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1/28/2015 XIICHEMISTRYSTUDYMATERIAL

Tuesday,February11,2014

Top200MCQinChemistry
1.Thephenomenonwhichprovestheparticlenatureofelectronis
a)diffractionb)interferancec)photoelectric
effectd)alltheabove
2.Thewaveassociatedwithaparticleiscalledas
a)electromagneticwaveb)matterwavec)micro
waved)alltheabove
3.IfthemomentumofaparticleBishalfofA,thenwavelengthofBis
equalto
a)A/2b)Ac)
2Ad)A2
4.deBroglieconceptissignificantfor
a)electronsb)protonsc)neutrons
d)alltheabove
5.Theenergyrequiredtoshiftanelectronfromn=1ton=is
a)+1312kJmol1b)+146kJmol1c)1312
kJmol1d)zero
6.Thenodalplanefor2pxorbitalis
a)XYplaneb)YZplanec)XZplane
d)alltheabove
7.Whichofthefollowingmoleculeishavingshortestbondlength
a)hydrogenb)nitrogenc)oxygen
d)lithium
8.Themoleculewithgreaterbonddissociationenergyis
a)H2b)Li2c)
O2d)N2
9.Energylevelsofthemolecularorbitalshavebeendetermined
experimentallyby
a)Crystallographicstudiesb)Xrayanalysisc)spectroscopic
studiesd)None
10.Whichofthefollowingwillhavelowestboilingpoint
a)onitrophenolb)mnitrophenolc)pnitro
phenold)alltheabove
11.Thecorrectorderofelectronegativityis
a)F>O>Nb)O>F>Nc)N>O>F
d)F<N<O
12.Thenumberofnodesinsorbitalofanyenergylevelisequalto
a)2n+1b)n+1c)2n1
d)n1
13.G.P.Thomsonperformedexperimentstoprovethewavenatureof
electronsusing

a)Nickelcrystalb)silverfoil
14.ThehybridisationinICl4is
a)sp3db)sp3d3
15.Whichofthefollowingisaweakbond
a)covalentbondb)hydrogenbond

c)goldfoild)zincsuphide

c)sp3d)sp3d2

c)ionicbondd)dipoledipoleinteractions

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16.Paulingsmethodofcalculationofionicradiiisnotapplicablefor
a)NaFb)KClc)CsCld)
RbBr
17.Thecorrectorderofsuccessiveionisationpotentialsis
a)I1>I2>I3b)I1=I2=I3c)
I1<I2<I3d)none
18.Thecontributionofotherelectronspresentin1sorbitaltoSvalue
is
a)0b)0.35c)0.85d)
0.30
19.Themetalwithnegativeelectronaffinityis
a)Goldb)Copperc)Zinc
d)Silver

20.Themetalwithcomparitivelyhighelectronaffinityis
a)Chlorineb)Cesiumc)Gold
d)Cadmium
21.Theioniccrystalinwhichtheanionandcationareisoelectronic
withneonis

a)NaFb)KClc)RbCld)
CsI
22.Inertpaireffectisacharecteristicfeatureofelements
a)sblockb)pblockc)dblock
d)fblock

23.Chloroplumbicacidis
a)H4PbCl2b)H2PbCl2c)
HPbCl2d)H2PbCl4
24.Theoxyacidofphosphoruswhichisapowerfulreducing
agent(reducessilvernitrate)is
a)H3PO3b)H3PO4c)
H4P2O7d)PH3
25.Theoxyacidofphosphoruswhichgivesyellowprecipitatewith
AgNO3is
a)H3PO3b)H3PO4c)
H4P2O7d)PH3
26.Thecompoundwithrottenfishodouris
a)P2O3b)H3PO3c)
PH3d)P2O5
27.Thehalogenwhichisthestrongestoxidisingagentis
a)fluorineb)chlorinec)bromine
d)iodine
28.Whichofthefollowingisnotpossible
a)I3b)F3c)
Br3d)Cl3
29.Duringthehydrolysisofinterhalogencompound,thelarger
halogenforms
a)halideionb)oxyhalideionc)bothaandbd)
none
30.Whichofthefollowinginertgasisnotfoundinair
a)heliumb)neonc)krypton
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d)radon
31.Theelementwhichisextremelytoxicinboronfamilyis
a)galliumb)indiumc)thalium
d)boron
32.Thecompoundwithgarlictasteis
a)P2O3b)H3PO3c)
PH3d)P2O5
33.Thecompoundusedassouringagentinthepreparationofsoft
drinksis
a)H3PO3b)H3PO4c)
H4P2O7d)P2O5
34.Themixturewhichisusedtopreventbends
a)He/Neb)Ar/N2c)
Ar/O2d)He/O2
35.Thecompoundusedtopreventknockingis
a)Pb3O4b)Pb(OH)2c)
Pb(C2H4)4d)PbO
36.Thecatalystusedinthemanufactureofpolytheneis
a)V2O5b)Cr2O3c)
TiCl4d)Fe2O3
37.Thetransitionmetalwhichshowszerooxidationstateinits
compoundis
a)Scb)Cuc)Nid)
Os
38.ThemagneticmomentinBMforTi3+isequalto
a)2b)8c)3d)
15
39.Whichofthefollowingtransitionmetalisattackedbyalkali
a)copperb)zincc)silverd)
chromium
40.Aquaregiacontainscon.HClandcon.HNO3intheratio
a)3:9b)1:3c)3:1d)
1:2

