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2012 IACSIT Coimbatore Conferences

IPCSIT vol. 28 (2012) (2012) IACSIT Press, Singapore

Properties of Concrete with Municipal Solid Waste Incinerator


Bottom Ash

Martin Keppert 1, Zbyek Pavlk1, Robert ern 1+ and Pavel Reiterman 2


1
Department of Materials Engineering and Chemistry, Faculty of Civil Engineering, Czech Technical
University in Prague, Czech Republic
2
Experimental Center, Faculty of Civil Engineering, Czech Technical University in Prague, Czech Republic

Abstract. The appropriate utilization of Municipal Solid Waste Incineration (MSWI) residues is a
worldwide studied topic over the last decades. One of the possibilities is to use MSWI ashes in concrete
production, as it is done with coal combustion products. The bottom ash features the most convenient
composition for this purpose, and it is available in highest amounts among the MSWI ashes. Untreated
bottom ash was used as partial replacement of sand in concrete; strength was not negatively affected up to
10 % replacement, the prepared concrete had sufficient durability. The longer-time behavior of concrete with
bottom ash differed from the control material due to presence of sulfates and chlorides in bottom ash.
Keywords: municipal solid waste incineration; bottom ash; concrete; compressive strength; durability

1. Introduction
Incineration of municipal solid wastes is an effective way (when compared with landfilling) of reduction
of the non-recyclable waste amount; the waste weight reduction by incineration is down to 30 % of initial
mass, the volume reduction is even more effective (about 10 %). Another positive aspect of the incineration
can be energy production (electricity, heat); the caloric content of municipal waste is comparable with lignite.
The unwanted but unavoidable outcomes from incineration are represented by bottom ash (BA; about 27
wt. % of incinerated waste) and air pollution control (APC) residues (fly ashes; ca 3 wt. %). The generated
amount and properties of particular ashes differ from plant to plant in dependence on the applied incineration
and air pollution control technology, composition of processed wastes and even on year season. Especially
the APC residues bring significant environmental risks due to heavy metals and Persistent Organic Pollutants
(POPs) content. The APC management strategies and treatment methods were summarized in [1]. Bottom
ash usually does not have to be treated because of its lower heavy metals and POPs content. BA can be
dumped or utilized as a material; common is employment of bottom ash as embankment material but even
this application is often matter of green objections due to possible leach out of heavy metals into
surroundings during the long time environmental exposure. Hence it would be attractive to use BA as a raw
material for a product where heavy metals would be immobilized and thus such product would be
environmental safe. Such requirements are fulfilled well by cementitious composites [2]. The BA can be
used either as concrete admixture or as raw material for cement clinker production [3].
Pera et al. [4] used MSWI bottom ash as partial coarse aggregates replacement in concrete; they
proposed to treat the BA by NaOH in order to prevent aluminium induced hydrogen evolution which causes
loss of strength. Such application of treated BA increased durability of concrete but still reduced its strength.
Bertolini et al. [5] compared water washing and dry and wet grinding as MSWI BA treatment; only the latter
process to prevent the concrete strength loss. Ferraris et al. [6] proposed melting MSWI BA at 1450 C and

+
Corresponding author. Tel.: +420224355044; fax: +420224354446.
E-mail address: cernyr@fsv.cvut.cz

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grinding the resulting slag to particles smaller than 90 m which can be used and filler or supplementary
cementitious material. Similar approach studied Lee and Rao [7]; they added to MSWI ashes also scrap glass
and the resulting slag was ground to particles finer than 38 m. This material was used for production of
blended cement [8]. Rmond et al. [9] studied effect of untreated MSWI fly ash on technological properties
of cement mortars. The fly ash caused significant increase of setting time and decrease of workability and
strength.
The goal of the present work is to evaluate influence of untreated MSWI bottom ash on technologically
important properties compressive strength, bulk density and durability.

