Professional Documents
Culture Documents
a r t i c l e i n f o a b s t r a c t
Article history: The cement industry is one of the most signicant sources of anthropogenic emissions of CO2 . It is con-
Received 1 December 2008 nected with the specic character of the production processes, during which great quantities of CO2 are
Received in revised form 1 February 2010 produced. Basic actions to reduce CO2 emissions recommended by the European Unions, Reference Docu-
Accepted 11 February 2010
ment on Best Available Techniques in the Cement and Lime Manufacturing Industries, include: reduction
Available online xxx
of fuel consumption, selection of raw materials with low content of organic compounds and fuels with
low coal contribution to heating value. All actions connected with the improvement of energy conversion
Keywords:
efciency of the cement production process cause CO2 emissions reduction. The use of at most acceptable
CO2 emissions
Cement industry
by the valid standards amounts of waste as raw materials and additives for cement production, also brings
CO2 emissions reduction about the reduction of signicant part of CO2 emissions. These measures have been and continue to be
Poland pursued by the cement factories in Poland. This article describes the evolution of the cement industry in
Emissions trading Poland over the period 19982008 and the resulting changes in CO2 emissions and explores the drivers
for these changes. The sources of CO2 emissions in cement industry have been presented in this article
as well as a discussion of potential ways to reduce Polish cement industry emissions even further.
2010 Elsevier Ltd. All rights reserved.
1. Introduction Poland has signed the Kyoto Protocol that commits all the coun-
tries that ratify this protocol, to reduce their greenhouse gases
The cement industry is one of the most signicant sources of emissions in the period of 20082012 by 5% below their 1990 levels.
anthropogenic emissions of carbon dioxide (CO2 ), amounting to The reductions have been specied for each country and vary from
around 7% of worldwide emissions (IPCC, 2005). 8% for European Union and associated countries (except Poland
The high emissions of CO2 are connected with cement produc- and Hungary), 7% for the United States, 6% for Japan, Canada, Hun-
tion technology. The elementary sources of CO2 emissions from gary and Poland, 0% for Russia and Ukraine. In this way, Poland has
cement industry are: raw material calcination and fuel combustion. committed to reduce its CO2 emissions.
It has been estimated that, on average for cement plants around The problem of reduction of CO2 emissions from cement
the world, CO2 emissions from the process of calcination amounts industry is particularly important when considering recent rapid
to about 50%, while from fuel combustion about 40% of total emis- economic development in Poland and noticeable, and the result-
sions (Humphreys and Mahasenan, 2002). Currently for the cement ing growing demand for growing need for cement, coupled
plants in Poland the emissions from calcination process amounts with the limitation of allowances for CO2 emissions in the
to 62%, and from fuel combustion 38%. Emissions of CO2 from these period of 20082012 introduced by the European Commis-
two processes are called direct emissions. The sources of indi- sion.
rect emissions (around 10% of emissions from cement plant) from The reduction of pollution emissions, especially of CO2 , is
cement industry result from transportation, electricity used within a great challenge for Poland. The CO2 emissions rate in 2005
the cement plant as well as upstream extraction of fossil fuels and per Gross Domestic Product (GDP) for Poland amounted to
mineral raw materials (Vanderborght and Brodmann, 2001). Emis- 1196.6 tonnes/mln Euro, and for the EU27360.5 tonnes/mln
sions of CO2 in the process of cement production depends mainly Euro, thus, it was more than 230% greater than in the Euro-
from: type of production process, type of the used fuel as well as the pean Union. Whereas, CO2 emissions rate per primary energy unit
clinker/cement ratio that is the proportional content of additives amounts to 3.09 tonnes/toe, and in EU272.18 tonnes/toe, thus, it
(Hendriks et al., 1998). was 42% greater than in the European Union (EETT, 2008).