41.18caratgoldcontainspartsbyweightofcopper
a)fourb)eightc)sixd)
eighteen

42.Thecolourofpottasiumdichromateinalkalinesolutionis

a)orangeredb)pinkc)yellow
d)colourless
43.Inacidicmedium,onemoleofK2Cr2O7givesatomsof
oxygen
a)fiveb)onec)threed)
six
44.Bordeauxmixturecontains
a)ZnSO4+H2SO4b)CuSO4+limec)AgNO3+
limed)CuSO4+NH4OH
45.TheoxidationstateofFeinFe(CO)5is
a)+3b)+2c)+5d)
0
46.Duringsmeltingprocessofcopperpyrites,thematteformedchiefly

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contains
a)Cu2S+FeSb)FeSiO3c)Cu2S
+FeOd)Cu2S+Cu2O
47.Blistercoppercontains%impurities
a)1b)2c)3d)
98
48.Gunmetalisanalloycontaining
a)Cu+Snb)Cu+Znc)Cu+Sn+Zn
d)Cu+Sn+Ni
49.Themetalusedforgalvanizingironsheetsis
a)copperb)chromiumc)siver
d)zinc
50.Thecompoundoftransitionmetalwhichdecomposeonexposure
tolightis
a)AuCl3b)CuSO4c)
AgNO3d)ZnCO3
51.Whichofthefollowingisaferromagneticsubstance
a)Scb)Tic)Znd)
Fe
52.Whichofthefollowingarealsoknownasrareearthelements
a)sblockb)pblockc)dblock
d)fblock
53.Whichofthefollowinghasthemaximumtendencytoactas
reducingagent
a)Lub)Cec)Pmd)
La
54.Whichofthefollowinghydroxideismostbasic
a)La(OH)3b)Ce(OH)3c)
Nd(OH)3d)Lu(OH)3
55.Themajorconstituentofmishmetalsis
a)ceriumb)lutitiumc)lanthanum
d)neodimium
56.ThecolourofU4+ionis
a)redb)yellowc)greend)
colourless
57.Uraniumexhibitsmaximumoxidationstatein
a)UO2b)
UF6c)UO2Cl2d)bothb
andc
58.Theexistenceofanactinideseriesanalogoustothelanthanide
serieswaspostulatedby
a)NeilsBohrb)MaryCuriec)HenryBecquerel
d)PierreCurie
59.Theactinidewhichispresentasanimpurityalongwithlanthanides
inmonozitesandis
a)Acb)Uc)Thd)
Pu
60.Whichofthefollowingiscalledaslatticecompounds
a)simplesaltb)acomplexc)doublesalt
d)alltheabove

