DOI:10.13840/j.cnki.cn21-1457/tq.2011.11.

031

40 11 Vol.40No.11
2011 11 Contemporary Chemical Industry November2011

Pt/Pd

113001

Pt/Pd
Pt/Pd
250 20 000 h-1 97%

; Pt/Pd
TQ 426 A 1671-0460201111-1101-03

Study on Treatment of Benzene Homologues-Containing Waste

Gas by Catalytic Combustion With Pt/Pd Catalyst
WANG Xiao-nanZHAO LeiHAO Xiao-xiaWANG XinLIU ZHong-sheng
Fushun Research Institute of Petroleum and PetrochemicalsLiaoning Fushun 113001China

Abstract: Benzene homologues-containing waste gas was treated by catalytic combustion with Pt/Pd catalyst.
The catalytic combustion experiment results show that benzene homologues-containing waste can effectively be
oxidized by Pt/Pd catalyst. When inlet temperature of the reactor is 250 and the space velocity is 20 000 h-1,
the removal effect of pollutants can be above 97%, treated gas can meet national emission standards.
Key words: Catalytic combustion Benzene emissions Pt/Pd catalysts Waste gas treatment

JUM
[1]

1.2

[2]
1
3
, 5 000 mg/m

[3] JUM

1

w1 w2
a= 100% 1
w1

[4] %
w1mg/m
3

CO2 H2O w2mg/m

3

[5,6]
2
5 m /h
3

FRIPP 1
Pt/Pd


1
CO2
1.1 H2O
99.99% Pt/Pd
2011-10-17
1985-2009
E-mailwangxiaonan.fshy@sinopec.com024-56389529
1102 2011 11
2
2.1 Pt/Pd
20 000
-1
h 250
Pt/Pd



1
Fig.1 The process of catalytic combustion

3Pt/Pd

FRIPP Pt/Pd
2.2
-1
20 000 h 250

4
Pt/Pd
Pt/Pd
2 2

Pt/Pd

97%
5
2
Table2 The experimental results of catalytic combustion

-3 -3 ,%
/ /(mgm ) /(mgm )

1 253 3 930 3.5 99.9

1
2 248 1 264 30.6 97.6
1 3 250 1 980 17.5 99.0
Table 1 Composition of simulated exhaust gas
-3
4 252 2 323 20.3 99.1
/(mgm )

-3
/(mgm ) 5 251 1 200 13.5 98.9

1 3 930 - - - - 3 930
2.3
2 - 1 264 - - - 1 264 -1
20 000 h
3 - - 1 980 - - 1 980
4 - - - 2 323 - 2 323
250 300 Pt/Pd
5 - - - - 1 200 1 200 4
6 210.2 240.4 60.1 1321.3 - 1 891.9 3
7 210.2 1 321.3 210.2 2 012 - 4 264.3
3
Table 3 The experimental results of catalytic combustion
-3
/(mgm )

/ ,%
251 1891.9 10.5 99.4
6
a. 300 1930 4.8 99.8

Pt/Pd 250 4264.3 19.3 99.5

7
300 4110 12.8 99.7

Pt/Pd
b.
99%

Pt/Pd 1106
1106 2011 11
2.7.2 (SEM) 73%
MCM-41 (2)FT-IR TiO2 S2O82-
8 SEM
TiO2
(3)


TiO2/S2O82-/MCM-41



(a)MCM-41 (b)
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Fig.8 SEM image of MCM-41and catalyst
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(), 2002,25(3)144-146.
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MCM-41 [5].,,. MCM-41

[J].:2011,40(5).
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3 ,2006.
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(1)
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5 h 550 ,2005.
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-1
1102 250 20 000 h
97%
3
1 Pt/Pd
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[J].200020(3):27-33
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[3] ,,.[J].
,2003,23(6):341-343.
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, 2006(01):32-56.

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3 Pt/Pd