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# Application of a New Multicomponent Gas Adsorption Model to Coal Gas Adsorption Systems

C.R. Clarkson, SPE, Burlington Resources Canada Ltd.

Summary

Introduction

Adsorption is the primary storage mechanism of gas in coal res- ervoirs. Adsorption models are often coupled with material bal-

Original SPE manuscript received for review 2 April 2002. Revised manuscript received 30 April 2003. Paper SPE 78146 peer approved 18 May 2003.

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September 2003 SPE Journal

gradient) in a basin, causing variability in multicomponent adsorp- tion characteristics. The current model requires only that single- component adsorption data be collected at a single temperature. The range of temperature that could be handled accurately by the current model is uncertain at this time, however. The new multicomponent adsorption model is tested against three data sets that exist in the literature. Two of the data sets consist of CH 4 +CO 2 binary gas adsorption on coal, and the third consists of CH 4 +C 2 H 6 binary gas adsorption on activated carbon. Only the binary gas application is demonstrated for the current model, but it can be easily extended to multicomponent systems.

Single-Component Adsorption. Numerous single-component adsorption equations have been used to model coal adsorption isotherm data. The most popular is the Langmuir equation 11 :

s

n

bP

= n L

1 + bP

.........................................

(1)

Multicomponent Adsorption. The extended Langmuir model 7 and IAS theory 16 are most commonly used for the prediction of mixed gas adsorption on coal. Both the extended Langmuir model and IAS theory require pure component isotherm data for multi- component predictions. The simplest model used for prediction of multicomponent adsorption isotherms is the extended Lang- muir equation:

s

n i

n L i b i P i

=

N c

,

1 +

b j P j

j1

......................................

(2)

where (n L ) i and b i the pure gas isotherm Langmuir constants. Partial pressures of the component gases in the free gas phase are determined with the following equation:

P i = PY i

. .............................................

(3)

Langmuir parameters for pure component isotherms are used to predict component adsorbed volumes for gas mixtures at any total gas pressure and free-gas composition. The IAS theory 16 is based upon the assumption that the ad- sorbed mixture behaves like an ideal, adsorbed solution, and there- fore is analogous to Raoults law for bulk solutions. Activity co- efficients of the adsorbed solution are therefore assumed to be unity, and the equilibrium between the gas-phase mole fraction of a component and the adsorbed phase mole fraction is given by

PY i = P° i where i

X i ,

(4)

.......................................

the gas (vapor) pressure of the pure component ad-

sorbed at the same temperature and spreading pressure as the so- lution. Fugacities may be substituted for pressures in Eq. 4 to account for gas phase nonidealities. The spreading pressure for the pure components may be determined through integration of the Gibbs adsorption isotherm to the vapour pressure of the pure com- ponent, i

*

i

=

i A

RT

### =0

P i o n P

P

dP,

..............................

(5)

where n(P) the pure component adsorption isotherm. The spreading pressure ( ) may be defined as the reduction in surface tension of a surface owing to the spreading of the adsorbate over the surface. Any pure component isotherm equation can be used to evaluate Eq. 5. Mole fraction constraints include

N c

N c

X i = 1; Y i = 1.

i=1

i=1

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(6)

The total amount of adsorbed gas in the mixture (for an ideal

solution) is given by

1

N c

### s =

n m

i=1

X

i

. ..........................................

n

s,o

i

(7)

The actual amount of each component adsorbed in the mixture is given by

s

n i

= n m

i

s

X

. ............................................

(8)

Eq. 5 may be evaluated for each component using an isotherm equation, such as the Langmuir single-component isotherm equa- tion, or may be determined graphically. The IAS model has also been modified to include nonidealities in the adsorbed and gaseous phases and has been used to model multicomponent coal adsorp- tion data. 17 Recently, 2D EOS models have been applied to coal adsorption data with some success. 6 These models are 2D analogs of the popular 3D EOS, such as those of van der Waals and Peng- Robinson. Hall et al. 6 demonstrated that IAS and 2D EOS models give similar predictions for binary gas adsorption on coal, but are more accurate than the extended Langmuir equation.