Reduction of CO2 emission factor per tonne of cement by in the
period of 19882008 amounted to 28%. Emission factor in 1988
Corresponding author. Tel.: +48 126323300; fax: +48 124233624. amounted to 0.879 tonnes of CO2 /tonne of cement and 1.1 tonnes
E-mail address: aub@min-pan.krakow.pl (A. Uliasz-Bochenczyk). of CO2 /tonne of clinker. Emission factor in 2008 amounted to 0.631
1750-5836/$ see front matter 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.ijggc.2010.02.002
Please cite this article in press as: Deja, J., et al., CO2 emissions from Polish cement industry. Int. J. Greenhouse Gas Control (2010),
doi:10.1016/j.ijggc.2010.02.002
G Model
IJGGC-275; No. of Pages 6 ARTICLE IN PRESS
2 J. Deja et al. / International Journal of Greenhouse Gas Control xxx (2010) xxxxxx
Table 1
Owners and characteristic of cement plants in Poland (PCA, 20012009).
ze
Grazd Cement S.A. Cement plant HeidelbergCement 25
Cementownia Grazd ze
Grinding plant
Ekocem Sp. z o.o.
Lafarge Cement Cement plants Lafarge 22
Cementownia Maogoszcz
Cementownia Kujawy
Grupa Ozarw S.A. Cement plants CRH 18
Grupa Ozarw
Cementownia Rejowiec
Dyckerhoff Polska Sp. z o.o. Cement plant Dyckerhoff 8
Cementownia Nowiny
Cemex Polska sp. z o.o. Cement plants Cemex 16
Cementownia Chem
Cementownia Rudniki
Cementownia Odra SA Cement plant Miebach 3
Grka Cement Cement plant (producer of aluminous cement) Mapei
Cementownia Warta Cement plant Polen Cement 7
Cementownia Nowa Huta Cement plant 1
tonnes of CO2 /tonne of cement and 0.865 tonnes of CO2 /tonne of In 2008, in Poland, 36 cement types were produced, with the
clinker (PCA, 20012009). most important being: CEM II 32.5 and CEM I 42.5.
The cement industry in Poland dates back 150 years. At present,
in Poland, there are 11 cement plants producing cement in a com-
plete manufacturing cycle, 1 cement grinding plant and 1 factory
2. Cement industry in Poland
of alumina cement, belonging to: HeidelbergCement, Lafarge, CRH,
The cement industry in Poland is one of the most signicant Cemex, Dyckerhoff, Miebach, Polen Cement, Mapei (Table 1).
cement producers in Europe. In 2005 in Poland 12.3 million tonnes The location of these cement plants has been presented in Fig. 1.
of cement were produced, which amounted to 0.49% of worldwide In Poland there are 17 modern dry method kilns as well as 6
production of cement amounting to 2293 milliard tonnes. In 2006 kilns of wet method.
14.6 million tonnes were produced, and in 2008 the production A number of investment has recently been initiated which in
increased to almost 17 million tonnes (PCA, 20012009). the period of 34 years will increase the production an additional
Please cite this article in press as: Deja, J., et al., CO2 emissions from Polish cement industry. Int. J. Greenhouse Gas Control (2010),
doi:10.1016/j.ijggc.2010.02.002
G Model
IJGGC-275; No. of Pages 6 ARTICLE IN PRESS
J. Deja et al. / International Journal of Greenhouse Gas Control xxx (2010) xxxxxx 3
possibilities to 2.5 mln tonnes of cement over current levels of 5. Possibilities of emissions reduction in cement industry
approximately 18.5 mln tonnes (PCA, 20012009). in the light of the measures of Polish cement industry
Table 2 Table 3
Emission from Polish cement industry in kt (PCA, 20012009). Share of wet and dry process of clinker production in Poland in % (PCA, 20012009;
Uliasz-Bochenczyk et al., 2007).
