UNIVERSIDAD NACIONAl DE INGENIERIA

Facultad de Ingenieria de Petr6leo, Gas Natural y Petroquimica
Escuela.Profesional de Ingenieria Petroquimica
PRAcTICA CALIFICADA N° 01
CURSO: BALANCE DE MASA Y ENERGiA (PQ-313-A)

Profesor Victor Pretell
Alumno ................................................... C6digo: .
Cicio Acadernico .: 2017-1
Ola y hora 05 de Abril del 2017 10:00 - 12:00

1.- Un flujo de 55 mol/min de metano se quema con aire seco. Un analisis-parcial del gas de
combusti6n muestra que la fracci6n molar del nitr6geno es 0.85 en base seca. Si la conversi6n
del metano es del 90%, la relaci6n molar del C02 al CO es 10 Y el exceso de aire es 23%.
Calcule (3 ptos c/u):
a.- EI flujo de gas de combusti6n seco y la fracci6n molar del CH4,CO2y CO en base seca.
b.- EI flujo molar de aire alimentado y la fracci6n molar del agua en el gas de combusti6n.

2.- Se produce formaldehido haciendo reaccionar vapor de metanol caliente y aire. Dentro del
reactor el hidrogeno producido reacciona con el oxigeno para formar agua. EI metanol se
convierte en su totalidad, los productos de la reaccion pasan a un separador donde por el
fondo se retira el formaldehido y por el tope los gases, estos gases contienen nitr6geno, agua
y 667 moles de hidrogeno. Si la carga de metanol es 1000 mol/h y ocurren las reacciones
mostradas: CH30H ---- > HCHO + H2
H2 + 0.502 --- > H20
a.- EI diagrama de flujo y el analisis de grados de libertad basado en el grado de avance de
la reacci6n. (3 ptos.)
b.- EI flujo d~ formaldehido y la fracci6n mol de hidrogeno en el gas de salida del separador
'~\l...'O ~S~
3.- Se alimenta una mezcla que contiene 5% de propano y 95 de propileno a un j : t para
producir butanal (C4HsO)sequn: C3H6+ CO + H2 --- > C4HsO.Se consigue una conversi6n
total de 0.9. EI propano es un inerte yes purgado para evitar su acumulaci6n en el proceso.
La conversi6n por paso del propileno es 0.3. La producci6n de butanal se mantiene en 180
kmollh. EI hidrogeno y mon6xido de carbono que no reacciona se separan y se envian a
tanques de almacenamiento. Calcule el flujo de la alimentaci6n fresca de propano/propileno,
el % mol de inertes en la corriente de purga y el flujo total de la carga alimentada al reactor.
(7 ptos.)

Indicaciones: Se permiten tablas de conversiones, formulario y anexos del Felder.

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