Fifth Form Chemistry Practical we 2006-10-16
ASp.Obj.8.1 __Enthalpy of Solution of Magnesium Sulphate EY 2007
MM & AI EY 2012
Ar: O=16 Mg=24 S=32.. Use specific heat capacity of HO = 4.2 J g" °C" as that for
the solution..Use density of soln. as =1g cm’ (same as that for pure water at 25°C)
‘You are required to determine the enthalpy of solution of magnesium sulphate.
Procedure:
Place the 50 cm’ beaker, which has been provided as the weighing vessel, on the top-pan
balance and determine its mass. Weigh out in the same beaker about 6.00g of solid
magnesium sulphate. Using a measuring cylinder measure 80cm’ of distilled water and
transfer the water to:the plastic cup provided. Find the initial temperature of the water by
monitoring the temperature over a three minute period keeping the thermometer in the
cup through out the period. Record the temperature after three minutes provided that the
temperature has reached a steady state. With the thermometer still in the cup, carefully
transfer the solid to the cup, stir immediately, taking due care, until the solid has
completely dissolved. Record the maximumy/minimum temperature reached. Reweigh the
beaker in order to find the mass of residual magnesium sulphate. This mass must be
subtracted from the mass of magnesium sulphate previously determined in order to find
the mass of the solid actually dissolved.
Results:
le of Balance Readings I
‘Mass of beaker +magnesium sulphate’/ g
Mass of empty beaker”/ g
Mass of magnesium sulphate’ 7g
4
Table of Balance Readings II
Mass of beakertresidue' /g
Mass of empty beaker /g
Mass of resiudue™ 7g
Mass of MgSO, used £.e.(3-5)/g
(4)‘Table of Thermometer Readings
Final Thermometer Reading/ * C
Initial Thermometer reading/ °C
‘Temperature Changel °C
{6}
west of.
1. The plastic cup used in this experiment has a low mass, How does this help in the
experiment ? re]
2. An improvement suggested for the experiment was the use of a Styrofoam cup with a
cover through which the thermometer passed rather than an open polythene cup. Suggest
in what ways these were improvements to the experiment described above.
@ Styrofoam cup
Gi) cover
B]
3. Calculate:
@ the no, of moles of MgSO4 dissolved. \
(Gi) the enthalpy change taking place in this reaction
ii) the enthalpy of solution of anhydrous magnesium sulphate3. Draw an energy profile diagram to show the relative positions of the anhydrous salt
and its solution
Bl
4, In solid hydrated magnesium sulphate the ions have molecules of water of
crystallisation partially surrounding them. Suggest an explanation for the lower
exothermicity of the heat of solution of the hydrated salt as compared with the anhydrous
salt. BI