Years Clinker production Cement production CO2 emission
Year Wet method Dry method
1998 11974.00 14970.0 11165.6
1999 11679.00 15403.0 11889.6 1989 61 39
2000 11566.0 15116.0 11359.1 1999 44 56
2001 9335.10 12264.8 8696.0 2000 33 67
2002 8751.1 11345.3 7824.0 2001 17 83
2003 8518.0 11009 7640.4 2002 11 89
2004 9354.9 11413.4 8171.6 2003 2 98
2005 9237.8 12268.3 8114.0 2004 2 98
2006 11163.1 14630.9 9705.5 2005 2 98
2007 13109.4 16796.7 11472.3 2006 2 98
2008 12380.3 16973.5 10456.6 2007 5 95
Please cite this article in press as: Deja, J., et al., CO2 emissions from Polish cement industry. Int. J. Greenhouse Gas Control (2010),
doi:10.1016/j.ijggc.2010.02.002
G Model
IJGGC-275; No. of Pages 6 ARTICLE IN PRESS
4 J. Deja et al. / International Journal of Greenhouse Gas Control xxx (2010) xxxxxx
Table 4 Table 6
Consumption of unit gross heat energy in Polish cement industry in kJ/tonne of Total of waste used as raw materials for cement production in Polish cement industry
clinker (PCA, 20012009). in kt (PCA, 20012009).
Please cite this article in press as: Deja, J., et al., CO2 emissions from Polish cement industry. Int. J. Greenhouse Gas Control (2010),
doi:10.1016/j.ijggc.2010.02.002
G Model
IJGGC-275; No. of Pages 6 ARTICLE IN PRESS
J. Deja et al. / International Journal of Greenhouse Gas Control xxx (2010) xxxxxx 5
Transfer of allowances act for emissions of greenhouse gases and nomic as well as ecological aspects. Economic aspects are mainly:
other substances on 22 December 2004 (JL, 2004). limitation of energy and fuel costs thanks to the introduction on
Regulation of the Council of Ministers, 1st July 2008, on approval a large-scale (98%) of less energy-consuming dry method, mod-
of the National Allocation Plan for CO2 emissions, in the period ernization of installations, introduction of alternative fuels, which
of 20082012, for the European Union Emission Trading Scheme consumption in recent years has considerably increased and the
(JL, 2008). use of waste as raw materials and additives to cement. Owing to
Regulation of Minister of the Environment on 12 January 2006 these measures CO2 emissions are also reduced.
on the methods of monitoring the quantities of emissions of sub- Polish cement industry reduced signicantly the emissions fac-
stances included in the Community Emission Trading Scheme (JL, tor per tonne of cement in the period of 19882008 by 28%. In
2006). 1988 the factor amounted to 0.879 tonnes CO2 /tonnes of cement
and 1.1 tonnes CO2 /tonnes of clinker, while in 2008, respectively
Polish cement industry has participated in the Scheme since
0.631 tonnes CO2 /tonnes of cement and 0.865 tonnes CO2 /tonnes of
2005 and received 4.76% of emission trading allowances in the years
clinker.
20052007. In the rst phase of ETS 20052007 the total allocation
Additionally, the introduction of Emission Trading Scheme
for the cement sector amounted to 33.639 million of allowances
forces cement industry to take actions, so as to limit the emissions
for emissions, that is an average of 11.231 million of allowances
of CO2 . That is why, studies on different CO2 emissions reduction
a year. In this period the emissions from industry (Table 2) con-
technologies are carried out. They include: research on the possi-
stituted, respectively: in 200572.2% of allocated allowances, in
bility of separation and capture of CO2 from exhaust gases from
200686.0% of allocated allowances, in 2007101.4% of allocated
cement plants (Hegerland et al., 2006), studies on production of
allowances.
calcium carbonate captured from CO2 (Romeo et al., 2006) or via
On 14 November 2008, in Journal of Laws No. 202, item 1248
mineral carbonation of metallurgical slag with the use of acetic acid
the Regulation of Council of Ministers was published dated on 1 July
(Teir et al., 2007).
2008 on National Plan on Dividing Allowances for CO2 emissions for
However, the basic method of emissions reduction still remains
the period of 20082012 in the Community Scheme of Emissions
the same, that is the decrease of energy consumption of the whole
Trading.
process as well as clinker replacement, as its calcination process
The total amount of allowances for CO2 emissions for the period
constitutes the majority of CO2 emissions, in cement contents with
of 20082012 in the cement industry comes to 54.5 million (exactly
mineral supplements.
