DK035

Semester III 2014/2015
Quiz 1/Set 3

KOLEJ MATRIKULASI KEDAH

QUIZ 1 (THERMOCHEMISTRY)
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NAME:_________________________________ TUTORIAL:___________________

Answer all questions.

1. Given; lattice energy of MgCl2 = -2500 kJ mol-1
Enthalpy hydration of ion chlorine = -364 kJ mol-1
Enthalpy hydration of ion magnesium = x kJ mol-1
Enthalpy of solution of MgCl2 = -163 kJ mol-1

a) Consruct a thermochemical sysle to show the relationship between enthalpy of
solution of MgCl2, lattice energy of MgCl2 and enthapy of hydration of both Mg2+ and
Cl- ion.

b) Calculate the enthalpy of hydration of magnesium ion.
[5 marks]

B. C ------------------------ ∆H5 = -644 kJ ∆H4 = + 204 kJ Be2+(g) + 2e + Br2(l) Be2+(g) + 2e + 2Br2(l) ∆H3 = +1761 kJ B ------------------------ ∆H2 = + 899 kJ ∆H6 = -2894 kJ Be(g) + Br2(l) ∆H1 = +320 kJ 0 A------------------------ ∆H7 = -645 kJ BeBr2(s) a) Write the equation fro reaction in A. b) State the name of ∆H3 [ 5 marks] .DK035 Semester III 2014/2015 Quiz 1/Set 3 2. BeBr2 is shown as follows. Born-Haber cycle for Berylium bromide. C and D.

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