61.Whichservesasalewisacidinacomplexcompound
a)Centralmetalionb)ligandc)cation
d)anion
62.ThenumberofClionsformedby[Cr(H2O)5Cl]Cl2.H2Oon
reactionwithAgNO3is
a)1b)2c)
3d)0
63.Geometricalisomersarenotpossibleforcomplex
a)octahedralb)tetrahedralc)squareplanar
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d)none
64.ThechelatingligandusedtoforminsolublecomplexofNickelis

a)enb)oxinec)DMGd)
Py
65. The masking agent used to remove a metal ion which
wouldinterferewiththeanalysisofasecond
metalionis
a)enb)CNc)oxined)
EDTA
66.Ifthehalflifeofasubstanceis100sec,itsaveragelifeis
a)1.44secb)50secc)144sec
d)100sec
67.Theradioactivedecayseriesfinallyresultsintheformationof
stableisotopeof
a)leadb)thoriumc)actinium
d)bismuth
68.Nuclearfusionreactiontakesplaceatveryhightemperatureof
about
a)10Kb)1010Kc)108K
d)1033K
69.Theisotopeusedinthedetectionofeyetumoursis
a)15P32b)53I131c)80Hg197d)11Na24
70.Radioisotopeswhichareusefulinindustryandinagricultureis
a)15P32b)27Co60c)80Hg197d)38Sr90
71.Radiocarbondecaysby
a)positrondecayb)decayc)decay
d)none
72.Actiniumdecayseriesisknownas
a)4nseriesb)4n+2seriesc)4n+1series
d)4n+3series
73.Innuclearreactions__________is/arebalancedonbothsides
a)massb)numberofatomsc)mass
numberd)mass&atomicnumber
74.Afossilwilllosehalftheamountofcarbon14presentinitsliving
stateinabout
a)6500yearsb)5700yearsc)4700years
d)6700years
75. In radio carbon dating,the age can be determined by
knowingthenumberof_______particles
emittedpergramperminute
a)+1e0b)
c)d)6C14
76.ThewavelengthofXraysisintheorderof
a)108cmb)108mc)108cm
d)108m
77.InBraggsspectrometermethod,whichofthefollowingarein
theratio1:2:3
a)1:2:3b)sin1:sin2:sin3c):
:dd)d1:d2:d3
78.Inioniccrystalstheionsareheldby
a)dipoledipoleforceb)coulombicforcec)Vanderwaals
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forced)alltheabove
79.Theioniccrystalwithcoordinationnumberequaltofouris
a)CsClb)FeSc)ZnSd)
NaCl
80.Elementslikesiliconandgermaniumexhibitappreciable
conductivityuponadditionofimpuritiesas
a)Arsenicb)Bismuthc)Borond)
botha)andc)

81.ThecrystalusedasathreedimentionaldiffractiongratinginLaues
experimentis
a)Nickelb)Zincsulphidec)Sodiumchloride
d)Cesiumchloride
82.Theforcewhichoccurinallkindsofmolecularsolidsis
a)coulombicforceb)Vanderwaalsforcec)dipoledipole
forced)alltheabove
83.ThenumberofcesiumchlorideunitsperunitcellofCsClis
a)1b)2c)3
d)4
84.Glassesareregardedas
a)supercooledliquidb)amorphoussolidsc)optically
isotropicd)alltheabove
85.Anexampleforcovalentcrystalsis

a)iceb)diamondc)sodium
chlorided)copper
86.Inafccarrangement,thecorneratomsareAtype
andthoseatfacecentresareBtype.The
simplestformulaofthecompoundis
a)
AB2b)A3B8c)AB3d)
AB4
87.Thestandardentropiesofeitherelementsorcompoundsatany
temperatureabove00Kis
a)zerob)positivec)
negatived)infinite
88.WhichofthefollowingwillnotobeyTroutansrule
a)CCl4b)H2Sc)
CHCl3d)H2O
89.Standardfreeenergiesofformationofelementsaretakenas
a)unityb)zeroc)
infinityd)none
90.Inanequilibriumreactionforwardreactionisfavouredwhen
a)Q>Kcb)Q=Kcc)Q<
Kcd)none
91. In an equilibrium reaction,if the number of moles of
gaseousproductsarelesserthanthenumber
ofmolesofgaseousreactants,then
a)Kp>Kcb)Kp<Kcc)Kp=
Kcd)none
92.ForthedissociationofPCl5reaction,thedegreeofdissociation(x)
isproportionalto
a)Pb)1/Pc)
1/Vd)Bothaandc