2. Experimental Methods
The granulometry of MSWI bottom ash (BA) was determined by standard sieving analysis [10]. The
compressive strength of 7, 28 and 90 days old concrete (cubes 150 mm) was measured using the common
test described in [11]. Resistance of concrete to freezing and thawing action was determined according [12]
by means of temperature cycling; one cycle consisted in 4 hours at -20 C and 2 hours at 20 C; the
compressive strength was measured after given number of cycles.

3. Materials
The subject of study was bottom ash (BA) collected in the winter period of 2009 in a modern
incineration facility in Czech Republic. The BA has been quenched in water after leaving the grate, and steel
pieces were removed by magnetic separation. The generated BA from incinerator involves wide range of
particles size; only the fraction 0-4 mm was used in the present work. The ash was dried before experiments.
The content of major components (in form of oxides) is presented in Tab. 1. It was determined by XRF
spectroscopy by apparatus Thermo ARL 9400 XP.
Table. 1: Content of major oxides in bottom ash (weight %).

SiO2 33.5
Al2O3 15.8
Fe2O3 8.4
CaO 19.4
MgO 2.0
SO3 9.3
ZnO 0.8
Na2O 3.6
K2O 1.9
TiO2 1.5
Cl 1.1

Nowadays the BA is (in this particular incinerator) mixed with treated fly ashes and used as backfill and
embankment material. An alternative use as fine aggregates in concrete was tested in this paper. Series of
concrete samples was prepared according Tab. 2. Ordinary Portland cement CEM I 42.5 R was used as
binder; natural aggregates were siliceous sand and gravel. The fresh concrete mixture was casted into
standard cubes of edge 150 mm and stored in water to age 7, 28 or 90 days. The reference specimens (C0)
were stored separately in order to prevent possible negative effects of chlorides and sulfates leached out form
the C5-C15 specimens.
Table. 2: Composition of concrete mixtures with different level of fine aggregates replacement by BA.

Natural aggregates
Material Cement BA 0-4 4-8 8-16 w/c
kg/m3 kg/m3 kg/m kg/m kg/m3
3 3

C0 400 0 607 260 867 0.52


C5 400 30 577 260 867 0.52

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C10 400 61 546 260 867 0.52
C15 400 91 516 260 867 0.52

4. Results and Discussion


The chemical composition of BA (Tab. 1) is highly unfavorable in order to be used in cementitious
products. The sulfate content is very high when compared with published values; the chloride content is
within common range of bottom ashes [2, 4]. Obviously the BA does not fulfill the standard requirements on
sulfate and chloride content in aggregates for concrete [13]. On the other hand, the grading curve (Fig. 1) of
studied 0-4 mm BA fraction is relatively close to granulometry of natural siliceous 0-4 mm sand. The fines
content is higher than in natural sand but the fineness is not sufficient to be considered microfiller.

100

BA
80
Sand
Cumulative passing [%]

60

40

20

0
0.01 0.1 1 10
Grain size [mm]

Fig. 1: Grading analysis of bottom ash and sand 0-4 mm.

60 2000

50
Compressive strength [MPa]

Bulk density [kg/m3]

40

30 1900

20
Compressive
strength
10
Bulk density

0 1800
0 5 10 15
BA sand replacement [%]

Fig. 2: Compressive strength (28 days) and bulk density of mixtures C0 to C15.

The dependence of concrete compressive strength upon level of sand replacement in plotted in Fig. 2.
The replacement up to 10 % does not influence the strength negatively. Bulk density (Fig. 2) is slightly
decreasing with the BA content but any visible expansion or spalling caused by aluminium-induced
hydrogen evolution [4, 14] has not been observed. It may be explained by fact that studied BA is quenched
by water after leaving the grate; the quench water is naturally alkaline (due to bottom ash soluble alkaline

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components) and present aluminium reacts already during this operation. Another (auxiliary) reason might
be relatively low consumption of aluminium wrappage in Czech Republic.

