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Corrosion

handbook

May 2015
Corrosion handbook

Foreword

Corrosion is a ubiquitous natural process. Most of us, at some point in our


everyday lives, become familiar with the effect that corrosion has on rusted
steel parts. Corrosion has a huge economic impact. About a fifth of the
worlds annual steel production goes towards simply replacing steel parts
damaged by corrosion. Even though it may involve higher up-front cost,
correct and efficient corrosion protection at the source helps save money and
resources in the long run. For fastening systems, its even more critical as
safety is key. Failure due to corrosion may have dramatic consequences.

The goal of this brochure is to raise your general awareness of what corrosion
is all about. It provides you with basic information on corrosion and the
behavior of the materials used to protect our products from corrosion.

Hilti conducts comprehensive laboratory and field-based tests to


assess the corrosion resistance of its products. Some long-term tests
started in the 1980s are still running today. Thanks to in-house research
and close collaboration with renowned universities and laboratories,
Hilti is in a position to offer the right solutions with the most suitable
corrosion protection for a wide variety of environmental conditions.

Nevertheless, the choice of the material or the corrosion protection


method for a specific application remains the responsibility of the user.
Your local Hilti contact will be pleased to provide further assistance. He or
she will also be able to obtain support at any time from the specialists in
our Corporate Research & Technology department, allowing you to take
advantage of the wealth of in-depth know-how they have available.

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Corrosion handbook

Content

Foreword2
1. Basics of corrosion  5
1.1. What is corrosion? 5
1.2. Forms of corrosion 7
1.2.1. Uniform corrosion/ shallow pitting corrosion 7
1.2.2. Pitting corrosion 8
1.2.3. Crevice corrosion 9
1.2.4. Environmental induced cracking 10
1.2.5. Intercrystalline (intergranular) corrosion 12
1.2.6. Galvanic (contact) corrosion 13
2. Hilti corrosion performance assessment and product qualification methods 14
2.1. Purpose of corrosion testing 14
2.2. Lab facilities/tests 14
2.3. Outdoor field tests 18
3. Hilti corrosion protection solutions 21
3.1. Corrosion and corrosion protection of carbon steel  22
3.2. Corrosion behavior of stainless steel 25
3.3. Preventing of galvanic corrosion 29
4. How to assess corrosion in an specific environment/application 31
4.1. Factors influencing atmospheric corrosion 31
4.2. Assessment of corrosivity for zinc coated products  34
4.3. Assessment of corrosivity for stainless steel products 36
5. How to select a suitable fastener and installation system 39
5.1. Selecting the right corrosion protection for anchors, powder-actuated
fasteners and screws 42
5.2. Selecting the right corrosion protection for wood nails 43
5.3. Selecting the right installation system 44
6. Bibliography  45
7.Disclaimer 47

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1. Basics of corrosion

1.1. What is corrosion?


Corrosion is the physicochemical interaction between a metal and its environment,
which results in changes in the metals properties and which may lead to significant
functional impairment of the metal, the environment, or the technical system of
which they form a part (see ISO 8044:2010).

We only talk about corrosion when there is a change in the metals or systems
properties which may lead to an undesirable outcome. This can range simply from
visual impairment to complete failure of technical systems that cause great eco-
nomic damage and even present a hazard to people.

With the metals commonly used in engineering, such as carbon steel, stainless
steel, zinc, copper and aluminium, the typical corrosion process can be regarded as
the thermodynamically favored reverse reaction of the metal-winning (extraction)
process (see Fig. 1).

metal winning
requires energy
Fe2O3 2 Fe + 3/2 O2

low-energy state corrosion reaction high-energy state


(stable) (unstable)

Fig. 1: Chemical reactions of iron during corrosion and the metal-winning process.

Types of corrosion reactions


Like all chemical reactions, corrosion processes take place when conditions are
in favor of the related chemical reactions (thermodynamics). Then, potential other
factors drive the speed of the reaction (kinetics). We will make a distinction between
the types of corrosion, generally describing the interaction between the metal
and the environment, and forms of corrosion describing the phenomenological
appearance.

Chemical reaction
A typical chemical corrosion reaction occurs at high temperatures, where the metal
reacts with hot gases and forms an oxide layer.

Metallophysical reaction
An example of this is the embrittlement caused by hydrogen which diffuses into a
metal, possibly leading to failure of a component. Embrittlement can be the result of
a careless manufacturing process, e.g. when surface coatings such as electro-
chemical zinc plating are not applied properly on high-strength steel products
(primary embrittlement). It can also be initiated by corrosion processes (metal
dissolution). In the latter case, reference is made to corrosion-induced hydrogen
assisted cracking (secondary embrittlement).

Electrochemical reaction (most frequent type of corrosion)


The most common corrosion reaction is electrochemical in nature. Such reactions
imply an electrical exchange by way of electrons in the metal and ions in a conduct-
ing electrolyte, such as a water film on its surface.

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Corrosion handbook

The overall reaction can be separated in two partial reactions:


Metal dissolution, also known as oxidation or anodic
Fe -> Fe2+ + 2 e-
Reduction or cathodic reaction, a reaction mainly involving the oxygen present
in the air with water
O2 + 2 H2O + 4 e- -> 4 OH-

These two partial reactions can take place on the metal surface in a fairly homoge-
nous distribution leading to uniform attack (see section 1.2.1) or can occur locally
and separately, leading to localized forms of corrosion such as pitting corrosion.

The mechanism and the electrochemical nature of the corrosion reaction define the
necessary requirements for corrosion to take place:
a conducting metal
an electrolyte (a thin moisture film on the surface is already sufficient)
oxygen for the cathodic reaction

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Fig. 2: Requirements for the atmospheric corrosion reaction.

The illustration in Fig. 2 shows the basic corrosion mechanism of iron under a drop
of water. Both metal dissolution and oxygen reduction reactions take place with
slight separation on the surface, and their products (Fe-ions and OH-ions) react in
the water drop to form red rust.
2+  2+
In general, the same scheme applies to other metals such as zinc or aluminium but
)H 2
2 with slightly different chemical reactions in the electrolyte.

H H H H
With the simple model of the corrosion reaction, as seen in Fig. 3, we are able to
explain many forms of corrosion and also to deduct measures to mitigate corrosion.
By preventing or slowing down one of the partial reactions, the overall corrosion
rate is also reduced.

Fig. 3: Corrosion of iron under a drop of


water, showing metal dissolution, oxy-
gen reduction and the formation of rust.

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1.2. Forms of corrosion

1.2.1. Uniform corrosion/ shallow pitting corrosion

Uniform corrosion is a form of corrosion where the surface is removed almost evenly.
The partial reactions (metal dissolution and oxygen reduction) are statistically
distributed over the surface, leading to more or less homogenous dissolution of the
metal and uniform formation of corrosion products (e.g. red rust on steel).
The extent of this form of corrosion can usually be well estimated on the basis of
previous experience. The rate of corrosion is usually given in micrometers per year
(m/a). Using these average values, it is possible to calculate the life expectancy of
a component, and thus to enhance its life expectancy by increasing its thickness.
Uniform corrosion takes place, for example, on unprotected carbon steel and on
zinc-coated steel under atmospheric conditions.

In reality, purely homogenous corrosion attack is unlikely to take place. There are
always areas, especially on complex metal parts, which will corrode faster than
others leading to a more or less rough surface with an irregular covering of corro-
sion products (see Fig. 4).

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4: Corrosion of steel components.

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1.2.2. Pitting corrosion

Pitting corrosion is a localized form of corrosion that leads to the creation of small
holes or pits in the metal (see Fig. 5). This form of corrosion is mainly found on
passive metals. Passive metals and alloys, such as aluminium, titanium and
stainless steel owe their corrosion resistance to a thin oxide layer on the surface
with a thickness of only a few nanometers. The corrosion initiating process starts
with a local break-down of the passive layer. Local corrosive attack can be initiated
on stainless steels, for example, by chloride ions.

Fig. 6 shows the most significant phases of this corrosion phenomenon on stainless
&, corrosion can be
steel. Pitting corrosion can be quite problematic. Whereas uniform
Fig. 5: Example of pitting corrosion on seen clearly on the surface, pitting corrosion often appears only as small pinholes
a stainless steel product. on the surface. The amount of material removed below the pinholes is generally
unknown, as hidden cavities may form, making pitting corrosion more difficult to
detect and predict. Technically, there is no reasonable way to control pitting
corrosion. This form of corrosion must be excluded right from the start through
design considerations and use of the right material.

In addition, pitting corrosion can often be the starting point for more severe
forms of corrosion such as stress corrosion cracking
2 (see section 2
Stress
 corrosion
cracking (SCC)). 2+  2+

&,
&,
)H)H H


a. Stainless steel with passivated b. Local breakdown of passivation due


surface. to attack of chloride ion.

