 t
= 2 (1 cos t) sin 500 t
= 2 sin 500 t 2 sin 500 t cos t
= 2 sin 500 t {sin 501 t + sin 499 t}
= 2 sin 500 t sin 501 t sin 499 t
Hence there are three waves. The maximum number of beats that can be
heard in ten seconds is
501 499
10 = (79.73 79.41) 10
2 2
= 0.32 10
= 3.2
43. (A) We have
dQ d
= KA
dt dx
d
= K 4 r2
dr
dQ
But = P, thermal power
dt
d
P = 4Kr 2
dr
dr 4K
i.e., 2
= d
r P
Integrating
r2 T2
dr 4 K
r2
=
P d
r1 T1
r
1 2 4 K
r = P (T2 T1 )
r1
1 1 4 K
i.e., = (T1 T2 )
r1 r2 P
P 1
, numerically
r1 r2 =
4 K (T1 T2 )
(r r )
1 2
T1 T2
Since 1 (given)
r1 r2
P
Product of the radii r1 r2
4 K
2r
44. (D) Time period T = = 0.63 s (given) (1)
v
Angular momentum = (mv) r
= 3vr
3 2 1
= 3 10 kgm s (2)
(1) 0.63 2 r /v 2
gives = =
(2) 3 103 3vr 3v 2
2 103
v2 = = 10 103
0.63
v = 100 m/s
3 103
From (2), r = = 10 m
3 100
mv 2 3 100 100
Centripetal force F(r) = =
r 10
= 3000 N
dU
But F(r) = ( central force is a conservative force)
dr
10
U = F(r) dr
0
10
= 3000 ( r )
0
3
= 30 10 J
The minus sign shows that the force is attractive.
SECTION II
dm
45. (9) Thrust force on the rocket, F = v rel
dt
= 15 1000 25 N
Mass of rocket at t = 3.5 min after blasting starts is
m=m 25 3.5 60
i
F
m=m 5250, where m is initial mass acceleration a = = 100
i i m
F
i.e., = 100
m i 5250
15 1000 25 = 100 m 5250 100
i
m = 15 10 25 + 5250
i
= 9000 kg
3
In powers of 10 kg, m = 9
i
46. (5) Volume of water flowing out per second = (0.05)2 x
4
Mass of water flowing out per second = (0.05)2 x 1000 kg /s
4
Momentum of water flowing out per second = (0.05)2 1000 x 2
4
Time rate of change of linear momentum in the x-direction is force F.
F = (0.05)2 1000 x2 cos 45
4
= (0.05)2 1000 x 2
4 2
F
The compression in the spring = = 1.74 10 2 (given)
k
(0.05)2 1000 x 2
2
= 1.74 10 2
4 2 20 10
1.74 10 2 4 2 20 102
x2 =
(0.05)2 1000
1.74 10 2 4 2 20 102
=
2.5
x = 5 m/s
In units of m/s, x = 5
47. (1) The frequency f in the nth mode of vibration of a closed organ pipe is given by
c
(2n 1) v
fc = , where n = 1, 2, 3
4 lc
nv
fo = , where n = 1, 2, 3
2 lo
v
= 110 Hz
4lc
330
lc = m
4 110
= 0.75 m
3v
I overtone of closed organ pipe =
4lc
2v
I overtone of open organ pipe =
2lo
These two produce beat frequency of 3.3 Hz when sounded together. Therefore
3v 2v
= 3.3
4lc 2lo
2v 3v
or = 3.3
2lo 4lc
330
3 110 = 3.3
lo
330
lo = = 1.0101 m
326.7
326.7
or lo = = 0.99 m
330
48. (1) Let J be the impulse exerted by the pivot P on the rod. Then from impulse-
momentum theorem,
J + J = Mv0 (1)
where v is the velocity acquired by the centre of mass. Further angular
0
impulse = change in angular momentum about the pivot P.
JL = I
ML2
i.e., JL = , where is the angular velocity of the rod about P.
