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ABC CLASSES FOR IIT-JEE


ALDEHYDES AND KETONES
D.P.P. - 3

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2. Identify A, and B in the following.

3. An organic compound A on treatment with ethyl alcohol gives a carboxylic acid B and compound
C. Hydrolysis of C under acidic conditions gives B and D. Oxidation of D with KMnO4 also gives
B. The compound B on heating with Ca(OH)2 ives E(C3H6O). E does not give Tollen’s Test and does
not reduce Fehling soln but forms a 2, 4 – di netrophenyl phdrazone. Identify A, B, C, D and E.
4. An organic acid (A) on heating with AlPO4 at 7000C forms (B). compound (B) also reacts with (A)
to give (C). compound (C) on reaction with 1, 3, 5 – trimethyl benzene in presence of AlCl3 gives a
ketone (D) and CH3COOH. (D) on treatment with Na(Hg)/HCl gives an aromatic hydrocarbon (E).
Give structures of (A) to (E) with proper reasoning.
5. State whether statement is true or false and Explain;
The reaction CH3COOC2H5 + H2O → CH3COOH + C2H5OH is slow in beginning but fastens
subsequently.
6. State whether statement is true or false and Explain;
Absolute ethyl alcohol can be obtained by simple fractional distillation of a mixture of alcohol and
water.
7. Effect the following conversion.

(a) (b)

8. Predict the products in following reactions.

9. Identify the products.

ABC CLASSES 126,2nd Floor , Kingsway Campus , Delhi-11009,Ph:011-


47041845, www.abcclasses.in
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10. Identify a to H in the following Mg2C3 + H2O → A (gas)

ABC CLASSES 126,2nd Floor , Kingsway Campus , Delhi-11009,Ph:011-


47041845, www.abcclasses.in