Unit O— Review Equilibrium Worksheet 1 For questions 1-8, consider the reaction: FeOaig) +3 Haig 2 Fey) +3H0 AH= 15 kd 1. The equilibrium concentrations under certain conditions were found to be [HjO]=1.0M — [HpJ=2.5M What is the value for K? (A) 0.40 (®) 0.064 ©) 156 (©) Insufficient information to calculate. 2. Kpis (A) loss than K. (®) greater than K. (©) equal to K. (©) insutficient information to calculate. 8. Use the following choices: (A) Shift lett (8) Shift right (C) No change (D) Not possible to predict to indicate the effect of each of the following stresses on the position of this system at equilibrium: (4) Decrease the volume of the contai r 6) Add Fe,Oze) (6) Remove H2O) (7) Increase the temperature. 4. For the reaction: 4 NHaiq) + 8 Ozig) <=====> 4 NO + 6 H2O(q) AH is negative. The position of this equilibrium would be shifted to the left by (A) Removing NO‘). (B) Adding Or). (C) Increasing the pressure by decreasing the volume of the container. (0) Decreasing the temperature. (E) None of these. 1604-PTAS, Page 1 of 2Equilibrium Worksheet 1 5. Calculate the equilibrium constant for the following reaction: 2A => Big) + 30.) given that a 1.0 L vessel was initially filled with 5.0 atm of pure A and the partial pressure of gas A was found to be 3.5 atm at equilibrium, (A) 1.1 atm? (B) 0.70 aim? (©) 38.atm? (D) 0.48 atm (E)_ None of these 6. _ Increasing the volume of the reaction vessel in question 5 would have what effect? (A) Increase the equilibrium constant. {B) Force the reaction to proceed to the right. (C) Force the product ratio [CVIB} to be greater than 3. (D) Only (A) and (B) are correct. (©) A), @), and (C) are correct. (©1004-PIAS, ra Page 2 of 2Equilibrium Worksheet 2 1. Ammonium chloride is @ crystalline solid that decomposes as follows: NH,Cley <= NHgiq) + HCkgy (A) Some solid NH,CI is placed in an evacuated vessel at 25°C. After equilibrium is attained, the total pressure inside the vessel is found to be 0.659 atm. Some solid NHC! remains in the vessel at equilibrium. For this decomposition, write the expression for Kp and calculate its numerical value at 25°C, (®) Some exira NHg gas is injected into the vessel containing the sample described in part (A). When equilibrium is reestablished at 25°C, the partial pressure of NH in the vessel is twice the partial pressure of HCI, Calculate the numerical value of the partial pressure of NHg and the partial pressure of HCI in the vessel after the NH has been added and equilibrium has been reestablished. (©) Ina different experiment, NHg gas and HCl gas are introduced into an empty 1.00 L vossel at 26°C. The initial partial pressure of each gas is 0.500 atm. Calculate the number of moles of solid NH4C that is present when equilibrium is established. 2. Given the following reaction at equilibrium: NO4g) < 2NOx) Initially, 0.0400 mol N2O4.g) ate placed in a previously evacuated flask and heated to 100°C, When equilibrium is established St 100°C, the equilibrium concentration of N>O,q is found to be 0.0134 M The volume of the flask is 1.00 L. (A) Calculate the equilibrium concentration of NOzigy. (B) Calculate the equilibrium constant, Ko, for the reaction at 100°C. (01004-PTAS, no Page 1 of 2Equilibrium Worksheet 2 (C) In another experiment, equilibrium was approached from the other direction by injecting a quantity of NOpiq) into a previously evacuated flask. After equilibrium is established in this system at 100°C, the equilldrium concentration of NO» is found to be 0.0248 M. Find the equilibrium concentration of NO, in the system. 3. The equilibrium constant, Ke, for the following reaction Najq) + Cara) < 2 NO is 4.00 x 10°2 at a very high temperature. The reaction is at equilibrium at this temperature with [Ng] = [02] = 0.100 M and [NO] = 0.0200 M in a 2.09 liter flask. If 0.120 mol of NO is suddenly added to the reaction mixture what will be the concentrations of all species when equilibrium is re-established? The reactio Hag) + lac@) 2Hlg) has an equilibrium constant, K,=64 at 400°C. The reaction is at equilibrium with a [H] = 0.040 M, [lp] = 0.040 M, and [Hl] = 0.32 M ina 2.0 liter flask at 400°C. Suddenly and unexpectedly, without notice! 