54,509,555) (annex to the Regulation of Council of Ministers dated
on 1st July, item 1248).
The number of allowances as credits for CO2 emissions in
References
cement industry has been reduced compared to the plan dated
on 12 February 2008 providing for the installations for cement Baker, D.J., Turner, S.A., Napier-Moore, P.A., Clark, M., Davison, J.E., 2009. CO2 capture
clinker production in rotary kilns 57.8 million (exactly 57,831,210) in the cement industry. Energy Procedia 1, 8794.
allowances. Davison, J., 2006. CO2 capture at cement kilns. Energy efciency and CO2 emis-
sion reduction potentials and policies in the cement industry. In: IEA/WBCSD
Workshop, Paris.
5.4. Reduction of emissions as a result of capture of the emitted EETT, 2008. European Energy and Transport Trends to 2030Update 2007. European
CO2 Commission, DG TREN.
Gartner, E., 2004. Industrially interesting approaches to low-CO2 cements. Cement
and Concrete Research 34, 14891498.
One of the possibilities of CO2 emissions reduction is its removal
Hegerland, G., Pande, J.O., Haugen, H.A., Eldrup, N., Tokheim, L.A., Hatlevik, L.M.,
from exhaust gases. CO2 may be captured in calcination and fuel 2006. Capture of CO2 from a cement planttechnical possibilities and econom-
combustion processes, and then stored or utilized. ical estimates. In: Proceedings Materials of 8th International Conference on
Greenhouse Gas Control Technologies. Elsevier.
Due to high CO2 content in the exhaust gases from calcination,
HeidelbergCement, 2008. Modernization of Kiln no. 2 in a Cement Plant. Hei-
oxy-fuel combustion (combustion in CO2 /O2 atmosphere) or cap- delbergCement, http://www.heidelbergcement.com/pl/pl/country/o nas/
ture after combustion with the use of amine absorption (Baker et aktualnosci/aktu2008/modernizacja 2008.htm.
al., 2009; Bosoaga et al., 2009; Davison, 2006; Hegerland et al., Hendriks, C.A., Worrell, E., DE Jager, D., Blok, K., Riemer, P., 1998. Emission reduction
of greenhouse gases from the cement industry. In: GHGT-4 Conference Proceed-
2006; IEA, 2008; Price, 2006; Zeman, 2009) may be used for CO2 ings: Greenhouse Gas Control Technologies 2002. Interlaken, Switzerland.
removal from cement production processes. Research conducted Humphreys, K., Mahasenan, M., 2002. Climate Change. Toward a sustainable cement
by Hegerland et al. (2006) indicated that for the operating cement industry. An Independent Study Commissioned by World Business Council for
Sustainable Development. www.wbcsdcement.org.
plants the best method is the capture after combustion with the IEA, 2008. IEA Greenhouse Gas R&D Programme (IEA GHG), CO2 Capture in the
employment of amine absorption. The issue of capture of CO2 from Cement Industry, 2008/3, July 2008.
exhaust gases from cement plants is being studied, and so far an IPCC, 2005. In: Metz, B., Davidson, O., de Coninck, H.C., Loos, M., Meyer, L.A. (Eds.),
IPCC Special Report on Carbon Dioxide Capture and Storage. Prepared by Work-
economically and energetically protable method has not been ing group III of the Intergovernmental Panel on Climate Change. Cambridge
developed. University Press, Cambridge, United Kingdom and New York, NY, USA, p. 442.
IPPC, 2001. Integrated pollution prevention and control. In: Reference Document on
5.5. Binding of CO2 in concrete Best Available Techniques in the Cement and Lime Manufacturing Industries.
European Commission, http://www.eippcb.jrc.es/pages/FActivities.htm.
JL, 2004. Journal of Laws 281, item 2784.