New Model Derivation

Suwanayuen and Danner 9,10 and Cochran et al. 18 applied the con- cept of a vacancysolution to the modeling of single- and mul- ticomponent gas adsorption. The vacancy solution model (VSM), as developed by those authors, uses the concept of vacancy solu- tions, originally described by Dubinin, 19 and a thermodynamic treatment similar to that of Lucassen-Reynders. 20 22 Details of the VSM derivation will not be discussed here, but the conceptual model will be introduced.

The VSM treats the components in the adsorbed solution as a

mixture of a hypothetical solvent called vacancy,with adsorbate species. The gaseous solution, in (osmotic) equilibrium with the adsorbed solution, is also treated as a mixture of these components.

September 2003 SPE Journal

237

The equilibrium relationship between the two vacancy solutions

can be derived from basic thermodynamic principles; the equilib-

rium between the bulk (gaseous) solution and the 2D adsorbed

phase solution is treated analogously to the equilibrium between

multicomponent vapor and liquid solutions. Adsorbed solution

nonideality is accounted for with the use of an activity coefficient.

The main difference between the VSM of Suwanayuen and Dan-

ner 9,10 and that of Cochran et al. 18 is that the compositional de-

pendence of the activity coefficient is described by the Wilson

equation in the work of the former authors and by the Flory-

Huggins activity coefficient equations in the work of the lat-

ter authors.

The model developed in the current work uses the concept of

equilibrium between the gaseous phase and an adsorbed-phase

vacancy solution. The single-component isotherms utilized in the

new model are based upon the Dubinin-Polanyi theory. Significant

procedural differences exist between the current VSM approach

and that of other authors because of the treatment of the gaseous

and liquid solutions as bulk solutions, as with traditional vapor-

liquid equilibria. The concept of a spreading pressure, as used for

2D adsorbed phase treatments, is thus eliminated. The develop-

ment of the new VSM, referred to as VSM-DA, is detailed below

for single- and binary-gas adsorption. The new model combines

the analytical simplicity of the models described previously, is

thermodynamically rigorous, and has the added feature of being

able to predict temperature dependence of adsorption.

Single-Component Adsorption. As with the VSM, the current

model treats single-component adsorption as a binary mixture of a

single-component gas with a hypothetical vacancy species that

also occupies spaces that could be filled with adsorbate. The D-A

equation is used to generate activity coefficients for the single-

component gas in the binary mixture.

Chen and Yang 23 demonstrated that the D-R and D-A equa-

tions were approximations of an adsorption isotherm equation that

they derived from statistical thermodynamic principals. A theoret-

ical basis for the D-R and D-A equations was thus demonstrated.

The equivalence of the D-A equation with Chen and Yangs

isotherm is shown with the following equation (Eq. 30 in Chen

and Yang 23 ):

ln = −

K ln P

kT

# o n = −

P

ln

RT

P

o n

KN o

P

,

.............

(9)

where W/W o .

Eq. 9 is the D-A equation with the following constraint:

KN o = E o

. ........................................

(10)

Eq. 9 was derived by equating the chemical potential for the bulk

(gas) phase and the adsorbed phase at temperature T for two dif-

ferent gas pressures, P and P o . The two relationships were summed

and several further approximations yielded Eq. 9. The following

critical approximation was used in the derivation of Eq. 9:

|ln | | ln

# o |

P

P

,

...................................

(11)

which is approximately valid for moderate values of .

If this assumption is not made, then Eq. 9 may be rewritten with

some algebraic manipulation as

ln +

KN o

RT

ln 1 n ln

# o

P

P

= 0.

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(12)

Using Eq. 10, Eq. 12 becomes

ln +

E o

RT

ln 1 n ln

o = 0,

P

P

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(13)

which is a more general form of the D-A equation. This equation

may be fitted to experimental isotherm by optimizing the param-

eters W o , n, and D

E o

RT

. Despite the successful application of the

D-A equation to many adsorption systems, the D-A equation (as

well as the D-R equation) has been criticized because of an incor-

rect low-pressure limit. Recently, Sundaram 24 proposed a modifi-

cation to the Dubinin isotherm that incorporates a Henry s

law limit.

