TUGAS KULIAH KIMIA ANALITIK DASAR BAGIAN I (MINGGU 1-4

)
Tahun 2017
Pengampu: Suherman, S.Si. M.Sc. Ph.D
1. For each of the following problems indicate whether its solution requires a qualitative,
quantitative, characterization, or fundamental study. More than one type of analysis may be
appropriate for some problems.
a. A hazardous-waste disposal site is believed to be leaking contaminants into the local
groundwater.
b. An art museum is concerned that a recent acquisition is a forgery.
c. A more reliable method is needed by airport security for detecting the presence of explosive
materials in luggage.
d. The structure of a newly discovered virus needs to be determined.
e. A new visual indicator is needed for an acid–base titration.
f. A new law requires a method for evaluating whether automobiles are emitting too much carbon
monoxide.

2. Ketika seorang analis kimia ingin mengetahui kadar besi dalam sayuran bayam (satu ikat
bayam) seberat 300 gram, maka selesaikanlah masalah ini berdasarkan runtutan ‘analytical
perspective’ / prosedur analitik yang baku (yang terdiri dari 6 tahapan).

3. A sample was analyzed for the concentration of two analytes, A and B, under two sets of
conditions. Under condition 1, the calibration sensitivities are
kA,1 = 76 ppm–1kB,1 = 186 ppm–1 and for condition 2
kA,2 = 33 ppm–1kB,2 = 243 ppm–1
The signals under the two sets of conditions are
Smeas,1 = 33.4 and Smeas,2 = 29.7
Determine the concentration of A and B. You may assume that Sreag is zero under both
conditions.

4. The class A 10-mL pipet characterized in Table 4.8 is used to deliver two successive volumes.
Calculate the absolute and relative uncertainties for the total delivered volume.