2 2 2 2
2 2
2+ 2+ 2+ 2+
&, 2+ 2+
&,
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)H)HH
)H)HH

c. Start of corrosion on the active d. Anodic dissolution of iron in the pit,


(not passive) part of the surface. oxygen reduction takes place outside.

Fig.26: Phases of pitting


2corrosion on stainless steel.
2 2
2+ 2+
2 2
2+ 2+
2+ 2+
&, )HH
)H
&,

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Corrosion handbook

1.2.3. Crevice corrosion

Crevice corrosion refers to corrosion occurring in cracks or crevices formed between


two surfaces (made from the same metal, different metals or even a metal and a
non-metal). This type of corrosion is initiated by the restricted entrance of oxygen
from the air by diffusion into the crevice area leading to different concentrations of
dissolved oxygen in the common electrolyte (the so-called aeration cell). Again, the
two partial reactions will take place on different parts of the surface. Oxygen reduc-
tion takes place in the outer areas with higher oxygen concentrations easily accessi-
ble by the surrounding air, whereas the anodic metal dissolution occurs in the crevice
area resulting in localized attack (e.g. pitting). It may also occur under washers or gas-
kets, when the entry of water underneath is not prevented (see Fig. 7).
There are lower and upper limits to the size of a crevice in which corrosion may be
induced. If the crevice is too tight, no electrolyte for corrosion will be introduced. If
the crevice is too wide to reduce oxygen entrance, the aeration cell and conse-
quently different concentrations of oxygen cannot develop. However, the critical
crevice width depends on several factors such as the type of metals involved, the
corroding environment and wet/dry cycles.

Oxygen rich

Oxygen starved

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Oxygen starved

Fig. 7: Possible areas for crevice corrosion in a fastening structure.

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1.2.4. Environmental induced cracking

Stress corrosion cracking (SCC)


Stress corrosion cracking (SCC) is a combined mechanical and electrochemical
corrosion process that results in cracking of certain materials. It can lead to unex-
pected sudden brittle failure of normally ductile metals subjected to stress levels well
below their yield strength. Internal stresses in a material can be sufficient to initiate an
attack of stress corrosion cracking.

Stress corrosion cracking is not simply an overlapping of corrosion and mechanical


stresses, but can be understood as an autocatalytic, self-accelerating process
leading to high metal dissolution rates (anodic reaction). Initially, a small pit is
formed and develops into a crack due to applied or residual stress in the material.
The crack formation opens up a new active (non-passive) metal surface, which
again will corrode very easily. This leads to further crack propagation and again to
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the exposure of new highly active metal surfaces in the crack. Metal dissolution in
the crack will advance rapidly until mechanical failure occurs.

SCC is a highly specific form of corrosion that occurs only when the following three
different requirements are fulfilled at the same time (see Fig. 9)
Mechanical (load, stress)
Material (susceptible alloy e.g.: austenitic stainless steel)
Environment (highly corrosive, chlorides)

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Fig. 9: Factors required for the occurrence of stress corrosion cracking.

Fig. 8: SCC of a bracket made of the It is well known that certain grades of austenitic stainless steel can suffer stress
material 1.4301 (A2, 304) after approx. 4 corrosion cracking in harsh environments such as indoor swimming pools. In most
years of use in an indoor swimming pool. of these cases, corrosion is initiated by chlorides attacking the passive layer.

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Hydrogen-assisted cracking
Hydrogen-assisted cracking is caused by the diffusion of hydrogen atoms into the
metal. The presence of hydrogen in the lattice weakens the mechanical integrity of
the metal and leads to crack growth and brittle fracture at stress levels below the
yield strength. Like stress corrosion cracking, it can lead to sudden failure of metal
parts without any detectable warning signs.
In common applications, hydrogen damage is usually only relevant for high-strength
steel with a tensile strength of approximately 1000N/mm2 or higher.

As for SCC, three different conditions must be present at the same time
(see Fig. 10)
Mechanical (load, stress)
Material (hardness structure)
Environmental (external, internal hydrogen)

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Fig. 10: Factors required for the occurrence of hydrogen-assisted cracking.

The source of hydrogen can be the production process such as steel making,
pickling and electrogalvanizing (primary hydrogen). A secondary source can be the
hydrogen formed during a corrosion process. During the corrosion process,
hydrogen is formed and diffuses into the material. This hydrogen intake leads to a
decrease in the toughness or ductility of a metal.

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1.2.5. Intercrystalline (intergranular) corrosion

Intercrystalline corrosion is a special form of localized corrosion, where the corro-


sive attack takes place in a quite narrow path preferentially along the grain bound-
aries in the metal structure. The most common effect of this form of corrosion is a
rapid mechanical disintegration (loss of ductility) of the material. Usually it can be
prevented
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right material and production process.

A well-known example relevant to the construction industry is the so called sensiti-


zation of stainless steel. When certain grades of this material are kept at a tempera-
ture within the range of 500C to 800C for a considerable time, e.g. during a
welding process, chromium-rich carbides are formed, resulting in chromium
depletion at the grain boundaries. Consequently, the grain boundaries possess a
lower degree of corrosion resistance than the residual material, leading to localized
corrosive attack (see Fig. 11).

Fig. 11: Scanning electron micrograph image of a selective attack


Welded zone of a 1.4401, (A4, 316) material.

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1.2.6. Galvanic (contact) corrosion

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Galvanic corrosion refers to corrosion damage where two dissimilar metals have an
electrically conducting connection and are in contact with a common corrosive
electrolyte. In the electrochemical model of corrosion, one of the two partial
reactions (anodic metal dissolution and cathodic oxygen reduction) takes place
almost exclusively on one metal.

Generally, the less noble metal will be dissolved (anodic metal dissolution), whereas
the more noble part is not attacked by corrosion (serves only as the cathode for
oxygen reduction). Where galvanic corrosion takes place, the rate of corrosion of
the less noble metal is higher than it would be in a free corroding environment
without contact to another metal.

Using thermodynamic data and taking common experience gained in typical


applications into account, it is possible to predict which material combinations will
be affected by galvanic corrosion (see 3.3). A positive example of active utilization of
the galvanic corrosion phenomenon described here is the way zinc protects carbon
steels and low-alloyed steels. Zinc is the less noble metal which actively protects
steel by being corroded itself (see Fig. 12).

Fig. 12: This is a typical case of contact corrosion. Zinc-plated carbon steel
(washer) and stainless steel (screw and part) were used together. The surface area
of the more noble metal the stainless steel is larger, causing strong corrosion of
the washer.

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2. Hilti corrosion performance assess-


ment and product qualification methods
Hilti conducts comprehensive laboratory and field corrosion tests to assess the
corrosion protection of its products. Thanks to in-house research Hilti has a wide
variety of tested corrosion protection solutions for different environmental condi-
tions.

Many methods for testing corrosion resistance are specific to particular materials
and are based on conditions prevailing in certain environments. A large number of
factors affect corrosion behavior. Hence there is not a unique and universal corro-
sion test covering all aspects of materials in use. The most reliable indicator of
corrosion behavior is service history, but this information is not always available
exactly as needed. For that reason, other tests are required, i.e. ranging from
accelerated laboratory tests to field tests. Additionally, it is necessary to test the
products in the condition they will have in the application for which they are to be
used. Corrosion protection on our fasteners is therefore also tested with the items
installed on steel or in concrete in order to simulate possible damage occurring
during the installation process.
Corrosion tests are a suitable method for assessing new products and to compare
them with known corrosion protection systems. However, such tests alone are not
sufficient to qualify a product for a certain application as corrosivity of the environ-
ment can differ greatly from one project to another. In the end, it is the responsibility
of the user to choose the right corrosion protection based on detailed information
about the application, long-term experience and fundamental knowledge of the
subject.

2.1. Purpose of corrosion testing


Accelerated corrosion lab tests are state-of-the-art when it comes to evaluating the
performance of materials, as they represent standardized and reproducible condi-
tions and allow an assessment to be made after a short period of testing (days to
weeks). One major use of this type of test is in the quality control of corrosion
protection coatings. In order to pass quality control, the products must exhibit the
required performance (e.g. two days without showing red rust). Moreover, these
types of tests are very useful in product development activities, where screening
and classifying new coatings and materials for new products is crucial.

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2.2. Lab facilities/tests


In our in-house research facilities, Hilti performs the most relevant lab corrosion
tests available for testing our products (see Fig. 13).