In the current work, the adsorbed phase is treated as a bulk

mixture of the hypothetical vacancy species and the single-

component adsorbate. Nonideal solution theory may then be used

to model the adsorbed-phase behavior, starting with the definition

of the chemical potential of the single component (nonvacancy) in

s

1

= s + RTln X

1

s

1

s

1

,

.................................

(14)

where

s

1

=

P 1

X

s

1

P

.

1

..........................................

(15)

If

s

1

1, then Raoults law results.

Gaseous Phase. Assuming ideal gas behavior,

s

1

= go + RT ln

1

# o

P

1

P

1

.

...............................

(16)

If the chemical potential of the component in the gas phase and

s + RT ln X

1

s

1

s

1

go RT ln

1

o = 0.

P

1

P

1

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(17)

If the reference state for the gas phase is chosen as the saturated

vapor pressure at temperature T, then

s

ln X

1

s

1

ln

P

1

P

1

= 0.

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(18)

In the work by Suwanayuen and Danner, 9 the assumption was

component was equal to the fractional coverage. If the assumption

is made that the degree of pore-filling is equal to the mole fraction

of the adsorbate in the current work, then Eq. 18 becomes

ln

s

1

ln

P

1

P

1

= 0.

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(19)

A method of determining the adsorbed-phase activity coefficient is

obtained if Eq. 19 and Eq. 13 are equated (noting that P P o ):

1

ln s 1 ln +

E o

RT

(−ln ) 1/ n , or

s

1

=

exp ln +

E o

RT

ln 1 n

= exp E o

RT

ln 1 n

. ....

(20a)

If Eq. 9 is used in the derivation of the activity coefficient instead

of Eq. 13, then

s

1

=

exp E o

RT

ln 1 n

. ............................

(20b)

Thus, a method for generating adsorbed phase activity coefficients

is obtained.

A method for predicting multicomponent activity coefficients

from the single-component data (binary vacancy solutions) is re-

quired to model multicomponent adsorption data. The Wilson

equation is chosen to fit the activity coefficients calculated from

Eq. 20 by optimizing the binary interaction coefficients. The equa-

phase is

s

1

= exp

1 ln X

# −

1

11 + X v 1v

X

s

1

11

s

s

v vv

s

X

s

v

v1

X

s

1

11 + X

s

v

1v

+

X

s

1

v1 + X

.......

(21)

is used here, but the following procedures may be extended to

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September 2003 SPE Journal

solution theory requires that binary equilibrium adsorption be

treated as equilibrium between ternary vacancy solutions (two

ponent in the adsorbed and gaseous phases becomes:

i s = i s + RT ln i s X

s

i

,

.................................

(22)

where i 1, 2 for adsorbed (nonvacancy) components.

Gaseous Phase. Assuming ideal gas behavior,

i g = i g + RT ln

# o

P

i

P

i

.................................

(23)

If the chemical potential of the component in the gas phase and

n s, is optimized instead of W o . In the current work, a least-squares

1

routine coupled with a multiparameter optimization algorithm in

MATLAB ® was used to optimize the isotherm parameters. Mul-

tiparameter optimization runs were re-initiated at several starting

points to ensure that the convergence to the same point occurred.

2) Calculate the activity coefficients as a function of degree of

filling for each component using the regressed parameters, calcu-

lated in Step 1, and Eq. 20.

3) Calculate binary interaction coefficients 1v , v1 by fitting

Eq. 21 to the activity coefficient curve generated by Eq. 20

(Step 2); for simplification, Lambda; 11 , vv may be assumed equal

to unity.

4) Assume a value for X 1 (X 2 1X 1 ).

5) Calculate n m from Eq. 29.

s,

6) Use Eq. 28 to calculate the activity coefficients for the ad-

sorbed components.

i s + RT ln i s X i s + RT ln

P

P

7) Solve the two equilibrium equations (components i and j)

(24)

s

derived from Eq. 27 simultaneously for Y 1 (Y 2 1Y 1 ) and n m .