Taking into consideration the emissions of CO2 in cement indus- JL, 2006. Journal of Laws 16, item 124.
try another aspect needs to be considered as well. From the JL, 2008. Journal of Laws 202, item 1248.
produced cement by the cement plants concrete is manufactured, Lafarge, 2003. A new cement production line in Poland. Lafarge, http://www.
lafarge.com/wps/portal/6 2 2TCDet?WCM GLOBAL CONTEXT=/wps/wcm/
which in natural conditions binds CO2 from the atmosphere (Martin connect/Lafarge.com/AllPR/2003/PR536879089/MainEN&xtmc=
et al., 1999). In this way, to some extent, the product of cement plant CO2Kujawy2003&xtcr=1.
indirectly causes emissions reduction. Martin, N., Worell, E., Price, L., 1999. Energy Efciency and Carbon Dioxide Emissions
Reduction Opportunities in the U.S. Cement Industry. Ernest Orlando Lawrence
Berkeley National Laboratory, Report no. LBNL44182.
6. Summary PCA, 20012009. Bulletin of the Polish Cement Association, Cracow, 2001, 2002,
2003, 2004, 2005, 2006, 2007, 2008, 2009.
Price, L., 2006. Global energy use, CO2 emissions, and the potential for reduction
Polish cement industry is taking large-scale measures allowing in the cement industry. In: IEA/WBCSD WorkshopEnergy Efciency and CO2
the CO2 emissions reduction. These actions are concerned with eco- emission Reduction Potentials and Policies in the Cement Industry, Paris.
Please cite this article in press as: Deja, J., et al., CO2 emissions from Polish cement industry. Int. J. Greenhouse Gas Control (2010),
doi:10.1016/j.ijggc.2010.02.002
G Model
IJGGC-275; No. of Pages 6 ARTICLE IN PRESS
6 J. Deja et al. / International Journal of Greenhouse Gas Control xxx (2010) xxxxxx
Romeo, L.M., Abanades, J.C., Ballesteros, J.C., Valero, A., Escosa, J.M., Gimenez, A., on Mine Planning and Equipment Selection (MPES 2007) and the Tenth Inter-
Cortes, C., Pano, J., 2006. Process optimization in postcombustion CO2 -capture national Symposium on Environmental Issues and waste Management in
by means of repowering and reversible carbonation/calcinations cycle. In: Pro- energy and Mineral production (SWEMP 2007). SINGHAL/FYTAS/JONGSIRE/GE,
ceedings Materials of 8th International Conference on Greenhouse Gas Control Bangkok.
Technologies. Elsevier. Vanderborght, B., Brodmann, U., 2001. The Cement CO2 Protocol: CO2
Roskovic, R., Bjegovic,
D., 2005. Role of mineral additions in reducing CO2 emission. Emissions Monitoring and Reporting Protocol for the Cement Industry,
Cement and Concrete Research 35, 974978. www.wbcsdcement.org/pdf/co2-protocol.pdf.
SCA, 2003. Blended Cements. Slag Cement Association, http://www.slagcement.org/ Venkateswaran, S.R., Lowitt, H.E., 1988. The U.S. Cement Industry, An Energy Per-
download/123800 U128801 185547/no21%20Blended%20Cements.pdf. spective. U.S. Department of Energy, Washington, DC, USA.
Teir, S., Eloneva, S., Fogelholm, C.J., Zevenhoven, R., 2007. Dissolution of steel making Worell, E., Price, L., Martin, N., Hendriks, Ch., Meida, L.O., 2001. Carbon dioxide emis-
slags in acetic acid for precipitated calcium carbonate production. Energy 32, sions from the global cement industry. Annual Review of Energy Environment
528539. 26, 303329.
Uliasz-Bochenczyk, A., Gawlik, L., Mokrzycki, E., 2007. Energy consumption in Zeman, F., 2009. Oxygen combustion in cement production. Energy Procedia 1,
cement industry. In: Proceedings of the Sixteenth International Symposium 187194.
Please cite this article in press as: Deja, J., et al., CO2 emissions from Polish cement industry. Int. J. Greenhouse Gas Control (2010),
doi:10.1016/j.ijggc.2010.02.002