Neutral salt spray test: EN ISO 9227


The salt spray test is one of the oldest and most widely-used accelerated corrosion
tests. The samples are exposed permanently to a saline fog made from a five
percent sodium chloride solution. The salt spray test is not directly representative of
corrosion protection in real atmospheres because of the high chloride concentration
and missing dry periods. However, it is a practical test primarily used for process
qualification and quality acceptance. Hilti uses the salt spray test to check the Fig. 13: Picture from our corrosion lab
homogeneity of zinc coatings on fasteners as quality control in production (see with various corrosion testing chambers.
Fig. 15 and Fig. 14).


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Fig. 15: Typical time until the first appearance of red rust (corrosion of the steel Fig. 14: Electrogalvanized screws with
substrate) in the salt spray for zinc coated products with varying coating thickness. around 5m zinc coating after 48h (up)
and 96h (down) in the salt spray test.

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Corrosion handbook

Cyclic corrosion test: EN ISO 16701


In the cyclic corrosion test according to EN ISO 16701, temperature and relative
humidity are varied to simulate typical wet/dry cycles like the ones taking place in
natural outdoor environments. Additionally, the samples are sprinkled with a dilute
sodium chloride solution (1%) twice a week to induce corrosion. While still not
directly representative of most real atmospheres, due to the wet/dry cycles as well
as the lower chloride concentration, this test is much better suited to triggering
natural corrosion processes than the simple salt spray test. However, it requires
longer test times (several weeks) (see Fig. 16 and Fig. 17).

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Fig. 16: Daily temperature and humidity Fig. 17: Zinc-coated steel (hot-dip galvanized, HDG) after one year in a tropical
cycle of the ISO 16701 cyclic corrosion coastal climate (left) and after 12weeks in the ISO 16701 cyclic corrosion test (right).
test: twice a week, a 1% NaCl-solution Similar corrosion behavior was observed in the field test and cyclic corrosion test.
is sprayed onto the samples for 3x15
minutes.

Cyclic corrosion test with exposure to UV radiation: ISO 20340


This test additionally exposes the samples to high-energy ultraviolet radiation. It is
combined with water condensation, with chloride exposure and a freezing period
(see Fig. 19). Organic polymers such as paints and varnishes can show degradation
when exposed to sun light. This test is therefore mainly used for products with
organic coatings (see Fig. 18). Apart from corrosion testing, it is also used to check
the ageing effect on UV sensitive products such as plastic parts.

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coating (organic flake topcoat) after ten  &

weeks in the ISO 20340 test with UV


radiation.

Fig. 19: Cyclic corrosion test procedure in combination with exposure to UV radiati-
on, salt spray and freezing cycle according to ISO 20340.

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Corrosion handbook

Humidity test: EN ISO 6270 and Kesternich-Test (sulphur dioxide):


EN ISO 6988
In the humidity test, samples are exposed to an atmosphere with 100% relative
humidity. This test can be combined with the addition of a certain amount of sulfur
dioxide gas. This will cause a highly corrosive and acidic environment to simulate
the effect of heavy industrial pollution (see Fig. 20).

Electrochemistry
The electrochemical nature of the corrosion process renders electrochemical tech-
niques a useful instrument for the investigation of corrosion reactions of certain ma- Fig. 20: Screws with highly corrosion-
terials. Besides the accelerated corrosion tests, our lab is equipped with electro- resistant multilayer coating after 15
chemical testing equipment (potentiostat) which is mainly used for the examination of cycles of the sulfur dioxide corrosion
pitting corrosion and the repassivation behavior of stainless steel. test (showing no corrosion).

Metallographic laboratory
Accelerated corrosion tests as well as field exposure tests always have to be support-
ed by various analytical methods for proper interpretation of the results. In the metal-
lography lab we use a state of the art scanning electron microscope (SEM) plus ele-
mental analysis for deeper investigation of our products (see Fig. 21, Fig. 23 and Fig. 22)

corrosion products
Fig. 21: Scanning electron
orignal coating microscope (SEM).

steel

Fig. 22: Metallographic cross section in the scanning electron microscope of a Fig. 23: Metallographic laboratory
Zn-alloy coating after three years exposure in a coastal climate. equipment (grinding and polishing).

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Corrosion handbook

2.3. Outdoor field tests


Corrosion protection of products can be assessed most accurately by exposure
tests of specimens and products in real atmospheric environmental conditions.
For this purpose, Hilti conducts multiple ongoing outdoor field tests for its products
at various sites all over the world, in conditions ranging from cold temperate to
tropical, and from coastal to industrial and even offshore atmospheres (see Fig. 24).

cold climate, coastal cold climate, coastal industrial, steelworks

Sweden
Germany
France
Austria

Mexico China

tropical, coastal moderate climate, coastal tropical, coastal

Fig. 24: Map showing the various field test locations for Hilti products

 The location near Le Havre on the Atlantic coast in France has been operated by
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 Hilti since the 1980s. Here we not only test the corrosion behavior of our fastening

products, but also their long-term functionality. The fastening elements, especially
anchors, are set in concrete. After certain periods of time, the remaining load values

are measured in pull-out tests (see Fig. 25).





        
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Fig. 25: Typical force-displacement


measurement result for an installed
anchor after 16 years of exposure in the
coastal environment.

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Corrosion handbook

From the beginning of the 1980s until 2005 Hilti also carried out extensive studies
on the corrosion behavior of various materials in road tunnels in the Alpine region.
These long-term observations have given us the ability to improve the performance
of our products in these highly corrosive surroundings and thus supply our custom-
ers with effective fastening systems for use in these environmental conditions. The
high-alloyed stainless steel grade 1.4529 (HCR) has proven to be the one material
that shows no signs of corrosion. The results of these studies have also influenced
standards and codes of practice for products and fasteners made of stainless steel
used for tunnel applications (see Fig. 26).

Our fasteners and installation products are not the only products that are thoroughly Fig. 26: Road tunnels present a very
tested. Hiltis power tools also undergo many functionality tests, combined with corrosive environment (de-icing salt and
typical corrosion conditions. This leads to high performance even in tough environ- exhaust fumes from traffic).
ments (see Fig. 27).

Fig. 27: Fastening tools in a humidity chamber.

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3. Hilti corrosion protection solutions

The corrosion protection solutions applied to Hilti products, their typical corrosion
behavior and their suitability for certain applications are described in this section.

Classification of corrosion protection measures

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The table below provides an overview of the corrosion protection coatings applied
to Hilti products.

Table 1: Corrosion protection coatings applied to Hilti products

Hilti corrosion protection Coating thickness Product examples


solution for carbon steel
Phosphating Screws
Electrogalvanizing From 5 to 20m Nails, anchors, screws
Hot-dip galvanizing From 35 to 100m Installation channels
Continuous hot-dip galvanizing From 20 to 40m Stud anchors,
/ Sendzimir galvanizing installation channels
Sherardizing/Thermal diffusion Up to 45m Anchors
Multilayer (Zn plus additional Anchors and installation
organic coating painting) parts

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Corrosion handbook

3.1. Corrosion and corrosion protection of carbon steel


The unalloyed steel (i.e. mild steel or carbon steel) from which the majority of our
fastening and installation products are manufactured requires corrosion protection.
In most environments, the corrosion rate of carbon steel (typically around
20 micrometers per year (m/a) in a rural outdoor atmosphere and rising to more
than 100m/a in coastal environments) is usually too high for a satisfactory applica-
tion.The Product design does not generally account for a basematerial loss. Hilti
therefore offers a wide range of suitable, cost-efficient corrosion protection solu-
tions for carbon steel products.

In alkaline surroundings, however, iron and steel usually remain stable. This explains
why, for example, reinforcing bars made of carbon steel are already very well
protected against corrosion in the alkaline environment of the surrounding concrete.

Phosphating

Steel is dipped into an acidic solution containing


5m metal (Zn, Fe) phosphate salts. The solution reacts
Process description with the steel surface forming a micro-crystalline
layer of phosphates on the surface (see Fig. 28). This
Fig. 28: Phosphate crystals on a steel results in a rough surface with excellent oil-retaining
surface at 3000X magnification in the properties.
scanning electron microscope.
Oil applied for corrosion protection is intended to
stay long enough on the surface in order to provide
Corrosion behavior and
protection during normal transport and slightly
further information
increased general corrosion protection. Such
products can be used only in dry indoor environ-
ments. Hilti uses phosphatizing on drywall screws.