0.15 mole of HI is added to the reaction mixture. What will be the concentration of all species when equilibrium is re-established??? (01004-PTAS, re Page 2 of 2Equilibrium Worksheet 3 1. COx < CO" 12 Ong) A.1.00 mole sample of CO, is placed in a 1.00 L container and allowed to come to equilibrium at 2500°K. When equilibrium is reached at 2500°K, 17.6% of the original CO, has decomposed to CO and Oz. Calculate the value of the equilibrium constant, Ke, for the dissociation reaction at 2500°K, 2. Given the reaction: NH4HS je) < ‘Suppose the substances in the reaction are at equilibrium at 500 K, State whether the partial pressure of NHgig) will have increased, decreased, or remained the same when equilibrium is re-established after each of the following disturbances of the original system. Justify each answer with a brief explanation. (A) Asmall quantity of H2S is added. (B) The temperature of the system is increased. (C) The volume of the system is increased. (0) Aquantity of Np is added. (E) Aquantity of NHg is added, ‘An equilibrium mixture: Heig) + COp,q) > Hz0(q + CO) in a 5.0 L container at a certain temperature was analyzed and found to contain H= 0.585 moles, CO» = 1.585 moles, HzO = 0.665 moles, and CO = 0.665 moles. (A) Calculate the equilibrium constant. (8) How would the equilibrium quantity (moles) of HO be affected by an increase in the total volume of the system? (C) How would the equilibrium concentration of HzO be affected by an increase in the total volume? .©1094-PTAS, Page 1 of 2Equilibrium Worksheet 3 4, AtS50 K, Ke is 0.14 for the reaction: 2BrCly, => Btoyg) + Claygy An equilibrium mixture at this temperature contains equal concentrations of bromine and chlorine, 0.0250 M. What is the equilibrium concentration of BrCl? 5. Keforthereaction: 2 IC <=: Cloigy is 0.11 ata certain temperature. Suppose the initial concentrations (mol/L) of ICI, Ip, and Cla, are 0.20 M, 0.00 M, and 0.00 M, respectively. Some of the IC! decomposes and the system reaches lum. What is the equilibrium concentration of each species? 6. The reaction: COpgy+ H20) <: C249) + Ho(q) has a Kg value of 4.0 at 500°C. Calculate the concentration of all species at equilibrium starting with: (A) [CO] =[H,0] = 0.100 M and [COz] = [Ha] = 0.00M (®) [CO] = [HzO] = [COp} = [Hz] = 0.040 M 7. At 460°C, the reaction: SOzig) + NOzg) NO + SOgq) has Ke = 85.0. What will be the equilibrium concentrations of the four gases if a mixture or SO and NO, is prepared in which they both have initial concentration of 0.0750 M? 8. For the system: POlgigy <=====> PClyig) + Clay) K, = 0.050 at 250°C. If 0.30 mol PPCig is placed in a 1.0 L container at this temperature. What are the equilibrium concentrations of all species? . For the reaction: CO Vg) + Hag) => COpiq) + Haig) equilibrium is established at a certain temperature when the concentration of CO, H,0, COp, and Hp are 0.010 M, 0,020 M, 0.012 M, and 0.012 M respeclively. (A) Calculate Ko. (B) If enough CO is added to raise its concentration temporarily to 0.020 M, what will be the concentrations of all species after equilibrium has been re-established? (©1904-PTAS, Ino Page 2 of 2Equilibrium Worksheet 1 For questions 1-3, consider the reaction: Weak + FepOae) +3 Haig) 2F eq) +3Hp0) He 18 kd 1, The equilibrium concentrations under certain conditions were found to be [H.0]=1.0M — [HpJ= 25M ‘ What is the value for K? 2 (A) 0.40 * ® 0,064 Kz TWO ? co > Ob ©) 166 cay Gs) Oot (D) Insufficient information to calculate. 2. Kpis (A) less than K. oh bik (B) greater than K. trol ch Gow Om ee © equaltok. edu (D) insufficient information to calculate. 