You are on page 1of 7

IITJEE CHEMISTRY SAMPLE PAPER - II

Data required : Atomic Mass : Na = 23, Ba = 137, C = 12, O = 16, H = 1


Atomic Number : Fe = 26, Cu = 29, Ni = 28
SECTION I
Straight Objective Type
This section contains 8 multiple choice questions numbered 1 to 8. Each question has
4 choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

1. Consider the following nucleophiles


H2O, CH3 COO , OH, CH 3 O
(I) (II) (III) (IV)
The correct order of decreasing nucleophilicity of these species is
(a) (I) > (II) > (III) > (IV) (b) (IV) > (II) > (III) > (I)
(c) (IV) > (III) > (II) > (I) (d) (IV) > (III) > (I) > (II)

2. [X] + H2SO4 [Y], a colourless gas with irritating smell


[Y] + K2Cr2O7 + H2SO4 green solution.
The species [X] and [Y] are
(a) SO3 2 , SO2 (b) Cl , HCl
(c) S2, H2S (d) CO3 2 , CO2

3. X mL of 0.05 M solution of a double salt Na2CO3 NaHCO3 2H2O is titrated against 0.05 M
HCl. When phenolphthalein is used as indicator A mL of HCl is required and B mL of the
same acid is required (separately) when methyl orange is the indicator. Find the ratio B/A.
1
(a) 3 (b)
3
(c) 5 (d) 2

Space for rough work


4. Assume that you are using an open-end manometer filled with mineral oil rather than
mercury. What is the gas pressure in the bulb (in millimeter of Hg) if the level of mineral oil
in the arm connected to the bulb is 237 mm higher than the level in the arm connected to the
atmosphere and atmospheric pressure is 746 mm Hg? The density of mercury is 13.6 g/ml and
the density of mineral oil is 0.822 g/ml.
(a) 731.7 mm Hg (b) 983 mm Hg
(c) 509 mm Hg (d) 790.3 mm Hg

5. The cubic unit cell of Al(molar mass 27 g mol1) has an edge length of 405 pm. Its density is
2.7 g cm3. The cubic unit cell is
(a) face centered (b) body centered
(c) primitive (d) hcp

6. How many isomeric bromides having molecular formula C6H13Br on conversion into
Grignard reagent followed by treatment with water would yield 2, 3-dimethylbutane?
(a) 1 (b) 2
(c) 3 (d) 4

7. Silver acetate + I2 In CS2


(2 : 1 Ratio)
The main product of this reaction is
(a) CH3I (b) CHI3
(c) CH3COI (d) CH3COOCH3

8. In the reaction,
2CuCl2 + 2H2O + SO2 A + H2SO4 + 2HCl
A is
(a) Cu2Cl2 (b) Cu
(c) CuSO4 (d) CuS

Space for rough work


SECTION II
Reasoning Type
This section contains 4 reasoning type questions numbered 9 to 12. Each question contains
Statement-1 and Statement-2. Each question has 4 choices (a), (b), (c) and (d), out of which
ONLY ONE is correct.

Directions: Read the following questions and choose


(A) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True ; Statement-2 is not a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

9. Statement-1: Ortho-substituted anilines are normally weaker base than aniline whether the
substituent is electron releasing or electron withdrawing in nature.
Statement-2: Substituent at ortho position hinders the approach of H2O molecule to solvate
the conjugate acid due to steric crowding.
(a) A (b) B (c) C (d) D

10. Statement-1: Addition of Br2 molecule to trans-2-butene gives meso product.


Statement-2: Addition of Br2 molecule to an alkene proceeds via carbocation intermediate.
(a) A (b) B (c) C (d) D

11. Statement-1: The acidic character of hydrides of the group 16 elements increases in the
order H2O < H2S < H2Se < H2Te
Statement-2: Oxygen is more electronegative than sulphur.
(a) A (b) B (c) C (d) D

Space for rough work


12. Statement-1: Enthalpy changes are positive when Na2SO4. 10 H2O and salts like NaCl, KCl
etc. which do not form hydrates are dissolved in water. But enthalpy changes are
negative when anhydrous salts capable of forming hydrates are dissolved in
water.
Statement-2: The difference in the behaviour is due to large difference in the molecular
weights of hydrated and anhydrous salts. The substances with larger molecular
weights usually show positive enthalpy change on dissolution.
(a) A (b) B (c) C (d) D

SECTION III
Linked Comprehension Type
This section contains 2 paragraphs C13 C18. Based upon the paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (a), (b), (c) and (d), out of which
ONLY ONE is correct.