Zinc coatings

Zinc is an excellent choice for the corrosion protection of carbon steel. Several
suitable processes are available for the application of zinc coatings on steel parts
ranging from small screws to channels of several meters in length.
The corrosion rate of zinc is more than ten times lower than that of steel, at
around 0.5m/a in rural/urban atmospheres and rising to up to around 5m/a in
coastal environments. Fig. 28 provides an overview of the typical service life of
zinc-coated steel under various conditions.
The low corrosion rates are the result of the formation of stable layers of corro-
sion products containing carbonates (from CO2 in the air) and chlorides (if they
are present in the atmosphere). Conditions where the formation of such insoluble
corrosion products is not possible will lead to much higher corrosion rates and
hence will limit the suitability of zinc as a protective coating. These include
permanently wet conditions or exposure to high concentrations of industrial
pollutants such as sulfur dioxide. In these environments, soluble corrosion
products are formed preferentially and they can be washed off by rainfall.
In addition to decreased corrosion rates, zinc also provides cathodic or sacrificial
protection to the underlying steel. Where scratching, chipping or any other
damage to the zinc coating exposes the steel, a special form of galvanic corro-
sion takes place (see section 1.2.6). Zinc, being a less noble metal than steel,
corrodes preferentially, thereby helping to keep the exposed steel surface
protected.

page 22 Corrosion handbook


Corrosion handbook

Zinc coatings are consumed quite homogenously during atmospheric corrosion.


Accordingly, in a given application, doubling of the coating thickness usually also
doubles the time until the zinc is consumed and red rust on the steel substrate
occurs.

Zinc is not stable in alkaline environments and is readily attacked in solutions


with a pH-value of 10 or higher. Likewise, on the jobsite, the spilling of aggressive
construction materials on zinc products, e.g. cement or fresh concrete, should
be avoided.

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Fig. 29: Typical service life of zinc-coated steel in various environments.

Electrogalvanizing
Electrical current is passed through an aqueous solu-
tion containing zinc ions which leads to the deposi-
tion of zinc metal on the steel substrate. Prior to this
step, the parts usually undergo a cleaning and pick-
Process description
ling process and subsequent passivation after the
deposition of zinc. It is an excellent way to protect
small threaded parts due to the formation of homo-
geneous and dense coatings.
Coating thickness It can vary from 5 to 15m.

Due to the limitations of the achievable coating


thickness, Zn electroplated parts without further
corrosion protection should only be used in dry
indoor conditions. Using electroplating, it is also
Corrosion behavior and possible to deposit Zn alloys such as ZnNi coatings.
further information Electrogalvanizing can lead to hydrogen uptake.
Hiltis high-strength fasteners such as nails for direct
fastening are therefore baked after electroplating
(kept at temperatures of around 180C for 24h) to
remove hydrogen.

Corrosion handbook page 23


Corrosion handbook

Hot-dip galvanizing
Zn-phase During this process, steel parts are dipped into a bath
ZnFe-phase of molten zinc. Large parts with a size of several meters
Process description can be coated using this technique. Small parts like
bolts and anchors are centrifuged after hot-dip galva-
nizing in order to remove excess zinc from the threads.
steel
The typical thickness is between 35 and 100 microns,
depending on the material thickness and the steel
Coating thickness
composition. The duration of dipping is usually several
minutes.
Fig. 30: Micrograph of hot-dip
The molten zinc reacts with the steel substrate form-
galvanized steel.
ing a ZnFe alloy layer with a thinner pure Zn layer on
top (see Fig. 30).
Corrosion behavior and
further information Corrosion products of hot-dip galvanizing may look
brownish due to Fe in the zinc coating. This, howev-
er, is not necessarily a sign of corrosion of the steel
substrate (see Fig. 31).
Fig. 31: Brown staining on a hot-dip
Continuous hot-dip galvanizing / Sendzimir galvanizing
galvanized channel after 200h in the salt
During this process, sheet metal from coils is drawn
spray test. No corrosion of the steel yet.
continuously through a bath of molten zinc after the
surface has been cleaned and it has been subjected
to a special annealing (heat treatment) process. The
Process description zinc bath contains small amounts of Al. The Al reacts
with the steel surface to create a so-called inhibition
layer with a thickness of a few nanometers, which in-
hibits the formation of ZnFe phases. The coating
consists mainly of pure zinc.
It can vary from 10 to 70 microns on both sides and it
Coating thickness
is controlled by removing excess zinc with a jet of air.
Apart from pure Zn, also coatings consisting of Zn al-
loys such as ZnAl and ZnAlMg can be produced by
continuous dip galvanizing. Typical coatings have
Corrosion behavior and around 2-4% of Al and Mg and show increased cor-
further information rosion protection, which is around two times higher
than that of a Zn coating with the same coating
weight.

Sherardizing/Thermal diffusion
Sherardizing is a method of zinc coating utilizing a
thermal diffusion process. The steel parts are placed
in a drum containing Zn powder and then heated to
Process description
temperatures above 320C. The Zinc is not liquid,
and the coating forms by thermal diffusion of the Zn
powder into the steel parts.
The achievable coating thickness ranges up to 45 mi-
Coating thickness
crons.
These coatings consist mainly of a ZnFe alloy which
offers very good protection against corrosion that
Other features can be compared with hot-dip galvanizing. Even on
complex threaded parts, this process produces
tough and uniform coatings.

page 24 Corrosion handbook


Corrosion handbook

Multilayer coatings
When the corrosion protection provided by the metallic coating is not sufficient,
the parts can be further protected by additional coatings, mainly organic paint
with or without metallic flakes.

An example of this is the multilayer coating on fasteners consisting of an electro-


plated Zn alloy coating with an additional organic top coat (see Fig. 32).

Top coat for chemical resistance


Zn-alloy electroplating for cathodic protection
Hardened carbon steel

Fig. 32: Illustration of multilayer coating on fasteners and connectors.

3.2. Corrosion behavior of stainless steel


Steel alloyed with at least 10% chromium is called stainless steel. The addition of
chromium causes the formation of a stable, very thin (few nanometers) oxide layer
(passivation layer) on the surface. Stainless steel therefore does not readily corrode
or stain when in contact with water like carbon steel does.
However, under some circumstances, the passivation layer can break down causing
local attack such as pitting corrosion (see 1.2.2). Pitting corrosion, as the predomi-
nant form of corrosion of stainless steel, does not allow lifetime prediction as is
possible with zinc coatings. In general, for a given application, a grade of stainless
steel which is stable and does not show any corrosion in the given environment has
to be selected.

The resistance of stainless steels against pitting corrosion can be roughly estimated
by the PREN (pitting resistance equivalent number). The PREN is based on the
chemical composition of steel, taking into account the amount of chromium,
molybdenum and nitrogen. In literature, various equations for this calculation are
given. The most common equations are:

PREN = %Cr + 3.3 x %Mo


(for stainless steels Mo < 3%)

PREN = %Cr + 3.3 x %Mo + 30 x %N


(for stainless steels Mo 3%)

Corrosion handbook page 25


Corrosion handbook

Another severe form of corrosion relevant for stainless steel is stress corrosion
cracking.
Austenitic stainless steel can be prone to this form of corrosion under specific
highly aggressive environments such as in indoor swimming pools. In such cases,
highly corrosion-resistant grades of stainless steel must be used for some applica-
tions, e.g. grades with a molybdenum content of more than 6%.

You will find more information about selecting stainless steel grades in section 4.

Stainless steel grades


There are various grades of stainless steel with different levels of stability. The most
common grade is alloyed with around 18% Cr and 10% Ni (see Fig. 33). Increasing
or reducing the amount of specific elements in the steel changes its corrosion
properties, its mechanical properties or some processing properties such as
weldability. If the Nickel content is significantly reduced the alloy phase will no
longer be purely austenitic, but will then combine austenitic and ferritic phases
(duplex stainless steel).

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page 26 Corrosion handbook


Corrosion handbook

Stainless steel designations


The illustration in Fig. 33 shows the three most common forms of stainless steel
grade designations:

Material number
Description
The system of numbering materials in accordance with EN 10088-1:2014 is used
in several countries. Each number has five digits, such as 1. 4404

The first digit 1 means steel, the second and third digits 44 mean chemically re-
sistant steels with Mo, and without Nb or Ti. In addition to designation 44, the
following designations for stainless steel exist:
41 = with Mo, without Nb and Ti, Ni < 2,5%
43 = without Mo, Nb and Ti, Ni 2,5%
44 = with Mo, without Nb and Ti, Ni 2,5%
45 = with additional elements

The last two digits 04 designate the exact alloy.

AISI designation (e.g. 316)


Description
The designation system of the American Iron and Steel Institute (AISI) is used
worldwide. It consists of a number to which one of several letters may be added
depending on the composition.
200 designates an austenitic steel containing chromium, nickel and manganese
300 designates an austenitic steel containing chromium, nickel
400 designates ferritic and martensitic chromium steels

The additional letters (some shown below) indicate the following:

L = low carbon Ti = titanium

The newly-developed duplex stainless steel grades have a four-digit designation


(e.g. 2205 for the 1.4462)

Corrosion handbook page 27


Corrosion handbook

Short name designation


Description

X 2 Cr Ni Mo 17 12 2

X= High-alloy steel
2= Carbon content in 1/100%, in this case: C= 0.02%
Cr= Chromium, in this case: 17%
Ni= Nickel, in this case: 12%
Mo= Molybdenium, 2%

This steel grade in the given examples corresponds to the AISI type 316 L and
the DIN material no. 1.4404.