3. Use the following choices: (A) Shift left (B) Shift right (©) No change (D) Not possible to predict to indicate the effect of each of the following stresses on the position of this system at equilibrium: (4). Decrease the volume of the container. pyasains ine, ur BAS quan enw Aguak : Het me Chrome (5) Add Fe0u sctitn do mot otyeck nyyibidateor (O) Femeve HO) LAU mye bo piouee mou AO, amare tong (7) Increase the peers, Wat amove Wo ndace WA, so UL ome tongs : 4. For the reaction: 4 NHaig) + 5 O2¢q) <= 4 NOG) +6HO%) +heot AH is negative. The position of this equilibrium would be shifted to the left by (A) Removing NOj¢), (8) Adding O29) a © peer pressure by decreasing the volume of the container. With Mout bo vd of (D) Decreasing the temperature. pose mol 4 goa? (E) None of these. (ifs sit) ‘S1994-PTAS, ne. PagEquilibrium Worksheet 1 5. & (©) (0) (e) (A) : (D) (E) Calculate the equilibrium constant for the following reaction: 2A) > Big) + 30g) given that a 1.0 L vessel was initially filed with 5.0 atm of pure A and the partial pressure of gas A was found to be 3.5 atm at equilibrium, 4.1 atm? 0.70 atm? rs 9,3 a 208 7s 3.8 atm? 7 So 0.48 atm? pe 35) None of these i £70 okw Increasing the volume of the reaction vessel in question 5 would have what effect? Increase the equilibrium constant, Force the reaction to proceed to the right, Vine artlume , mtorr? Force the product ratio [CY[B] to be greater than 3. ’ au Only (A) and (B) are correct. die we pun, (A), (8), and (C) are correct. wh dt vl mmo mabe 4 gow (nig aH) (©1004-PTAS, ne Page 2 of 2Equilibrium Worksheet 2 1, Ammonium chioride is a crystalline solid that decomposes as follows: NHjClig) NHaig) + HCligy (A) Some solid NH,Cl is placed in an evacuated vessel at 25°C. After equilibrium is attained, the total pressure inside the vessel is found to be 0,659 atm. Some solid NH,Cl remains in the vessel at ee For this decomposition, write the expression for Kp and ‘calculate its numerical value at 25°C. Kp? Pong Pret esd > XA Tay = Le Aye dis * We asd, * ay Kp: (.350 am) +] Lagat? wey yy +¥ (B) Some extra NH gas is injected into the vessel containing the sample described in part (A). When equilibrium is reestablished at 25°C, the partial pressure of NH, in the vessel is twice the partial pressure of HCl. Calculate the numerical value of the partial pressure of NHg and the partial pressure of HCI in the vessel after the NHg has been added and equilibrium has been reestablished. Whyth = pls + a (ax) > 109 oq st Ok ty. ar x (C) Ina different experiment, NH, gas and HC! gas are introduced into al The initial partial pressure of each gas is 0.500 atm. Calculate the number of moles of solid NH4C that is present when equilibrium is established. a (500-*) = 109 Nkycl S why + ACL was-k Hits 109 1500 +e = = Keane Oo i dena a XE 8807 oF ITD offi rh »500-% .500- y ays We 2. Given the following reaction at equilibrium: N2Oqig) <===5=> 2 NO2@) Initially, 0.0400 mol NaO4iq) are placed in a previously evacuated flask and heated to 100°C. When equilsrium is established St 100°C, the equlibrium concentration of NpOgiq is found to be 0.0134 M The volume of the flask is 1.00 L. (A) Calculate the equilibrium concentration of NOzig)- NiOy = gvnod - boss* 7 aM © Ke? ae Qi mw ~ oe +0532 Old [osse (B) Calculate the equilibrium constant, Ke, for the reaction at 100°C. ‘er864-PTAS, ie Page 1 of 2Equilibrium Worksheet 2 (C) In another experiment, equilibrium was approached from the other direction by injecting a quantity of NOziq) into a previously evacuated flask. After equilibrium is established in this system at 100°C, the equilibrium concentration of NOz is found to be 0.0243 M. Find the equilibrium concentration of NzO4 inthe system. N04 = aN0r * ame 7 6343 Kye all = (oa4ay'/e 2iy A at .O243 x is wht 8. The equilibrium constant, Ke, for the following reaction Nowe) * 24g) <= 2 NO) is 4.00 x 10°2 at a very high temperature. The reaction is at equilibrium at this temperature with No} = [Oz] = 0.100 M and [NO] = 0.0200 M in a 2.00 liter flask. If 0.120 mol of NO is suddenly added to the reaction mixture what wil be the concentrations of all species when equilibrium is re-established? N, +0, S ano OOU4 = eX aa earn 102 10d 0.02 + 06 “Deane ¢ 4x10 a 4 Sant ac OOOH = slek 4¥7E dyno 4 oo8x + 0 (os- Fex® = ,14dx + 006 > © < a axe” edts X= 0500 cet TW CONV ism C90 oscdat 4. The reactio Ho(g)+ lag) <==52=> 2 Hl) : has an equilibrium constant, K,=64 at 400°C. The reaction is at equilibrium with a [Hp] = 0.040 M, [lo] = 0.040 M, and [HI] = 0.32 M in a 2.0 liter flask at 400°C. Suddenly and unexpectedly, without Notice! 