3
ML
J = (2)
3
L
But v0 =
2
L
Then Mv0 = M
2
L
J + J = M from (1)
2
3J
J + J = on using (2)
2
J
J =
2
J
, J = 1
In units of
2
49. (7) In the standard Dopplers formula, putting
v = + 13.0 m/s
s
v = + 3 m/s and
0
v = 333 m/s, we obtain
v v0
n = n
v vs
333 3.0
= 66 = 68.06 kHz
333 13.0
The moth moving with a velocity of 3.0 m/s reflects the wave of frequency
66 Hz. The frequency of wave received by the chasing bat is
(v v0 )
n = n
(v vs )
333 ( 13)
= 68
333 ( 3)
= 70.02 kHz
4
= 7 10 Hz
SECTION III
50. (C) The electric field at a distance x on the axis of a ring is given by
1 Qx
E= 3
4 0
(R 2 + x 2 ) 2
The net force on the dipole is
dE 2aq d x
F=p = Q 3
dx 4 0 dx
2 2
(R + x ) 2
aQq R 2 2x 2
=
20 5
(R 2 + x 2 ) 2
aQq
Hence in multiple of
20
R 2 2x 2
F=
5
(R 2 + x 2 ) 2
51. (A) Work done in rotating a dipole is equal to negative of the change in its
potential energy. Hence
W = U
U = (U U )=U U
f i i f
U i = p E = pE cos 0
= pE
Uf = p E
= pE cos 180
= pE
work done on the dipole W = U = 2pE
2(2a) Qxq
=
4 0 3
2 2 2
(R + x )
aQq
Hence in multiple of
0
x
W=
3
(R 2 + x2 ) 2
2ma 2 8 2 ma 2
T = 2 =
pE pE
53. (D) For an isochore W = 0. The corresponding straight line, namely, OD coincides
with Q-axis. The line OD is valid for both the gases. Hence correct choice is (D).
54. (D) From I law of thermodynamics,
Q = W + U
For an isothermal process Q = W. Hence slope of W Q graph is 1, ir-
respective of the atomicity of the gases. Hence the line OC represents an
isotherm for both the gases. Hence correct choice is (D).
55. (A) For an isobaric process
W = R T (for one mole of a gas)
and Q = C T
p
f + 2 f + 2
= R T Cp = 2 R
2
where f is the number of degrees of freedom
W R T 2
= =
Q f + 2 f +2
2 R T
For a monatomic gas,
W 2
= ( f = 3)
Q 5
For a diatomic gas,
W 2
= ( f = 5)
Q 7
Thus OA denotes an isobar for a monatomic gas, while OB represents an
isobar for a diatomic gas.
SECTION IV
56. (A) (p), (q); (B) (p), (r), (s); (C) (p), (r), (s); (D) (p), (t)
The equation of motion of the centre of mass is given by M a cm = F ext
After simplification 2T + T T
2 m1 (m 2 + m3 ) g
T= (3)
(m1 + m2 + m3 )
cm
Substitute for T in (1) from (3) we get
(m1 + m2 + m3 )2 g 4m1 (m 2 + m3 ) g
(a cm ) y =
(m1 + m 2 + m3 )2
(m1 + m 2 + m3 ) g
2 2 2
(m1 + m 2 + m3 + 2m1 m 2 + 2m 2 m3 + 2m 3 m1
4m1 m 2 4m1 m3 ) g
=
(m1 + m 2 + m 3 )2
2 2 2
(m1 + m 2 + m 3 2m1 m 2 + 2m 2 m 3 2m1 m 3 ) g
=
(m1 + m 2 + m 3 )2
2
m m 2 m3
(a cm )y = 1 g (4)
m1 + m 2 + m 3
From the expression for (a ) we infer that the acceleration of centre of mass
cm y
always moves vertically downwards irrespective of whether m is heavier or
1
(m + m ) is heavier . By substituting the values of m = m = m = 2 kg we find
2 3 1 2 3
tension T = 27 N.
2
Putting m = 2 kg, m = 3 kg and m = 0 we find acceleration of m or m is 2 m/s
1 3 2 1 3
2
and acceleration of centre of mass i.e., (a ) = 0.4 m/s
cm y
5
Putting m = 5 kg, m = 2 kg and m = 1 kg, we find (a cm )y = m / s2
1 2 3 8
57. (A) (p), (s); (B) (r); (C) (p), (t); (D) (q), (t)
As system is isolated,
W +W =0
ext parallel
dU > 0, charge of the capacitor increases and hence work done by the battery
is greater than zero.