Going zinc

Going zinc- free

Anticorrosive Pigments

Z inc- free Ant i co r ro s i ves

Smart , innovative and effective

Calcium Modified Silica Pigment HE U C OS IL CTF is a high-performance pigment for demanding coating systems. Modified Polyphosphates HE U C OPHOS ® CAPP gives good results in water based two-part epoxy resins and coating systems based on dispersions. The search for chromate replacements in high performance applications. It is a calcium aluminum polyphosphate silicate hydrate. 2 . It is an alternative to standard zinc phosphate. It is therefore no surprise that the call for zinc-free anti- corrosive pigments or those that do not require labeling has steadily increased in recent years. ecological and regulatory factors play an increasingly decisive role nowadays in the formulation of innovative coating systems. as alternative to versatile pigments for long-term performance. HE U COP HOS ® S APP & HEUCOPHOS ® S R PP are strontium aluminum polyphosphate hydrates and high-performance pigments. It is a highly effective zinc-free Anticorrosive based on a calcium modified silica gel meeting the specific performance requirements for thin-film applications. such as coil coatings and aircraft primers led to the development of the polyphosphate line. The corrosion protection of pre-treated steel and aluminum sheets is becoming increasingly important and requires continuous R&D efforts to provide suitable and effective corrosion protection solutions. Heubach‘s range of zinc-free Anticorrosives provides environmentally friendly solutions even in demanding primer systems. SRPP and CAPP. alternatives to zinc and chromate containing Anticorrosives. HE U COP HOS ® AC P is a modified calcium phosphate silicate. which comprises the types HEUCOPHOS® ZAPP. SAPP. It is a calcium magnesium orthophosphate as alternative to versatile pigments for long-term performance. Requ irements > Modified non-zinc metal complex > Anodic inhibition and barrier properties > Universal applicability > Easy handling > Stability in a broad range of resins Pro d uc t Portf olio Ca l c i u m Phos phate CP is a zinc-free anti-corrosive pigment for the application in protective coatings. Modified Orthophosphates HE U COP HOS ® CMP is a new unique zinc-free Anticorrosive with universal applicability. Heubach´s high performance polyphosphates are among the technically most sophisticated anti- corrosive inhibitors in today´s market and the preferred option wherever ultimate protection is required. Zinc-free Anticorrosives Product Portfolio Besides economic considerations.

e.e.e.: under evaluation Resins with low or no VOCs 3 .e. +++ +++ ++ + Wash and shop primers + ++ ++ Direct to metal one coat +++ u. + UV cured systems u. ++ Powder coatings + ++ ++ +++ Excellent choice ++ Good choice + Possible choice In addition recommended in combination with HEUCORIN® (zinc containing) u.e.e. ++ WATER BASED COATINGS Alkyd emulsions ++ ++ ++ ++ Epoxy dispersions + ++ +++ + +++ 1-part polyurethanes + ++ + 2-part polyurethanes + ++ +++ + ++ ++ Silicone resins u.Zinc-free Anticorrosives Application Guide Calcium Orthophosphates Polyphosphates Others Phosphate HEUCOPHOS® HEUCOSIL NEW SOLVENT BASED COATINGS CP ACP CMP SAPP SRPP CAPP CTF Short and medium oil alkyds ++ +++ +++ ++ Long oil alkyds + ++ ++ High solids alkyds ++ + Epoxies + + +++ +++ ++ ++ Epoxyesters ++ +++ ++ High solids epoxies +++ + ++ Polyurethanes + ++ ++ +++ ++ ++ ++ High solids polyurethanes + ++ ++ ++ ++ Moisture cured polyurethanes + + Silicone resins ++ +++ u. +++ +++ ++ +++ Aircraft primers u. ++ + Acrylics and modified acrylics + + ++ ++ Butadienes ++ +++ +++ + SPECIALTY COATINGS Coil coatings u.e.

Calcium Phosphate CP 504h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: Solvent based short-oil alkyd DFT: 70 microns Substrate: Cold rolled steel panels ST 1205 Control Zinc Phosphate Calcium Phosphate CP 4 . slightly soluble calcium phosphate. Zinc-free Anticorrosives Calcium Phosphate Acc e lera t e d We a th e r i ng Te s ts Blistering Adhesion Undercutting Field Rusting C alc iu m P h o s p h a te is a cost-effective. for medium-level corrosion protection in water and solvent-based coatings.