# oi i

Because the standard state for the adsorbed and gaseous compo-

nents are assumed to be equal, then

P

i

Temperature Invariance Condition

Eq. 9 and the D-R equation (assuming n 2) were derived from the

following relation:

ln i s X i s = ln

P

# •

i

(25)

= f E A ,n ,

(30)

As with Suwanayuen and Danner, 10 the following relationships

are assumed:

where

X i s = X i ,

s

n m

(26)

A = RT ln P o ,

P

......................................

(31)

where =

s,

n m

.

and

Substituting Eq. 26 into Eq. 25,

E = E o

(32)

ln i s X i = ln Y i P ,

P

i

A unique feature of Dubinin-Polanyi theory is that character-

..................................

(27)

istic curves, or plots of vs. A, are temperature-invariant for many

where Daltons law is assumed for component partial pressure.

The activity coefficient for each component in the ternary ad-

system, then E and n are also temperature-invariant. Thus, if E and

sorbed solution may be described by the Wilson equation:

n are derived from an isotherm at one temperature, then isotherms

at different temperatures may be easily derived. Dubinin 8 dis-

cusses the range of for which the temperature-invariance condi-

i s = exp

1 ln X i s + X j s ij + X

s

• v iv

• X s

tion holds.

• i X j s ji

X i s ji + X j s + X

s

v jv

Illustrations of how the temperature-invariance principle can be

used to calculate single-component isotherms for coal gas systems

at different temperatures have been discussed elsewhere (i.e., Rup-

pel et al. 13 and Clarkson et al. 14 ). The current study uses the new

multicomponent adsorption model derived above to calculate bi-

nary gas total adsorption at different temperatures. Procedurally,

this is achieved as follows:

1) Follow Steps 1 and 2 in the previous section using single-

component isotherms at one temperature.

# −

X i s + X j s ij + X

• X v s vi

s

v iv

+

+

• X i s vi + X j s vj + X

• v

s

(28)

E o

2) Recalculate D =

RT

for both component gases at the new

temperature(s), assuming E is temperature-invariant.

where i,j 1,2 or 2,1.

An expression is now required for n m , the maximum total

s,

number of moles in the adsorbed mixture. The expression utilized

3) Follow Steps 2 through 7 in the previous section to calculate

binary adsorption amounts at the new temperature.

Implicit in the above procedure is that n s, or W o is tempera-

1

by Suwanayuen and Danner 10 for the adsorbed vacancy solution is

= X 1 n

s,

n m

s, 1 + X 2 n

s,

• 2 . .................................

(29)

ture-invariant. Dubinin 8 provides a method for correcting for the

temperature dependence of the maximum adsorbed amount.

Application of Model to Binary Gas Adsorption

Calculation Procedure

The following procedure is required to calculate mixed gas ad-

sorption equilibrium compositions and total mixed gas adsorption

isotherms from the pure component data, using the example of

1) Use Eq. 13 or Eq. 9 to obtain the parameters W o , n, and

D= E o for each component through regression from experimental

RT

data. P o in Eq. 13 or Eq. 9 is calculated using the reduced Kirchoff

equation (Kapoor et al. 25 ). In the case of experimental data

expressed as n

s

1

 s as a function of pressure, n 1 , and therefore n s, 1

September 2003 SPE Journal

Data Sets

Three binary gas adsorption data sets were chosen to test the new

model predictions: CH 4 +CO 2 binary gas adsorption on moist

Fruitland coal data of Hall et al., 6 CH 4 +CO 2 binary gas adsorption

on dry Westcliff Bulli seam-coal data of Stevenson et al., 17 , and

CH 4 +C 2 H 6 binary gas adsorption on activated carbon data of

Reich et al. 26 The new model predictions are compared graphically

against those of IAS theory, 16 using the Langmuir equation to

CH 4 +CO 2 Adsorption Data on Moist Fruitland Coal. Hall et

al. 6 collected adsorption data for pure CH 4 and CO 2 (as well as N 2 )