0,15 mole of HI is added to the reaction mixture. What will be the concentration of all species when equilibrium is re-established??? Ao + TT. =F anh 0+ 04 324.078 +x ax 7 Ody DU Was - ad 2 (34s ax) t . i Sues =p lo ~ WSELAN ETS IOLA T, 12+ CHU Hex) a \ los? + G7 ¥ -.05420 ab 7 USB y dy ay Geer eee Page 2 of 2 01904-PTAS. ie ObIw + OFX ¥y* Chad = Cts 04m Parl. animEquilibrium Worksheet 3 is CO pq) CO (gt 1/2 Orig) ‘4.1.00 mole sample of CO» is placed in a 1.00 L container and allowed to come to equilibrium at 2500°K. When equilibrium is reached at 2500°K, 17.6% of the original CO, has decomposed to CO land Op, Calculate the value of the equilibrium constant, Ke, for the dissociation reaction at 2500°K. Ml, Cor F Co + OL (ogee) 1 0 7 Ket ~ 21 ete + ORE 4 Mb 088 904 : = ,0u34 ee ; ion oe 2. Given the reaction: M* NH,HS,.) NHaig) + HSig) AH = +197.8 kd. ‘Suppose the substances in the reaction are at equilibrium at 500 K. State whether the padiial pressure OLNHg(o) Will have increased, decreased, or remained the same when equilibrium is re-established atter ath of the following disturbances of the original system. Justify each answer with a brief explanation. (A) Asmall quantity of HpS is added, Wik Wit te Lk t uar ug Oly 3 Pony with drouor (©) The temperature ofthe system Is increased, writs gui ak. to Mae ug Mad’, Prony wath fit Pang ot ipsa : nemo , (C) The volume of the systems increased. gas duc , vith SYA Mb to pod (O) Aaquantity of Np is added. dotnk c@porr wacker, mo ofcl cq Why, Pon decuce (©) Aquantity of Ng is added. VIL! [oer Macha fo Uh gt mag Why, 3. An equlibrium mixture: Haig) + COpiq) <==22=> HpOiq) + COig) ina.5.0L container at a certain temperature was analyzed and found to contain Hy= 0.585 moles, CO, =(1)585 moles, HO = 0,665 moles, and CO = 0.665 moles. (A) Calculate the equilibrium constant. 183) (133) (TyGan) © PT 1.28 (B) How would the equilibrium quantity (moles) of HO be affected by an increase in the total volume of the system? i, Melua ude puma die, uke simet # of role both sidy om one” Some | mo (©) How would the equilibrium concentration of HO be affected by an increase in the total volume? 2m. Ne = dacuasr ( tone T GET cmeb) esse PAS. Page 1 0f2Tera Cet,2 US Kos Teccey~ LOD = Cet d = .Qasom ot ug, ( “4? (.0as0)(.case) 2 : CBrcty* Cece cots 5) FIG) AG Clee) e oF ° oO 108. 8K 44x =f AR +t ay Pe Senet i: "aay " Xs 0044 ~ 08K #.Yy wow) OF -.stc? — o8fy +,.0044 AXE ct —,* X= 297s 1035 Garay eon (UIs: cel + .0399 >) CIV 4120 mm ——~ c)a) Cot AAD SE toy F Ae e o 6 Coeargeatae Beer Reece Be of ie fs ia = 04 Bk ¢ 3K a, DueT 4 ou ieee fee eerae areca ae Teord (Hd > .0667 Ceo J+ tol + 1033; cot Ho FCO, * tell we) Qe1 of oH * e woh > joole 4 OL 41"s coud =. 824 le Mee ved a 0+ .0048 4 18" so mud mnt gre teod sOYty products cag eee ke 4% , 0183 (oa se Lotte, (oe) C04 ¥ ily + KA Jeol =. 4! To} + CA,01* .0aLT Ler d> CHa > 6533 m2 i ap) 50, + D0, TF NO + SO, Sa . 7.84 1075 075 ° oO “~k -k eo xs 47g -lansx $85x" 2 sD15 -4 OTS -% ce O= 479 asx Fr wrte) > .gYds, 0408 (o7s-4)(or -e) 7 1F ——— Cools Tso] 7 .0683 m Es, 1 eC VAIT> ,CO67 M ?) Pols =A Pols + Ce 2 01s -.05 % 3 ° ° oes aeeLTEeEeECI A Gee x? t.osy>.0 40 18% “ « iz a ke lo ou. Caen * 108 ae Chtyd= Cyd! CPeks] = ya Toma CHa I tigaaie eS Fob wich , MUS Tose wm Regain CALUI uM 9 (o) ce i WO FCO, 4 Hy 1000144 4.6 2 i : 1OA OR 101A 012 i RYKEK COO ~. 008K HTL 7K “4 Fy +x «BY +. O5QK ~ 0001867 Ca~X OAK DIATE OIA TK ree (.Olaty)(.O1atx) ———— (0~ #) (.0a-¥) 10146 M Tod: CAI = Cooly + Chol? .o14