Terms V2A and V4A designation according to EN ISO 3506-1:2009


Description
The terms V2A and V4A date back more than 100 years and have their origin in
the designation of the first trial productions of stainless steel. The V stands for
Versuch, which is German for test or trial, and the A for austenite. V2A de-
notes a Cr/Ni alloy and V4A a CrNiMo alloy. The terms are still used as synonyms
for stainless steel in some countries.

The EN ISO 3506-1:2009 standard (mechanical properties of corrosion-resistant


stainless steel fasteners, bolts, screws and studs) uses designations ranging
from A1 to A5 for austenitic stainless steel. This range is based on the alloy com-
position and does not reflect corrosion behavior. For example, the grade 1.4401
is in the A4 group and 1.4571 is in the A5 group. However, both stainless steel
alloys exhibit practically the same corrosion resistance.

Often the terms A2 and A4 are used to talk about a group of stainless steel
grades with certain corrosion resistance. However, this is not completely accu-
rate, since specific information about the alloy composition and thus also some
properties such as weldability cannot be deduced from these terms.

page 28 Corrosion handbook


Corrosion handbook

3.3. Preventing of galvanic corrosion


Galvanic corrosion (described in section 1.2.6) can be avoided by the right choice
of material combinations. This, however, is not always possible and sometimes
other measures have to be considered. One example is galvanic separation of the
different materials, as shown in Fig. 34.

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Fig. 34: Conditions for metal combinations without risk of galvanic corrosion.

To minimize galvanic corrosion, the difference in free corrosion potential between the
materials should be as low as possible, and/or the surface ratio of less noble metal to
nobler metal should be very high. The free corrosion potential depends on the standard
potential, a given thermodynamic value for each metal and the corrosive environment.

Fig. 35 shows the free corrosion potential of various materials when immersed in
seawater. The higher the potential, the nobler is the metal. Contact to a metal with a
lower potential leads to galvanic corrosion of that less-noble metal.

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Corrosion handbook page 29


Corrosion handbook

As a general rule of thumb, a fastener should always be made of the same or a


more noble metal than the part to be fastened, since it typically has the smaller
surface area, and failure of the fastener is usually critical.

Table 2 shows the impact of galvanic corrosion under atmospheric outdoor


conditions for various material combinations.

Table 2: Impact on lifetime of the fastener by galvanic (contact) corrosion

Fastener (small area)


Fastened part Electrogalva- Duplex-coat- Hot-dip Stainless
(large area) nized ed carbon galvanized steel
steel
Electrogalvanized

Hot-dip galvanized

Aluminium
n n n

Structural
n n n
or cast steel

Stainless steel
n n n
(CrNi or CrNiMo)

Tin
n n n

Copper
n n n

Brass
n n n

No impact on lifetime
n Moderate impact on lifetime, technically acceptable in many cases
n Strong impact on lifetime

In dry indoor applications contact corrosion can be neglected and usually there
are no susceptible material combinations. In most indoor or outdoor applications
with combinations of materials one always has to consider the general guidelines
and limitations for certain materials. For example, the rate of galvanic corrosion of
zinc in contact with aluminium is usually very low. However, the coating thickness
on zinc-electroplated fasteners is usually too small for an outdoor use with consid-
erable lifetime requirement.

In the selection tables shown in section 5, galvanic corrosion is taken into account
by providing two different rows for the fastened part (divided into steel, alumini-
um and stainless steel).

page 30 Corrosion handbook


Corrosion handbook

4. How to assess corrosion in an specific


environment/application

The following section describes ways of assessing the corrosivity of certain


environments. The parameters influencing the corrosion can only be checked by
specialists working locally on a specific project. Accordingly, the final decision
regarding the chosen material and products is the responsibility of the user and/or
specifier. While Hilti personnel can provide you with the necessary basic information
about our products, it is not possible to carry out a fully comprehensive check of
the expected corrosivity of the intended application.

4.1. Factors influencing atmospheric corrosion


Under specific circumstances, the corrosivity and, respectively, the corrosion rates
of zinc and steel products can be estimated when typical atmospheric parameters
are known for a certain application (see Fig. 36).

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Fig. 36: Factors influencing atmospheric corrosion.

Corrosion handbook page 31


Corrosion handbook

The important variables for atmospheric corrosion are:

Temperature
An increase in temperature leads to an increase of the
General influence rate of chemical reaction and therefore also an in-
crease of the corrosion rate. This is especially true at
constant relative humidity levels.
On the other hand, increasing temperature facilitates
Additional information the drying of wet surfaces and can slow down corro-
sion rates. At temperatures below the freezing point
corrosion is negligible. The influence of the tempera-
ture on corrosion can therefore go in both directions.
For similar environments such as maritime regions,
Examples
which usually show high humidity levels, an increase
in the average temperature also accelerates the cor-
rosion rate. As a result, coastal and offshore areas in
tropical climates show much higher corrosivity than
similar zones in colder regions.

Humidity
Atmospheric corrosion only takes place when a thin
General influence
moisture film is present on the metal surface. In the ab-
sence of humidity, most contaminants would have little
or no corrosive effect. The period in which a moisture
film is present is also called time of wetness. As a
commonly used rule of thumb according to the
ISO 9223:1998 standard, the time of wetness is de-
fined as the periods where the relative humidity ex-
ceeds 80%.This is only a rough estimation since the
formation of a moisture film on the surface also de-
pends on the presence of hygroscopic salts (e.g. cor-
rosion products or salt deposits). Condensation in mar-
itime environments with chlorides will therefore take
place at lower levels of relative humidity. Calculation of
corrosion rates according to the latest ISO 9223:2012
standard takes into account only the mean relative hu-
midity measured in one year (see 5.1).
Additional information Water in the form of rain does not always increase
corrosivity. It may even have a beneficial effect by
washing away chlorides and pollutants. However, in
usually dry and mildly corrosive environments, rain-
water can provide the moisture necessary to trigger a
corrosion reaction.
Examples In rural/urban atmospheres, sheltered parts usually
show less corrosion than the ones exposed to rain.
On the other hand, the lack of the washing effect of
the rain in coastal areas often leads to stronger corro-
sion.

page 32 Corrosion handbook


Corrosion handbook

Chlorides
Atmospheric salinity distinctly increases corrosion
General influence
rates.

Chlorides have multiple detrimental effects on the


corrosion of metals. In particular these are:
Decrease in the saturation humidity: the pres-
ence of salts facilitates condensation at lower
relative humidity values. This leads to longer pe-
riods with wet metal surfaces
Formation of soluble corrosion products: the dis-
solved metal ions form metal chlorides, which
usually do not provide enough protection from
further corrosion.
Destruction of passive films: chlorides attack the
oxide films formed on passive metals such as
stainless steel and aluminium

Additional information The corrosion behavior of a certain metal in atmo-


spheres containing chloride strongly depends on its
ability to form stable and insoluble corrosion products
together with the present chlorides. For example, this
is the case with zinc, which explains the much lower
corrosion rate of zinc compared to steel.
Examples In maritime atmospheres the main source of chlorides
is the seawater. It contains mainly sodium chloride
(more than 90% of the salt), accompanied by calcium
and magnesium chlorides. The main source of an-
thropogenic chlorides is the use of de-icing salts on
roads during winter time.

Sulphur dioxide
Of all the atmospheric contaminants originating from
General influence industrial processes such as fuel combustion and
metal smelting, sulfur dioxide is the most important
one in terms of concentration and its effect on corro-
sion rates. Sulfur dioxide gas in the atmosphere acidi-
fies the electrolyte on the surface and leads to the
formation of soluble corrosion products. Corrosion
rates are thus increased on many metals, e.g. zinc,
steel, aluminium and stainless steel.
Sulfur dioxide emissions are on the decline in large
Additional information parts of the industrialized world and have reached in-
significant levels in many urban and even industrial
areas (below 10g/m3 or even lower). However, heavi-
ly polluted hot spots around the world still exist,
where an increase in corrosion due to SO2 has to be
considered when it comes to material selection.
The ISO 9223:2012 standard classes atmospheres
Examples
with SO2 concentrations of over 50g/m3 (yearly
average) as strongly contaminated environments.