239

and for their binary mixtures at 115ºF on moist Fruitland coal at

Optimized parameters for the D-A and Langmuir equations are

 pressures up to 1,800 psia. Only the CH 4 +CO 2 data is modeled given in Tables 2a and 2b. The optimized parameters for the D-A here. CO 2 isotherm data for pressures below 1,010 psia were used equations (Eq. 9 and Eq. 13) were obtained from using lnP/P o because of the inflection adsorption data at higher pressures, as (experimental and calculated) in the least-squares function, as op- discussed in Hall et al. 6 The feedgas compositions used for binary posed to adsorbed amount (experimental and calculated) for the adsorption were 20, 40, 60, and 80%, thus providing a large range Langmuir equation. in compositions that are ideal for model testing. The Langmuir equation fit to the data is not as good as the D-A The fit of the D-A equation (Eq. 13 is plotted) to CH 4 and CO 2 equation, as discussed previously. 27 This is because the D-A equa- isotherm data is shown in Fig. 1a. Eq. 9 gave a very similar match, tion has three optimized parameters vs. two for the Langmuir and is not plotted. The quality of fit (%AAD, see Table 1 for equation.

definition) for the D-A and Langmuir equation is also shown in

Fig. 1a. Note that the %AAD is given for the D-A Eq. 9 instead of

Eq. 13 (which is plotted in the figure). The reason for this is that

Eq. 9 can be written explicitly in terms of the adsorbed amount

(Eq. 13 cannot), facilitating a direct comparison with the Langmuir

equation because the adsorbed amount is used in the least-squares

function for both Eq. 9 and the Langmuir equation (as opposed to

lnP/P o for Eq. 13).

The pure component gas adsorbed-phase activity coefficients

generated from the D-A equation (Eq. 20a and Eq. 20b) for CH 4

and CO 2 are shown in Figs. 2 and 3, along with the Wilson

equation fit to the activity coefficient curves. The Wilson equation

was fit to the activity coefficient curve over the pore-filling range

represented by the experimental data. The Wilson equation fit is

not particularly good over the range of pore-filling shown, sug-

gesting that another activity coefficient equation may be more

Fig. 1—(a) Hall et al. 6 CH 4 and CO 2 isotherm data (115°F) and model fits; (b) Stevenson et al. 17 CH 4 and CO 2 isotherm data (86°F) and model fits.

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September 2003 SPE Journal

appropriate for binary interaction parameter calculation. Equilib-

rium (isobaric) compositional diagrams at 1,800, 1,000, and 120

psia are shown in Figs. 4a through 6a. The new model predictions

(using activity coefficients calculated from Eq. 20a and Eq. 20b),

along with those of IAS theory, are shown. The new model pre-

dictions are comparable, if not slightly better than, IAS theory. The

predictions using Eq. 20b to model single-component adsorbed

phase activity coefficients are better than those using Eq. 20a, as

demonstrated in Table 1, which summarizes the relative error cal-

culations for total adsorption and gaseous-phase mole fraction.

Total adsorption vs. gaseous-phase mole fraction is shown in

Figs. 4b through 6b for 1,800, 1,000, and 120 psia. At 1,800 psia,

the new model underpredicts the total adsorption for high values of

CO 2 gaseous-phase mole fraction because of the inflection in CO 2

adsorption at high pressures. Overall, the model predictions for

total adsorption are very good, being within 10% of the experi-

mental data.

CH 4 +CO 2 Adsorption Data on Dry Bulli Seam Coal. Stevenson

et al. 17 collected adsorption data for pure CH 4 and CO 2 (as well as

N 2 ), and their binary and ternary mixtures at 86ºF on dry Westcliff

Bulli seam coal at pressures up to 850 psia. Again, only the

CH 4 +CO 2 data are modeled. The feedgas compositions for the

Stevenson et al. 17 binary data set span a wide range as with

the Hall et al. 6 data set. The new model predictions, using Eq. 20b

to calculate pure component adsorbed-phase coefficients, are

shown only.