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93.Theoptimumtemperaturemaintainedincontactprocessisnearly
a)5005500Cb)3005000Cc)400
4500Cd)70012000C
94.Therateequationfor,2HCrO4+6I+14H+2Cr3++
3I2+8H2Ois
r=k[HCrO4][I]2[H+]2,theorderofthereactionis
a)1b)2c)
3d)5
95. For the decomposition of H2O2 reaction,the progress of
thereactionisfollowedbytitratingequal
volumesofreactionmixtureagainststandard
a)NaOHb)HClc)
KMnO4d)alltheabove
96. In acid catalysed hydrolysis of ester,the rate of the
reactionisfollowedbytitratingthereaction
mixtureagainststandard
a)NaOHb)HClc)
KMnO4d)alltheabove
97.Thenumberofmolesofwaterpresentin1litreis
a)18b)1c)
55.55d)1000
98. Keeping the concentration constant,when measured at a
temperature10Kgreaterthantheinitial
temperature,theratebecomes
a)Sameb)twotimesgreaterc)twotimes
lowerd)tentimesgreater
99.ForArrheniusequation,aplotoflogkagainst1/Tgivesastraight
linewithslopeequalto
a)Ea/Rb)Ea/2.303Rc)Ea/2.303
Rd)2.303Ea/R
100.HigherthevalueofEa,therateofthereactionis
a)higherd)moderatec)
slowerd)zero

101.Thetimerequiredtocomplete1/uthfractionisindependentof
a)rateconstantb)initialconcentrationc)halflife
periodd)alltheabove
102.Whichofthefollowinggasesareadsorbedmoreeasily
a)hydogenb)oxygenc)
chlorined)nitrogen

103.Whichofthefollowingprocessishomogeneouscatalysis

a)Habersprocessb)Contactproces

c)Ostwaldsprocessd)leadchamberprocess

104.Theoxidationofsodiumsulphitebyairisretardedby
a)Glycerineb)As2O3c)
alcohold)H2S
105.IntheoxidationofoxalicacidbyKMnO4,theautocatalystis
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a)K2SO4b)KMnO4c)
MnSO4d)H2SO4
106.Thecatalyticpoisonusedincontactprocessis
a)Mob)
As2O3c)H2Sd)V2O5
107.TheintermediateformedinthecatalyticoxidationofSO2toSO3
inleadchamberprocessis
a)NOb)O2c)
NO2d)SO
108.ThepromoterusedinBoschsprocessforthemanufactureof
hydrogenis

a)Nickelb)Chromicoxidec)ferricoxide
109.Whichofthefollowingisacrystalloid
a)gelatinb)sugarc)albumen
110.Anexampleforaerosoltypeofcolloidis
a)cloudb)hazec)mist
111.Silverchloridecanbeconvertedintosolbyadding
a)HClb)H2SO4
c)NaOH
112.ThecolourofAs2S3solis
a)redb)blackc)yellow
113. Electrodialysis method is not applicable for impurities
like
a)ureab)sugarc)HCl
114.Thecolloidusedincuringkalazaris
a)argyrolb)milkofmagnesiac)colloidalgold
115.AnexampleforW/Otypeemulsionis
a)milkb)butterc)vanishingcream
116.TheemulsifyingagentusedtostabiliseO/Wtypeemulsion
is
a)lampblackb)longchainalcoholsc)protiens
117.Emulsionscanbebrokenintoconstituentliquidsby
a)heatingb)freezingc)centrifuging
118.Anexampleforsemiconductorsis
a)benzeneb)glassc)cobaltoxide

d)Molybdenum

d)glue

d)alltheaboved)KOH

d)colourless

d)bothaandb

d)colloidalantimony

d)alltheabove

d)alltheabove

d)alltheabove

d)none

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119.Theenthalpyofneutralisationofastrongacidbystrongbaseis
equalto
a)57.32kJ/molb)22.0kJ/molc)47kJ/mol
d)57.32kJ/mol
120.Whichofthefollowingshowsabnormalcolligativeproperties
a)sugarb)ureac)NaCld)
alltheabove

121.Forstrongelectrolytes,thedegreeofdissociation()isequalto
a)0.1b)0c)1.0d)
infinite

122.AccordingtoOstwalddilutionlaw,theconcentrationofH+for
weakelectrolytesisgivenby
a)Ka/Cb)Ka.Cc)2.C
d)2/C
123.Equivalentconductanceisequaltomolarconductancefor
electrolyteslike
a)AlCl3b)K2SO4c)
NaCld)alltheabove
124.UsingDebyeHuckelOnsagarequation,theplotof
CversusCforstrongelectrolytesgives
interceptequalto
a)A+Bb)1c)
d)