PassageI
The electrons in a poly-electronic atom are filled one by one in order of increasing energy
level. The energy of subshells and orientation of orbitals depends upon the values of three
quantum numbers (i.e., n, l and m respectively) derived from Schrodinger wave equation.
However, the different orbitals of a subshell possess same energy level and are called
degenerate orbitals but their energy level changes in presence of magnetic field and the
orbitals are non-degenerate. A spectral line is noticed if an electron jumps from one level to
other. The paramagnetic nature of element is due to the presence of unpaired electron(s).

13. Which in each pair is electronically most stable ion: Cu+ or Cu2+ and Fe2+ or Fe3+
(a) Cu+, Fe3+ (b) Cu2+, Fe3+
2+ 2+
(c) Cu , Fe (d) Cu+, Fe2+

14. The total magnetic moment of Ni2+ ion is


(a) 6 BM (b) 8 BM
(c) 15 BM (d) 12 BM

Space for rough work


15. The possible number of spectral lines when an electron can jump from 5th shell to 2nd shell is
(a) 4 (b) 2
(c) 3 (d) 6

Passage-II
Any nucleophilic substitution reaction proceeds via two processes:
(a) SN1 i.e. substitution nucleophilic unimolecular
(b) SN2 i.e. substitution nucleophilic bimolecular
The examples which serve for these are the solvolysis of alkyl halides. Let solvolysis of tert-
butyl bromide takes place via two conditions given below.
Reaction A: Here tert-butyl bromide was refluxed with ethanol containing small amount of
sodium ethoxide. The reaction was proceeding with a half life of only a few minutes and this
resulted in products (A) an ether and (B) C4H8. The rate for the reaction is given by the
expression,
Rate = k1 [tert-butyl bromide] + k2 [tert-butyl bromide] [C2H5O]
Reaction B: Here tert-butyl bromide was refluxed with a mixture of solvents containing 70%
ethanol and 30% water.

16. The number of products possible for the second reaction is


(a) 1 (b) 2
(c) 3 (d) reaction will not occur

17. Here the two constants k1 and k2 respectively for the reaction A are for
(a) SN1 and SN2 respectively. (b) SN1 and E2 respectively.
(c) E1 and SN2 respectively. (d) E1 and SN1 respectively.

18. During substitution reactions with weak base via carbocation mechanism
(a) SN1 predominates (b) SN2 predominates
(c) E1 predominates (d) E2 predominates

Space for rough work


SECTION IV
Matrix Match Type
This section contains 2 questions. Each question contains statements given in two columns
which have to be matched. Statements (A), (B), (C), (D) in Column I have to be matched
with statements (1, 2, 3, 4) in Column II. One statement in first column has one or more than
one match with the statements in second column. The answers to these questions have to be
appropriately bubbled as illustrated in the following example.
If the correct matches are A 1,3, B 3, C 2,3 and D 2,4, then the correctly bubbled
4 4 matrix should be as follows:
1 2 3 4
A 1 2 3 4
B 1 2 3 4
C 1 2 3 4
D 1 2 3 4

1.
Column I Column II
(A) Variation of equilibrium constants with 1. Kirchoffs equation
temperature
(B) Hneutralisation of HCl. 2. Hesss law
(C) Law of conservation of energy. 3. Vant Hoff equation
(D) Variation of heat of reaction with 4. 57.2 kJ/equivalent
temperature

2.
Column I Column II
(A) Cellulose 1. Anomers
(B) -D glucose and -D-glucose 2. Epimers
(C) Glucose and Mannose 3. Polymer
(D) Protein 4. can be hydrolysed

Space for rough work


SECTION V
Subjective or Numerical Type

The answer to these questions would lie between


0 to 9999. For any answer all four bubbles must be
filled, for example if you plan to answer as 16 then fill
0016 and if you plan to answer 0 then fill 0000 in the
grid provided in answer sheet. In case the answer is a
fraction, round it off to the nearest whole number. For
example, 725.3 is rounded off to 0725. Any incomplete
filling will be considered as incorrect filling.
Illustration: If you want to fill 2379 as your answer
then it will be filled as

1. How many mole of electrons are required to reduce 1.5 mole of nitro-benzene into aniline,
if current efficiency, in this experiment is 50%.

2. What is the pH of a mixture obtained by mixing 75 ml M/5 HCl and 25 ml M/5 NaOH
aqueous solution?

Space for rough work