The fit of the D-A equation (Eq. 13 is plotted) to CH 4 and CO 2

isotherm data is shown in Fig. 1b. As with Fig. 1a, %AAD is given

for the D-A Eq. 9 (using adsorbed amount in the least-squares

function) instead of Eq. 13. Optimized parameters for the D-A and

Langmuir equations are given in Tables 3a and 3b. The optimized

parameters for the D-A equations (Eq. 9 and Eq. 13) were obtained

from using lnP/P o (experimental and calculated) in the least-

squares function, whereas the adsorbed amount (experimental and

calculated) was used for the Langmuir equation. The Langmuir

equation fit to the data is also shown, and is not as good as the D-A

Eq. 9, as with the Hall et al. 6 data. Note that the units of adsorption

in Fig. 1 are kept consistent with the original authors, even though

the pressure axis was changed from units of kPa to psia.

The pure component gas adsorbed-phase activity coefficients

generated from the D-A equation (Eq. 20b) for CH 4 and CO 2 are

shown in Fig. 7, along with the Wilson equation fit to the activity

coefficient curves. The Wilson equation was again fit to the ac-

tivity coefficient curve over the pore-filling range represented by

the experimental data. The Wilson equation fit to the CO 2 curve is

not particularly good over the range of pore-filling shown, further

supporting the application of another activity coefficient equation

to the adsorption data. The match is particularly poor for high

degrees of pore-filling. The Wilson equation fit to the CH 4 curve

is better, owing to fitting over a smaller range of data.

Equilibrium (isobaric) compositional diagrams at 800 and 120

psia are shown in Figs. 8a and 9a. The new model predictions for

this data set are worse than IAS theory, probably because of the

poor fit of the Wilson equation to the activity coefficient curves.

Table 4 summarizes the relative error calculations for total ad-

sorption and gaseous-phase mole fraction.

Total adsorption vs. gaseous-phase mole fraction is shown in

Figs. 8b and 9b for 800 and 120 psia, respectively. At both pres-

sures, the new model underpredicts total adsorption. Overall, the

model predictions for total adsorption are very good, being within

5% of the experimental data.

CH 4 +C 2 H 6 Adsorption Data on Activated Carbon: Tempera-

ture Dependence Predictions. The CH 4 +C 2 H 6 pure and binary

gas adsorption data of Reich et al. 26 are used to test the predictions

of the new model for adsorption at various temperatures. This data

set was chosen as the pure, and binary data was collected at vari-

ous temperatures.

The ability of the new multicomponent adsorption model to

predict adsorption as a function of temperature is contingent upon

the temperature invariance of the characteristic energy of adsorp-

tion, E, and the D-A exponent n. The CH 4 and C 2 H 6 pure com-

ponent isotherms at 8.7°F were first fit with Eq. 9, and the param-

eters n s, , n, and D, obtained from nonlinear regression. The pure

1

component isotherms at 82.9°F were then predicted from the 8.7°F

isotherm data by recalculating the D parameter at 82.9°F. This is

done by assuming E is temperature-invariant, and by using the

following relation:

September 2003 SPE Journal

241

D 2 =

T 1 D 1

T 2

data. In this analysis, n s, is not adjusted for the thermal expansion
1
...........................................
(33)
of the adsorbate (i.e., Dubinin 8 ). The procedure for calculating the

binary gas equilibrium at the new temperature then follows that

The pure component isotherms are then calculated at the new

temperature (82.9°F) using the D parameter, adjusted for tem-

perature, n, and n 1 s, , calculated from the 8.7°F pure component

described in the Calculation Procedure section given above.

The fit of the D-A Eq. 9 to the pure component data at 8.7°F,

the 82.9 ° F predictions, and the experimental data are

Fig. 2(a) CO 2 activity coefficient plot, derived from D-A (Eq. 20a); (b) CH 4 activity coefficient plot, derived from D-A (Eq. 20a).