125.Thequantityofelectricityneededtodeposit1gmequivalentof
Al3+is
a)1Fb)2Fc)
3Fd)0.5F
126.ThedegreeofdissociationofAgClisreducedbyadding
a)NaFb)NH4OHc)
NaCld)CH3COONa
127.Thevalueofionicproductofwaterat298Kis
a)1014mol2dm6b)107mol2dm6c)
1014mol2dm6d)107mol2dm6
128.Whichofthefollowingisnotabuffersolution
a)CH3COOH+CH3COONab)NH4OH+NH4Clc)
H2SO4+Na2SO4d)none
129.Forabuffersolutionhavingequimolaramountsofacidandsalt
a)pH=pKab)pH=pOHc)pH=
1d)pKa=0
130.ThepHofbuffercontainingequimolaramountsofaceticacidand
sodiumacetateis

a)1.0b)14.0c)4.77
131.ThepHrangeofphenolpthalienindicatoris
a)6.88.4b)3.14.4c)4.46.2
132.ThesuitableindicatorforthetitrationofCH3COOH Vs
NH4OHis
a)methylorangeb)phenolpthalienc)phenol

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red
133.Thecarbinolnameofsecbutylalcoholis
a)dimethylcarbinolb)isopropylcarbinolc)ethylmethyl
carbinol
134.Thealcoholwhichiscalledwoodspiritis
a)methylalcoholb)ethylalcoholc)benzylalcohol

d)0

d)8.310

d)none

d)trimethylcarbinold)phenol

135. When alcohols are converted to alkyl chlorides by


thionylchlorideinpresenceofpyridine,the
reactionbelongsto
a)SN1b)
SN2c)
SNid)none
136.Inbreathanalysistesttheoxidationstateofchromiumin
potassiumdichromatechangesfrom
a)IIItoIVb)VItoIIIc)IIIto
VId)IVtoIII
137.Thealcoholwhichdoesnotanswersiodoformtestis
a)ethanolb)methanolc)isopropyl
alcohold)none
138.Denaturedspiritisethanolcontaining
a)95%methanolb)5%waterc)5%
methanold)95%water
139.Diolsareisomericwith
a)diethersb)aldehydesc)hydroxy
ethersd)botha)andc)
140.Themolecularformulaforstearicacidis
a)C17H33COOHb)C17H35COOHc)
C15H31COOHd)C16H33COOH
141.Glycerolreactswithmetallicsodiumathightemperaturetogive
a)monosodiumglycerolateb)disodiumglycerolatec)trisodium
glycerolated)alltheabove
142.Glycerolformsmesoxalicacidwith
a)conHNO3b)FeSO4/H2O2c)
bismuthnitrated)KMnO4

143.Glyceroseisamixtureofglyceraldehydeand
a)mesoxalicacidb)tartronicacidc)dihydroxy
acetoned)oxalicacid

144.Benzylalcoholisisomericwith
a)phenolsb)anisolec)
cresolsd)bothb)andc)
145.Thecompoundpresentinjasmineoilsis

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a)phenylbenzoateb)benzylacetatec)phenyl
acetated)benzylbenzoate
146.Thecompoundusedinthetreatmentofasthmais
a)phenylbenzoateb)benzylacetatec)phenyl
acetated)benzylbenzoate
147.TheIUPACnameofPyrogallolis
a) 1,2,3 trihydroxy benzene b)1,2,4 trihydroxy
benzenec)1,3,5trihydroxybenzened)none
148. The compound which dissolves in sodium
hydroxidebutnotinsodiumbicarbonateis
a)ethylalcoholb)benzylalcoholc)
phenold)aceticacid
149.Phenolsarestrongeracidsthan
a)alcoholsb)mineralacidsc)carboxylic
acidsd)carbonicacids
150.Whichofthefollowingismostacidic
a)pnitrophenolb)phenolc)p
cresold)paminophenol
151.ThemainproductobtainedinthereactionofphenolwithPCl5is
a)C6H5Clb)POCl3c)
(C6H5O)3POd)HCl
152.Bakeliteisapolymerofphenoland
a)methanalb)ethanolc)formic
acidd)none
153.Thenumberofetherisomersposibleforacompoundwith
molecularformulaC3H8Ois
a)1b)3c)
2d)4
154.Theintermediateformedinthereactionofalkylhalideswithdry
silveroxideis
a)ROXb)ROAgc)
AgXd)ROR
155.Ethersdonotreactwith
a)acidsb)alkaliesc)
Sodiumd)alltheabove
156.WhichofthefollowingisusedasasolventforGrignardreagent
a)alcoholb)waterc)
etherd)alltheabove
157.ThealkylhalideformedinthereactionofHIwithC2H5OCH3
a)C2H5Ib)CH3Ic)bothaand
bd)none
158.ThereagentusedinZieselsmethodis
a)KMnO4b)PCl5c)
BF3d)HI
159.Zieselsmethodisusedtodetectwhichofthefollowinggroupsin
alkaloids
a)CH3b)Oc)
OCH3d)alltheabove
160.Whichofthefollowingisusedasamediuminthepreparationof
Grignardreagent
a)CH3OC2H5b)C2H5OCH3c)C2H5O
C2H5d)C3H7OC2H5
161.WhichisnotformedinthereactionofanisolewithHI
a)phenolb)methyliodidec)
iodobenzened)none
162.Pyridoxalanaldehydeisderivedfrom
a)vitaminDb)vitaminB12c)vitamin