Corrosion handbook page 33


Corrosion handbook

4.2. Assessment of corrosivity for zinc coated products


The following section describes a way of assessing and estimating the expected
corrosion in a given environment for zinc-coated products. It has to be noted that this
only applies to pure atmospheric corrosion where the item is fully exposed to the
weather. Applications where, for example, the item is in contact with soil, immersed in
sea water or positioned in the splash zone are excluded, as are additional effects
resulting from galvanic corrosion, erosion or exposure to chemical substances.
Estimation of the corrosivity of the application can be carried out in two different
ways according to the ISO 9223:2012 standard (see Fig. 37).

1. Corrosivity estimation using the classification of ISO 9223:1998 or the dose-


response function given in the new version of this standard (ISO 9224:2012).
2. By conducting one-year exposure tests of the material/product to be used and
measuring the corrosion rate.

For most projects it is not feasible to conduct one-year exposure tests and there-
fore estimation becomes the most frequently used approach. For the estimation
approach, the main climatic and environmental parameters previously described are
required as input. These are, in particular, the mean temperature, mean relative
humidity, chloride deposition and SO2 concentration.

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Fig. 37: Methods for assessment of atmospheric corrosivity.

The outcome of this approach is an estimated rate of corrosion of zinc or steel in a


given environment. The resulting corrosion rates define the prevalent corrosivity
category (C-class, see table 3).

As stated in the standard, the possible deviation using environmental data and the
dose-response function may be up to 50%. It must be noted that the results are
only valid for macroclimatic and fully exposed (unsheltered) conditions.

page 34 Corrosion handbook


Corrosion handbook

Moreover, factors such as accumulation of corrosive substances or galvanic


corrosion, which can have a significant effect on the corrosion rate, are not taken
into account in this approach. Nevertheless, as long as these other potential
sources of corrosion are not present, the results of this calculation are usually
accurate enough to allow selection of the right material.
Corrosion is a natural process influenced by varying environmental factors which
cannot be foreseen for the entire designed lifetime. A conservative approach is
therefore always advised when it comes to the use of fastening and installation
products.

Table 3: Corrosivity categories and description of typical environments as stated in


the ISO 9223 standard

Corrosivity Corrosion Typical environments


category C level Indoor Outdoor
C1 Very low Heated spaces with low relative humidity and insignifi- Dry or cold zone, atmospheric environment with very low
cant pollution, e.g. offices, schools, museums. pollution and time of wetness, e.g. certain deserts, Central
Arctic / Antarctica.
C2 Low Unheated spaces with varying temperature and humidity. Temperate zone, atmospheric environment with low pollu-
Low frequency of condensation and low pollution, e.g. tion (SO2 < 5g/m3), e.g. rural areas, small towns.
storage, sports halls.
Dry or cold zone, atmospheric environment with short time of
wetness, e.g. deserts, subarctic area.
C3 Medium Spaces with moderate frequency of condensation and Temperate zone, atmospheric environment with medium
moderate pollution from production processes, e.g. food- pollution (SO2: 5g/m3 to 30g/m3) or some effect of chlo-
processing plants, laundries, breweries, dairies. rides, e.g. urban areas, coastal areas with low deposition
of chlorides.

Subtropical and tropical zone, atmosphere with low pollu-


tion.
C4 High Spaces with high frequency of condensation and high Temperate zone, atmospheric environment with high pollu-
pollution from production processes, e.g. industrial pro- tion (SO2: 30g/m3 to 90g/m3) or substantial effect of
cessing plants, swimming pools. chlorides, e.g. polluted urban areas, industrial areas,
coastal areas, without spray of salt water or, exposure to
strong effect of de-icing salts.

Subtropical and tropical zone, atmosphere with medium


pollution.
C5 Very high Spaces with very high frequency of condensation and/or Temperate and subtropical zone, atmospheric environment
with high pollution from production processes, e.g. with very high pollution (SO2: 90g/m3 to 250g/m3) and/
mines, caverns for industrial purposes, unventilated or significant effect of chlorides, e.g. industrial areas,
sheds in subtropical and tropical zones. coastal areas, sheltered positions on coastline.
CX Extreme Spaces with almost permanent condensation or exten- Subtropical and tropical zone (very high time of wetness),
sive periods of exposure to extreme humidity effects and/ atmospheric environment with very high SO2 pollution
or with high pollution from production processes, e.g. un- (higher than 250g/m3) including accompanying and pro-
ventilated sheds in humid tropical zones with penetration duction factors and/or strong effect of chlorides, e.g. ex-
of outdoor pollution including airborne chlorides and cor- treme industrial areas, coastal and offshore areas, occa-
rosion-stimulating particulate matter. sional contact with salt spray.

This table gives a verbal description of possible environments with respect to the
corrosion class. Although it can be used to estimate the corrosion class of the
application, one has to keep in mind that strictly following the standard means that
the corrosion class has to be determined by measurement of the corrosion rate or
the most important environmental parameters. And, again, the table only considers
typical atmospheric conditions.

The corrosion rates for steel, zinc, aluminium and copper with respect to the
corrosivity classes can be found in the ISO 9223 standard.

Corrosion handbook page 35


Corrosion handbook

4.3. Assessment of corrosivity for stainless steel products


Strictly speaking, the corrosivity categories (C-classes) according to the ISO 9223
standard are applicable only to zinc, carbon steel, aluminium and copper. The
different corrosion mechanism of stainless steel makes it necessary to work with a
system of classification different to that used for zinc. Stainless steel is generally
stable against humidity and water when no corrosive contaminants are present. The
breakdown of the passive layer by substances like chlorides however has to be
taken into account specifically and limits the use of certain grades of stainless steel.

Unlike for zinc, the influence of pure humidity without other contaminants is
negligible for the corrosion of stainless steel. For stainless steel it is more important
to consider the effect of chlorides and of rain in washing off the corrosion products
and corrosive substances. In many applications the effect of this washing renders
the use of weaker grades of stainless steel possible. For applications like roofs and
the facades of buildings this can be an option. However, in typical applications
where fasteners and installation products are used there can be areas sheltered
from the rain.

International (Eurocode 3, EN 1993-1-4 draft version) and national standards and


guidelines (like the German technical approval DIBt Z.30.3-6) usually work with a
special scoring system when evaluating the suitability of certain stainless steel
grades.
This system takes the risks presented by the main influencing factors into account,
from which a corrosion resistance factor (CRF) is calculated.
Each risk factor (chlorides, sulfur dioxide, washing effect) is linked to a certain
number of points.

The CRF depends on the severity of the environment and is calculated as follows:
CRF = F1 + F2 + F3
where
F1 = Risk of exposure to chlorides from salt water or deicing salts
(categories ranging from +1 to -15, mainly determined by the distance
from the coast or roads, where de-icing salts are used)
F2 = Risk of exposure to sulfur dioxide;
(categories ranging from 0 to -15, determined by the average sulphur dioxide
concentration)
F3 = Cleaning regime or exposure to washing by rain.
(categories ranging from +1 to -7)

Summing up all of the factors results in a number of points (the CRF) which then
relate to five corrosion resistance classes (see Table 4). This is only an excerpt of
the procedure, for details please refer to the standards.

page 36 Corrosion handbook


Corrosion handbook

Table 4: List of stainless steel grades in the corrosion resistance classes based on
the tables in the EN 1993-1-4:2006 (final draft version 2014)

Corrosion resistance class CRC (link to the corrosion resistance factor CRF)
I II III IV V
CRF = 1 0 CRF > -7 -7 CRF > -15 -15 CRF -20 CRF < -20
1.4003 1.4301 1.4401 1.4439 1.4565
1.4016 1.4307 1.4404 1.4462 1.4529
1.4512 1.4311 1.4435 1.4539 1.4547
1.4541 1.4571 1.4410
1.4318 1.4429 1.4501
1.4306 1.4432 1.4507
1.4567 1.4162
1.4482 1.4662
1.4362
1.4062
1.4578

In the Hilti range of fasteners and installation systems you will find grades such as
1.4301, 1.4404 and the most stable 1.4529 (see Table 6), covering all important
corrosion resistance classes.

Table 5: Examples of stainless steels used in Hilti products

Steel grades Corrosion Products


resistance class
1.4301 (A2, 304) II Screws, anchors, installation prod-
ucts
1.4401 (A2, 316) III Screws, anchors, installation prod-
ucts, fasteners driven by powder or
gas-actuated tools
1.4404 (A4, 316L) III Screws, anchors, installation chan-
nels, fasteners driven by powder or
gas-actuated tools
1.4571 (A5, 316Ti) III Installation products
1.4362 (duplex, 2304) III Fasteners driven by powder or gas-
actuated tools
1.4462 (duplex, 2205) IV Fasteners driven by powder or gas-
actuated tools
1.4529 (HCR) V Anchors

For more detailed information on the stainless steel grades used in our products
please refer to our product catalogs or visit www.hilti.com.