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September 2003 SPE Journal

Fig. 3(a) CO 2 activity coefficient plot, derived from D-A (Eq. 20b); (b) CH 4 activity coefficient plot, derived from D-A (Eq. 20b).

given in Fig. 10a. Optimized parameters (using lnP/P o in least-

squares function) for the D-A equation are given in Table 5. The

prediction of adsorption at 82.9°F is reasonable at low pressures,

but some deviation occurs at high pressures. The deviation is likely

caused by the fact that n s, was not corrected for thermal effects.

1

Table 6 summarizes the relative error calculations for the

VSM-D-A model applied to the 8.7°F binary (74.5% CH 4 /25.5%

C 2 H 6 ) adsorption data.

The predictions for binary (74.5% CH 4 /25.5% C 2 H 6 ) gas total

adsorption at 82.9°F are shown in Fig. 10b. The predictions are

very good, with only small deviation occurring at high pressure.

Discussion

The proposed multicomponent adsorption model, which is a hybrid

of the Dubinin-Polanyi and vacancy solution theories, describes

binary gas adsorption behavior of coal systems quite well, al-

though some improvements could possibly be made.

The Wilson equation has been used to model pure gas (binary

with inclusion of vacancy species) adsorbed-phase activity coef-

ficients, as well as the binary gas (ternary with inclusion of va-

cancy species) adsorbed-phase activity coefficients. It is apparent

that the Wilson equation fit to the pure component data is not

optimal, and is likely the cause of some error in binary predictions.

The original vacancy solution theory also utilized the Wilson equa-

tion to model nonideality in the adsorbed-phase solution, but im-

provements were later made by incorporating the Flory-Huggins

activity coefficient equations. 18 Future studies will include the

application of other activity coefficient equations and their effect

upon the new model predictions.

The development of the new model assumed that the gaseous

phase behaved ideally, and thus activity coefficients for the gas-

eous phase were not included. Although this assumption is not

necessary, it reduces computational complexity. Some insight into

the effect of noninclusion of gas-phase nonideality corrections

September 2003 SPE Journal

243

Fig. 4(a) Binary CH 4 +CO 2 equilibrium compositions; (b) binary CH 4 +CO 2 total adsorption: 1,800 psi.

upon predictions may be obtained from a study by Manik. 28 In this

study, predictions of binary gas adsorption were compared by

using IAS theory with (IAS-RG) and without (IAS-PG) correction

for gas-phase nonideality. The data set of Stevenson et al. 17 was

used. Equilibrium concentration and adsorption capacity predic-

tions for IAS-RG and IAS-PG appear to be in good agreement for

low (120 psia) and high (800 psia) pressures. The impact of the

ideal gas assumption upon binary gas prediction for the new model

is similarly expected to be small, but will be studied in future work.

Conclusions

• 1. A new multicomponent adsorption model, which was derived by combining the vacancy solution and Dubinin-Polanyi theories, is reasonably accurate for binary gas/coal adsorption systems.

• 2. Adsorbed-phase activity coefficient curves derived for pure component adsorption are not accurately fit by the Wilson equa- tion, causing some error in binary gas predictions.

• 3. Improvements to the new model could be made through the use of different activity coefficient equations and the incorporation of gaseous-phase activity coefficients.

• 4. The prediction of adsorption temperature dependence is easily achieved with the new model, owing to the incorporation of

Dubinin-Polanyi theory. Limited testing of the model (over

a small temperature range) illustrates these predictions to

be accurate.

Nomenclature

A specific surface area of adsorbent, m 2 /g

b Langmuir model constant, 1/psi

D

E o

RT

, D-A equation parameter, dimensionless

E o characteristic energy of adsorption for standard

vapor, J/mol

k Boltzmanns constant, 1.381 ×10 23 J/K

K constant in Eq. 9

n constant in Dubinin-Astakhov equation,

dimensionless

n L Langmuir model constant, mol/g

n s number of moles of pure component in the adsorbed

phase (Eq. 1), mol/g

n s number of moles of component i in the adsorbed

i

phase mixture, mol/g

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September 2003 SPE Journal

Fig. 5(a) Binary CH 4 +CO 2 equilibrium compositions; (b) binary CH 4 +CO 2 total adsorption: 1,000 psi.