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Kd)vitaminB6
163.Aldehydesarefunctionalisomersof
a)ketonesb)carboxylicacidsc)unsaturated
alcoholsd)bothaandc
164.TheproductinRosenmundreductionintheabsenceofBaSO4is
a)acidchlorideb)aldehydec)primary
alcohold)ketone
165.WhichofthefollowingcannotbepreparedbyRosenmund
reduction
a)acetaldehydeb)formaldehyde
c)benzaldehyded)none

166.Thereactionusedtolocatethepositionofdoublebondis
a)Haloformreactionb)hydrolysisc)
oxidationd)ozonolysis
167.Whichofthefollowingisleastreactivecarbonylcompound

a)HCHOb)RCHOc)RCO
Rd)ROR
168.Aldolonheatingforms
a)acrolienb)cinnamaldehydec)
crotonaldehyded)allylalcohol
169.AcyanohydrinofacompoundXonhydrolysisgives
mandelicacid.TheXis
a)HCHOb)CH3CHOc)
(CH3)2COd)C6H5CHO
170.TheelectronsourceusedinClemmensonreductionis
a)mercuryb)zincmetal
c)HCld)aldehyde
171.TheintermediateformedinWolffkishnerreductionis
a)alkanesb)hydrazinec)
ketoned)hydrazone
172.Thecompoundusedasahypnoticunderthenamehypnoneis
a)acetoneb)benzophenone
c)acetophenoned)acetaldehyde
173.Thecompoundwhichdoesnotformadditionproductwithsodium
bisulphiteis

a)acetoneb)benzophenonec)acetophenone
174.WhichofthefollowingisobtainedfromLaureloil
a)C3H7COOHb)C11H23COOHc)C4H9COOH
175.Theacidwhichundergointermoleculardehydrationis
a)formicacidb)succinicacidc)aceticacid
176.ThestableproductformedwhenformicacidreactswithPCl5is
a)CH3COClb)HCOClc)C6H5COCl
177.ThereagentusedtoconvertCH3COOHCH3CH3is
a)LiAlH4b)H2/Ruc)HI/P
178.Theacidusedinthetreatmentofgoutis
a)aceticacidb)oxalicacidc)salicylicacid
179.Theacidwhichundergohaloformreactionis
a)aceticacidb)formicacidc)lacticacid
180.Theacidwhichisusedasurinaryantisepticis
a)aceticacidb)formicacidc)benzoicacid
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181.Whichisthemostreactivederivativeofcarboxylicacid
a)esterb)amidec)acidchloride
182.Whichofthefollowingcompoundisusedassolderingflux
a)acetylchlorideb)acetamidec)methylacetate
183.Whichofthefollowingdoesnotexhibittautomerism
a)CH3CH2NO2b)(CH3)2CHNO2c)CH3
NO2
184.Nitroalkanesarefunctionalisomersof
a)Aminesb)alkylnitritesc)Alkylcyanides
185.WhichofthefollowingisinsolubleinNaOH
a)2nitropropaneb)Nitroethanec)1nitropropane
186.Whichofthefollowingisastrongerbase
a)methylamineb)Dimethylaminec)Benzylamine