Corrosion handbook page 37


Corrosion handbook

page 38 Corrosion handbook


Corrosion handbook

5. How to select a suitable fastener and


installation system

Information about the selection tables


Hilti offers fasteners and installation systems in a wide range of suitable, cost-effi-
cient materials. However, the differences in corrosion behavior, the complexity of
the factors influencing corrosion and the number of national and international
standards and guidelines applicable to the field of corrosion can present a chal-
lenge when it comes to making the right choice of material for a certain application.

In order to provide an initial overview of the performance of the various products,


our tables show general suitability and, where applicable, also a rough estimate of
lifetime of products in some typical environments.
Important notes provides information that must always be taken into account
when using the tables:

Important notes
The ultimate decision on the required corrosion protection must be made by the
customer. Hilti accepts no responsibility regarding the suitability of a product for a
specific application, even if informed of the application conditions.
The tables are based on an average service life for typical applications.
For metallic coatings, e.g. zinc layer systems, the end of lifetime is the point at
which red rust is visible over a large fraction of the product and widespread
structural deterioration can occur the initial onset of rust may occur sooner.
National or international codes, standards or regulations, customer and/or
industry specific guidelines must be independently considered and evaluated.
These guidelines apply to atmospheric corrosion only. Special types of corrosion,
such as crevice corrosion or hydrogen assisted cracking must be independently
evaluated.

The tables published in this brochure describe only a general guideline for
commonly accepted applications in typical atmospheric environments.
Suitability for a specific application can be significantly affected by localized
conditions, including but not limited to:
Elevated temperatures and humidity
High levels of airborne pollutants
Direct contact with corrosive products, such as found in some types of chemi-
cally-treated wood, waste water, concrete additives, cleaning agents, etc.
Direct contact to soil, stagnant water
Electrical current
Contact with dissimilar metals
Confined areas, e.g. crevices
Physical damage or wear
Extreme corrosivity due to combined effects of different influencing factors

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In Table 6 the environmental conditions given in the tables are described in more
detail. The underlying predominant corrosion categories and corrosion resistance
classes are also listed.

Table 6: Environmental conditions and their link to corrosivity categories and


corrosion resistance classes, per ISO 9223:2012.

Corrosion catego-

resistance class
ries according to

Stainless steel
ISO 9223:2012

Corrosion
Indoor applications
Dry indoor environments C1, C2 1
(heated or air-conditioned areas) without condensation,
e.g. office buildings, schools
C1, C2 1
Indoor environments with temporary condensation
(unheated areas without pollutants), e.g. storage sheds

Outdoor applications
Outdoor, rural or urban environment with C2,C3 2
low pollution
Large distance (> 10km) from the sea
Outdoor, rural or urban environment with moderate C2,C3,C4 2,3
concentration of pollutants and/or salt from sea water
Distance from the sea 1-10km
C3, C4, 3,4
Coastal areas
Distance from the sea < 1km C5, CX

C4,C5,CX 3,4
Outdoor, areas with heavy industrial pollution
Close to plants < 1km (e.g. petrochemical, coal industry)

Close proximity to roadways treated with de-icing salts


C3, C4,
Distance from roadways < 10m 3,4
C5

Special applications
Special applications Special 4,5
Areas with special corrosive conditions, e.g. road tunnels climates
with de-icing salt, indoor swimming pools, special not cov-
applications in the chemical industry ered by
(exceptions possible). C-classes

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Corrosion handbook

Selection tables for fasteners, wood nails and installation systems


Fasteners such as anchors, nails and screws are often used for single-point and
safety-relevant fixtures. Poor or limited visibility of the fasteners after installation,
the lack of the possibility to repair or replace them and the complex interaction with
the applied loads, the part to be fastened and the friction conditions in the drilled
hole (in the case of expansion anchors) make it necessary, for establishing a general
guideline, to take a conservative approach in order to minimize the risk of corrosion
of the fastener material. With zinc-coated fasteners, the end of the fasteners
lifetime coincides with the starting of base material loss of the underlying steel. The
selection table for fasteners therefore does not state a lifetime range, but gives a
general yes/no recommendation based on the building service defined in the
approval guidelines e.g. 25 or 50 years see selection tables footnotes for details.
Fasteners often form part of a buildings structure, which means that the lifetime of
the fastener is required to be equal to the design lifetime of the building.
Secondary structures such as installation supports are often not required to last
the entire lifetime of the primary structure as building services are subject to more
frequent exchanges and modifications.
Furthermore, many applications with installation channels allow repair or lifetime
extension measures, for example, through application of zinc spray. With proper
assessment of the corrosivity of the environment including the planned lifetime and
also the implementation of periodic inspection and repair intervals, coated carbon
steel products can be used suitably and economically for a wide range of applica-
tions in a wide range of surroundings.
In the case of zinc-coated installation systems and wood nails the onset of corro-
sion of the steel substrate does not cause immediate problems in terms of mechan-
ical integrity. The occurrence of around 5% of red rust on the surface is considered
to indicate the end of the period of protection provided by the zinc coating. It is
therefore possible to state a guideline range of expected lifetime for a specific
environment.

European Technical Approval metal anchors for use in concrete


For anchors, the current European Technical Approval (ETA) requires use of stain-
less steel in the corrosion resistance class III (A4 class) for outdoor applications in
general. Special applications such as road tunnels and indoor swimming pools
require an even higher grade (class IV or V). The reason for this is, of course, to
provide the user with a conservative and practical guideline for selection of a proper
material for outdoor applications. The intent of the ETA approach is to eliminate the
need for a detailed assessment of the environment and the application when strictly
following the ETA (assuming non-atmospheric corrosion issues are not present).
The user, for instance, does not have to evaluate the influence of chlorides on the
jobsite resulting from proximity to sea water or the use of de-icing salts.
However, in cases where chlorides can be neglected it is possible to go beyond the
ETA specifications. From a technical point of view, hot-dip galvanized or stainless
steel anchors in the CRC II (A2 class) are suitable for outdoor environments with
certain lifetime and application restrictions. This is based on long-term experience
with these materials. Please note that this requires a specific assessment and
deeper understanding of the application and the environment (see following tables).

Corrosion handbook page 41


Corrosion handbook

5.1. Selecting the right corrosion protection for anchors,


powder-actuated fasteners and screws

For fasteners to be perfectly satisfactory and reliable for their entire service life, all
the influencing factors must be identified before a suitable fastener can be selected.

The following table provides a general guideline for the most common applications
for fastening elements. The appropriate corrosion protection for each fastening
material is shown based on the typical atmospheric environments (see notes).

product examples
Anchors, HSA, HUS3, HUS3-HF HSA-F, HSA-R2, HUS-HR, HSA-R HST-HCR
Anchors HST, HIT-V, HIT-V-F HRD-R2 HST-R, HIT-V-R
power driven HRD HIT-Z-R, HRD-R
fasteners and
screws Screws S-DS01, S-MD Z, S-CD C, S-IT C S-MD S, S-MD SS,
S-DD01 S-MP Z S-CD S S-CD SS

Power driven X-ENP 1), X-U X-FCM-M, X-BT, X-BT-ER On demand


fasteners X-GHP, X-GN X-GR X-CR, X-FCM-R

Coating/ Carbon steel Electro Duplex-coated HDG/ sherard- A2 A4 HCR,


material with or without galvanized carbon steel ized 45-50 m AISI 304 AISI 316 e.g. 1.4529
phosphating

Environmental conditions Fastened part

Steel (zinc-coated,
Dry indoor painted), aluminium, n n n n n n n
stainless steel

Steel (zinc-coated,
Indoor with tempo- painted), aluminium
n n
n n n
rary condensation
Stainless steel
Steel (zinc-coated, 2) 2)
Outdoor with low painted), aluminium

2)
n n n
pollution
Stainless steel
Outdoor with Steel (zinc-coated, 2)
2)

moderate concen- painted), aluminium 2)
n n n
tration of pollutants Stainless steel
Steel (zinc-coated,
Coastal areas painted), aluminium, n n
stainless steel

Outdoor, areas with Steel (zinc-coated,


heavy industrial painted), aluminium, n n
pollution stainless steel

Steel (zinc-coated,
Close proximity to
painted), aluminium, n n
roads stainless steel

Special
applica- Consult experts n
tions
n = expected lifetime of anchors made from this material is typically satisfactory in the specified environment based on the typically expected lifetime of a building. The as-
sumed service life in European Technical Assessments is 50 years for concrete anchors, 25 years for power actuated fasteners, steel and sandwich panel screws, and
10 years for flat roof insulation screws.
= a decrease in the expected lifetime of non-stainless fasteners in these atmospheres must be taken into account ( 25 years). Higher expected lifetime needs a specific
assessment.
= fasteners made from this material are not suitable in the specified environment. Exceptions need a specific assessment.
1)
Outdoor exposure for up to 6 months during construction is permissible for high-strength electro-galvanized siding and decking fasteners such as the X-ENP (see instructions for
use for details).
2)
From a technical point of view, HDG/duplex coatings and A2/304 material are suitable for outdoor environments with certain lifetime and application restrictions. This is
based on long-term experience with these materials as reflected e.g. in the corrosion rates for Zn given in the ISO 9224:2012 (corrosivity categories, C-classes), the selec-
tion table for stainless steel grades given in the national technical approval issued by the DIBt Z.30.3-6 (April 2014) or the ICC-ES evaluation reports for our KB-TZ anchors
for North America (e.g. ESR-1917, May 2013). The use of those materials in outdoor environments however is currently not covered by the European Technical Assessments
(ETA) of anchors, where it is stated that anchors made of galvanized carbon steel or stainless steel grade A2 may only be used in structures subject to dry indoor conditions,
based on an assumed working life of the anchor of 50 years.