Sr.) Steel HEUCOPHOS® CMP 408h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: Solvent based short-oil alkyd DFT: 70 microns Substrate: Cold rolled steel panels ST 1205 Control Magnesium Phosphate HEUCOPHOS® CMP HEUCOPHOS® CMP 504h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: Solvent borne 2-part epoxy primer DFT: 70 microns Substrate: Sand blasted steel Control Zinc Phosphate HEUCOPHOS® CMP HEUCOPHOS® ACP 288h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: Water based alkyd emulsion DFT: 80 microns Substrate: Cold rolled steel panels ST 1205 Competition zinc-free Control HEUCOPHOS® ACP pigment 5 .Zinc-free Anticorrosives Orthophosphates Mo d ifie d O r th o p h o s p h a te s O 3- | Corrosion protection with zinc-free orthophosphates O= P– O | orthophosphate > Anodic passivation-phosphate layers O anion > Precipitation of M(OH)x (barrier) -> (M=Ca. Mg….

Zinc-free Anticorrosives Polyphosphates Mo d ifie d Po l y p h o s p h a te s O 3- O O O 5- | | | | Corrosion protection with zinc-free polyphosphates O= P– O O– P– O– P– O– P –O | || || || > Deposition of polyphosphate films on the metal surface O O O O > S tabilizing metal cations by chelating effect on iron-> Ion scavenger orthophosphate Tripolyphosphate anion anion > Dissociation back to orthophosphates. Sr. anodic passivation > Precipitation of M(OH)x (barrier) -> (M=Ca.) HEUCOPHOS® CAPP 1406h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: 2K-Polyurethane DFT: 60 microns Substrate: Hot dipped galvanized steel Control Calcium Phosphate HEUCOPHOS® CAPP HEUCOPHOS® SAPP 432h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: High-Solids 2K-Polyurethane DFT: 70 microns Substrate: Cold rolled steel panels ST 1205 Control Magnesium Phosphate HEUCOPHOS® SAPP HEUCOPHOS® SRPP 3360h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: Polyester coil primer with polyester top coat DFT: Primer: 6-8 microns Top Coat: 20-24 microns Substrate: Hot dipped galvanized steel. Mg…. Control Magnesium Phosphate HEUCOPHOS® SRPP Cr-free pre-treated 6 .

Control Strontium Chromate HEUCOSIL CTF Cr-free pre-treated HEUCOSIL CTF 816h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: Solvent borne 2-part epoxy / Polyamide primer DFT: 60 microns Substrate:  C old rolled steel panels ST 1205 Competition zinc-free Control HEUCOSIL CTF pigment 7 . etc. PVDF Topcoat DFT: Primer: 6-8 microns Top Coat: 20-24 microns Substrate: Hot dipped galvanized steel.) Paint Ca– HEUCOSIL CTF is a highly effective zinc-free > C ontrolled Anticorrosive based on a calcium modified film Steel release silica gel. H Ca2+ H > Maintains > Formation of a passive layer (barrier) Steel film integrity > Adsorption of corrosion stimulators HEUCOSIL CTF 2000h Salt Spray (ASTM B 117-11) DIN EN ISO 9227: 2012-09 Primer: High molecular polyester coil primer.Zinc-free Anticorrosives Calcium Modified Silica Pigment Calcium Modified Silica Pigment H + (Na+.

Our product specifications. Our standard specification is then valid if no specification has been agreed upon between the customer and ourselves. In addition to that.. · 2nd Floor.heubachcolor. Ltd.de 03/2015 . PA 19030 · USA · Tel 1-800-HEUBACH · Fax 1-215-736-2249 Asia: Heubach Colour Pvt. As their use lies beyond our knowledge and control.® = Registered trademark of Heubach GmbH. Ltd · Room 11-1-302. They are non-binding and cannot be taken as a guarantee. application information and any other information in this document is based on our current state of knowledge at the Revision Date mentioned below. 168 Jian Ding Road. the legal rights of third parties must always be considered. Da Shi Jie Wu Jin Cheng. Landmark-Building · Race Course Circle · Baroda 390 007 · India · Tel 91-265-2343-310 · Fax 91-265-2341-682    Hangzhou Heubach Pigment Co. www.de Europe: Heubach GmbH · Heubachstraße 7 · 38685 Langelsheim · Germany · Tel 49-5326-52-0 · Fax 49-5326-52-213 USA: Heucotech Ltd. · 99 Newbold Road · Fairless Hills. we cannot accept any liability relating to the use of our products in particular applications. Hangzhou 310021 · China · Tel 86-573-87634106 · Fax 86-573-87967925 E-Mail: sales@heubachcolor. The specification agreed between the customer and ourselves is the basis upon which our general sales and delivery conditions are set and is the deciding factor concerning any liabilities. The processing company must establish the suitability of individual products itself.