n s,o amount of pure component adsorbed from pure gas at

i

the same temperature and spreading pressure as the

n s, maximum number of moles of component i in the

i

n

s

m

number of moles of mixture in the adsorbed phase,

mol/g

maximum number of moles of mixture in the

s,
n m

N c number of components

N o Avogadros number, 6.022 × 10 23 mol 1

N p number of data points

P pressure of the gas phase, psi

P o saturated vapor pressure, psi

P

° reference-state pressure of the pure gaseous

i

component i, or gas (vapor) pressure of the pure

component adsorbed at the same temperature and

September 2003 SPE Journal

spreading pressure as the solution (Eqs. 4 and 5),

psi

P i reference-state pressure of the pure component i

chosen as saturated vapor pressure of component i at

same temperature as adsorbed solution, psi

R universal gas constant, 8.314 J/mol K

T absolute temperature, K

W adsorbed amount at pressure, P, cm 3 /g

W o adsorbed amount at saturated vapor pressure (limiting

volume of the adsorption space), cm 3 /g

X i mole fraction of component i in the adsorbed phase

(no vacancy), dimensionless

X s mole fraction of component i in the adsorbed phase

i

vacancy solution, dimensionless

Y i mole fraction of component i in the gaseous phase,

dimensionless

similarity coefficient, dimensionless

245

Fig. 6(a) Binary CH 4 +CO 2 equilibrium compositions; (b) binary CH 4 +CO 2 total adsorption: 120 psi.

s activity coefficient of component i in adsorbed phase

i

vacancy solution, dimensionless

ij , ji Wilson equation parameter, binary interaction

constant between components i and j, dimensionless

s chemical potential of component i in adsorbed phase

i

vacancy solution, J/mol

s i reference-state chemical potential of component i in

g i chemical potential of component i in gaseous phase,

J/mol

g i ° reference state chemical potential of component i in

gaseous phase, J/mol

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September 2003 SPE Journal

* reduced spreading pressure, Eq. 5, mol/g

(see Chen and Yang 23 )

exp experimental

i component i

L Langmuir

m mixture

Subscripts
calc calculated
v vacancy

Fig. 7(a) CO 2 activity coefficient plot, derived from D-A (Eq. 20b); (b) CH 4 activity coefficient plot, derived from D-A (Eq. 20b).

September 2003 SPE Journal

247

Fig. 8(a) Binary CH 4 +CO 2 equilibrium compositions; (b) binary CH 4 +CO 2 total adsorption: 800 psi.

Superscripts

g gaseous phase value

o, reference state

Acknowledgments

The author would like to thank the management of Burlington

Resources for granting permission to publish this paper. I would

also like to gratefully acknowledge Drs. R.L. Robinson and K.A.M

Gasem of Oklahoma State U. for reviewing the new model

thermodynamic derivation. Their insights and suggestions

are appreciated.

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September 2003 SPE Journal

Fig. 9(a) Binary CH 4 +CO 2 equilibrium compositions; (b) binary CH 4 +CO 2 total adsorption: 120 psi.

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Fig. 10Reich et al. 26 CH 4 and C 2 H 6 : (a) Isotherm data and model fits; (b) binary (CH 4 +C 2 H 6 ) total adsorption data. The prediction of temperature dependence is shown.

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the 1991 SPE Asia-Pacific Conference, Perth, Western Australia, 47 November.

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SI Metric Conversion Factors

 °F (ºF–32)/1.8 ºC psi × 6.894 757 E+00 kPa

Christopher R. Clarkson is a senior reservoir engineer with Bur- lington Resources Canada Ltd. e-mail: cclarkson@br-inc.ca. His work focus has been on exploration for and development of coalbed methane reservoirs. He has studied both primary and enhanced coalbed methane recovery processes in the San Juan basin of New Mexico/Colorado and is particularly interested in the application of reservoir simulation to optimize coalbed gas recovery and well performance. Clarkson holds a PhD degree in geological engineering from the U. of British Columbia, Canada.

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