Hilti anchor channel (HAC) is available in hot-dip galvanized according to E ISO 1460:2009-10. HBC special bolts are available in electro-galvanized, hot-dip galvanized and
A4 versions. HAC may be used together with HBC in any material combination in dry indoor environments according to ETA-11/0006 (28th February 2012). When HBC are
hot-dip galvanized, they may be also used in indoor environments with temporary condensation

page 42 Corrosion handbook


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5.2. Selecting the right corrosion protection for wood


nails

Wood can be corrosive due to the organic acids it contains. Besides atmospheric
conditions, corrosive attack by the wood itself must also be considered when
selecting the type of corrosion protection for wood nails.

The following table provides a general guideline for common applications in which
wood nails are used in typical atmospheric environments for wood-to-wood
connections.

Wood Service Classes Service Service Service


in accordance with class 1 class 2 class 3
nails
EN 1995 (Eurocode 5)
Hilti GX-WF
Coating/ Carbon steel Electro HDG A21) A4
material with / without galvanized 45-50m AISI 304 AISI 316
phosphating

Environmental conditions lifetime in years

Dry indoor 20 to 50 up to 50 up to 100 n n

Indoor with temporary


10 to 50 60 to 100 n n
condensation

Outdoor with low pollution 5 to 20 40 to 100 n n

Outdoor with moderate


2 to 10 20 to 40 n n
concentration of pollutants

less
Coastal areas
than 5
10 to 30 n

Outdoor, areas with heavy less


10 to 30 n
industrial pollution than 5

Close proximity to roads n

Special
Consult experts
applications

The table above provides typically assumed service life estimations based on corrosion considerations. Other fac-
tors determining the service life of fasteners must be evaluated separately.

n = expected lifetime of nails made from this material is typically satisfactory in the specified environment based
on the typically expected lifetime of a building.
= nails made from this material are not suitable for the environment or the typical lifetime of a building is not
achieved.
1)
For nails made of A2 material, discoloration of nail heads can occur before the service life in the table above is
reached. To avoid this, use A4 material.

Certain wood species including, but not limited to, oak, Douglas fir or western red cedar, require the use of stain-
less steel nails, independent of Service Class and environmental conditions.
The use of certain wood treatments including, but not limited to, fire retardants or preservatives can change the
chemical composition of the wood and may require the use of stainless steel nails, independent of Service Class
and environmental conditions.

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Corrosion handbook

5.3. Selecting the right installation system

The typical lifetime rating of initial coatings depends on the corrosivity of the
atmosphere, which differs significantly throughout the world. For a practical
approach, Hilti differentiates between two zones:

Zone 1

Zone 2

Zone 1 is countries where air quality and climate data prove there is generally an
absence of polluted and tropical environments. Today these countries are European
countries and North America. Zone 2 countries are those outside zone 1, which
either lack the availability of reliable air quality data or the data proves the presence
of heavy pollution (especially in urban zones) and/or hot tropical climate regions.

The typical lifetime expectancy of Hilti installation systems is shown in the table below.

Installation Channel MM + MQ + MQ F MQ ASTM MI HDG MQ system MQ system


systems system MC system MC-OC MC-OC-A system stainless A2/ stainless A4/
system system AISI 304 AISI 316

Pipe Indoor pipe HDG pipe rings2 MI-UB, Stainless pipe rings3
fastening rings
1 MI-PS

Environmental conditions lifetime in years for zone 1 and zone 2

70 to100 up to100 up to100 up to100


Dry indoor 70 to100 up to100 up to100 up to100
n n

Indoor with temporary 25 to 70 40 to100 60 to 100 60 to 100


n n
condensation 25 to 70 40 to100 60 to 100 60 to 100

Outdoor with low 4 to 10 25 to 50 40 to 100 40 to 100


n n
pollution 2 to 10 15 to 60 25 to 100 25 to 100

Outdoor with mode


20 to 40 25 to 50 25 to 50
rate concentration of
10 to 40 20 to 50 20 to 50
n n
pollutants

10 to 20 15 to 40 15 to 40
Coastal areas
7 to 20 10 to 40 10 to 40
n

Outdoor, areas with


10 to 20 15 to 40 15 to 40
heavy industrial
5 to 20 10 to 40 10 to 40
n
pollution

Close proximity to
n
roads

Special
applica- Consult experts
tions
n = expected lifetime of an installation system made from this material is typically satisfactory in the specified environment
based on the typically expected lifetime of a building.
1)
Indoor pipe rings: MP-H, MP-HI, MP-LH, MP-LHI, MPN, MP-MI, MP-MIS, MP-M, MP-MXI, MP-MX, MP-PI, SDC, MP-SP
2)
HDG pipe rings: MP-MI-F, MP-M-F, MP-MXI-F, MP-MX-F
3)
Stainless pipe rings: MP-SRN, MP-SRNI, MP-MR, MP-MRI, MP-MRXI

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6. Bibliography

Internet resources
General corrosion
http://corrosion-doctors.org/

Zinc coatings
http://www.feuerverzinken.com/
http://www.galvanizeit.org/
http://www.nordicgalvanizers.com/

Stainless steel
http://www.edelstahl-rostfrei.de/
http://www.bssa.org.uk/
http://www.worldstainless.org/
http://www.euro-inox.org/ (information available in many languages)

Standards
EN ISO 8044:1999-08
EN ISO 9223:2012-02
EN ISO 9224:2012-02
EN ISO 9227:2012-05
EN ISO 16701:2008-04
ISO 20340:2009-04
EN ISO 6270-1:2001-08
EN ISO 6988:1994-10
EN ISO 3506-1:2009

Literature
G. Kreysa M. Schtze, Corrosion Handbook Volume 6: Atmosphere, Industrial Waste
Gases, Wiley VCH, 2004

P. R. Roberge, Handbook of Corrosion Engineering, McGrawHill, 2012

H. Kaesche, Corrosion of Metals: Physicochemical Principles and Current Problems,


Springer, 2003

X.G. Zhang, Corrosion and Electrochemistry of Zinc, Springer, 1996

U. Nrnberger, Korrosion und Korrosionsschutz im Bauwesen, Bauverlag, 1995

page 46 Corrosion handbook


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7. Disclaimer

All information given in this brochure is based on the tests, principles, formulas,
standards and approvals described in this brochure, current as of the date
of printing (May 2015). It applies only to applications comparable to the
conditions described. Extrapolation of the results to other environments is not
permissible. The selection guidelines and life expectancy information is based
on atmospheric corrosion only, and is intended only as an approximate guide to
assist in initial assessment. Site-specific conditions, including general corrosion
parameters (e.g., temperature, air- and water-movement, localized pollutants,
mechanical abrasion), other forms of corrosion, lifetime requirements, application
criticality, inspection programs, and local legal / code / project requirements
can significantly affect the selection process and must always be evaluated.
Significant scatter of values may also occur within the bandwidth of coating /
material performance and environmental parameters applicable to a specific
structure. Full assessment and final selection is the responsibility of the project
specialist or, respectively, the purchaser. This report must be regarded as a unit
and may be passed on to others or copied for further use only in its entirety.
As this information is intended only as a general guideline, Hilti accepts no
liability whatsoever for damage or injury resulting from use of this report.

Corrosion handbook page 47


Hilti. Outperform. Outlast.
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Hilti = registered trademark of Hilti Corp., Schaan | W 4412 0515 0-en | 2 Printed in Liechtenstein | 2015 | Right of technical and programme changes reserved S. E. & O.