187.Whichofthefollowinggivessecondaryaminesonreduction
a)Nitromethaneb)methylcyanidec)Acetamide

d)acetaldehyde

d)CH3COOH

d)alltheabove

d)HCl+CO

d)NaOH/CaO

d)formicacid

d)salicylicacid

d)salicylicacid

d)acidanhydride

d)aceticanhydride

d)(CH3)3CNO2

d)Aldehydes

d)2nitro2methylpropane

d)Trimethylamine

d)methylisocyanide

188.TheelectrondeficientspeciesformedduringHoffmann
bromamidereactionis
a)Carbeneb)diazoniumionc)Nitrene
d)Carboniumion

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189.Thecompoundwhichhasfishyodouris
a)Nitrobenzeneb)Nitrilesc)Amines
d)Alltheabove

190.Thesubstancewithmusturdlikesmellis
a)methylisocyanateb)Methylisocyanidec)methyl
isothiocyanated)methylcyanide
191.WhichofthefollowingdoesnotformSchiffsbase
a)CH3NH2b)CH3CH2NH2c)
C6H5NH2d)CH3NHCH3
192.Whichofthefollowingdoesnotundergocouplingreactionwith
C6H5N2Cl
a)phenolb)Anilinec)Anisole
d)Nitrobenzene
193.Whichofthefollowingreagentreactswithanilinegivingmeta
product
a)Br2/H2Ob)fumingH2SO4c)Con.
HNO3/Con.H2SO4d)CH3COCl
194.Nitromethaneformsnitroalcoholsinpresenceofalkalion
condensationwith

a)alcoholsb)aldehydec)amines
195.Whichofthefollowingisusedassoilsterilisingagent
a)picricacidb)chloralc)chloropicrin
196.ThenitrileusedinthemanufactureofPANis
a)acrylonitrileb)propionitrilec)acetonitrile
197.Which of the following aryl diazonium salt is stable in dry
condition
a)
ArN2+Clb)ArN2+NO2c)ArN2+BF4
198. Which of the following are used in the preparation of Sulpha
drugs
a)Nitrobenzeneb)Methylaminec)acetamide
199.Nitrationofnitrobenzenewithfumingnitricacidgives
(a)odinitrobenzene(b)1,3,5trinitrobenzene(c)pdinitrobenzene

d)carboxylicacids

d)alltheabove

d)formonitrile

d)None

d)Aniline

(d)mdinitrobenzene

200.Anaminewhichformsquarternaryammoniumsaltwithtwomolar
proportionofalkylhalideis
(a)10amine(b)20amine(c)30amine(d)None
201.Whichofthefollowingisatrisaccharide
a)sucroseb)glucosec)lactose
d)raffinose
202.Whichiscalledgrapesugar
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a)glucoseb)fructosec)galactose
d)starch
203.MixtureofequalmoleculesofD(+)glucoseandD()fructoseis
called
a)fruitsugarb)invertsugarc)canesugar
d)nonsugar
204.Thenumberofassymetriccarbonatomspresentinfructoseis
a)oneb)twoc)three
d)four
205.Sucroseonheatingupto2000Cforms
a)barleysugarb)caramelc)dextrind)burnt
sugar
206.Inpolysacchridesthemonosacchrideunitsarelinkedtogetherby
linkage
a)pepdideb)amidec)glycosidicd)
ester
207.Starchyieldsmaltosewhentreatedwiththeenzyme
a)zymaseb)maltasec)diastase
d)invertase
208.Thecolourformedwhenstarchsolutionisaddedwithadropof
iodine
a)yellowb)greenc)pinkd)
blue
209.Starchwhenheatedtoatemperaturebetween2002500C,it
changesto
a)barleysugarb)caramelc)dextrin
d)burntsugar
210.Themostabunduntofallcarbohydratesis
a)starchb)glucosec)inulind)
cellulose
211.Celluloseonboilingwithdil.H2SO4,getscompletelyhydrolysedto
a)Dglucoseb)Lfructosec)d
fructosed)Lglucose
212.Inprotiensaminoacidsarelinkedthroughlinkage
a)pepdideb)amidec)glycosidic
d)ester
213.Inacidicsolutionanaminoacidexistsintheformof
a)cationb)zwitterionc)anion
d)neutralmolecule
214.Whichofthefollowingisaphospholipid
a)waxb)fatc)cephalind)
alltheabove
215.Whichlipidisinvolvedintheorganisationofcellstructure
a)cephalinb)lecithinc)glycolipid
d)fat
216.Whichlipidhasbeenimplicatedintheprocessofblood
coagulation

a)cephalinb)lecithinc)glycolipid
d)fat

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