70

60

Compressive strength [MPa]


50

40

30

C0
20
C10

10

0
0 30 60 90
Time of curing [days]

Fig. 3: Evolution of compressive strength upon time of water curing of reference mixture C0 and BA containing C10.

Since the strength of C10 has been about the same as in case of reference C0, this material has been
chosen for more detailed characterization. The evolution of compressive strength upon time (Fig. 3) reveals
that up to 28 days the rate of strength increase of the reference mixture and C10 has been comparable but
later the hydration of reference concrete has continued while the strength of BA containing material has
increased only moderately. The frost resistance tests results (Fig. 4) showed a very good durability of BA
containing concrete which has sustained 125 freezing cycles without decrease of strength and integrity.
Beyond this, the frost resistance experiment has demonstrated again the difference of hardening course
which was already observed C10 specimen reached its maximum strength earlier than reference C0 which
hydrated significantly also during the freezing/thawing cycles.

70

60
Compressive strength [MPa]

50

40

30

20

10

0
C0 C10

28 days 75 cycles 125 cycles

Fig. 4: Compressive strength after 75 and 125 freezing thawing cycles.

It can be explained by different hydration mechanism of cement clinker minerals in presence of chlorides
and sulfates from bottom ash [15]; they cause hydration retardation on the beginning of hydration (ettringite
and its chloride analogues hydrated chloroaluminates). Later the hydration proceeds faster but the final
composition of hydrated cement binder is different from the standard cement with only low content of
sulfates and almost none chlorides. Material C10 hydrated and reached its final strength faster but this final

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strength is lower than in case of reference C0. Such behavior was observed also by authors [9] who used
untreated MSWI fly ash with high content of chlorides and sulfates while in other papers dealing with treated
ashes the strengthening rate was similar for reference and ash-containing mixtures [5, 6]. Obviously concrete
made from untreated ashes is excluded from reinforced structures.

5. Conclusions
The untreated MSWI bottom ash (fraction 0-4 mm) was used as partial sand replacement in concrete.
This ash, by its chemical composition, does not fulfill the standard requirements on concrete admixtures but
the prepared concrete had acceptable properties. The 28-days compressive strength of material with 10 %
sand replacement was comparable with the reference concrete; the 90-days strength was lower which can be
explained by different hydration process. The frost resistance of bottom ash containing concrete was very
good. The prepared concrete contained relatively low content of MSWI ash; this approach represents a
compromise between the ecological request on a practical utilization of MSWI ashes and properties of the
acquired product. Higher ash dosage without any accompanied loss of concrete properties would be
possible only when the ash would be treated in some way (e.g. by vitrification) but in such case there would
arise additional costs suppressing the MSWI ashes utilization attractiveness for building industry.

6. Acknowledgement
This research has been supported by the Czech Science Foundation, under grant No. P104/11/0438.

7. References
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methods. International Solid Waste Association, Copenhagen, 2008.
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municipal waste incineration ashes, Paliva, vol. 2, pp. 113-118 (in Czech).
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Sustainability, vol. 2, 2010, pp. 1943-1968.
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[10] SN EN 933-2, Tests for geometrical properties of aggregates. Determination of particle size distribution. Test
sieves, nominal size of apertures, 1996.
[11] SN EN 12390-3, Testing hardened concrete Part 3: Compressive strength of test specimens, 2002.
[12] SN 73 1322, Determination of concrete frost resistance, 1968, change Z1 (2003).
[13] SN EN 12620, Aggregates for concrete, 2006.
[14] U. Mller and K. Rbner, The microstructure of concrete made with municipal waste incinerator bottom ash as
an aggregate component, Cement and Concrete Research, vol. 36, 2006, pp. 1434-1443.
[15] P. Ubbriaco and D. Calabrese, Hydration behaviour of mixtures of cement and fly ash with high sulfate and
chloride content, Journal of Thermal Analysis and Calorimetry, vol. 61, 2000, pp. 615-623.

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